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Title: A pentadentate nitrogen-rich copper electrocatalyst for water reduction with pH-dependent molecular mechanisms

Abstract

A copper catalyst is active towards water reduction with distinctive pH-dependent mechanisms. The Cu III–H intermediate is bypassed by PCET processes.

Authors:
 [1];  [1];  [2];  [1];  [2]; ORCiD logo [1]; ORCiD logo [1]
  1. Department of Chemistry; Wayne State University; Detroit; USA
  2. Department of Chemistry; Hofstra University; Hempstead; USA
Publication Date:
Research Org.:
Wayne State Univ., Detroit, MI (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1539913
DOE Contract Number:  
SC0001907
Resource Type:
Journal Article
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Volume: 46; Journal Issue: 48; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
Chemistry

Citation Formats

Ekanayake, Danushka M., Kulesa, Krista M., Singh, Jaffarguriqbal, Kpogo, Kenneth K., Mazumder, Shivnath, Bernhard Schlegel, H., and Verani, Cláudio N. A pentadentate nitrogen-rich copper electrocatalyst for water reduction with pH-dependent molecular mechanisms. United States: N. p., 2017. Web. doi:10.1039/c7dt02711g.
Ekanayake, Danushka M., Kulesa, Krista M., Singh, Jaffarguriqbal, Kpogo, Kenneth K., Mazumder, Shivnath, Bernhard Schlegel, H., & Verani, Cláudio N. A pentadentate nitrogen-rich copper electrocatalyst for water reduction with pH-dependent molecular mechanisms. United States. doi:10.1039/c7dt02711g.
Ekanayake, Danushka M., Kulesa, Krista M., Singh, Jaffarguriqbal, Kpogo, Kenneth K., Mazumder, Shivnath, Bernhard Schlegel, H., and Verani, Cláudio N. Sun . "A pentadentate nitrogen-rich copper electrocatalyst for water reduction with pH-dependent molecular mechanisms". United States. doi:10.1039/c7dt02711g.
@article{osti_1539913,
title = {A pentadentate nitrogen-rich copper electrocatalyst for water reduction with pH-dependent molecular mechanisms},
author = {Ekanayake, Danushka M. and Kulesa, Krista M. and Singh, Jaffarguriqbal and Kpogo, Kenneth K. and Mazumder, Shivnath and Bernhard Schlegel, H. and Verani, Cláudio N.},
abstractNote = {A copper catalyst is active towards water reduction with distinctive pH-dependent mechanisms. The CuIII–H−intermediate is bypassed by PCET processes.},
doi = {10.1039/c7dt02711g},
journal = {Dalton Transactions},
issn = {1477-9226},
number = 48,
volume = 46,
place = {United States},
year = {2017},
month = {1}
}

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