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Title: Performance and failure modes of Si anodes patterned with thin-film Ni catalyst islands for water oxidation

Abstract

Silicon photoanodes patterned with thin-film Ni catalyst islands exhibited stable sunlight-driven O 2evolution for over 240 h of continuous operation in 1.0 M KOH.

Authors:
ORCiD logo [1];  [2]; ORCiD logo [1];  [2];  [3];  [4]; ORCiD logo [1]; ORCiD logo [1];  [5]; ORCiD logo [6]; ORCiD logo [7]
  1. Division of Chemistry and Chemical Engineering; California Institute of Technology; Pasadena; USA
  2. Theiss Research; USA; National Institute of Standards and Technology; Material Measurement Laboratory; Gaithersburg
  3. Department of Chemistry; University of Southampton; Southampton; UK
  4. Division of Engineering and Applied Sciences; California Institute of Technology; Pasadena; USA
  5. National Institute of Standards and Technology; Material Measurement Laboratory; Gaithersburg; USA
  6. Beckman Institute Molecular Materials Research Center; California Institute of Technology; Pasadena; USA
  7. Division of Chemistry and Chemical Engineering; California Institute of Technology; Pasadena; USA; Beckman Institute Molecular Materials Research Center
Publication Date:
Research Org.:
California Inst. of Technology (CalTech), Pasadena, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1539957
DOE Contract Number:  
SC0004993
Resource Type:
Journal Article
Journal Name:
Sustainable Energy & Fuels
Additional Journal Information:
Journal Volume: 2; Journal Issue: 5; Journal ID: ISSN 2398-4902
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
Chemistry; Energy & Fuels; Materials Science

Citation Formats

Sun, Ke, Ritzert, Nicole L., John, Jimmy, Tan, Haiyan, Hale, William G., Jiang, Jingjing, Moreno-Hernandez, Ivan, Papadantonakis, Kimberly M., Moffat, Thomas P., Brunschwig, Bruce S., and Lewis, Nathan S. Performance and failure modes of Si anodes patterned with thin-film Ni catalyst islands for water oxidation. United States: N. p., 2018. Web. doi:10.1039/c7se00583k.
Sun, Ke, Ritzert, Nicole L., John, Jimmy, Tan, Haiyan, Hale, William G., Jiang, Jingjing, Moreno-Hernandez, Ivan, Papadantonakis, Kimberly M., Moffat, Thomas P., Brunschwig, Bruce S., & Lewis, Nathan S. Performance and failure modes of Si anodes patterned with thin-film Ni catalyst islands for water oxidation. United States. doi:10.1039/c7se00583k.
Sun, Ke, Ritzert, Nicole L., John, Jimmy, Tan, Haiyan, Hale, William G., Jiang, Jingjing, Moreno-Hernandez, Ivan, Papadantonakis, Kimberly M., Moffat, Thomas P., Brunschwig, Bruce S., and Lewis, Nathan S. Mon . "Performance and failure modes of Si anodes patterned with thin-film Ni catalyst islands for water oxidation". United States. doi:10.1039/c7se00583k.
@article{osti_1539957,
title = {Performance and failure modes of Si anodes patterned with thin-film Ni catalyst islands for water oxidation},
author = {Sun, Ke and Ritzert, Nicole L. and John, Jimmy and Tan, Haiyan and Hale, William G. and Jiang, Jingjing and Moreno-Hernandez, Ivan and Papadantonakis, Kimberly M. and Moffat, Thomas P. and Brunschwig, Bruce S. and Lewis, Nathan S.},
abstractNote = {Silicon photoanodes patterned with thin-film Ni catalyst islands exhibited stable sunlight-driven O2evolution for over 240 h of continuous operation in 1.0 M KOH.},
doi = {10.1039/c7se00583k},
journal = {Sustainable Energy & Fuels},
issn = {2398-4902},
number = 5,
volume = 2,
place = {United States},
year = {2018},
month = {1}
}

Works referenced in this record:

Thermodynamic Oxidation and Reduction Potentials of Photocatalytic Semiconductors in Aqueous Solution
journal, September 2012

  • Chen, Shiyou; Wang, Lin-Wang
  • Chemistry of Materials, Vol. 24, Issue 18
  • DOI: 10.1021/cm302533s

Thermodynamic Potential for the Anodic Dissolution of n-Type Semiconductors
journal, January 1977

  • Bard, Allen J.
  • Journal of The Electrochemical Society, Vol. 124, Issue 11
  • DOI: 10.1149/1.2133140

Will Solar-Driven Water-Splitting Devices See the Light of Day?
journal, September 2013

  • McKone, James R.; Lewis, Nathan S.; Gray, Harry B.
  • Chemistry of Materials, Vol. 26, Issue 1
  • DOI: 10.1021/cm4021518

Atomic layer-deposited tunnel oxide stabilizes silicon photoanodes for water oxidation
journal, June 2011

  • Chen, Yi Wei; Prange, Jonathan D.; Dühnen, Simon
  • Nature Materials, Vol. 10, Issue 7
  • DOI: 10.1038/nmat3047

Amorphous TiO2 coatings stabilize Si, GaAs, and GaP photoanodes for efficient water oxidation
journal, May 2014


Stabilization of Si microwire arrays for solar-driven H 2 O oxidation to O 2 (g) in 1.0 M KOH(aq) using conformal coatings of amorphous TiO 2
journal, January 2015

  • Shaner, Matthew R.; Hu, Shu; Sun, Ke
  • Energy & Environmental Science, Vol. 8, Issue 1
  • DOI: 10.1039/C4EE03012E

Photoelectrochemical Behavior of n-type Si(100) Electrodes Coated with Thin Films of Manganese Oxide Grown by Atomic Layer Deposition
journal, March 2013

  • Strandwitz, Nicholas C.; Comstock, David J.; Grimm, Ronald L.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 10
  • DOI: 10.1021/jp311207x

High Photocurrent in Silicon Photoanodes Catalyzed by Iron Oxide Thin Films for Water Oxidation
journal, November 2011

  • Jun, Kimin; Lee, Yun Seog; Buonassisi, Tonio
  • Angewandte Chemie International Edition, Vol. 51, Issue 2
  • DOI: 10.1002/anie.201104367

Nickel oxide functionalized silicon for efficient photo-oxidation of water
journal, January 2012

  • Sun, Ke; Park, Namseok; Sun, Zhelin
  • Energy & Environmental Science, Vol. 5, Issue 7
  • DOI: 10.1039/c2ee21708b

Metal Oxide Composite Enabled Nanotextured Si Photoanode for Efficient Solar Driven Water Oxidation
journal, April 2013

  • Sun, Ke; Pang, Xiaolu; Shen, Shaohua
  • Nano Letters, Vol. 13, Issue 5
  • DOI: 10.1021/nl400343a

Enhanced photoelectrochemical water-splitting performance of semiconductors by surface passivation layers
journal, January 2014

  • Liu, Rui; Zheng, Zhi; Spurgeon, Joshua
  • Energy Environ. Sci., Vol. 7, Issue 8
  • DOI: 10.1039/C4EE00450G

Efficient and Sustained Photoelectrochemical Water Oxidation by Cobalt Oxide/Silicon Photoanodes with Nanotextured Interfaces
journal, April 2014

  • Yang, Jinhui; Walczak, Karl; Anzenberg, Eitan
  • Journal of the American Chemical Society, Vol. 136, Issue 17
  • DOI: 10.1021/ja501513t

An electrodeposited inhomogeneous metal–insulator–semiconductor junction for efficient photoelectrochemical water oxidation
journal, September 2015

  • Hill, James C.; Landers, Alan T.; Switzer, Jay A.
  • Nature Materials, Vol. 14, Issue 11
  • DOI: 10.1038/nmat4408

A multifunctional biphasic water splitting catalyst tailored for integration with high-performance semiconductor photoanodes
journal, November 2016

  • Yang, Jinhui; Cooper, Jason K.; Toma, Francesca M.
  • Nature Materials, Vol. 16, Issue 3
  • DOI: 10.1038/nmat4794

High-Performance Silicon Photoanodes Passivated with Ultrathin Nickel Films for Water Oxidation
journal, November 2013


Si photoanode protected by a metal modified ITO layer with ultrathin NiO x for solar water oxidation
journal, January 2014

  • Sun, Ke; Shen, Shaohua; Cheung, Justin S.
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 10
  • DOI: 10.1039/C4CP00033A

NiFe Alloy Protected Silicon Photoanode for Efficient Water Splitting
journal, November 2016


Metal-Free Carbon-Based Nanomaterial Coatings Protect Silicon Photoanodes in Solar Water-Splitting
journal, November 2016


570 mV photovoltage, stabilized n-Si/CoO x heterojunction photoanodes fabricated using atomic layer deposition
journal, January 2016

  • Zhou, Xinghao; Liu, Rui; Sun, Ke
  • Energy & Environmental Science, Vol. 9, Issue 3
  • DOI: 10.1039/C5EE03655K

Sustained Water Oxidation by Direct Electrosynthesis of Ultrathin Organic Protection Films on Silicon
journal, March 2016

  • Azarpira, Anahita; Schedel-Niedrig, Thomas; Lewerenz, H. -J.
  • Advanced Energy Materials, Vol. 6, Issue 10
  • DOI: 10.1002/aenm.201502314

Enhanced photoelectrochemical efficiency and stability using a conformal TiO2 film on a black silicon photoanode
journal, March 2017


Stable Solar-Driven Water Oxidation to O 2 (g) by Ni-Oxide-Coated Silicon Photoanodes
journal, January 2015

  • Sun, Ke; McDowell, Matthew T.; Nielander, Adam C.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 4
  • DOI: 10.1021/jz5026195

Junction behavior of n-Si photoanodes protected by thin Ni elucidated from dual working electrode photoelectrochemistry
journal, January 2017

  • Laskowski, Forrest A. L.; Nellist, Michael R.; Venkatkarthick, Radhakrishnan
  • Energy & Environmental Science, Vol. 10, Issue 2
  • DOI: 10.1039/C6EE03505A

Sputtered NiO x Films for Stabilization of p + n-InP Photoanodes for Solar-Driven Water Oxidation
journal, March 2015

  • Sun, Ke; Kuang, Yanjin; Verlage, Erik
  • Advanced Energy Materials, Vol. 5, Issue 11
  • DOI: 10.1002/aenm.201402276

Enabling Silicon for Solar-Fuel Production
journal, January 2014

  • Sun, Ke; Shen, Shaohua; Liang, Yongqi
  • Chemical Reviews, Vol. 114, Issue 17
  • DOI: 10.1021/cr300459q

High Performance and Stability of Micropatterned Oxide-Passivated Photoanodes with Local Catalysts for Photoelectrochemical Water Splitting
journal, December 2015


Localized dielectric breakdown and antireflection coating in metal–oxide–semiconductor photoelectrodes
journal, November 2016

  • Ji, Li; Hsu, Hsien-Yi; Li, Xiaohan
  • Nature Materials, Vol. 16, Issue 1
  • DOI: 10.1038/nmat4801

Dispersed Ni Nanoparticles Stabilize Silicon Photoanodes for Efficient and Inexpensive Sunlight-Assisted Water Oxidation
journal, February 2017


Silicon Photoanodes Partially Covered by Ni@Ni(OH) 2 Core-Shell Particles for Photoelectrochemical Water Oxidation
journal, July 2017


Nickel–Iron Oxyhydroxide Oxygen-Evolution Electrocatalysts: The Role of Intentional and Incidental Iron Incorporation
journal, April 2014

  • Trotochaud, Lena; Young, Samantha L.; Ranney, James K.
  • Journal of the American Chemical Society, Vol. 136, Issue 18
  • DOI: 10.1021/ja502379c

TEM Sample Preparation and FIB-Induced Damage
journal, May 2007

  • Mayer, Joachim; Giannuzzi, Lucille A.; Kamino, Takeo
  • MRS Bulletin, Vol. 32, Issue 5
  • DOI: 10.1557/mrs2007.63

The thermally-induced reaction of thin Ni films with Si: Effect of the substrate orientation
journal, December 2011

  • Gaudet, S.; Desjardins, P.; Lavoie, C.
  • Journal of Applied Physics, Vol. 110, Issue 11
  • DOI: 10.1063/1.3662110

Formation of Ultrathin Single-Crystal Silicide Films on Si: Surface and Interfacial Stabilization of Si-Ni Si 2 Epitaxial Structures
journal, February 1983


Schottky barrier height measurements of epitaxial NiSi 2 on Si
journal, October 1985

  • Hauenstein, R. J.; Schlesinger, T. E.; McGill, T. C.
  • Applied Physics Letters, Vol. 47, Issue 8
  • DOI: 10.1063/1.96007

Schottky barriers of epitaxial NiSi 2 on Si(111)
journal, January 1988

  • Ospelt, M.; Henz, J.; Flepp, L.
  • Applied Physics Letters, Vol. 52, Issue 3
  • DOI: 10.1063/1.99527

Orientation dependence of nickel silicide formation in contacts to silicon nanowires
journal, May 2009

  • Dellas, N. S.; Liu, B. Z.; Eichfeld, S. M.
  • Journal of Applied Physics, Vol. 105, Issue 9
  • DOI: 10.1063/1.3115453

Current-voltage characteristics of coupled photodiode-electrocatalyst devices
journal, September 2013

  • Shaner, Matthew R.; Fountaine, Katherine T.; Lewerenz, Hans-Joachim
  • Applied Physics Letters, Vol. 103, Issue 14
  • DOI: 10.1063/1.4822179

Methods for comparing the performance of energy-conversion systems for use in solar fuels and solar electricity generation
journal, January 2015

  • Coridan, Robert H.; Nielander, Adam C.; Francis, Sonja A.
  • Energy & Environmental Science, Vol. 8, Issue 10
  • DOI: 10.1039/C5EE00777A

The Catalysis of the Oxygen Evolution Reaction by Iron Impurities in Thin Film Nickel Oxide Electrodes
journal, January 1987

  • Corrigan, Dennis A.
  • Journal of The Electrochemical Society, Vol. 134, Issue 2
  • DOI: 10.1149/1.2100463

Etching of Silicon in NaOH Solutions
journal, January 1993

  • Allongue, P.
  • Journal of The Electrochemical Society, Vol. 140, Issue 4
  • DOI: 10.1149/1.2056190

Au–Pt core–shell nanoemitters on silicon for photoelectrochemical solar energy conversion
journal, December 2012


Advances in Photoelectrocatalysis with Nanotopographical Photoelectrodes
journal, March 2010


Efficient photoelectrochemical nanoemitter solar cell
journal, August 2008

  • Stempel, Thomas; Aggour, Mohammed; Skorupska, Katarzyna
  • Electrochemistry Communications, Vol. 10, Issue 8
  • DOI: 10.1016/j.elecom.2008.05.041

A comparison of the chemical, optical and electrocatalytic properties of water-oxidation catalysts for use in integrated solar-fuel generators
journal, January 2017

  • Sun, Ke; Moreno-Hernandez, Ivan A.; Schmidt, William C.
  • Energy & Environmental Science, Vol. 10, Issue 4
  • DOI: 10.1039/C6EE03563A

Barrier heights of real Schottky contacts explained by metal-induced gap states and lateral inhomogeneities
journal, January 1999

  • Mönch, Winfried
  • Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 17, Issue 4
  • DOI: 10.1116/1.590839

Hydrogen-Evolving Solar Cells
journal, March 1984


H2 evolution at Si-based metal–insulator–semiconductor photoelectrodes enhanced by inversion channel charge collection and H spillover
journal, May 2013

  • Esposito, Daniel V.; Levin, Igor; Moffat, Thomas P.
  • Nature Materials, Vol. 12, Issue 6
  • DOI: 10.1038/nmat3626

A silicon-based photocathode for water reduction with an epitaxial SrTiO3 protection layer and a nanostructured catalyst
journal, December 2014

  • Ji, Li; McDaniel, Martin D.; Wang, Shijun
  • Nature Nanotechnology, Vol. 10, Issue 1
  • DOI: 10.1038/nnano.2014.277

Experiment and theory of ‘transparent’ metal films
journal, February 1985

  • Porter, John D.; Heller, Adam; Aspnes, David E.
  • Nature, Vol. 313, Issue 6004
  • DOI: 10.1038/313664a0

Bias-Dependent Etching of Silicon in Aqueous KOH
journal, January 1985

  • Glembocki, Orest J.
  • Journal of The Electrochemical Society, Vol. 132, Issue 1
  • DOI: 10.1149/1.2113750

Ellipsometric Investigation of the Silicon / Anodic-Oxide Interface
journal, December 1983


Study of the Etch-Stop Mechanism in Silicon
journal, January 1982

  • Palik, E. D.
  • Journal of The Electrochemical Society, Vol. 129, Issue 9
  • DOI: 10.1149/1.2124367