Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Recent progress towards high performance of tin chalcogenide thermoelectric materials

Journal Article · · Journal of Materials Chemistry. A
DOI:https://doi.org/10.1039/c7ta09941j· OSTI ID:1539967
 [1];  [1];  [2];  [1]
  1. Department of Materials Science and Engineering; Harbin Institute of Technology; Shenzhen; P. R. China
  2. Department of Physics; TcSUH; University of Houston; Houston; USA

This review summarizes the recent advances in tin chalcogenide (SnTe, SnSe, and SnS) bulk alloys, provides the possible directions for further improving the thermoelectric properties and elucidates the challenges for optimization and application of tin chalcogenides.

Research Organization:
Univ. of Houston, TX (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0010831
OSTI ID:
1539967
Journal Information:
Journal of Materials Chemistry. A, Vol. 6, Issue 6; ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (174)

CRC Handbook of Thermoelectrics January 2017
Quantum Dot Superlattice Thermoelectric Materials and Devices September 2002
New Directions for Low-Dimensional Thermoelectric Materials April 2007
Complex thermoelectric materials February 2008
Cooling, Heating, Generating Power, and Recovering Waste Heat with Thermoelectric Systems September 2008
Heavy Doping and Band Engineering by Potassium to Improve the Thermoelectric Figure of Merit in p-Type PbTe, PbSe, and PbTe 1– y Se y June 2012
New trends, strategies and opportunities in thermoelectric materials: A perspective June 2017
Nanostructures in high-performance (GeTe) x (AgSbTe 2 ) 100− x thermoelectric materials May 2008
Nanostructured AgPb m SbTe m +2 System Bulk Materials with Enhanced Thermoelectric Performance April 2008
Combining alloy scattering of phonons and resonant electronic levels to reach a high thermoelectric figure of merit in PbTeSe and PbTeS alloys January 2011
Multiple-Filled Skutterudites: High Thermoelectric Figure of Merit through Separately Optimizing Electrical and Thermal Transports May 2011
High Performance Na-doped PbTe–PbS Thermoelectric Materials: Electronic Density of States Modification and Shape-Controlled Nanostructures October 2011
High Thermoelectric Figure of Merit in PbTe Alloys Demonstrated in PbTe-CdTe April 2012
Realizing high figure of merit in heavy-band p-type half-Heusler thermoelectric materials September 2015
High-performance bulk thermoelectrics with all-scale hierarchical architectures September 2012
Ultrahigh Thermoelectric Performance in Mosaic Crystals May 2015
Superior thermoelectric performance in PbTe–PbS pseudo-binary: extremely low thermal conductivity and modulated carrier concentration January 2015
Nanostructured YbAgCu 4 for Potentially Cryogenic Thermoelectric Cooling August 2014
CsBi4Te6: A High-Performance Thermoelectric Material for Low-Temperature Applications February 2000
High thermoelectric performance of MgAgSb-based materials July 2014
High Performance α-MgAgSb Thermoelectric Materials for Low Temperature Power Generation January 2015
BiCuSeO oxyselenides: new promising thermoelectric materials January 2014
High figures of merit and natural nanostructures in Mg2Si0.4Sn0.6 based thermoelectric materials September 2008
Thermoelectric properties of highly efficient Bi-doped Mg 2 Si 1− x−y Sn x Ge y materials September 2014
Discovery of high-performance low-cost n-type Mg3Sb2-based thermoelectric materials with multi-valley conduction bands January 2017
Recent progress and future challenges on thermoelectric Zintl materials June 2017
On the Design of High-Efficiency Thermoelectric Clathrates through a Systematic Cross-Substitution of Framework Elements March 2010
Disordered zinc in Zn4Sb3 with phonon-glass and electron-crystal thermoelectric properties June 2004
Peierls distortion as a route to high thermoelectric performance in In4Se3-δ crystals June 2009
Improvement of Thermoelectric Properties of In 4 Se 3 Bulk Materials with Cu Nanoinclusions August 2013
Chemical Potential Tuning and Enhancement of Thermoelectric Properties in Indium Selenides March 2015
Copper ion liquid-like thermoelectrics March 2012
Chalcopyrite CuGaTe2: A High-Efficiency Bulk Thermoelectric Material June 2012
Thermoelectric properties of Ag-doped Cu2Se and Cu2Te January 2013
White Polymer Light-Emitting Devices for Solid-State Lighting: Materials, Devices, and Recent Progress March 2014
Ultrahigh thermoelectric performance in Cu 2−y Se 0.5 S 0.5 liquid-like materials June 2017
Enhanced stability and thermoelectric figure-of-merit in copper selenide by lithium doping June 2017
Yb 14 MnSb 11 :  New High Efficiency Thermoelectric Material for Power Generation April 2006
Band engineering of high performance p-type FeNbSb based half-Heusler thermoelectric materials for figure of merit zT > 1 January 2015
Enhancing the Figure of Merit of Heavy-Band Thermoelectric Materials Through Hierarchical Phonon Scattering March 2016
Short and long range order of Half-Heusler phases in (Ti,Zr,Hf)CoSb thermoelectric compounds August 2016
Improved thermoelectric performance of n-type half-Heusler MCo1-xNixSb (M = Hf, Zr) June 2017
Effects of partial substitution of Ni by Pd on the thermoelectric properties of ZrNiSn-based half-Heusler compounds December 2001
Effect of Ti substitution on the thermoelectric properties of (Zr,Hf)NiSn half-Heusler compounds February 2005
Promoting SnTe as an Eco-Friendly Solution for p-PbTe Thermoelectric via Band Convergence and Interstitial Defects March 2017
Ultralow thermal conductivity and high thermoelectric figure of merit in SnSe crystals April 2014
Tuning the shape and thermoelectric property of PbTe nanocrystals by bismuth doping January 2010
Resonant levels in bulk thermoelectric semiconductors January 2012
Enhancement of thermoelectric figure-of-merit by resonant states of aluminium doping in lead selenide January 2012
High thermoelectric performance by resonant dopant indium in nanostructured SnTe July 2013
Convergence of electronic bands for high performance bulk thermoelectrics May 2011
Low Electron Scattering Potentials in High Performance Mg 2 Si 0.45 Sn 0.55 Based Thermoelectric Solid Solutions with Band Convergence April 2013
High thermoelectric performance in Te-free (Bi,Sb) 2 Se 3 via structural transition induced band convergence and chemical bond softening January 2016
Point Defect Engineering of High-Performance Bismuth-Telluride-Based Thermoelectric Materials June 2014
High Performance Mg 2 (Si,Sn) Solid Solutions: a Point Defect Chemistry Approach to Enhancing Thermoelectric Properties April 2014
Interstitial Point Defect Scattering Contributing to High Thermoelectric Performance in SnTe May 2016
Effect of quantum-well structures on the thermoelectric figure of merit May 1993
High Thermoelectric Figure of Merit and Nanostructuring in Bulk p-type Na1−xPbmSbyTem+2 June 2006
High-Thermoelectric Performance of Nanostructured Bismuth Antimony Telluride Bulk Alloys May 2008
Spinodal Decomposition and Nucleation and Growth as a Means to Bulk Nanostructured Thermoelectrics:  Enhanced Performance in Pb 1- x Sn x Te−PbS August 2007
Anomalous Band Gap Evolution from Band Inversion in Pb 1− x Sn x Te Nanocrystals April 2009
Prospective Thermoelectric Materials: (AgSbTe2)100–x(SnTe)x Quaternary System (x = 80, 85, 90, and 95) August 2011
Lead-Free Thermoelectrics: High Figure of Merit in p-type AgSnmSbTem+2 December 2011
SnTe-AgSbTe2 Thermoelectric Alloys November 2011
Deviations from stoichiometry and electrical properties in SnTe January 1963
EVIDENCE THAT SnTe IS A SEMICONDUCTOR March 1964
Optimization of thermoelectric efficiency in SnTe: the case for the light band January 2014
Valence band structure of SnTe July 1968
Weak-Field Magnetoresistance and the Valence-Band Structure of SnTe March 1972
Transport properties of SnTe interpreted by means of a two valence band model August 1981
THERMOPOWER OF SnTe FROM BOLTZMANN TRANSPORT CALCULATIONS December 2010
Band Structure and Laser Action in Pb x Sn 1 − x Te June 1966
New Type of Negative Resistance in Barrier Tunneling June 1966
Anomalous Thermoelectric Power as Evidence for Two-Valence Bands in SnTe July 1963
Anharmonicity and atomic distribution of SnTe and PbTe thermoelectrics December 2014
Effect of Small Substitutions of Tin by Neodymium on Thermoelectric Properties of SnTe January 1967
High Thermoelectric Performance of p-Type SnTe via a Synergistic Band Engineering and Nanostructuring Approach May 2014
Mg Alloying in SnTe Facilitates Valence Band Convergence and Optimizes Thermoelectric Properties January 2015
Extraordinary role of Hg in enhancing the thermoelectric performance of p-type SnTe January 2015
Codoping in SnTe: Enhancement of Thermoelectric Performance through Synergy of Resonance Levels and Band Convergence April 2015
High Power Factor and Enhanced Thermoelectric Performance of SnTe-AgInTe 2 : Synergistic Effect of Resonance Level and Valence Band Convergence September 2016
Manipulating Band Convergence and Resonant State in Thermoelectric Material SnTe by Mn–In Codoping April 2017
Lead-free thermoelectrics: promising thermoelectric performance in p-type SnTe1−xSex system January 2014
SnTe–AgBiTe 2 as an efficient thermoelectric material with low thermal conductivity January 2014
Synergistically optimized electrical and thermal transport properties of SnTe via alloying high-solubility MnTe January 2015
Band Degeneracy, Low Thermal Conductivity, and High Thermoelectric Figure of Merit in SnTe–CaTe Alloys December 2015
Ultralow Lattice Thermal Conductivity and Enhanced Thermoelectric Performance in SnTe:Ga Materials December 2016
High Thermoelectric Performance of Co-Doped Tin Telluride Due to Synergistic Effect of Magnesium and Indium March 2017
Interstitial Defects Improving Thermoelectric SnTe in Addition to Band Convergence February 2017
Thermoelectric Performance of Se/Cd Codoped SnTe via Microwave Solvothermal Method June 2017
Enhancement of Thermoelectric Efficiency in PbTe by Distortion of the Electronic Density of States July 2008
Resonant level formed by tin in Bi 2 Te 3 and the enhancement of room-temperature thermoelectric power December 2009
Thermoelectric and spin-caloritronic coolers: from basics to recent developments March 2016
Band and scattering tuning for high performance thermoelectric Sn1−xMnxTe alloys December 2015
Valence Band Modification and High Thermoelectric Performance in SnTe Heavily Alloyed with MnTe August 2015
Enhanced Thermoelectric Properties in the Counter-Doped SnTe System with Strained Endotaxial SrTe February 2016
Soft phonon modes driven reduced thermal conductivity in self-compensated Sn 1.03 Te with Mn doping September 2016
Lead-free SnTe-based thermoelectrics: enhancement of thermoelectric performance by doping with Gd/Ag January 2016
Lower limit to the thermal conductivity of disordered crystals September 1992
Large-Scale Surfactant-Free Synthesis of p-Type SnTe Nanoparticles for Thermoelectric Applications February 2017
Enhanced thermoelectric properties of Yb doped SnTe January 2017
Investigation of SnSe, SnSe2, and Sn2Se3 alloys for phase change memory applications April 2008
Characteristics of SnSe and SnSe2 thin films grown onto polycrystalline SnO2-coated glass substrates December 2010
The effect of Te doping on the electronic structure and thermoelectric properties of SnSe November 2012
Refinement of the structures of GeS, GeSe, SnS and SnSe January 1978
Neutron diffraction study of the structural phase transition in SnS and SnSe January 1986
High-pressure Mössbauer study of SnSe March 1990
Ideal Strength and Deformation Mechanism in High-Efficiency Thermoelectric SnSe February 2017
Investigation of the Anisotropic Thermoelectric Properties of Oriented Polycrystalline SnSe June 2015
Orbitally driven giant phonon anharmonicity in SnSe October 2015
Phonon engineering through crystal chemistry January 2011
Intrinsically Minimal Thermal Conductivity in Cubic I−V−VI2 Semiconductors July 2008
The anharmonicity blacksmith October 2015
Manipulating the Combustion Wave during Self-Propagating Synthesis for High Thermoelectric Performance of Layered Oxychalcogenide Bi 1– x Pb x CuSeO June 2016
Hierarchical Chemical Bonds Contributing to the Intrinsically Low Thermal Conductivity in α-MgAgSb Thermoelectric Materials October 2016
Thinking Like a Chemist: Intuition in Thermoelectric Materials April 2016
Lone pair electrons minimize lattice thermal conductivity January 2013
The Thermal Conductivity of Nonmetallic Crystals January 1979
Thermal conductivity of germanium, silicon, and carbon nitrides December 2002
Origin of low thermal conductivity in SnSe September 2016
Materials selection guidelines for low thermal conductivity thermal barrier coatings January 2003
Direct observation of vast off-stoichiometric defects in single crystalline SnSe May 2017
Optimized Thermoelectric Properties of Sb-Doped Mg 2(1+ z ) Si 0.5– y Sn 0.5 Sb y through Adjustment of the Mg Content December 2011
Quasiparticle band structures and thermoelectric transport properties of p-type SnSe February 2015
Ultrahigh power factor and thermoelectric performance in hole-doped single-crystal SnSe November 2015
Single crystal growth of Sn 0.97 Ag 0.03 Se by a novel horizontal Bridgman method and its thermoelectric properties February 2017
Achieving ZT=2.2 with Bi-doped n-type SnSe single crystals December 2016
Broad temperature plateau for high ZTs in heavily doped p-type SnSe single crystals January 2016
Thermoelectric performance of SnS and SnS–SnSe solid solution January 2015
Thermoelectric transport properties of pristine and Na-doped SnSe 1−x Te x polycrystals January 2015
Thermoelectric transport properties of polycrystalline SnSe alloyed with PbSe January 2017
Thermoelectric properties of p-type polycrystalline SnSe doped with Ag January 2014
Studies on Thermoelectric Properties of n-type Polycrystalline SnSe 1- x S x by Iodine Doping April 2015
The thermoelectric performance of anisotropic SnSe doped with Na January 2016
Distinct Impact of Alkali-Ion Doping on Electrical Transport Properties of Thermoelectric p -Type Polycrystalline SnSe July 2016
Raising thermoelectric performance of n-type SnSe via Br doping and Pb alloying January 2016
Understanding of the Extremely Low Thermal Conductivity in High-Performance Polycrystalline SnSe through Potassium Doping August 2016
Studies on thermoelectric figure of merit of Na-doped p-type polycrystalline SnSe January 2016
Optimization of thermoelectric properties in n -type SnSe doped with BiCl 3 February 2016
The effect of doping on thermoelectric performance of p-type SnSe: Promising thermoelectric material May 2016
Thermoelectric Properties of Tl-Doped SnSe: A Hint of Phononic Structure March 2016
Boosting the Thermoelectric Performance of (Na,K)-Codoped Polycrystalline SnSe by Synergistic Tailoring of the Band Structure and Atomic-Scale Defect Phonon Scattering July 2017
Enhanced thermoelectric performance of p-type SnSe doped with Zn January 2017
Enhanced thermoelectric performance in p-type polycrystalline SnSe benefiting from texture modulation January 2016
High-temperature oxidation behavior of thermoelectric SnSe June 2016
SnSe: a remarkable new thermoelectric material January 2016
A Second Amorphous Layer Underneath Surface Oxide February 2017
Assessment of the thermoelectric performance of polycrystalline p-type SnSe May 2014
Enhancing the thermoelectric performance of SnSe 1−x Te x nanoplates through band engineering January 2017
Extremely Low Lattice Thermal Conductivity and Point Defect Scattering of Phonons in Ag-doped (SnSe) 1– x (SnS) x Compounds May 2017
Study on Thermoelectric Properties of Polycrystalline SnSe by Ge Doping March 2017
Enhancing p-Type Thermoelectric Performances of Polycrystalline SnSe via Tuning Phase Transition Temperature July 2017
Enhanced thermoelectric performance of SnSe doped with layered MoS 2 /graphene April 2017
Thermoelectric performance of polycrystalline Sn 1-x Cu x Se ( x  = 0–0.03) prepared by high pressure method October 2017
Texturing degree boosts thermoelectric performance of silver-doped polycrystalline SnSe August 2017
Structural phase transition of SnSe under uniaxial stress and hydrostatic pressure: an ab initio study March 2011
Pressure-driven semiconducting-semimetallic transition in SnSe January 2016
Enhanced power factor via the control of structural phase transition in SnSe May 2016
Lead-free tin chalcogenide thermoelectric materials January 2016
Electronic structure and thermoelectric properties of n - and p -type SnSe from first-principles calculations May 2015
First-principles study of anisotropic thermoelectric transport properties of IV-VI semiconductor compounds SnSe and SnS September 2015
Outstanding thermoelectric performances for both p- and n-type SnSe from first-principles study September 2015
Simplified chemical deposition technique for good quality SnS thin films February 1991
Photovoltaic structures using chemically deposited tin sulfide thin films February 2009
Photovoltaic properties of SnS based solar cells November 2006
Preparation and properties of zinc blende and orthorhombic SnS films by chemical bath deposition May 2011
Investigations on SnS October 1961
Electronic structure of SnS deduced from photoelectron spectra and band-structure calculations September 1992
First principles investigations of the thermoelectric behavior of tin sulfide October 2010
Temperature dependence of the electrical conductivity, Hall effect and thermoelectric power of SnS single crystals August 2005
Enhanced thermoelectric performance of layered SnS crystals: the synergetic effect of temperature and carrier concentration January 2015
Thermoelectric Properties of Sn-S Bulk Materials Prepared by Mechanical Alloying and Spark Plasma Sintering April 2014
Thermoelectrics with earth abundant elements: low thermal conductivity and high thermopower in doped SnS January 2014
Thermoelectric SnS and SnS-SnSe solid solutions prepared by mechanical alloying and spark plasma sintering: Anisotropic thermoelectric properties February 2017