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Thermal stability of iron–sulfur clusters

Journal Article · · Physical Chemistry Chemical Physics. PCCP (Print)
DOI:https://doi.org/10.1039/c8cp00515j· OSTI ID:1539998
 [1];  [2];  [3];  [2];  [4];  [4]
  1. Institute of Surface Chemistry and Catalysis; University of Ulm; 89069 Ulm; Germany; School of Physics
  2. Department of Basic Science; School of Arts and Sciences; The University of Tokyo; Meguro; Japan
  3. Institute of Surface Chemistry and Catalysis; University of Ulm; 89069 Ulm; Germany
  4. School of Physics; Georgia Institute of Technology; Atlanta; USA
+ Show Author Affiliations

FexSy+clusters thermally decomposeviaa complex fragmentation mechanism with the preferred formation of stoichiometric FexSx+.

Research Organization:
Georgia Institute of Technology, Atlanta, GA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
FG05-86ER45234
OSTI ID:
1539998
Journal Information:
Physical Chemistry Chemical Physics. PCCP (Print), Vol. 20, Issue 11; ISSN 1463-9076
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (62)

Iron-Sulfur Clusters: Nature's Modular, Multipurpose Structures journal August 1997
Iron-sulfur proteins: ancient structures, still full of surprises journal February 2000
Nitrogenase MoFe-Protein at 1.16 A Resolution: A Central Ligand in the FeMo-Cofactor journal September 2002
Investigating and Exploiting the Electrocatalytic Properties of Hydrogenases journal October 2007
Activation and Inactivation of Hydrogenase Function and the Catalytic Cycle:  Spectroelectrochemical Studies journal October 2007
Dithiomethylether as a Ligand in the Hydrogenase H-Cluster journal April 2008
Gas phase metal cluster model systems for heterogeneous catalysis journal January 2012
Gas-Phase Catalysis by Atomic and Cluster Metal Ions: The Ultimate Single-Site Catalysts journal March 2005
Interaction of Iron–Sulfur Clusters with N 2 : Biomimetic Systems in the Gas Phase journal June 2016
A theoretical investigation on geometry and electronic structure of small FemSn nanoclusters (1⩽m,n⩽4) journal December 2012
Structural, Electronic, and Magnetic Properties of Iron Disulfide Fe n S 2 0/± ( n = 1–6) Clusters journal May 2017
Structure and thermochemistry of Fe 2 S 2 −/0/+ gas phase clusters and their fragments. B3LYP calculations journal January 2002
Redox Properties of the Diatomic Bare Iron Chalcogenides FeO and FeS in the Gas Phase journal October 1996
Low-energy spectrum of iron–sulfur clusters directly from many-particle quantum mechanics journal August 2014
Electronic, magnetic and structural properties of neutral, cationic and anionic Fe 2 S 2 , Fe 3 S 4 and Fe 4 S 4 clusters journal July 2010
The electronic states of Fe2S2−/0/+/2+ journal January 2002
A CASSCF/ACPF study of spectroscopic properties of FeS and FeS− and the photoelectron spectrum of FeS− journal September 1998
Probing the structural, electronic and magnetic properties of multicenter Fe2S2 0/−, Fe3S4 0/− and Fe4S4 0/− clusters journal December 2012
Photoelectron spectroscopy of iron–sulfur cluster anions journal March 1996
Properties of iron sulfide, hydrosulfide, and mixed sulfide/hydrosulfide cluster anions through photoelectron spectroscopy and density functional theory calculations journal October 2016
Study on iron–sulfur cluster in gas phase: electronic structure and reactivity journal December 1997
Photoelectron Spectroscopy and Density Functional Theory Studies of Iron Sulfur (FeS) m – ( m = 2–8) Cluster Anions: Coexisting Multiple Spin States journal September 2017
Thermochemistry of small cationic iron–sulfur clusters journal December 2002
On the Structural Dichotomy of Cationic, Anionic, and Neutral FeS 2 journal July 1999
A gas-phase study of FeSn+ (n = 1-6) journal January 1989
Gas-phase reactions of MS+ ions (M = Fe, Co, Ni) with alkanes. An FTMS study journal October 1986
The production and photodissociation of iron–sulfur cluster ions journal August 1993
Formation and Reactivity of Gaseous Iron-Sulfur Clusters journal January 2004
Formaldehyde and methanol formation from reaction of carbon monoxide and hydrogen on neutral Fe2S2 clusters in the gas phase journal January 2013
Methane to Methanethiol Conversion by FeS + . A Combined Experimental and Theoretical Study † journal March 2001
Tuning the oxidative power of free iron–sulfur clusters journal January 2017
Hydrodesulfurization of FeS+:  Predominance of Kinetic over Thermodynamic Control journal July 1999
Reaction of Fe2S2+ with C2H2 studied with a radiofrequency ion trap/time-of-flight mass spectrometer journal September 1995
Dissociation energy for O2 release from gas-phase iron oxide clusters measured by temperature-programmed desorption experiments journal April 2015
Stable Stoichiometry of Gas-Phase Manganese Oxide Cluster Ions Revealed by Temperature-Programmed Desorption journal July 2015
Rhodium Oxide Cluster Ions Studied by Thermal Desorption Spectrometry journal January 2016
Stable Stoichiometry of Gas-Phase Cerium Oxide Cluster Ions and Their Reactions with CO journal February 2015
Thermal desorption of oxygen from near-stoichiometric cationic vanadium oxide clusters journal May 2016
Demonstration of a pulsed photoelectron spectrometer on mass-selected negative ions: O−, O2−, and O4− journal November 1986
Collision Processes of Size-Selected Cluster Anions, (C6F6)n- (n = 1-5), with a Silicon Surface journal April 1995
Born-Oppenheimer molecular-dynamics simulations of finite systems: Structure and dynamics of ( H 2 O ) 2 journal July 1993
Efficient pseudopotentials for plane-wave calculations journal January 1991
Generalized Gradient Approximation Made Simple journal October 1996
The challenge of generating iron-sulfur clusters journal August 2015
Photoionization of High‐Temperature Vapors. II. Sulfur Molecular Species journal May 1968
Photoionization spectra and electronic structure of small iron clusters journal November 1984
Chemical probes of metal cluster ionization potentials journal March 1990
Reactivity of Oxygen Deficient Cerium Oxide Clusters with Small Gaseous Molecules journal May 2015
Release of Oxygen from Palladium Oxide Cluster Ions by Heat journal July 2015
Two-State Reactivity in Organometallic Gas-Phase Ion Chemistry journal September 1995
On the spin-forbiddeness of gas-phase ion–molecule reactions: a fruitful intersection of experimental and computational studies journal September 2004
Reactivity Trends in the Oxidation of CO by Anionic Transition Metal Oxide Clusters journal November 2009
Release of Oxygen from Copper Oxide Cluster Ions by Heat and by Reaction with NO journal January 2015
Thermally and Chemically Stable Mixed Valence Copper Oxide Cluster Ions Revealed by Post Heating journal September 2013
Collision-induced dissociation studies of FemOn+ : Bond energies in small iron oxide cluster cations, FemOn+ (m=1–3, n=1–6) journal October 2009
Guided ion-beam studies of the reactions of Fen+ (n=1–18) with CO2: Iron cluster oxide bond energies journal October 1997
Experimental and Theoretical Study of the Structure and Reactivity of Fe m O n + ( m = 1, 2; n = 1−5) with CO journal December 2007
Isomer Separation of Iron Oxide Cluster Cations by Ion Mobility Mass Spectrometry journal May 2014
Ground State Structures of Fe 2 O 4−6 + Clusters Probed by Reactions with N 2 journal May 2009
Experimental and Theoretical Study of the Structure and Reactivity of Fe 1 - 2 O ≤ 6 - Clusters with CO journal May 2007
Influence of charge state on the reaction of FeO 3 + / - with carbon monoxide journal February 2007
Formation, detection, and stability studies of neutral vanadium sulfide clusters journal May 2007

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