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Title: Anchoring groups for photocatalytic water oxidation on metal oxide surfaces

Abstract

The synthesis, binding modes, water stability, and electron-transfer dynamics are compared for carboxylate, phosphonate, hydroxamate, and silatrane anchoring groups.

Authors:
 [1]; ORCiD logo [1]; ORCiD logo [1]
  1. Department of Chemistry; Yale University; New Haven; USA; Yale Energy Sciences Institute
Publication Date:
Research Org.:
Yale Univ., New Haven, CT (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1539895
DOE Contract Number:  
FG02-07ER15909
Resource Type:
Journal Article
Journal Name:
Chemical Society Reviews
Additional Journal Information:
Journal Volume: 46; Journal Issue: 20; Journal ID: ISSN 0306-0012
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
Chemistry

Citation Formats

Materna, Kelly L., Crabtree, Robert H., and Brudvig, Gary W. Anchoring groups for photocatalytic water oxidation on metal oxide surfaces. United States: N. p., 2017. Web. doi:10.1039/c7cs00314e.
Materna, Kelly L., Crabtree, Robert H., & Brudvig, Gary W. Anchoring groups for photocatalytic water oxidation on metal oxide surfaces. United States. https://doi.org/10.1039/c7cs00314e
Materna, Kelly L., Crabtree, Robert H., and Brudvig, Gary W. 2017. "Anchoring groups for photocatalytic water oxidation on metal oxide surfaces". United States. https://doi.org/10.1039/c7cs00314e.
@article{osti_1539895,
title = {Anchoring groups for photocatalytic water oxidation on metal oxide surfaces},
author = {Materna, Kelly L. and Crabtree, Robert H. and Brudvig, Gary W.},
abstractNote = {The synthesis, binding modes, water stability, and electron-transfer dynamics are compared for carboxylate, phosphonate, hydroxamate, and silatrane anchoring groups.},
doi = {10.1039/c7cs00314e},
url = {https://www.osti.gov/biblio/1539895}, journal = {Chemical Society Reviews},
issn = {0306-0012},
number = 20,
volume = 46,
place = {United States},
year = {Sun Jan 01 00:00:00 EST 2017},
month = {Sun Jan 01 00:00:00 EST 2017}
}

Works referenced in this record:

Renewable energy resources: Current status, future prospects and their enabling technology
journal, November 2014


Finding the Way to Solar Fuels with Dye-Sensitized Photoelectrosynthesis Cells
journal, September 2016


Light-driven water oxidation for solar fuels
journal, November 2012


Molecular Chromophore–Catalyst Assemblies for Solar Fuel Applications
journal, August 2015


Design and development of photoanodes for water-splitting dye-sensitized photoelectrochemical cells
journal, January 2013


Recent advances in dye-sensitized photoelectrochemical cells for solar hydrogen production based on molecular components
journal, January 2015


Towards multielectron photocatalysis: a porphyrin array for lateral hole transfer and capture on a metal oxide surface
journal, January 2015


High-Potential Porphyrins Supported on SnO 2 and TiO 2 Surfaces for Photoelectrochemical Applications
journal, December 2016


Artificial photosynthesis – functional devices for light driven water splitting with photoactive anodes based on molecular catalysts
journal, January 2014


Photostability of Phosphonate-Derivatized, Ru II Polypyridyl Complexes on Metal Oxide Surfaces
journal, February 2012


Role of Molecular Anchor Groups in Molecule-to-Semiconductor Electron Transfer
journal, December 2006


Modular Assembly of High-Potential Zinc Porphyrin Photosensitizers Attached to TiO 2 with a Series of Anchoring Groups
journal, July 2013


Water-stable, hydroxamate anchors for functionalization of TiO2 surfaces with ultrafast interfacial electron transfer
journal, January 2010


Hydroxamate anchors for water-stable attachment to TiO2 nanoparticles
journal, January 2009


Anchoring Groups for Dye-Sensitized Solar Cells
journal, February 2015


Acetylacetonate Anchors for Robust Functionalization of TiO 2 Nanoparticles with Mn(II)−Terpyridine Complexes
journal, October 2008


A visible light water-splitting cell with a photoanode formed by codeposition of a high-potential porphyrin and an iridium water-oxidation catalyst
journal, January 2011


Watching Photoactivation in a Ru(II) Chromophore–Catalyst Assembly on TiO 2 by Ultrafast Spectroscopy
journal, November 2013


Surface-Induced Deprotection of THP-Protected Hydroxamic Acids on Titanium Dioxide
journal, June 2016


Comparison of silatrane, phosphonic acid, and carboxylic acid functional groups for attachment of porphyrin sensitizers to TiO2 in photoelectrochemical cells
journal, January 2013


Silatranes for binding inorganic complexes to metal oxide surfaces
journal, January 2015


Heterogenized Iridium Water-Oxidation Catalyst from a Silatrane Precursor
journal, July 2016


Phosphonate-Based Bipyridine Dyes for Stable Photovoltaic Devices
journal, November 2001


Synthesis of Phosphonic Acid Derivatized Bipyridine Ligands and Their Ruthenium Complexes
journal, October 2013


Hydroxamate Anchors for Improved Photoconversion in Dye-Sensitized Solar Cells
journal, May 2013


Substitution of a hydroxamic acid anchor into the MK-2 dye for enhanced photovoltaic performance and water stability in a DSSC
journal, January 2014


Silatranes: Intra-complex heterocyclic compounds of pentacordinated silicon
journal, January 1966


Organosilatrane building blocks
journal, January 2014


Photoelectrochemistry of tris(bipyridyl)ruthenium(II) covalently attached to n-type tin(IV) oxide
journal, August 1980


Silatranes: a review on their synthesis, structure, reactivity and applications
journal, January 2011


Amide bond formation and peptide coupling
journal, November 2005


The Sonogashira Reaction:  A Booming Methodology in Synthetic Organic Chemistry
journal, March 2007


Cu-Catalyzed Azide−Alkyne Cycloaddition
journal, August 2008


Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds
journal, November 1995


Michaelis-Arbuzov rearrangement
journal, August 1981


Effects of Surface Anchoring Groups (Carboxylate vs Phosphonate) in Ruthenium-Complex-Sensitized TiO 2 on Visible Light Reactivity in Aqueous Suspensions
journal, September 2004


Molecular titanium–hydroxamate complexes as models for TiO 2 surface binding
journal, January 2016


Anchoring of Phosphonate and Phosphinate Coupling Molecules on Titania Particles
journal, November 2001


Stabilization of Ruthenium Sensitizers to TiO 2 Surfaces through Cooperative Anchoring Groups
journal, January 2013


Structure–Property Relationships in Phosphonate-Derivatized, Ru II Polypyridyl Dyes on Metal Oxide Surfaces in an Aqueous Environment
journal, July 2012


Proton-Coupled Electron Transfer in a Strongly Coupled Photosystem II-Inspired Chromophore–Imidazole–Phenol Complex: Stepwise Oxidation and Concerted Reduction
journal, September 2016


Improving the efficiency of water splitting in dye-sensitized solar cells by using a biomimetic electron transfer mediator
journal, April 2012


Mimicking the electron transfer chain in photosystem II with a molecular triad thermodynamically capable of water oxidation
journal, May 2012


Stabilization of [Ru(bpy) 2 (4,4′-(PO 3 H 2 )bpy)] 2+ on Mesoporous TiO 2 with Atomic Layer Deposition of Al 2 O 3
journal, December 2012


Water splitting–biosynthetic system with CO 2 reduction efficiencies exceeding photosynthesis
journal, June 2016