A pentadentate nitrogen-rich copper electrocatalyst for water reduction with pH-dependent molecular mechanisms
Abstract
A copper catalyst is active towards water reduction with distinctive pH-dependent mechanisms. The CuIII–H-intermediate is bypassed by PCET processes.
- Authors:
-
- Department of Chemistry; Wayne State University; Detroit; USA
- Department of Chemistry; Hofstra University; Hempstead; USA
- Publication Date:
- Research Org.:
- Wayne State Univ., Detroit, MI (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1539913
- DOE Contract Number:
- SC0001907
- Resource Type:
- Journal Article
- Journal Name:
- Dalton Transactions
- Additional Journal Information:
- Journal Volume: 46; Journal Issue: 48; Journal ID: ISSN 1477-9226
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- Chemistry
Citation Formats
Ekanayake, Danushka M., Kulesa, Krista M., Singh, Jaffarguriqbal, Kpogo, Kenneth K., Mazumder, Shivnath, Bernhard Schlegel, H., and Verani, Cláudio N. A pentadentate nitrogen-rich copper electrocatalyst for water reduction with pH-dependent molecular mechanisms. United States: N. p., 2017.
Web. doi:10.1039/c7dt02711g.
Ekanayake, Danushka M., Kulesa, Krista M., Singh, Jaffarguriqbal, Kpogo, Kenneth K., Mazumder, Shivnath, Bernhard Schlegel, H., & Verani, Cláudio N. A pentadentate nitrogen-rich copper electrocatalyst for water reduction with pH-dependent molecular mechanisms. United States. https://doi.org/10.1039/c7dt02711g
Ekanayake, Danushka M., Kulesa, Krista M., Singh, Jaffarguriqbal, Kpogo, Kenneth K., Mazumder, Shivnath, Bernhard Schlegel, H., and Verani, Cláudio N. 2017.
"A pentadentate nitrogen-rich copper electrocatalyst for water reduction with pH-dependent molecular mechanisms". United States. https://doi.org/10.1039/c7dt02711g.
@article{osti_1539913,
title = {A pentadentate nitrogen-rich copper electrocatalyst for water reduction with pH-dependent molecular mechanisms},
author = {Ekanayake, Danushka M. and Kulesa, Krista M. and Singh, Jaffarguriqbal and Kpogo, Kenneth K. and Mazumder, Shivnath and Bernhard Schlegel, H. and Verani, Cláudio N.},
abstractNote = {A copper catalyst is active towards water reduction with distinctive pH-dependent mechanisms. The CuIII–H-intermediate is bypassed by PCET processes.},
doi = {10.1039/c7dt02711g},
url = {https://www.osti.gov/biblio/1539913},
journal = {Dalton Transactions},
issn = {1477-9226},
number = 48,
volume = 46,
place = {United States},
year = {Sun Jan 01 00:00:00 EST 2017},
month = {Sun Jan 01 00:00:00 EST 2017}
}
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