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Effect of steam and CO 2 on ethane activation over Zn-ZSM-5

Journal Article · · Catalysis Science and Technology
DOI:https://doi.org/10.1039/c7cy01850a· OSTI ID:1539908
 [1];  [1];  [1];  [1]
  1. Center for Catalytic Science and Technology; Department of Chemical and Biomolecular Engineering; University of Delaware; Newark; USA
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Hydrolysis of Zn(ii) sites in Zn-ZSM-5 suppresses ethane oligomerization and aromatization.

Research Organization:
Univ. of Delaware, Newark, DE (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0014436
OSTI ID:
1539908
Journal Information:
Catalysis Science and Technology, Vol. 8, Issue 1; ISSN 2044-4753
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (39)

Structure and function of metal cations in light alkane reactions catalyzed by modified H-ZSM5 journal December 1996
Reaction Pathways and Rate-Determining Steps in Reactions of Alkanes on H-ZSM5 and Zn/H-ZSM5 Catalysts journal February 1999
Transformation of Lower Alkanes into Aromatic Hydrocarbons over ZSM-5 Zeolites journal August 1992
Ethane and ethylene aromatization on zinc-containing zeolites journal January 2017
Activation of Light Alkanes over Zinc Species Stabilized in ZSM-5 Zeolite:  A Comprehensive DFT Study journal February 2007
Unprecedented Reversible Redox Process in the ZnMFI-H 2 System Involving Formation of Stable Atomic Zn 0 journal June 2012
Intensities of IR Stretching Bands as a Criterion of Polarization and Initial Chemical Activation of Adsorbed Molecules in Acid Catalysis. Ethane Adsorption and Dehydrogenation by Zinc Ions in ZnZSM-5 Zeolite † journal February 2005
DRIFT study of molecular and dissociative adsorption of light paraffins by HZSM-5 zeolite modified with zinc ions: methane adsorption journal July 2004
On two alternative mechanisms of ethane activation over ZSM-5 zeolite modified by Zn2+ and Ga1+ cations journal January 2005
Molecular zinc hydrides journal May 2016
The Solid-State Structures of Dimethylzinc and Diethylzinc journal September 2011
Hydrogen transfer and activation of propane and methane on ZSM5-based catalysts journal January 1993
Identifying Different Types of Catalysts for CO 2 Reduction by Ethane through Dry Reforming and Oxidative Dehydrogenation journal November 2015
Reforming and oxidative dehydrogenation of ethane with CO2 as a soft oxidant over bimetallic catalysts journal November 2016
Decomposition of Ethane and Its Reaction with CO2 over Rh/ZSM-5 Catalyst journal September 1999
High-performance Cr/H-ZSM-5 catalysts for oxidative dehydrogenation of ethane to ethylene with CO2 as an oxidant journal June 2002
Oxidative Dehydrogenation of Ethane over Cr/ZSM-5 Catalysts Using CO 2 as an Oxidant journal November 2006
Role of Carbon Dioxide in the Dehydrogenation of Ethane over Gallium-Loaded Catalysts journal October 2001
Effects of CO2 addition on the aromatization of propane over metal-loaded ZSM-5 catalysts journal January 2000
Investigation of the stability of Zn-based HZSM-5 catalysts for methane dehydroaromatization journal September 2015
ZnO supported on high silica HZSM-5 as new catalysts for dehydrogenation of propane to propene in the presence of CO2 journal November 2009
The Effect of Adsorbed Molecule Gas-Phase Deprotonation Enthalpy on Ion Exchange in Sodium Exchanged Zeolites: An In Situ FTIR Investigation journal April 2015
Initial stages of propane activation over Zn/MFI catalyst studied by in situ NMR and IR spectroscopic techniques journal February 2006
NO evolution reaction with NO2 adsorption over Fe/ZSM-5: In situ FT-IR observation and relationships with Fe sites journal July 2010
Revisiting the nature of Cu sites in the activated Cu-SSZ-13 catalyst for SCR reaction journal January 2015
IR mechanistic studies on NO reduction with NH3 in the presence of oxygen over cerium-exchanged mordenite journal January 1996
IR study of ethene and propene oligomerization on H-ZSM-5: hydrogen-bonded precursor formation, initiation and propagation mechanisms and structure of the entrapped oligomers journal January 1994
A Fourier-transform infrared spectral study of propene reactions on acidic zeolites journal July 1986
Surface species formed during propane aromatization over Zn/MFI catalyst as determined by in situ spectroscopic techniques journal June 2009
The surface chemistry of ZnO nanoparticles applied as heterogeneous catalysts in methanol synthesis journal June 2009
Structure and Density of Active Zn Species in Zn/H-ZSM5 Propane Aromatization Catalysts journal October 1998
Determination of Integrated Molar Extinction Coefficients for Infrared Absorption Bands of Pyridine Adsorbed on Solid Acid Catalysts journal June 1993
Silver‐Promoted Dehydroaromatization of Ethylene over ZSM‐5 Catalysts journal March 2017
Electrostatic Acceleration of Electrolytic Reactions by Metal Cation Complexation: The Cyclization of 1,3-cis-5-Hexatriene into 1,3-Cyclohexadiene and the 1,5-Hydrogen Shift in Cyclopentadiene. The Aromaticity of the Transition Structures journal November 1995
Highly regioselective hydride transfer, oxidative dehydrogenation, and hydrogen-atom abstraction in the thermal gas-phase chemistry of [Zn(OH)] + /C 3 H 8 journal January 2014
Non-oxidative reactions of propane on Zn/Na-ZSM5 journal January 1999
Introduction of Zn, Ga, and Fe into HZSM-5 Cavities by Sublimation:  Identification of Acid Sites journal June 1999
Structure and Reactivity of Zn-Modified ZSM-5 Zeolites: The Importance of Clustered Cationic Zn Complexes journal December 2011
Water-Promoted Hydrocarbon Activation Catalyzed by Binuclear Gallium Sites in ZSM-5 Zeolite journal September 2007

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