Exchange equilibria of carboxylate-terminated ligands at PbS nanocrystal surfaces

Kessler, Melody L.; Starr, Hannah E.; Knauf, Robin R.; Rountree, Kelley J.; Dempsey, Jillian L.

doi:10.1039/c8cp04275f

Exchange equilibria of carboxylate-terminated ligands at PbS nanocrystal surfaces

Journal Article · 01 January 2018 · Physical Chemistry Chemical Physics. PCCP (Print)

DOI:https://doi.org/10.1039/c8cp04275f· OSTI ID:1540021

^[1]; Starr, Hannah E. ^[1]; Knauf, Robin R. ^[1]; ^[1]; ^[1]

Department of Chemistry; University of North Carolina; Chapel Hill; USA

Exchange equilibria between carboxylic acids are quantified and ligand displacement mechanisms are probed on PbS nanocrystals synthesizedviatwo different methods.

Research Organization:: Univ. of North Carolina, Chapel Hill, NC (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0001011

OSTI ID:: 1540021

Journal Information:: Physical Chemistry Chemical Physics. PCCP (Print), Vol. 20, Issue 36; ISSN 1463-9076

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (33)

Colloidal PbS Quantum Dot Solar Cells with High Fill Factor Zhao, Ni; Osedach, Tim P.; Chang, Liang-Yi ACS Nano, Vol. 4, Issue 7 https://doi.org/10.1021/nn100129j	journal	June 2010
Gains and Losses in PbS Quantum Dot Solar Cells with Submicron Periodic Grating Structures Hara, Yukihiro; Gadisa, Abay; Fu, Yulan The Journal of Physical Chemistry C, Vol. 120, Issue 15 https://doi.org/10.1021/acs.jpcc.6b01498	journal	April 2016
Colloidal Quantum Dot Solar Cells Carey, Graham H.; Abdelhady, Ahmed L.; Ning, Zhijun Chemical Reviews, Vol. 115, Issue 23 https://doi.org/10.1021/acs.chemrev.5b00063	journal	June 2015
Semiconductor Quantum Dots for Bioimaging and Biodiagnostic Applications Kairdolf, Brad A.; Smith, Andrew M.; Stokes, Todd H. Annual Review of Analytical Chemistry, Vol. 6, Issue 1 https://doi.org/10.1146/annurev-anchem-060908-155136	journal	June 2013
Colloidal nanocrystal synthesis and the organic–inorganic interface Yin, Yadong; Alivisatos, A. Paul Nature, Vol. 437, Issue 7059, p. 664-670 https://doi.org/10.1038/nature04165	journal	September 2005
Versatile PbS Quantum Dot Ligand Exchange Systems in the Presence of Pb-Thiolates Shestha, Aabhash; Yin, Yanting; Andersson, Gunther G. Small, Vol. 13, Issue 5 https://doi.org/10.1002/smll.201602956	journal	November 2016
Colloidally Prepared 3-Mercaptopropionic Acid Capped Lead Sulfide Quantum Dots Reinhart, Chase C.; Johansson, Erik Chemistry of Materials, Vol. 27, Issue 21 https://doi.org/10.1021/acs.chemmater.5b02786	journal	October 2015
Near-Quantitative Yield for Transfer of Near-Infrared Excitons within Solution-Phase Assemblies of PbS Quantum Dots Lee, Ki-Ryong; Bettis Homan, Stephanie; Kodaimati, Mohamad The Journal of Physical Chemistry C, Vol. 120, Issue 39 https://doi.org/10.1021/acs.jpcc.6b06880	journal	September 2016
“Darker-than-Black” PbS Quantum Dots: Enhancing Optical Absorption of Colloidal Semiconductor Nanocrystals via Short Conjugated Ligands Giansante, Carlo; Infante, Ivan; Fabiano, Eduardo Journal of the American Chemical Society, Vol. 137, Issue 5 https://doi.org/10.1021/ja510739q	journal	January 2015
Fast Energy Transfer in CdSe Quantum Dot Layered Structures: Controlling Coupling with Covalent-Bond Organic Linkers Cohen, Eyal; Komm, Pavel; Rosenthal-Strauss, Noa The Journal of Physical Chemistry C, Vol. 122, Issue 10 https://doi.org/10.1021/acs.jpcc.7b11799	journal	February 2018
Soluble, Chloride-Terminated CdSe Nanocrystals: Ligand Exchange Monitored by ¹ H and ³¹ P NMR Spectroscopy Anderson, Nicholas C.; Owen, Jonathan S. Chemistry of Materials, Vol. 25, Issue 1 https://doi.org/10.1021/cm303219a	journal	December 2012
Short-Chain Alcohols Strip X-Type Ligands and Quench the Luminescence of PbSe and CdSe Quantum Dots, Acetonitrile Does Not Hassinen, Antti; Moreels, Iwan; De Nolf, Kim Journal of the American Chemical Society, Vol. 134, Issue 51 https://doi.org/10.1021/ja308861d	journal	December 2012
Binding of Phosphonic Acids to CdSe Quantum Dots: A Solution NMR Study Gomes, Raquel; Hassinen, Antti; Szczygiel, Agnieszka The Journal of Physical Chemistry Letters, Vol. 2, Issue 3 https://doi.org/10.1021/jz1016729	journal	January 2011
Ligand Exchange and the Stoichiometry of Metal Chalcogenide Nanocrystals: Spectroscopic Observation of Facile Metal-Carboxylate Displacement and Binding Anderson, Nicholas C.; Hendricks, Mark P.; Choi, Joshua J. Journal of the American Chemical Society, Vol. 135, Issue 49, p. 18536-18548 https://doi.org/10.1021/ja4086758	journal	November 2013
Ligand Displacement Exposes Binding Site Heterogeneity on CdSe Nanocrystal Surfaces Drijvers, Emile; De Roo, Jonathan; Martins, José C. Chemistry of Materials, Vol. 30, Issue 3 https://doi.org/10.1021/acs.chemmater.7b05362	journal	January 2018
Insights into the Structural Complexity of Colloidal CdSe Nanocrystal Surfaces: Correlating the Efficiency of Nonradiative Excited-State Processes to Specific Defects Saniepay, Mersedeh; Mi, Chenjia; Liu, Zhihui Journal of the American Chemical Society, Vol. 140, Issue 5 https://doi.org/10.1021/jacs.7b10649	journal	January 2018
In situ spectroscopic characterization of a solution-phase X-type ligand exchange at colloidal lead sulphide quantum dot surfaces Kroupa, D. M.; Anderson, N. C.; Castaneda, C. V. Chemical Communications, Vol. 52, Issue 96 https://doi.org/10.1039/C6CC08114B	journal	January 2016
Quantifying Ligand Exchange Reactions at CdSe Nanocrystal Surfaces Knauf, Robin R.; Lennox, J. Christian; Dempsey, Jillian L. Chemistry of Materials, Vol. 28, Issue 13 https://doi.org/10.1021/acs.chemmater.6b01827	journal	June 2016
Binding and Packing in Two-Component Colloidal Quantum Dot Ligand Shells: Linear versus Branched Carboxylates De Nolf, Kim; Cosseddu, Salvatore M.; Jasieniak, Jacek J. Journal of the American Chemical Society, Vol. 139, Issue 9 https://doi.org/10.1021/jacs.6b11328	journal	February 2017
A tunable library of substituted thiourea precursors to metal sulfide nanocrystals Hendricks, M. P.; Campos, M. P.; Cleveland, G. T. Science, Vol. 348, Issue 6240 https://doi.org/10.1126/science.aaa2951	journal	June 2015
Size-Dependent Optical Properties of Colloidal PbS Quantum Dots Moreels, Iwan; Lambert, Karel; Smeets, Dries ACS Nano, Vol. 3, Issue 10 https://doi.org/10.1021/nn900863a	journal	September 2009
Colloidal PbS Nanocrystals with Size-Tunable Near-Infrared Emission: Observation of Post-Synthesis Self-Narrowing of the Particle Size Distribution Hines, M. A.; Scholes, G. D. Advanced Materials, Vol. 15, Issue 21, p. 1844-1849 https://doi.org/10.1002/adma.200305395	journal	November 2003
Utilizing Self-Exchange To Address the Binding of Carboxylic Acid Ligands to CdSe Quantum Dots Fritzinger, Bernd; Capek, Richard K.; Lambert, Karel Journal of the American Chemical Society, Vol. 132, Issue 29 https://doi.org/10.1021/ja104351q	journal	July 2010
A Solution NMR Toolbox for Characterizing the Surface Chemistry of Colloidal Nanocrystals Hens, Zeger; Martins, José C. Chemistry of Materials, Vol. 25, Issue 8 https://doi.org/10.1021/cm303361s	journal	February 2013
Control of the Redox Activity of PbS Quantum Dots by Tuning Electrostatic Interactions at the Quantum Dot/Solvent Interface He, Chen; Weinberg, David J.; Nepomnyashchii, Alexander B. Journal of the American Chemical Society, Vol. 138, Issue 28 https://doi.org/10.1021/jacs.6b03970	journal	July 2016
Composition and Permeability of Oleate Adlayers of CdS Quantum Dots upon Dilution to Photoluminescence-Relevant Concentrations Nepomnyashchii, Alexander B.; Harris, Rachel D.; Weiss, Emily A. Analytical Chemistry, Vol. 88, Issue 6 https://doi.org/10.1021/acs.analchem.5b04786	journal	March 2016
Tuning colloidal quantum dot band edge positions through solution-phase surface chemistry modification Kroupa, Daniel M.; Vörös, Márton; Brawand, Nicholas P. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15257	journal	May 2017
Highly Monodispersed PbS Quantum Dots for Outstanding Cascaded-Junction Solar Cells Hou, Bo; Cho, Yuljae; Kim, Byung Sung ACS Energy Letters, Vol. 1, Issue 4 https://doi.org/10.1021/acsenergylett.6b00294	journal	September 2016
Revisiting the Valence and Conduction Band Size Dependence of PbS Quantum Dot Thin Films Miller, Elisa M.; Kroupa, Daniel M.; Zhang, Jianbing ACS Nano, Vol. 10, Issue 3 https://doi.org/10.1021/acsnano.5b06833	journal	February 2016
Linking surface chemistry to optical properties of semiconductor nanocrystals Krause, Michael M.; Kambhampati, Patanjali Physical Chemistry Chemical Physics, Vol. 17, Issue 29 https://doi.org/10.1039/C5CP02173A	journal	January 2015
A Molecule to Detect and Perturb the Confinement of Charge Carriers in Quantum Dots Frederick, Matthew T.; Amin, Victor A.; Cass, Laura C. Nano Letters, Vol. 11, Issue 12 https://doi.org/10.1021/nl203222m	journal	December 2011
Hydroxylation of the surface of PbS nanocrystals passivated with oleic acid Zherebetskyy, D.; Scheele, M.; Zhang, Y. Science, Vol. 344, Issue 6190 https://doi.org/10.1126/science.1252727	journal	May 2014
On the Origin of Surface Traps in Colloidal II–VI Semiconductor Nanocrystals Houtepen, Arjan J.; Hens, Zeger; Owen, Jonathan S. Chemistry of Materials, Vol. 29, Issue 2 https://doi.org/10.1021/acs.chemmater.6b04648	journal	January 2017

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