Pressure-induced anomalies and structural instability in compressed β-Sb 2 O 3

Zou, Yongtao; Zhang, Wei; Li, Xuefei; Ma, Maining; Li, Xing’ao; Wang, Chun-Hai; He, Bin; Wang, Shanmin; Chen, Zhiqiang; Zhao, Yusheng; Li, Baosheng

doi:10.1039/c8cp00084k

Title: Pressure-induced anomalies and structural instability in compressed β-Sb ₂ O ₃

Journal Article · Mon Jan 01 00:00:00 EST 2018 · Physical Chemistry Chemical Physics. PCCP (Print)

DOI:https://doi.org/10.1039/c8cp00084k· OSTI ID:1539994

^[1]; Zhang, Wei ^[2]; Li, Xuefei ^[3]; Ma, Maining ^[4]; Li, Xing’ao ^[5]; Wang, Chun-Hai ^[1]; He, Bin ^[1]; Wang, Shanmin ^[1]; Chen, Zhiqiang ^[6]; Zhao, Yusheng ^[1]; Li, Baosheng ^[6]

Academy for Advanced Interdisciplinary Studies; and Department of Physics; Southern University of Science and Technology; Shenzhen; China
School of Science; Southwest University of Science and Technology; Mianyang; China
Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education; Jilin Normal University; Siping 136000; China
Key Laboratory of Computational Geodynamics of Chinese Academy of Sciences; University of Chinese Academy of Sciences; Beijing 100049; China
School of Science; Nanjing University of Posts and Telecommunications; Nanjing 210046; China
Mineral Physics Institute; State University of New York; Stony Brook; N.Y. 11794; USA

Here, we have discovered a new high-pressure phase of Sb₂O₃, and reported pressure-induced anomalies in orthorhombic β-Sb₂O₃(valentinite) by the combination of synchrotronin situX-ray diffraction and first-principles theoretical calculations up to 40.5 GPa.

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Research Organization:: State Univ. of New York (SUNY), Albany, NY (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

DOE Contract Number:: NA0002907

OSTI ID:: 1539994

Journal Information:: Physical Chemistry Chemical Physics. PCCP (Print), Vol. 20, Issue 16; ISSN 1463-9076

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (19)

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