Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Hydrogen transfer reactions relevant to Guerbet coupling of alcohols over hydroxyapatite and magnesium oxide catalysts

Journal Article · · Catalysis Science and Technology
DOI:https://doi.org/10.1039/c7cy01393k· OSTI ID:1539907

The rates of double bond hydrogenation, deuterium exchange, and benzyl alcohol dehydrogenation were compared to those of ethanol coupling.

Research Organization:
Univ. of Virginia, Charlottesville, VA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
FG02-95ER14549
OSTI ID:
1539907
Journal Information:
Catalysis Science and Technology, Vol. 8, Issue 6; ISSN 2044-4753
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (47)

A novel catalytic property of magnesium oxide for hydrogenation of 1,3-butadiene July 1976
Selective Hydrogenation of 1,3-Butadiene over Alkaline Earth Metal Oxides January 1976
Heterogeneously catalysed hydrogenation using gold catalysts September 2005
Catalysis by Alkaline Earth Metal Oxides. II. The Mechanism of Ethylene Hydrogenation on Magnesium Oxides August 1981
Hydrogenation of Olefins Catalyzed by Alkaline Earth Metal Oxides July 1975
Probing the Basic Character of Alkali-Modified Zeolites by CO2 Adsorption Microcalorimetry, Butene Isomerization, and Toluene Alkylation with Ethylene January 2000
Heterogeneous Basic Catalysis May 1995
Activation of hydrogen at 78.deg.K on paramagnetic centers of magnesium oxide September 1972
Heterogeneous catalysis in organic chemistry. 2. A mechanistic comparison of noble-metal catalysts in olefin hydrogenation June 1984
Heterogeneous Catalysts for the Guerbet Coupling of Alcohols June 2013
Review of catalytic systems and thermodynamics for the Guerbet condensation reaction and challenges for biomass valorization January 2015
Fuel options: The ideal biofuel June 2011
On the Chemistry of Ethanol on Basic Oxides: Revising Mechanisms and Intermediates in the Lebedev and Guerbet reactions December 2014
Isotopic transient analysis of the ethanol coupling reaction over magnesia February 2013
Dimerisation of ethanol to butanol over solid-base catalysts September 2003
Structural Requirements and Reaction Pathways in Condensation Reactions of Alcohols on MgyAlOx Catalysts March 2000
Hydrotalcite-derived mixed oxides as catalysts for different C–C bond formation reactions from bioorganic materials June 2011
Ethanol catalytic condensation over Mg–Al mixed oxides derived from hydrotalcites April 2011
Bimolecular Condensation of Ethanol to 1-Butanol Catalyzed by Alkali Cation Zeolites July 1993
Direct Synthesis of n -Butanol from Ethanol over Nonstoichiometric Hydroxyapatite December 2006
Selective synthesis of 1-butanol from ethanol over strontium phosphate hydroxyapatite catalysts July 2011
Mechanism and Kinetics of Ethanol Coupling to Butanol over Hydroxyapatite January 2016
Mechanistic Insight to C–C Bond Formation and Predictive Models for Cascade Reactions among Alcohols on Ca- and Sr-Hydroxyapatites June 2016
Multiproduct Steady-State Isotopic Transient Kinetic Analysis of the Ethanol Coupling Reaction over Hydroxyapatite and Magnesia February 2015
Selective synthesis of isobutanol by means of the Guerbet reaction June 2003
Selective synthesis of isobutanol by means of the Guerbet reaction June 2002
Self-condensation of propanol over solid-base catalysts November 2004
Ethanol condensation to butanol at high temperatures over a basic heterogeneous catalyst: How relevant is acetaldehyde self-aldolization? March 2014
Aldol Condensation of Acetaldehyde over Titania, Hydroxyapatite, and Magnesia April 2016
Kinetics, Selectivity, and Deactivation in the Aldol Condensation of Acetaldehyde on Anatase Titanium Dioxide January 2011
Pulse microreactor examination of the vapor-phase aldol condensation of acetone June 1980
Base catalysis for the synthesis of α,β-unsaturated ketones from the vapor-phase aldol condensation of acetone March 1996
Solvent free aldol condensation of propanal to 2-methylpentenal using solid base catalysts December 2007
Acetone and Acetaldehyde Oligomerization on TiO2 Surfaces July 1999
Adsorption and surface reactions of acetaldehyde on TiO2, CeO2 and Al2O3 June 2005
Condensation and esterification reactions of alkanals, alkanones, and alkanols on TiO2: Elementary steps, site requirements, and synergistic effects of bifunctional strategies August 2016
Bifunctional Condensation Reactions of Alcohols on Basic Oxides Modified by Copper and Potassium May 1998
Guerbet condensation of methanol with n-propanol to isobutyl alcohol over heterogeneous copper chromite/Mg–Al mixed oxides catalysts October 2004
Guerbet condensation of methanol with n-propanol to isobutyl alcohol over heterogeneous bifunctional catalysts based on Mg–Al mixed oxides partially substituted by different metal components May 2005
Acid–base properties and active site requirements for elimination reactions on alkali-promoted MgO catalysts December 2000
Influence of surface acid and base sites on the Guerbet coupling of ethanol to butanol over metal phosphate catalysts August 2017
1-Butanol synthesis from ethanol over strontium phosphate hydroxyapatite catalysts with various Sr/P ratios December 2012
Dehydrogenation of alcohols and hydrogen transfer from alcohols to ketones over hydroxyapatite catalysts October 1973
Catalysis by Alkaline Earth Metal Oxides. III. X-Ray Photoelectron Spectroscopic Study of Catalytically Active MgO, CaO, and BaO Surfaces May 1981
Influence of Preparation Factors on Ca/P Ratio and Surface Basicity of Hydroxyapatite Catalyst January 2009
Compilation of thermal properties of hydrogen in its various isotopic and ortho-para modifications November 1948
Use of catalytic reactions to probe Mg-Al mixed oxide surfaces January 1994

Similar Records

Cascade Reaction of Ethanol to Butadiene over Multifunctional Silica-Supported Ag and ZrO2 Catalysts
Journal Article · 2022 · ACS Sustainable Chemistry & Engineering · OSTI ID:1865052

Oxidation, Reduction, and Condensation of Alcohols over (MO3)3 (M=Mo, W) Nanoclusters
Journal Article · 2014 · Journal of Physical Chemistry C, 118(39):22620-22634 · OSTI ID:1164964

Related Subjects