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Title: Superprotonic conduction through one-dimensional ordered alkali metal ion chains in a lanthanide-organic framework

Abstract

An ultrahigh proton conductivity of 2.91 × 10 −2S cm −1and an ultralow activation energy of 0.10 eV were observed in an anionic lanthanide-organic framework. Both values approach the records for proton-conducting MOF materials.

Authors:
 [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1]; ORCiD logo [1]
  1. State Key Laboratory of Radiation Medicine and Protection; School for Radiological and Interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions; Soochow University; Suzhou 215123; China
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Actinide Science & Technology (CAST); Florida State Univ., Tallahassee, FL (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1539975
DOE Contract Number:  
SC0016568
Resource Type:
Journal Article
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 54; Journal Issue: 35; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
Chemistry

Citation Formats

Wang, Xia, Wang, Yanlong, Silver, Mark A., Gui, Daxiang, Bai, Zhuanling, Wang, Yaxing, Liu, Wei, Chen, Lanhua, Diwu, Juan, Chai, Zhifang, and Wang, Shuao. Superprotonic conduction through one-dimensional ordered alkali metal ion chains in a lanthanide-organic framework. United States: N. p., 2018. Web. doi:10.1039/c8cc00572a.
Wang, Xia, Wang, Yanlong, Silver, Mark A., Gui, Daxiang, Bai, Zhuanling, Wang, Yaxing, Liu, Wei, Chen, Lanhua, Diwu, Juan, Chai, Zhifang, & Wang, Shuao. Superprotonic conduction through one-dimensional ordered alkali metal ion chains in a lanthanide-organic framework. United States. doi:10.1039/c8cc00572a.
Wang, Xia, Wang, Yanlong, Silver, Mark A., Gui, Daxiang, Bai, Zhuanling, Wang, Yaxing, Liu, Wei, Chen, Lanhua, Diwu, Juan, Chai, Zhifang, and Wang, Shuao. Mon . "Superprotonic conduction through one-dimensional ordered alkali metal ion chains in a lanthanide-organic framework". United States. doi:10.1039/c8cc00572a.
@article{osti_1539975,
title = {Superprotonic conduction through one-dimensional ordered alkali metal ion chains in a lanthanide-organic framework},
author = {Wang, Xia and Wang, Yanlong and Silver, Mark A. and Gui, Daxiang and Bai, Zhuanling and Wang, Yaxing and Liu, Wei and Chen, Lanhua and Diwu, Juan and Chai, Zhifang and Wang, Shuao},
abstractNote = {An ultrahigh proton conductivity of 2.91 × 10−2S cm−1and an ultralow activation energy of 0.10 eV were observed in an anionic lanthanide-organic framework. Both values approach the records for proton-conducting MOF materials.},
doi = {10.1039/c8cc00572a},
journal = {ChemComm},
issn = {1359-7345},
number = 35,
volume = 54,
place = {United States},
year = {2018},
month = {1}
}

Works referenced in this record:

Single-crystal structure validation with the program PLATON
journal, January 2003