Sensing and capture of toxic and hazardous gases and vapors by metal–organic frameworks

Wang, Hao; Lustig, William P.; Li, Jing

doi:10.1039/c7cs00885f

Sensing and capture of toxic and hazardous gases and vapors by metal–organic frameworks

Journal Article · 01 January 2018 · Chemical Society Reviews

DOI:https://doi.org/10.1039/c7cs00885f· OSTI ID:1539904

Wang, Hao ^[1]; ^[1]; ^[1]

Department of Chemistry and Chemical Biology; Rutgers University; Piscataway; USA

This review summaries recent progress in the luminescent detection and adsorptive removal of harmful gases and vapors by metal–organic frameworks, as well as the principles and strategies guiding the design of these materials.

Research Organization:: Univ. of Texas at Dallas, Richardson, TX (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: FG02-08ER46491

OSTI ID:: 1539904

Journal Information:: Chemical Society Reviews, Vol. 47, Issue 13; ISSN 0306-0012

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (183)

Terminology of metal–organic frameworks and coordination polymers (IUPAC Recommendations 2013) No authors listed Pure and Applied Chemistry https://doi.org/10.1351/PAC-REC-12-11-20		July 2013
Metal–Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit? No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja3055639		August 2012
A magnesium MOF as a sensitive fluorescence sensor for CS ₂ and nitroaromatic compounds No authors listed J. Mater. Chem. A https://doi.org/10.1039/C3TA15071B		January 2014
Multifunctional metal–organic frameworks: from academia to industrial applications No authors listed Chemical Society Reviews https://doi.org/10.1039/C5CS00307E		January 2015
Methane storage in flexible metal–organic frameworks with intrinsic thermal management No authors listed Nature https://doi.org/10.1038/nature15732		October 2015
Porous Metal-Organic Frameworks: Promising Materials for Methane Storage No authors listed Chem https://doi.org/10.1016/j.chempr.2016.09.009		October 2016
The current status of hydrogen storage in metal–organic frameworks—updated No authors listed Energy & Environmental Science https://doi.org/10.1039/c1ee01240a		January 2011
Hydrogen Storage in Metal–Organic Frameworks No authors listed Chemical Reviews https://doi.org/10.1021/cr200274s		September 2011
Metal–Organic Frameworks for Separations No authors listed Chemical Reviews https://doi.org/10.1021/cr200190s		September 2011
Potential of microporous metal–organic frameworks for separation of hydrocarbon mixtures No authors listed Energy & Environmental Science https://doi.org/10.1039/C6EE01886F		January 2016
Commensurate Adsorption of Hydrocarbons and Alcohols in Microporous Metal Organic Frameworks No authors listed Chemical Reviews https://doi.org/10.1021/cr200216x		September 2011
Hydrocarbon Separations in Metal–Organic Frameworks No authors listed Chemistry of Materials https://doi.org/10.1021/cm402897c		September 2013
Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene No authors listed Science https://doi.org/10.1126/science.aaf2458		May 2016
Metal–Organic Frameworks for Heterogeneous Basic Catalysis No authors listed Chemical Reviews https://doi.org/10.1021/acs.chemrev.7b00091		May 2017
Metal–Organic Frameworks: Versatile Materials for Heterogeneous Photocatalysis No authors listed ACS Catalysis https://doi.org/10.1021/acscatal.6b02228		October 2016
Multifunctional metal–organic framework catalysts: synergistic catalysis and tandem reactions No authors listed Chemical Society Reviews https://doi.org/10.1039/C6CS00250A		January 2017
A series of isoreticular chiral metal–organic frameworks as a tunable platform for asymmetric catalysis No authors listed Nature Chemistry https://doi.org/10.1038/nchem.738		July 2010
Metal–organic frameworks: functional luminescent and photonic materials for sensing applications No authors listed Chemical Society Reviews https://doi.org/10.1039/C6CS00930A		January 2017
Luminescent metal–organic frameworks for chemical sensing and explosive detection No authors listed Chem. Soc. Rev. https://doi.org/10.1039/C4CS00010B		January 2014
Effective Detection of Mycotoxins by a Highly Luminescent Metal–Organic Framework No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.5b10308		December 2015
Luminescent metal–organic frameworks No authors listed Chemical Society Reviews https://doi.org/10.1039/b802352m		January 2009
Proton-conductive metal-organic frameworks: Recent advances and perspectives No authors listed Coordination Chemistry Reviews https://doi.org/10.1016/j.ccr.2017.03.027		August 2017
Effect of Imidazole Arrangements on Proton-Conductivity in Metal–Organic Frameworks No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.7b01559		April 2017
Proton Conduction with Metal-Organic Frameworks No authors listed Science https://doi.org/10.1126/science.1239872		July 2013
MOFs as proton conductors – challenges and opportunities No authors listed Chem. Soc. Rev. https://doi.org/10.1039/C4CS00093E		January 2014
Emerging Applications of Metal–Organic Frameworks and Covalent Organic Frameworks No authors listed Chemistry of Materials https://doi.org/10.1021/acs.chemmater.6b04677		November 2016
Application of metal − organic frameworks: Application of metal − organic frameworks No authors listed Polymer International https://doi.org/10.1002/pi.5315		February 2017
A metal-organic framework-based splitter for separating propylene from propane No authors listed Science https://doi.org/10.1126/science.aaf6323		July 2016
Toxic Effects of Gases and Vapors: Mechanism of Poisoning by Volatile Solvents No authors listed New England Journal of Medicine https://doi.org/10.1056/NEJM194801082380204		January 1948
Metal–Organic Frameworks for Air Purification of Toxic Chemicals No authors listed Chemical Reviews https://doi.org/10.1021/cr4006473		April 2014
Metal–organic frameworks for the control and management of air quality: advances and future direction No authors listed Journal of Materials Chemistry A https://doi.org/10.1039/C5TA07068F		January 2016
Carbon Dioxide Capture in Metal–Organic Frameworks No authors listed Chemical Reviews https://doi.org/10.1021/cr2003272		September 2011
The energy–climate challenge: Recent trends in CO2 emissions from fuel combustion No authors listed Energy Policy https://doi.org/10.1016/j.enpol.2007.07.001		November 2007
Life cycle energy and greenhouse gas emissions of nuclear energy: A review No authors listed Energy Conversion and Management https://doi.org/10.1016/j.enconman.2008.01.033		August 2008
Radioactive Iodine and Krypton Control for Nuclear Fuel Reprocessing Facilities No authors listed Science and Technology of Nuclear Installations https://doi.org/10.1155/2013/702496		January 2013
History of chemical and biological warfare agents No authors listed Toxicology https://doi.org/10.1016/j.tox.2005.06.011		October 2005
A review on adsorption refrigeration technology and adsorption deterioration in physical adsorption systems No authors listed Renewable and Sustainable Energy Reviews https://doi.org/10.1016/j.rser.2009.08.001		January 2010
Lanthanide-Based Coordination Polymers for the Size-Selective Detection of Nitroaromatics No authors listed Crystal Growth & Design https://doi.org/10.1021/acs.cgd.7b00536		May 2017
Recognition of harmful fused aromatic hydrocarbons via a metal-organic framework with hydrophobic pores No authors listed Inorganic Chemistry Communications https://doi.org/10.1016/j.inoche.2017.10.015		December 2017
An efficient and sensitive fluorescent pH sensor based on amino functional metal–organic frameworks in aqueous environment No authors listed Dalton Transactions https://doi.org/10.1039/C6DT00361C		January 2016
Preparation and thiols sensing of luminescent metal–organic framework films functionalized with lanthanide ions No authors listed Microporous and Mesoporous Materials https://doi.org/10.1016/j.micromeso.2013.06.008		September 2013
Encapsulating Naphthalene in an Electron-Deficient MOF to Enhance Fluorescence for Organic Amines Sensing No authors listed Inorganic Chemistry https://doi.org/10.1021/acs.inorgchem.6b00252		March 2016
Eu( iii )-functionalized ZnO@MOF heterostructures: integration of pre-concentration and efficient charge transfer for the fabrication of a ppb-level sensing platform for volatile aldehyde gases in vehicles No authors listed Journal of Materials Chemistry A https://doi.org/10.1039/C6TA10019H		January 2017
Rigidifying Fluorescent Linkers by Metal–Organic Framework Formation for Fluorescence Blue Shift and Quantum Yield Enhancement No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja5006866		May 2014
Achieving exceptionally high luminescence quantum efficiency by immobilizing an AIE molecular chromophore into a metal–organic framework No authors listed Chemical Communications https://doi.org/10.1039/C4CC07642G		January 2015
Engineering metal-based luminescence in coordination polymers and metal–organic frameworks No authors listed Chemical Society Reviews https://doi.org/10.1039/c3cs60232j		January 2013
Host–Guest Engineering of Coordination Polymers for Highly Tunable Luminophores Based on Charge Transfer Emissions No authors listed ACS Applied Materials & Interfaces https://doi.org/10.1021/acsami.6b14554		January 2017
Metal–organic frameworks based on bipyridinium carboxylate: photochromism and selective vapochromism No authors listed Journal of Materials Chemistry C https://doi.org/10.1039/C6TC04724F		January 2017
Chromophore-Based Luminescent Metal–Organic Frameworks as Lighting Phosphors No authors listed Inorganic Chemistry https://doi.org/10.1021/acs.inorgchem.6b00897		May 2016
Protonation effect on ligands in EuL: a luminescent switcher for fast naked-eye detection of HCl No authors listed Dalton Transactions https://doi.org/10.1039/C5DT01791B		January 2015
Gas detection by structural variations of fluorescent guest molecules in a flexible porous coordination polymer No authors listed Nature Materials https://doi.org/10.1038/nmat3104		September 2011
Hypersensitive dual-function luminescence switching of a silver-chalcogenolate cluster-based metal–organic framework No authors listed Nature Chemistry https://doi.org/10.1038/nchem.2718		February 2017
Copper(I) Metal–Organic Framework: Visual Sensor for Detecting Small Polar Aliphatic Volatile Organic Compounds No authors listed Inorganic Chemistry https://doi.org/10.1021/acs.inorgchem.5b02150		December 2015
Metal–Organic Frameworks as Micromotors with Tunable Engines and Brakes No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.6b11899		January 2017
Multiroute Synthesis of Porous Anionic Frameworks and Size-Tunable Extraframework Organic Cation-Controlled Gas Sorption Properties No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja906302t		November 2009
Fe-based metal organic framework/graphene oxide composite as an efficient catalyst for Fenton-like degradation of methyl orange No authors listed RSC Advances https://doi.org/10.1039/C7RA10145G		January 2017
CdS nanoparticles immobilized on porous carbon polyhedrons derived from a metal-organic framework with enhanced visible light photocatalytic activity for antibiotic degradation No authors listed Applied Surface Science https://doi.org/10.1016/j.apsusc.2017.05.102		October 2017
Synthesis of a Zr-Based Metal–Organic Framework with Spirobifluorenetetrabenzoic Acid for the Effective Removal of Nerve Agent Simulants No authors listed Inorganic Chemistry https://doi.org/10.1021/acs.inorgchem.7b02022		October 2017
In Situ Probes of Capture and Decomposition of Chemical Warfare Agent Simulants by Zr-Based Metal Organic Frameworks No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.6b11373		January 2017
A Fine-Tuned Metal–Organic Framework for Autonomous Indoor Moisture Control No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.7b04132		July 2017
Fine-Tuning the Activity of Metal–Organic Framework-Supported Cobalt Catalysts for the Oxidative Dehydrogenation of Propane No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.7b09365		October 2017
Ultra-Tuning of the Rare-Earth fcu-MOF Aperture Size for Selective Molecular Exclusion of Branched Paraffins No authors listed Angewandte Chemie International Edition https://doi.org/10.1002/anie.201506345		October 2015
Stepwise engineering of pore environments and enhancement of CO ₂ /R22 adsorption capacity through dynamic spacer installation and functionality modification No authors listed Chem. Commun. https://doi.org/10.1039/C7CC06352K		January 2017
In silico discovery of metal-organic frameworks for precombustion CO ₂ capture using a genetic algorithm No authors listed Science Advances https://doi.org/10.1126/sciadv.1600909		October 2016
Capture of organic iodides from nuclear waste by metal-organic framework-based molecular traps No authors listed Nature Communications https://doi.org/10.1038/s41467-017-00526-3		September 2017
Postsynthetic Methods for the Functionalization of Metal–Organic Frameworks No authors listed Chemical Reviews https://doi.org/10.1021/cr200179u		September 2011
Metal-organic frameworks with high capacity and selectivity for harmful gases No authors listed Proceedings of the National Academy of Sciences https://doi.org/10.1073/pnas.0804900105		August 2008
A Straight Forward Route for the Development of Metal–Organic Frameworks Functionalized with Aromatic −OH Groups: Synthesis, Characterization, and Gas (N ₂ , Ar, H ₂ , CO ₂ , CH ₄ , NH ₃ ) Sorption Properties No authors listed Inorganic Chemistry https://doi.org/10.1021/ic302010e		January 2013
Metal–organic frameworks for the removal of toxic industrial chemicals and chemical warfare agents No authors listed Chemical Society Reviews https://doi.org/10.1039/C7CS00108H		January 2017
Effect of Humidity on the Performance of Microporous Coordination Polymers as Adsorbents for CO ₂ Capture No authors listed Langmuir https://doi.org/10.1021/la200547k		May 2011
Applications of water stable metal–organic frameworks No authors listed Chemical Society Reviews https://doi.org/10.1039/C6CS00362A		January 2016
Increasing the Stability of Metal-Organic Frameworks No authors listed Advances in Chemistry https://doi.org/10.1155/2014/182327		September 2014
Zr-based metal–organic frameworks: design, synthesis, structure, and applications No authors listed Chemical Society Reviews https://doi.org/10.1039/C5CS00837A		January 2016
A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area No authors listed Science https://doi.org/10.1126/science.1116275		September 2005
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja8057953		October 2008
Enhanced stability and CO2 affinity of a UiO-66 type metal–organic framework decorated with dimethyl groups No authors listed Dalton Transactions https://doi.org/10.1039/c2dt30950e		January 2012
An ultrastable Zr metal–organic framework with a thiophene-type ligand containing methyl groups No authors listed CrystEngComm https://doi.org/10.1039/C5CE00269A		January 2015
Superhydrophobicity: Constructing Homogeneous Catalysts into Superhydrophobic Porous Frameworks to Protect Them from Hydrolytic Degradation No authors listed Chem https://doi.org/10.1016/j.chempr.2016.09.008		October 2016
Cooperative insertion of CO2 in diamine-appended metal-organic frameworks No authors listed Nature https://doi.org/10.1038/nature14327		March 2015
Reversible CO Scavenging via Adsorbate-Dependent Spin State Transitions in an Iron(II)–Triazolate Metal–Organic Framework No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.6b00248		April 2016
Nitroaromatic compounds: Environmental toxicity, carcinogenicity, mutagenicity, therapy and mechanism: Nitro aromatic pollutants No authors listed Journal of Applied Toxicology https://doi.org/10.1002/jat.2980		February 2014
A Luminescent Microporous Metal-Organic Framework for the Fast and Reversible Detection of High Explosives No authors listed Angewandte Chemie International Edition https://doi.org/10.1002/anie.200804853		January 2009
ℝPM3: A Multifunctional Microporous MOF with Recyclable Framework and High H ₂ Binding Energy ^† No authors listed Inorganic Chemistry https://doi.org/10.1021/ic9002115		August 2009
Selective, Sensitive, and Reversible Detection of Vapor-Phase High Explosives via Two-Dimensional Mapping: A New Strategy for MOF-Based Sensors No authors listed Crystal Growth & Design https://doi.org/10.1021/cg4012185		August 2013
Aqueous- and vapor-phase detection of nitroaromatic explosives by a water-stable fluorescent microporous MOF directed by an ionic liquid No authors listed Journal of Materials Chemistry A https://doi.org/10.1039/C5TA00322A		January 2015
Fluorescence Detection of Anilines and Photocatalytic Degradation of Rhodamine B by a Multifunctional Metal-Organic Framework: Fluorescence Detection of Anilines and Degradation of Rhodamine B No authors listed European Journal of Inorganic Chemistry https://doi.org/10.1002/ejic.201402770		November 2014
New Microporous Metal−Organic Framework Demonstrating Unique Selectivity for Detection of High Explosives and Aromatic Compounds No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja106851d		March 2011
Luminescent metal–organic frameworks as explosive sensors No authors listed Dalton Trans. https://doi.org/10.1039/C4DT01196A		January 2014
Vapor phase detection of nitroaromatic and nitroaliphatic explosives by fluorescence active metal–organic frameworks No authors listed CrystEngComm https://doi.org/10.1039/c3ce41680a		January 2013
A Systematic Study of Fluorescence-Based Detection of Nitroexplosives and Other Aromatics in the Vapor Phase by Microporous Metal-Organic Frameworks No authors listed Chemistry - A European Journal https://doi.org/10.1002/chem.201301194		October 2013
An ultrastable porous metal–organic framework luminescent switch towards aromatic compounds No authors listed Materials Horizons https://doi.org/10.1039/C4MH00210E		January 2015
Known and Unexplored Organic Constituents in the Earth's Atmosphere No authors listed Environmental Science & Technology https://doi.org/10.1021/es072476p		March 2007
Reactive adsorption of ammonia and ammonia/water on CuBTC metal-organic framework: A ReaxFF molecular dynamics simulation No authors listed The Journal of Chemical Physics https://doi.org/10.1063/1.4774332		January 2013
A Family of Metal–Organic Frameworks with a New Chair-Conformation Resorcin[4]arene-Based Ligand: Selective Luminescent Sensing of Amine and Aldehyde Vapors, and Solvent-Mediated Structural Transformations No authors listed Crystal Growth & Design https://doi.org/10.1021/acs.cgd.6b00213		April 2016
PEG-Induced Synthesis of Coordination-Polymer Isomers with Tunable Architectures and Iodine Capture No authors listed Chemistry - An Asian Journal https://doi.org/10.1002/asia.201700018		February 2017
“Turn-on” Fluorescence Sensing and Discriminative Detection of Aliphatic Amines Using a 5-Fold-Interpenetrated Coordination Polymer No authors listed Inorganic Chemistry https://doi.org/10.1021/acs.inorgchem.7b00787		May 2017
A Luminescent Metal-Organic Framework as a Turn-On Sensor for DMF Vapor No authors listed Angewandte Chemie International Edition https://doi.org/10.1002/anie.201207610		November 2012
High and Reversible Ammonia Uptake in Mesoporous Azolate Metal–Organic Frameworks with Open Mn, Co, and Ni Sites No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.6b05723		July 2016
Modeling Water and Ammonia Adsorption in Hydrophobic Metal–Organic Frameworks: Single Components and Mixtures No authors listed The Journal of Physical Chemistry C https://doi.org/10.1021/jp410758t		December 2013
Emission of ammonia from indoor concrete wall and assessment of human exposure No authors listed Environment International https://doi.org/10.1016/j.envint.2005.06.002		April 2006
Tetrazine functionalized zirconium MOF as an optical sensor for oxidizing gases No authors listed Chemical Communications https://doi.org/10.1039/C4CC08136F		January 2015
Simultaneous determination of indoor ammonia pollution and its biological metabolite in the human body with a recyclable nanocrystalline lanthanide-functionalized MOF No authors listed Nanoscale https://doi.org/10.1039/C5NR06066D		January 2016
Selective Turn-On Ammonia Sensing Enabled by High-Temperature Fluorescence in Metal–Organic Frameworks with Open Metal Sites No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja407778a		August 2013
An in situ self-assembled Cu ₄ I ₄ –MOF-based mixed matrix membrane: a highly sensitive and selective naked-eye sensor for gaseous HCl No authors listed Chemical Communications https://doi.org/10.1039/C6CC00189K		January 2016
Capture of Nerve Agents and Mustard Gas Analogues by Hydrophobic Robust MOF-5 Type Metal–Organic Frameworks No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja2042113		August 2011
Simple and Compelling Biomimetic Metal-Organic Framework Catalyst for the Degradation of Nerve Agent Simulants No authors listed Angewandte Chemie International Edition https://doi.org/10.1002/anie.201307520		November 2013
Destruction of chemical warfare agents using metal–organic frameworks No authors listed Nature Materials https://doi.org/10.1038/nmat4238		March 2015
A visually detectable pH responsive zirconium metal–organic framework No authors listed Chemical Communications https://doi.org/10.1039/C5CC10384C		January 2016
Construction of terpyridine–Ln(iii) coordination polymers: structural diversity, visible and NIR luminescence properties and response to nerve-agent mimics No authors listed CrystEngComm https://doi.org/10.1039/c3ce42091d		January 2014
Mixed Cu( i )/Au( i ) coordination polymers as reversible turn-on vapoluminescent sensors for volatile thioethers No authors listed Chemical Communications https://doi.org/10.1039/C7CC03428H		January 2017
Designing Tunable White-Light Emission from an Aurophilic Cu ^I /Au ^I Coordination Polymer with Thioether Ligands No authors listed Chemistry - A European Journal https://doi.org/10.1002/chem.201505075		May 2016
Smart textiles of MOF/g-C ₃ N ₄ nanospheres for the rapid detection/detoxification of chemical warfare agents No authors listed Nanoscale Horiz. https://doi.org/10.1039/C7NH00081B		January 2017
Metal Loaded Zeolite Adsorbents for Phosphine Removal No authors listed Industrial & Engineering Chemistry Research https://doi.org/10.1021/ie071074n		March 2008
Use of zeolites for the removal of H 2 S: A mini-review No authors listed Fuel Processing Technology https://doi.org/10.1016/j.fuproc.2015.08.015		November 2015
Toxic gases removal onto activated carbons obtained from hay with the use of microwave radiation No authors listed Chemical Engineering Research and Design https://doi.org/10.1016/j.cherd.2016.02.018		May 2016
Ammonia adsorption in a fixed bed of activated carbon No authors listed Bioresource Technology https://doi.org/10.1016/j.biortech.2006.03.024		March 2007
Removal of perfluorinated surfactants by sorption onto granular activated carbon, zeolite and sludge No authors listed Chemosphere https://doi.org/10.1016/j.chemosphere.2008.04.029		August 2008
Newly detected ozone-depleting substances in the atmosphere No authors listed Nature Geoscience https://doi.org/10.1038/ngeo2109		March 2014
Fluorocarbon adsorption in hierarchical porous frameworks No authors listed Nature Communications https://doi.org/10.1038/ncomms5368		July 2014
Thermally robust and porous noncovalent organic framework with high affinity for fluorocarbons and CFCs No authors listed Nature Communications https://doi.org/10.1038/ncomms6131		October 2014
Mesoporous Fluorinated Metal-Organic Frameworks with Exceptional Adsorption of Fluorocarbons and CFCs No authors listed Angewandte Chemie International Edition https://doi.org/10.1002/anie.201505149		October 2015
Tuning fluorocarbon adsorption in new isoreticular porous coordination frameworks for heat transformation applications No authors listed Chemical Science https://doi.org/10.1039/C4SC03985H		January 2015
Precise Modulation of the Breathing Behavior and Pore Surface in Zr-MOFs by Reversible Post-Synthetic Variable-Spacer Installation to Fine-Tune the Expansion Magnitude and Sorption Properties No authors listed Angewandte Chemie International Edition https://doi.org/10.1002/anie.201604023		July 2016
Pore-Engineered Metal–Organic Frameworks with Excellent Adsorption of Water and Fluorocarbon Refrigerant for Cooling Applications No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.7b04872		July 2017
Opportunities and challenges for a sustainable energy future No authors listed Nature https://doi.org/10.1038/nature11475		August 2012
Capture of iodine and organic iodides using silica zeolites and the semiconductor behaviour of iodine in a silica zeolite No authors listed Energy & Environmental Science https://doi.org/10.1039/C5EE02843D		January 2016
488. The kinetics of the reaction of methyl iodide with silver nitrate and silver perchlorate in aqueous solution No authors listed Journal of the Chemical Society (Resumed) https://doi.org/10.1039/jr9640002542		January 1964
Rigid Pillars and Double Walls in a Porous Metal-Organic Framework: Single-Crystal to Single-Crystal, Controlled Uptake and Release of Iodine and Electrical Conductivity No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja908293n		March 2010
Capture of Volatile Iodine, a Gaseous Fission Product, by Zeolitic Imidazolate Framework-8 No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja204757x		August 2011
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks No authors listed Proceedings of the National Academy of Sciences https://doi.org/10.1073/pnas.0602439103		June 2006
Trapping Guests within a Nanoporous Metal–Organic Framework through Pressure-Induced Amorphization No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja2085096		November 2011
Competitive I ₂ Sorption by Cu-BTC from Humid Gas Streams No authors listed Chemistry of Materials https://doi.org/10.1021/cm401762g		June 2013
A Chemically Functionalizable Nanoporous Material [Cu₃(TMA)₂(H₂O)₃]_n No authors listed Science https://doi.org/10.1126/science.283.5405.1148		February 1999
Iodine Confinement into Metal–Organic Frameworks (MOFs): Low-Temperature Sintering Glasses To Form Novel Glass Composite Material (GCM) Alternative Waste Forms No authors listed Industrial & Engineering Chemistry Research https://doi.org/10.1021/ie200248g		May 2011
The water-based synthesis of chemically stable Zr-based MOFs using pyridine-containing ligands and their exceptionally high adsorption capacity for iodine No authors listed Dalton Transactions https://doi.org/10.1039/C7DT01084B		January 2017
Influence of an amine group on the highly efficient reversible adsorption of iodine in two novel isoreticular interpenetrated pillared-layer microporous metal–organic frameworks No authors listed CrystEngComm https://doi.org/10.1039/C4CE01331J		January 2014
Adsorption of Iodine Based on a Tetrazolate Framework with Microporous Cages and Mesoporous Cages No authors listed Inorganic Chemistry https://doi.org/10.1021/acs.inorgchem.6b02696		December 2016
Two heterovalent copper–organic frameworks with multiple secondary building units: high performance for gas adsorption and separation and I ₂ sorption and release No authors listed Journal of Materials Chemistry A https://doi.org/10.1039/C6TA05142A		January 2016
Tuning CO ₂ Uptake and Reversible Iodine Adsorption in Two Isoreticular MOFs through Ligand Functionalization No authors listed Chemistry - An Asian Journal https://doi.org/10.1002/asia.201403123		December 2014
A Luminescent Zinc(II) Metal–Organic Framework (MOF) with Conjugated π-Electron Ligand for High Iodine Capture and Nitro-Explosive Detection No authors listed Inorganic Chemistry https://doi.org/10.1021/acs.inorgchem.6b01312		August 2016
A 4-fold interpenetrated diamondoid metal-organic framework with large channels exhibiting solvent sorption properties and high iodine capture No authors listed Microporous and Mesoporous Materials https://doi.org/10.1016/j.micromeso.2016.05.016		September 2016
Face-Capped M ⁴ L ₄ Tetrahedral Metal-Organic Cage: Iodine Capture and Release, Ion Exchange, and Electrical Conductivity No authors listed Chemistry - An Asian Journal https://doi.org/10.1002/asia.201501161		November 2015
A 3D Coordination Network Built from Cu ^II ₄ Cl ₃ (H ₂ O) ₂ Linear Clusters and Tetrapyridyl Tetrahedral Silane Ligands: Reversible Iodine Uptake and Friedel–Crafts Alkylation Reactions No authors listed Inorganic Chemistry https://doi.org/10.1021/acs.inorgchem.7b01781		September 2017
Kinetic Assembly of a Thermally Stable Porous Coordination Network Based on Labile CuI Units and the Visualization of I ₂ Sorption No authors listed Angewandte Chemie International Edition https://doi.org/10.1002/anie.201306776		September 2013
[Fe ₃ (HCOO) ₆ ]: A Permanent Porous Diamond Framework Displaying H ₂ /N ₂ Adsorption, Guest Inclusion, and Guest-Dependent Magnetism No authors listed Advanced Functional Materials https://doi.org/10.1002/adfm.200600676		April 2007
Highly efficient iodine species enriching and guest-driven tunable luminescent properties based on a cadmium(ii)-triazole MOF No authors listed Chemical Communications https://doi.org/10.1039/c1cc11402f		January 2011
Luminescent MOFs comprising mixed tritopic linkers and Cd(II)/Zn(II) nodes for selective detection of organic nitro compounds and iodine capture No authors listed Journal of Solid State Chemistry https://doi.org/10.1016/j.jssc.2014.05.012		March 2015
Micro-Cu ₄ I ₄ -MOF: reversible iodine adsorption and catalytic properties for tandem reaction of Friedel–Crafts alkylation of indoles with acetals No authors listed Chemical Communications https://doi.org/10.1039/C6CC07027B		January 2016
Highly Efficient Enrichment of Volatile Iodine by Charged Porous Aromatic Frameworks with Three Sorption Sites No authors listed Angewandte Chemie International Edition https://doi.org/10.1002/anie.201503362		August 2015
An azo-linked porous triptycene network as an absorbent for CO ₂ and iodine uptake No authors listed Polymer Chemistry https://doi.org/10.1039/C5PY01671A		January 2016
Capture and Reversible Storage of Volatile Iodine by Novel Conjugated Microporous Polymers Containing Thiophene Units No authors listed ACS Applied Materials & Interfaces https://doi.org/10.1021/acsami.6b06569		August 2016
High surface area amorphous microporous poly(aryleneethynylene) networks using tetrahedral carbon- and silicon-centred monomers No authors listed Chemical Communications https://doi.org/10.1039/B815044C		January 2009
Synthesis of conjugated microporous polymer nanotubes with large surface areas as absorbents for iodine and CO ₂ uptake No authors listed Journal of Materials Chemistry A https://doi.org/10.1039/C4TA04235B		January 2015
Highly efficient and reversible iodine capture using a metalloporphyrin-based conjugated microporous polymer No authors listed Chem. Commun. https://doi.org/10.1039/C4CC01783H		January 2014
Ultrahigh iodine adsorption in porous organic frameworks No authors listed J. Mater. Chem. A https://doi.org/10.1039/C4TA00049H		January 2014
Removal efficiency of radioactive methyl iodide on TEDA-impregnated activated carbons No authors listed Fuel Processing Technology https://doi.org/10.1016/j.fuproc.2010.04.014		February 2011
Radioactive Iodine Capture in Silver-Containing Mordenites through Nanoscale Silver Iodide Formation No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja103110y		July 2010
Investigation of Silver-Impregnated Alumina for Removal of Radioactive Methyl Iodide No authors listed Nuclear Technology https://doi.org/10.13182/NT95-A35085		March 1995
Functionalized metal organic frameworks for effective capture of radioactive organic iodides No authors listed Faraday Discussions https://doi.org/10.1039/C7FD00013H		January 2017
Metal–organic framework with optimally selective xenon adsorption and separation No authors listed Nature Communications https://doi.org/10.1038/ncomms11831		June 2016
Potential of Metal–Organic Frameworks for Separation of Xenon and Krypton No authors listed Accounts of Chemical Research https://doi.org/10.1021/ar5003126		December 2014
The first example of commensurate adsorption of atomic gas in a MOF and effective separation of xenon from other noble gases No authors listed Chemical Science https://doi.org/10.1039/C3SC52348A		January 2014
Direct Observation of Xe and Kr Adsorption in a Xe-Selective Microporous Metal–Organic Framework No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.5b02556		May 2015
Metal–Organic Frameworks for Removal of Xe and Kr from Nuclear Fuel Reprocessing Plants No authors listed Langmuir https://doi.org/10.1021/la301870n		July 2012
Made-to-order metal-organic frameworks for trace carbon dioxide removal and air capture No authors listed Nature Communications https://doi.org/10.1038/ncomms5228		June 2014
Toxic gas removal – metal–organic frameworks for the capture and degradation of toxic gases and vapours No authors listed Chem. Soc. Rev. https://doi.org/10.1039/C3CS60475F		January 2014
Adsorptive desulfurization and denitrogenation using metal-organic frameworks No authors listed Journal of Hazardous Materials https://doi.org/10.1016/j.jhazmat.2015.08.045		January 2016
Magnesium-based systems for carbon dioxide capture, storage and recycling: from leaves to synthetic nanostructured materials No authors listed RSC Advances https://doi.org/10.1039/C5RA02835C		January 2015
A Guide to CO₂ Sequestration No authors listed Science https://doi.org/10.1126/science.1079033		June 2003
Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg₂(dobpdc) No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja300034j		April 2012
Porous materials with optimal adsorption thermodynamics and kinetics for CO₂ separation No authors listed Nature https://doi.org/10.1038/nature11893		February 2013
CO ₂ Capture and Separations Using MOFs: Computational and Experimental Studies No authors listed Chemical Reviews https://doi.org/10.1021/acs.chemrev.6b00626		April 2017
Metal–organic frameworks in mixed-matrix membranes for gas separation No authors listed Dalton Transactions https://doi.org/10.1039/c2dt31550e		January 2012
Reversible CO Binding Enables Tunable CO/H ₂ and CO/N ₂ Separations in Metal–Organic Frameworks with Exposed Divalent Metal Cations No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja505318p		July 2014
Metallo-organic molecular sieve for gas separation and purification No authors listed Microporous and Mesoporous Materials https://doi.org/10.1016/S1387-1811(02)00405-5		September 2002
Immobilizing Highly Catalytically Active Pt Nanoparticles inside the Pores of Metal–Organic Framework: A Double Solvents Approach No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja3043905		August 2012
Hydrogen Sulfide Capture: From Absorption in Polar Liquids to Oxide, Zeolite, and Metal–Organic Framework Adsorbents and Membranes No authors listed Chemical Reviews https://doi.org/10.1021/acs.chemrev.7b00095		May 2017
Comparative Study of Hydrogen Sulfide Adsorption in the MIL-53(Al, Cr, Fe), MIL-47(V), MIL-100(Cr), and MIL-101(Cr) Metal−Organic Frameworks at Room Temperature No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja901587t		July 2009
Metal–organic frameworks to satisfy gas upgrading demands: fine-tuning the soc -MOF platform for the operative removal of H ₂ S No authors listed Journal of Materials Chemistry A https://doi.org/10.1039/C6TA09406F		January 2017
Ultrahigh and Selective SO ₂ Uptake in Inorganic Anion-Pillared Hybrid Porous Materials No authors listed Advanced Materials https://doi.org/10.1002/adma.201606929		May 2017
Interaction of Acid Gases SO ₂ and NO ₂ with Coordinatively Unsaturated Metal Organic Frameworks: M-MOF-74 (M = Zn, Mg, Ni, Co) No authors listed Chemistry of Materials https://doi.org/10.1021/acs.chemmater.7b00005		May 2017
Interactions of NO ₂ with Zr-Based MOF: Effects of the Size of Organic Linkers on NO ₂ Adsorption at Ambient Conditions No authors listed Langmuir https://doi.org/10.1021/la302869m		December 2012
Extraordinary NO ₂ Removal by the Metal-Organic Framework UiO-66-NH ₂ No authors listed Angewandte Chemie International Edition https://doi.org/10.1002/anie.201601782		April 2016

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