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Title: Additive engineering for high-performance room-temperature-processed perovskite absorbers with micron-size grains and microsecond-range carrier lifetimes

Journal Article · · Energy & Environmental Science
DOI:https://doi.org/10.1039/c7ee02272g· OSTI ID:1539925
 [1]; ORCiD logo [2];  [3];  [1];  [1];  [2];  [4];  [5]; ORCiD logo [1];  [6];  [7];  [8]; ORCiD logo [6]; ORCiD logo [2];  [2]; ORCiD logo [1]
  1. Department of Mechanical Engineering and Materials Science, Duke University; Durham; USA; Department of Chemistry, Duke University; Durham
  2. Department of Chemistry, Duke University; Durham; USA
  3. Department of Mechanical Engineering and Materials Science, Duke University; Durham; USA; Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Science; Beijing
  4. Department of Mechanical Engineering and Materials Science, Duke University; Durham; USA
  5. Department of Electrical and Computer Engineering, Duke University; Durham; USA
  6. Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Science; Beijing; China; University of Chinese Academy of Science; Beijing 100049
  7. Department of Chemistry, Duke University; Durham; USA; Department of Electrical and Computer Engineering, Duke University; Durham
  8. Department of Mechanical Engineering and Materials Science, Duke University; Durham; USA; Department of Electrical and Computer Engineering, Duke University; Durham

CH3NH3PbI3films with micrometer grains and microsecond carrier lifetimes are prepared through additive engineering.

Research Organization:
Duke Univ., Durham, NC (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0001517
OSTI ID:
1539925
Journal Information:
Energy & Environmental Science, Vol. 10, Issue 11; ISSN 1754-5692
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (34)

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Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9% journal August 2012
Interface engineering of highly efficient perovskite solar cells journal July 2014
High-performance photovoltaic perovskite layers fabricated through intramolecular exchange journal May 2015
Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency journal January 2016
Self-formed grain boundary healing layer for highly efficient CH3NH3PbI3 perovskite solar cells journal June 2016
Intrinsic Thermal Instability of Methylammonium Lead Trihalide Perovskite journal June 2015
Origin of the Thermal Instability in CH 3 NH 3 PbI 3 Thin Films Deposited on ZnO journal June 2015
Towards enabling stable lead halide perovskite solar cells; interplay between structural, environmental, and thermal stability journal January 2017
Hybrid Organic-Inorganic Perovskites (HOIPs): Opportunities and Challenges journal July 2015
Perovskite/polymer monolithic hybrid tandem solar cells utilizing a low-temperature, full solution process journal January 2015
Low-temperature-processed efficient semi-transparent planar perovskite solar cells for bifacial and tandem applications journal November 2015
Monolithic perovskite/silicon-heterojunction tandem solar cells processed at low temperature journal January 2016
Halide Perovskites for Tandem Solar Cells journal April 2017
Room-temperature crystallization of hybrid-perovskite thin films via solvent–solvent extraction for high-performance solar cells journal January 2015
Room temperature formation of organic–inorganic lead halide perovskites: design of nanostructured and highly reactive intermediates journal January 2017
Toward All Room-Temperature, Solution-Processed, High-Performance Planar Perovskite Solar Cells: A New Scheme of Pyridine-Promoted Perovskite Formation journal January 2017
Room-Temperature Formation of Highly Crystalline Multication Perovskites for Efficient, Low-Cost Solar Cells journal January 2017
Perovskite solar cells with a planar heterojunction structure prepared using room-temperature solution processing techniques journal December 2013
Simple post annealing-free method for fabricating uniform, large grain-sized, and highly crystalline perovskite films journal April 2017
Employing Lead Thiocyanate Additive to Reduce the Hysteresis and Boost the Fill Factor of Planar Perovskite Solar Cells journal May 2016
Efficient and reproducible CH 3 NH 3 PbI 3−x (SCN) x perovskite based planar solar cells journal January 2015
Effects of icotinib with and without radiation therapy on patients with EGFR mutant non-small cell lung cancer and brain metastases journal March 2017
Impact of microstructure on local carrier lifetime in perovskite solar cells journal April 2015
Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals journal January 2015
Low-bandgap mixed tin–lead iodide perovskite absorbers with long carrier lifetimes for all-perovskite tandem solar cells journal March 2017
Unreacted PbI 2 as a Double-Edged Sword for Enhancing the Performance of Perovskite Solar Cells journal August 2016
Controllable Self-Induced Passivation of Hybrid Lead Iodide Perovskites toward High Performance Solar Cells journal June 2014
Review of recent progress in chemical stability of perovskite solar cells journal December 2014
Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells journal July 2014
Controllable Grain Morphology of Perovskite Absorber Film by Molecular Self-Assembly toward Efficient Solar Cell Exceeding 17% journal August 2015
Hybrid Halide Perovskite Solar Cell Precursors: Colloidal Chemistry and Coordination Engineering behind Device Processing for High Efficiency journal March 2015
Synthesis and crystal structure of lead thiocyanate complexes with 18-crown-6 and two isomers of dicyclohexane-18-crown-6 journal September 1994
Thermal degradation of CH 3 NH 3 PbI 3 perovskite into NH 3 and CH 3 I gases observed by coupled thermogravimetry–mass spectrometry analysis journal January 2016

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