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Title: Ni( ii ) complex on a bispyridine-based porous organic polymer as a heterogeneous catalyst for ethylene oligomerization

Abstract

A Ni(ii) catalyst incorporated into a new porous organic polymer,Ni(ii)-POP-1, is preparedviaa click reaction followed by metalation with NiCl 2. It shows good catalytic activity for ethylene dimerization.

Authors:
 [1];  [2];  [1];  [3];  [2];  [4]; ORCiD logo [1]
  1. Dept. of Chemistry; Research Institute for Natural Sciences; Korea University; Seoul 136-701; Republic of Korea
  2. Dept. of Chemical and Biological Engineering; Northwestern University; Evanston; USA
  3. Dept. of Chemistry; Northwestern University; Evanston; USA
  4. Dept. of Chemistry; Northwestern University; Evanston; USA; Dept. of Chemistry
Publication Date:
Research Org.:
Univ. of Minnesota, Minneapolis, MN (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1539906
DOE Contract Number:  
SC0012702
Resource Type:
Journal Article
Journal Name:
Catalysis Science and Technology
Additional Journal Information:
Journal Volume: 7; Journal Issue: 19; Journal ID: ISSN 2044-4753
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
Chemistry

Citation Formats

Kim, Min Jeong, Ahn, Sol, Yi, Jigyoung, Hupp, Joseph T., Notestein, Justin M., Farha, Omar K., and Lee, Suk Joong. Ni( ii ) complex on a bispyridine-based porous organic polymer as a heterogeneous catalyst for ethylene oligomerization. United States: N. p., 2017. Web. doi:10.1039/c7cy01274h.
Kim, Min Jeong, Ahn, Sol, Yi, Jigyoung, Hupp, Joseph T., Notestein, Justin M., Farha, Omar K., & Lee, Suk Joong. Ni( ii ) complex on a bispyridine-based porous organic polymer as a heterogeneous catalyst for ethylene oligomerization. United States. doi:10.1039/c7cy01274h.
Kim, Min Jeong, Ahn, Sol, Yi, Jigyoung, Hupp, Joseph T., Notestein, Justin M., Farha, Omar K., and Lee, Suk Joong. Sun . "Ni( ii ) complex on a bispyridine-based porous organic polymer as a heterogeneous catalyst for ethylene oligomerization". United States. doi:10.1039/c7cy01274h.
@article{osti_1539906,
title = {Ni( ii ) complex on a bispyridine-based porous organic polymer as a heterogeneous catalyst for ethylene oligomerization},
author = {Kim, Min Jeong and Ahn, Sol and Yi, Jigyoung and Hupp, Joseph T. and Notestein, Justin M. and Farha, Omar K. and Lee, Suk Joong},
abstractNote = {A Ni(ii) catalyst incorporated into a new porous organic polymer,Ni(ii)-POP-1, is preparedviaa click reaction followed by metalation with NiCl2. It shows good catalytic activity for ethylene dimerization.},
doi = {10.1039/c7cy01274h},
journal = {Catalysis Science and Technology},
issn = {2044-4753},
number = 19,
volume = 7,
place = {United States},
year = {2017},
month = {1}
}

Works referenced in this record:

Design and fabrication of mesoporous heterogeneous basic catalysts
journal, January 2015

  • Sun, Lin-Bing; Liu, Xiao-Qin; Zhou, Hong-Cai
  • Chemical Society Reviews, Vol. 44, Issue 15
  • DOI: 10.1039/C5CS00090D

A new metal–organic framework with ultra-high surface area
journal, January 2014

  • Grünker, Ronny; Bon, Volodymyr; Müller, Philipp
  • Chemical Communications, Vol. 50, Issue 26
  • DOI: 10.1039/c4cc00113c

Magnetically Separable Nanocatalysts: Bridges between Homogeneous and Heterogeneous Catalysis
journal, April 2010

  • Shylesh, Sankaranarayanapillai; Schünemann, Volker; Thiel, Werner R.
  • Angewandte Chemie International Edition, Vol. 49, Issue 20
  • DOI: 10.1002/anie.200905684

De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities
journal, September 2010

  • Farha, Omar K.; Özgür Yazaydın, A.; Eryazici, Ibrahim
  • Nature Chemistry, Vol. 2, Issue 11, p. 944-948
  • DOI: 10.1038/nchem.834

Ultrahigh Porosity in Metal-Organic Frameworks
journal, July 2010


Hydrogen storage in metal–organic frameworks
journal, January 2009

  • Murray, Leslie J.; Dincă, Mircea; Long, Jeffrey R.
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1294-1314
  • DOI: 10.1039/b802256a

Supported Single-Site Organometallic Catalysts for the Synthesis of High-Performance Polyolefins
journal, November 2014

  • Stalzer, Madelyn M.; Delferro, Massimiliano; Marks, Tobin J.
  • Catalysis Letters, Vol. 145, Issue 1, p. 3-14
  • DOI: 10.1007/s10562-014-1427-x

Cooperative insertion of CO2 in diamine-appended metal-organic frameworks
journal, March 2015

  • McDonald, Thomas M.; Mason, Jarad A.; Kong, Xueqian
  • Nature, Vol. 519, Issue 7543
  • DOI: 10.1038/nature14327

Reusable Oxidation Catalysis Using Metal-Monocatecholato Species in a Robust Metal–Organic Framework
journal, March 2014

  • Fei, Honghan; Shin, JaeWook; Meng, Ying Shirley
  • Journal of the American Chemical Society, Vol. 136, Issue 13
  • DOI: 10.1021/ja411627z

Metal–organic framework materials as catalysts
journal, January 2009

  • Lee, JeongYong; Farha, Omar K.; Roberts, John
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459
  • DOI: 10.1039/b807080f

Design, Synthesis, Characterization, and Catalytic Properties of a Large-Pore Metal-Organic Framework Possessing Single-Site Vanadyl(monocatecholate) Moieties
journal, July 2013

  • Nguyen, Huong Giang T.; Weston, Mitchell H.; Sarjeant, Amy A.
  • Crystal Growth & Design, Vol. 13, Issue 8
  • DOI: 10.1021/cg400500t

Metal–Organic Framework Materials as Chemical Sensors
journal, September 2011

  • Kreno, Lauren E.; Leong, Kirsty; Farha, Omar K.
  • Chemical Reviews, Vol. 112, Issue 2, p. 1105-1125
  • DOI: 10.1021/cr200324t

Electrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2
journal, March 2016

  • Miner, Elise M.; Fukushima, Tomohiro; Sheberla, Dennis
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms10942

Metal–Organic Framework Nodes as Nearly Ideal Supports for Molecular Catalysts: NU-1000- and UiO-66-Supported Iridium Complexes
journal, June 2015

  • Yang, Dong; Odoh, Samuel O.; Wang, Timothy C.
  • Journal of the American Chemical Society, Vol. 137, Issue 23, p. 7391-7396
  • DOI: 10.1021/jacs.5b02956

Nanoparticles as Recyclable Catalysts: The Frontier between Homogeneous and Heterogeneous Catalysis
journal, December 2005

  • Astruc, Didier; Lu, Feng; Aranzaes, Jaime Ruiz
  • Angewandte Chemie International Edition, Vol. 44, Issue 48
  • DOI: 10.1002/anie.200500766

Carbon−Carbon Coupling Reactions Catalyzed by Heterogeneous Palladium Catalysts
journal, January 2007

  • Yin, ; Liebscher, Jürgen
  • Chemical Reviews, Vol. 107, Issue 1
  • DOI: 10.1021/cr0505674

Heterogeneous enantioselective catalysts: strategies for the immobilisation of homogeneous catalysts
journal, January 2004

  • McMorn, Paul; Hutchings, Graham J.
  • Chemical Society Reviews, Vol. 33, Issue 2
  • DOI: 10.1039/b200387m

Vanadium-Node-Functionalized UiO-66: A Thermally Stable MOF-Supported Catalyst for the Gas-Phase Oxidative Dehydrogenation of Cyclohexene
journal, June 2014

  • Nguyen, Huong Giang T.; Schweitzer, Neil M.; Chang, Chih-Yi
  • ACS Catalysis, Vol. 4, Issue 8, p. 2496-2500
  • DOI: 10.1021/cs5001448

Structural stability and elastic properties of prototypical covalent organic frameworks
journal, October 2010


Structural Stability of Metal Organic Framework MOF-177
journal, November 2009

  • Saha, Dipendu; Deng, Shuguang
  • The Journal of Physical Chemistry Letters, Vol. 1, Issue 1
  • DOI: 10.1021/jz900028u

Photochemical Activation of a Metal-Organic Framework to Reveal Functionality
journal, November 2010

  • Tanabe, Kristine K.; Allen, Corinne A.; Cohen, Seth M.
  • Angewandte Chemie International Edition, Vol. 49, Issue 50
  • DOI: 10.1002/anie.201004736

Highly tunable porous organic polymer (POP) supports for metallocene-based ethylene polymerization
journal, October 2017


Porous Organic Polymers in Catalysis Opportunities and Challenges
journal, May 2011

  • Kaur, Parminder; Hupp, Joseph T.; Nguyen, SonBinh T.
  • ACS Catalysis, Vol. 1, Issue 7, p. 819-835
  • DOI: 10.1021/cs200131g

Ethylene dimerization and oligomerization to butene-1 and linear α-olefins
journal, April 1992


A “click-based” porous organic polymer from tetrahedral building blocks
journal, January 2011

  • Pandey, Prativa; Farha, Omar K.; Spokoyny, Alexander M.
  • Journal of Materials Chemistry, Vol. 21, Issue 6
  • DOI: 10.1039/c0jm03483e

Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination
journal, October 2013

  • Feng, Dawei; Chung, Wan-Chun; Wei, Zhangwen
  • Journal of the American Chemical Society, Vol. 135, Issue 45
  • DOI: 10.1021/ja408084j

Anhydrous proton-conducting properties of triazole–phosphonic acid copolymers: a combined study with MAS NMR
journal, January 2008

  • Çelik, Sevim Ü.; Akbey, Ümit; Graf, Robert
  • Physical Chemistry Chemical Physics, Vol. 10, Issue 39
  • DOI: 10.1039/b807659f

Sodium ascorbate potentiates the growth inhibitory effect of certain agents on neuroblastoma cells in culture.
journal, February 1979

  • Prasad, K. N.; Sinha, P. K.; Ramanujam, M.
  • Proceedings of the National Academy of Sciences, Vol. 76, Issue 2
  • DOI: 10.1073/pnas.76.2.829

Click-based porous cationic polymers for enhanced carbon dioxide capture
journal, January 2017

  • Dani, Alessandro; Crocellà, Valentina; Magistris, Claudio
  • Journal of Materials Chemistry A, Vol. 5, Issue 1
  • DOI: 10.1039/C6TA08574A

Gas-Phase Dimerization of Ethylene under Mild Conditions Catalyzed by MOF Materials Containing (bpy)Ni II Complexes
journal, October 2015

  • Madrahimov, Sherzod T.; Gallagher, James R.; Zhang, Guanghui
  • ACS Catalysis, Vol. 5, Issue 11
  • DOI: 10.1021/acscatal.5b01604

Ni-, Pd-, or Pt-catalyzed ethylene dimerization: a mechanistic description of the catalytic cycle and the active species
journal, January 2010

  • Roy, Dipankar; Sunoj, Raghavan B.
  • Organic & Biomolecular Chemistry, Vol. 8, Issue 5
  • DOI: 10.1039/b921492e

Deactivation Pathways of Neutral Ni(II) Polymerization Catalysts
journal, February 2009

  • Berkefeld, Andreas; Mecking, Stefan
  • Journal of the American Chemical Society, Vol. 131, Issue 4
  • DOI: 10.1021/ja808855v

MOF-Supported Selective Ethylene Dimerization Single-Site Catalysts through One-Pot Postsynthetic Modification
journal, March 2013

  • Canivet, Jerome; Aguado, Sonia; Schuurman, Yves
  • Journal of the American Chemical Society, Vol. 135, Issue 11
  • DOI: 10.1021/ja312120x

Ethylene oligomerization in metal–organic frameworks bearing nickel( ii ) 2,2′-bipyridine complexes
journal, January 2017

  • Gonzalez, Miguel I.; Oktawiec, Julia; Long, Jeffrey R.
  • Faraday Discussions, Vol. 201
  • DOI: 10.1039/C7FD00061H

Electrocatalytic reduction of aryldichlorophosphines with the (2,2′-bipyridine)nickel complexes
journal, May 2007

  • Yakhvarov, D. G.; Hey-Hawkins, E.; Kagirov, R. M.
  • Russian Chemical Bulletin, Vol. 56, Issue 5
  • DOI: 10.1007/s11172-007-0142-9

Decomposition pathways of homogeneous catalysts
journal, April 2001


Homogeneous and Heterogeneous Catalysis: Bridging the Gap through Surface Organometallic Chemistry
journal, January 2003

  • Copéret, Christophe; Chabanas, Mathieu; Petroff Saint-Arroman, Romain
  • Angewandte Chemie International Edition, Vol. 42, Issue 2, p. 156-181
  • DOI: 10.1002/anie.200390072