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Title: Thermodynamic signatures and cluster properties of self-assembly in systems with competing interactions

Abstract

Colloidal clustering driven by isotropic competing interactions can resemble surfactant micellization or exhibit novel, non-pressure-affecting clustering, depending on conditions.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [1]
  1. Department of Chemical and Biological Engineering; Princeton University; Princeton; USA
  2. Institute of Physical Chemistry; Polish Academy of Sciences; 01-224 Warszawa; Poland
Publication Date:
Research Org.:
Princeton Univ., NJ (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1539961
DOE Contract Number:  
SC0002128
Resource Type:
Journal Article
Journal Name:
Soft Matter
Additional Journal Information:
Journal Volume: 13; Journal Issue: 44; Journal ID: ISSN 1744-683X
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
Chemistry; Materials Science; Physics; Polymer Science

Citation Formats

Santos, Andrew P., Pȩkalski, Jakub, and Panagiotopoulos, Athanassios Z. Thermodynamic signatures and cluster properties of self-assembly in systems with competing interactions. United States: N. p., 2017. Web. doi:10.1039/c7sm01721a.
Santos, Andrew P., Pȩkalski, Jakub, & Panagiotopoulos, Athanassios Z. Thermodynamic signatures and cluster properties of self-assembly in systems with competing interactions. United States. doi:10.1039/c7sm01721a.
Santos, Andrew P., Pȩkalski, Jakub, and Panagiotopoulos, Athanassios Z. Sun . "Thermodynamic signatures and cluster properties of self-assembly in systems with competing interactions". United States. doi:10.1039/c7sm01721a.
@article{osti_1539961,
title = {Thermodynamic signatures and cluster properties of self-assembly in systems with competing interactions},
author = {Santos, Andrew P. and Pȩkalski, Jakub and Panagiotopoulos, Athanassios Z.},
abstractNote = {Colloidal clustering driven by isotropic competing interactions can resemble surfactant micellization or exhibit novel, non-pressure-affecting clustering, depending on conditions.},
doi = {10.1039/c7sm01721a},
journal = {Soft Matter},
issn = {1744-683X},
number = 44,
volume = 13,
place = {United States},
year = {2017},
month = {1}
}

Works referenced in this record:

Self-Assembly at All Scales
journal, March 2002

  • Whitesides, George M.; Grzybowski, Bartosz
  • Science, Vol. 295, Issue 5564, p. 2418-2421
  • DOI: 10.1126/science.1070821

Colloids with valence and specific directional bonding
journal, October 2012


Anisotropic self-assembly of spherical polymer-grafted nanoparticles
journal, March 2009

  • Akcora, Pinar; Liu, Hongjun; Kumar, Sanat K.
  • Nature Materials, Vol. 8, Issue 4
  • DOI: 10.1038/nmat2404

Domain Shapes and Patterns: The Phenomenology of Modulated Phases
journal, January 1995


Compression of hard core–soft shell nanoparticles at liquid–liquid interfaces: influence of the shell thickness
journal, January 2017


Equilibrium cluster formation in concentrated protein solutions and colloids
journal, November 2004

  • Stradner, Anna; Sedgwick, Helen; Cardinaux, Frédéric
  • Nature, Vol. 432, Issue 7016
  • DOI: 10.1038/nature03109

Block Copolymers—Designer Soft Materials
journal, February 1999

  • Bates, Frank S.; Fredrickson, Glenn H.
  • Physics Today, Vol. 52, Issue 2
  • DOI: 10.1063/1.882522

Self-assembly of block copolymers
journal, June 1996


Determination of the critical micelle concentration in simulations of surfactant systems
journal, January 2016

  • Santos, Andrew P.; Panagiotopoulos, Athanassios Z.
  • The Journal of Chemical Physics, Vol. 144, Issue 4
  • DOI: 10.1063/1.4940687

Tiny changes in local order identify the cluster formation threshold in model fluids with competing interactions
journal, January 2017

  • Bomont, Jean-Marc; Costa, Dino; Bretonnet, Jean-Louis
  • Physical Chemistry Chemical Physics, Vol. 19, Issue 23
  • DOI: 10.1039/C7CP01811H

Equilibrium and non-equilibrium cluster phases in colloids with competing interactions
journal, January 2014

  • Mani, Ethayaraja; Lechner, Wolfgang; Kegel, Willem K.
  • Soft Matter, Vol. 10, Issue 25
  • DOI: 10.1039/C3SM53058B

Equilibrium Phase Behavior of a Continuous-Space Microphase Former
journal, February 2016


Colloidal systems with competing interactions: from an arrested repulsive cluster phase to a gel
journal, January 2009

  • Toledano, Juan Carlos Fernandez; Sciortino, Francesco; Zaccarelli, Emanuela
  • Soft Matter, Vol. 5, Issue 12
  • DOI: 10.1039/b818169a

Columnar and lamellar phases in attractive colloidal systems
journal, July 2006


Model colloidal fluid with competing interactions: Bulk and interfacial properties
journal, January 2007

  • Archer, A. J.; Pini, D.; Evans, R.
  • The Journal of Chemical Physics, Vol. 126, Issue 1
  • DOI: 10.1063/1.2405355

Observation of a microcrystalline gel in colloids with competing interactions
journal, January 2009

  • Zhang, Tian Hui; Groenewold, Jan; Kegel, Willem K.
  • Physical Chemistry Chemical Physics, Vol. 11, Issue 46
  • DOI: 10.1039/b917254h

Two-dimensional colloidal fluids exhibiting pattern formation
journal, December 2015

  • Chacko, Blesson; Chalmers, Christopher; Archer, Andrew J.
  • The Journal of Chemical Physics, Vol. 143, Issue 24
  • DOI: 10.1063/1.4937941

Periodic ordering of clusters and stripes in a two-dimensional lattice model. II. Results of Monte Carlo simulation
journal, April 2014

  • Almarza, N. G.; Pȩkalski, J.; Ciach, A.
  • The Journal of Chemical Physics, Vol. 140, Issue 16
  • DOI: 10.1063/1.4871901

Periodic ordering of clusters and stripes in a two-dimensional lattice model. I. Ground state, mean-field phase diagram and structure of the disordered phases
journal, March 2014

  • Pȩkalski, J.; Ciach, A.; Almarza, N. G.
  • The Journal of Chemical Physics, Vol. 140, Issue 11
  • DOI: 10.1063/1.4868001

Origin of similarity of phase diagrams in amphiphilic and colloidal systems with competing interactions
journal, January 2013

  • Ciach, A.; Pękalski, J.; Góźdź, W. T.
  • Soft Matter, Vol. 9, Issue 27
  • DOI: 10.1039/c3sm50668a

Periodic ordering of clusters in a one-dimensional lattice model
journal, April 2013

  • Pȩkalski, J.; Ciach, A.; Almarza, N. G.
  • The Journal of Chemical Physics, Vol. 138, Issue 14
  • DOI: 10.1063/1.4799264

Self-assembly of lipids in water. Exact results from a one-dimensional lattice model
journal, November 2014


Microphase separation in two-dimensional systems with competing interactions
journal, April 2006

  • Imperio, A.; Reatto, L.
  • The Journal of Chemical Physics, Vol. 124, Issue 16
  • DOI: 10.1063/1.2185618

Phase behaviour of polyoxyethylene surfactants with water. Mesophase structures and partial miscibility (cloud points)
journal, January 1983

  • Mitchell, D. John; Tiddy, Gordon J. T.; Waring, Loraine
  • Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 79, Issue 4
  • DOI: 10.1039/f19837900975

Phase Behavior and Microstructure in Binary Block Copolymer/Selective Solvent Systems:  Experiments and Theory
journal, February 1999

  • Svensson, Mårten; Alexandridis, Paschalis; Linse, Per
  • Macromolecules, Vol. 32, Issue 3
  • DOI: 10.1021/ma9812940

Phase Diagrams of Self-Assembled Mono-Tethered Nanospheres from Molecular Simulation and Comparison to Surfactants
journal, October 2005

  • Iacovella, Christopher R.; Horsch, Mark A.; Zhang, Zhenli
  • Langmuir, Vol. 21, Issue 21
  • DOI: 10.1021/la051035l

Phase Behavior of Binary Homopolymer/Diblock Blends:  Temperature and Chain Length Dependence
journal, February 1998

  • Janert, Philipp K.; Schick, M.
  • Macromolecules, Vol. 31, Issue 4
  • DOI: 10.1021/ma971093g

Discovering New Ordered Phases of Block Copolymers
journal, October 2000


Equilibrium cluster fluids: pair interactions via inverse design
journal, January 2015

  • Jadrich, R. B.; Bollinger, J. A.; Lindquist, B. A.
  • Soft Matter, Vol. 11, Issue 48
  • DOI: 10.1039/C5SM01832C

Interactions and design rules for assembly of porous colloidal mesophases
journal, January 2017

  • Lindquist, Beth A.; Dutta, Sayantan; Jadrich, Ryan B.
  • Soft Matter, Vol. 13, Issue 7
  • DOI: 10.1039/C6SM02718K

One-Dimensional Cluster Growth and Branching Gels in Colloidal Systems with Short-Range Depletion Attraction and Screened Electrostatic Repulsion
journal, November 2005

  • Sciortino, F.; Tartaglia, P.; Zaccarelli, E.
  • The Journal of Physical Chemistry B, Vol. 109, Issue 46
  • DOI: 10.1021/jp052683g

Structural and Dynamical Features of Multiple Metastable Glassy States in a Colloidal System with Competing Interactions
journal, April 2010


Low-Density Ordered Phase in Brownian Dipolar Colloidal Suspensions
journal, May 2009


Pattern Formation and Glassy Phase in the ϕ 4 Theory with a Screened Electrostatic Repulsion
journal, February 2006


Cluster formation in fluids with competing short-range and long-range interactions
journal, March 2014

  • Sweatman, Martin B.; Fartaria, Rui; Lue, Leo
  • The Journal of Chemical Physics, Vol. 140, Issue 12
  • DOI: 10.1063/1.4869109

Osmotic Pressure and Interparticle Interactions in Ionic Micellar Surfactant Solutions
journal, April 1998

  • Amos, D. A.; Markels, J. H.; Lynn, S.
  • The Journal of Physical Chemistry B, Vol. 102, Issue 15
  • DOI: 10.1021/jp9805407

Micellization in Model Surfactant Systems
journal, April 1999

  • Floriano, M. Antonio; Caponetti, Eugenio; Panagiotopoulos, Athanassios Z.
  • Langmuir, Vol. 15, Issue 9
  • DOI: 10.1021/la9810206

Equilibrium Phase Behavior of the Square-Well Linear Microphase-Forming Model
journal, April 2016

  • Zhuang, Yuan; Charbonneau, Patrick
  • The Journal of Physical Chemistry B, Vol. 120, Issue 26
  • DOI: 10.1021/acs.jpcb.6b02167

Equation of State Calculations by Fast Computing Machines
journal, June 1953

  • Metropolis, Nicholas; Rosenbluth, Arianna W.; Rosenbluth, Marshall N.
  • The Journal of Chemical Physics, Vol. 21, Issue 6
  • DOI: 10.1063/1.1699114

A general and efficient Monte Carlo method for sampling intramolecular degrees of freedom of branched and cyclic molecules
journal, October 2011

  • Shah, Jindal K.; Maginn, Edward J.
  • The Journal of Chemical Physics, Vol. 135, Issue 13
  • DOI: 10.1063/1.3644939

Electrostatic analogy for surfactant assemblies
journal, May 1992

  • Wu, David; Chandler, David; Smit, Berend
  • The Journal of Physical Chemistry, Vol. 96, Issue 10
  • DOI: 10.1021/j100189a030

General purpose molecular dynamics simulations fully implemented on graphics processing units
journal, May 2008

  • Anderson, Joshua A.; Lorenz, Chris D.; Travesset, A.
  • Journal of Computational Physics, Vol. 227, Issue 10
  • DOI: 10.1016/j.jcp.2008.01.047

Strong scaling of general-purpose molecular dynamics simulations on GPUs
journal, July 2015

  • Glaser, Jens; Nguyen, Trung Dac; Anderson, Joshua A.
  • Computer Physics Communications, Vol. 192
  • DOI: 10.1016/j.cpc.2015.02.028

Mayer Sampling: Calculation of Cluster Integrals using Free-Energy Perturbation Methods
journal, June 2004


Etomica : An object-oriented framework for molecular simulation
journal, January 2015

  • Schultz, Andrew J.; Kofke, David A.
  • Journal of Computational Chemistry, Vol. 36, Issue 8
  • DOI: 10.1002/jcc.23823

New Monte Carlo technique for studying phase transitions
journal, December 1988


Optimized Monte Carlo data analysis
journal, September 1989


Percolation and cluster distribution. I. Cluster multiple labeling technique and critical concentration algorithm
journal, October 1976


The Shapes of Random Walks
journal, July 1987


Monte Carlo simulation of micelle formation in block copolymer solutions
journal, November 1998


Characterization of micellar solutions using surfactant ion electrodes
journal, March 1980

  • Kale, Kalidas M.; Cussler, E. L.; Evans, D. F.
  • The Journal of Physical Chemistry, Vol. 84, Issue 6
  • DOI: 10.1021/j100443a007

Growth of Sodium Dodecyl Sulfate Micelles with Detergent Concentration
journal, November 1995

  • Quina, Frank H.; Nassar, Patricia M.; Bonilha, Joao B. S.
  • The Journal of Physical Chemistry, Vol. 99, Issue 46
  • DOI: 10.1021/j100046a031

Surfactant Concentration Effects on Micellar Properties
journal, January 2012

  • Jusufi, Arben; LeBard, David N.; Levine, Benjamin G.
  • The Journal of Physical Chemistry B, Vol. 116, Issue 3
  • DOI: 10.1021/jp2102989

Atomistic Simulations of Micellization of Sodium Hexyl, Heptyl, Octyl, and Nonyl Sulfates
journal, February 2012

  • Sanders, Samantha A.; Sammalkorpi, Maria; Panagiotopoulos, Athanassios Z.
  • The Journal of Physical Chemistry B, Vol. 116, Issue 8
  • DOI: 10.1021/jp209207p

Characterization of Micelles of Quaternary Ammonium Surfactants as Reaction Media I:  Dodeclytrimethylammonium Bromide and Chloride
journal, February 2002

  • Bales, Barney L.; Zana, Raoul
  • The Journal of Physical Chemistry B, Vol. 106, Issue 8
  • DOI: 10.1021/jp013813y

Surfactant association into micelles. An electrostatic approach
journal, November 1980

  • Gunnarsson, Gudmundur; Joensson, Bengt; Wennerstroem, Haakan
  • The Journal of Physical Chemistry, Vol. 84, Issue 23
  • DOI: 10.1021/j100460a029

Micellization and Phase Separation of Diblock and Triblock Model Surfactants
journal, April 2002

  • Panagiotopoulos, Athanassios Z.; Floriano, M. Antonio; Kumar, Sanat K.
  • Langmuir, Vol. 18, Issue 7
  • DOI: 10.1021/la0156513

Formation of Polymorphic Cluster Phases for a Class of Models of Purely Repulsive Soft Spheres
journal, January 2006


Clustering in the Absence of Attractions:  Density Functional Theory and Computer Simulations
journal, November 2007

  • Mladek, Bianca M.; Gottwald, Dieter; Kahl, Gerhard
  • The Journal of Physical Chemistry B, Vol. 111, Issue 44
  • DOI: 10.1021/jp074652m

Why do ultrasoft repulsive particles cluster and crystallize? Analytical results from density-functional theory
journal, June 2007

  • Likos, Christos N.; Mladek, Bianca M.; Gottwald, Dieter
  • The Journal of Chemical Physics, Vol. 126, Issue 22
  • DOI: 10.1063/1.2738064

Can purely repulsive soft potentials predict micelle formation correctly?
journal, January 2006

  • Pool, René; Bolhuis, Peter G.
  • Phys. Chem. Chem. Phys., Vol. 8, Issue 8
  • DOI: 10.1039/B512960E

Novel kinetic trapping in charged colloidal clusters due to self-induced surface charge organization
journal, June 2013

  • Klix, Christian L.; Murata, Ken-ichiro; Tanaka, Hajime
  • Scientific Reports, Vol. 3, Issue 1
  • DOI: 10.1038/srep02072