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Transition of surface phase of cobalt oxide during CO oxidation

Journal Article · · Physical Chemistry Chemical Physics. PCCP (Print)
DOI:https://doi.org/10.1039/c7cp07407g· OSTI ID:1539889
 [1];  [2];  [1];  [3];  [1];  [4];  [3];  [1];  [3];  [1]
  1. Department of Chemical and Petroleum Engineering and Department of Chemistry, University of Kansas; Lawrence; USA
  2. Department of Chemical and Petroleum Engineering and Department of Chemistry, University of Kansas; Lawrence; USA; Department of Chemistry, Qufu Normal University; Qufu
  3. Department of Chemical and Petroleum Engineering and Department of Physics and Astronomy, University of Pittsburgh; USA
  4. Department of Chemistry, Qufu Normal University; Qufu; China

Transition of surface phase of cobalt oxide nanoparticle catalyst during CO oxidation in 60–200 °C tracked through AP-XPS.

Research Organization:
Univ. of Kansas, Lawrence, KS (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0014561
OSTI ID:
1539889
Journal Information:
Physical Chemistry Chemical Physics. PCCP (Print), Vol. 20, Issue 9; ISSN 1463-9076
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (55)

Intrinsic Relation between Catalytic Activity of CO Oxidation on Ru Nanoparticles and Ru Oxides Uncovered with Ambient Pressure XPS journal October 2012
Size- and shape-dependent catalytic performances of oxidation and reduction reactions on nanocatalysts journal January 2016
Atomic-Scale Observations of Catalyst Structures under Reaction Conditions and during Catalysis journal March 2016
Atomic-Scale Structural Evolution of Rh(110) during Catalysis journal December 2016
In Situ Oxidation Study of Pt(110) and Its Interaction with CO journal December 2011
Different Reactivity of the Various Platinum Oxides and Chemisorbed Oxygen in CO Oxidation on Pt(111) journal April 2014
In Situ Ambient Pressure XPS Study of CO Oxidation Reaction on Pd(111) Surfaces journal August 2012
Break-Up of Stepped Platinum Catalyst Surfaces by High CO Coverage journal February 2010
Interplay of theoretical calculations and experiments for a study of catalysis by gold journal January 2016
Catalytic Oxidation of Carbon Monoxide over Transition Metal Oxides journal December 2010
Preferential Oxidation of CO in H 2 on Pure Co 3 O 4− x and Pt/Co 3 O 4− x journal June 2015
On the Catalytic Activity of Co3O4 in Low-Temperature CO Oxidation journal October 2002
The role of low-coordinate oxygen on Co 3 O 4 (110) in catalyticCO oxidation journal January 2011
Surface Studies by Scanning Tunneling Microscopy journal July 1982
Low-temperature oxidation of CO catalysed by Co3O4 nanorods journal April 2009
Catalytic CO Oxidation over Well-Defined Cobalt Oxide Nanoparticles: Size-Reactivity Correlation journal August 2015
Ordered Crystalline Mesoporous Oxides as Catalysts for CO Oxidation journal March 2009
Ultrathin Co3O4 nanowires with high catalytic oxidation of CO journal January 2011
Co3O4 nanocrystals with predominantly exposed facets: synthesis, environmental and energy applications journal January 2013
Surface active sites on Co3O4 nanobelt and nanocube model catalysts for CO oxidation journal April 2010
Synthesis of Co3O4 nanotubes and their catalytic applications in CO oxidation journal December 2013
Co3O4 nanosheets: synthesis and catalytic application for CO oxidation at room temperature journal April 2014
Crystal-facet dependent CO oxidation, preferential oxidation of CO in H2-rich, water-gas shift reactions, and supercapacitor application over Co3O4 nanostructures journal June 2016
Structural Effects of Cerium Oxides on Their Thermal Stability and Catalytic Performance in Propane Oxidation Dehydrogenation journal July 2012
A DFT Study on CO Oxidation over Co3O4 journal August 2002
Bulk and surface properties of spinel Co3O4 by density functional calculations journal February 2009
A DFT Study of CO Catalytic Oxidation by N 2 O or O 2 on the Co 3 O 4 (110) Surface journal November 2009
Origin of extraordinarily high catalytic activity of Co3O4 and its morphological chemistry for CO oxidation at low temperature journal December 2012
Structure Sensitivity of CO Oxidation on Co 3 O 4 : A DFT Study journal November 2012
A DFT study on adsorption behaviour of CO on Co3O4 nanostructures journal November 2016
Pretreatments of Co3O4 at moderate temperature for CO oxidation at −80°C journal October 2009
Restructuring Transition Metal Oxide Nanorods for 100% Selectivity in Reduction of Nitric Oxide with Carbon Monoxide journal June 2013
Commentary: The Materials Project: A materials genome approach to accelerating materials innovation journal July 2013
Development of a reaction cell for in-situ/operando studies of surface of a catalyst under a reaction condition and during catalysis journal June 2016
Integrated In Situ Characterization of a Molten Salt Catalyst Surface: Evidence of Sodium Peroxide and Hydroxyl Radical Formation journal July 2017
Catalytic Conversion of Carbon Dioxide to Methane on Ruthenium–Cobalt Bimetallic Nanocatalysts and Correlation between Surface Chemistry of Catalysts under Reaction Conditions and Catalytic Performances journal September 2012
Catalysis and In Situ Studies of Rh 1 /Co 3 O 4 Nanorods in Reduction of NO with H 2 journal April 2013
WGS Catalysis and In Situ Studies of CoO 1– x , PtCo n /Co 3 O 4 , and Pt m Co m /CoO 1– x Nanorod Catalysts journal May 2013
Effect of Cobalt on Reduction Characteristics of Ceria under Ethanol Steam Reforming Conditions: AP-XPS and XANES Studies journal June 2016
Tuning Catalytic Selectivity of Oxidative Catalysis through Deposition of Nonmetallic Atoms in Surface Lattice of Metal Oxide journal June 2016
Catalysis on singly dispersed bimetallic sites journal August 2015
Understanding complete oxidation of methane on spinel oxides at a molecular level journal August 2015
Mechanistic Aspects of Wet and Dry CO Oxidation on Co 3 O 4 Nanorod Surfaces: A NAP-UPS Study journal March 2017
Oxidation triggered atomic restructures enhancing the electrooxidation activities of carbon supported platinum–ruthenium catalysts journal January 2014
Epitaxial growth of CoO films on semiconductor and metal substrates by constructing a complex heterostructure journal January 2003
Fabrication of polar CoO(111) thin films on Pt(111) journal September 2004
Cobalt oxide surface chemistry: The interaction of CoO(100), Co3O4(110) and Co3O4(111) with oxygen and water journal February 2008
Cu2O(110) formation on Co3O4(110) induced by copper impurity segregation journal December 2005
Surface composition and structure of Co3O4(110) and the effect of impurity segregation journal July 2004
Deconvolution of the Co3O4(110) Fuchs–Kliewer phonon spectrum
  • Marsh, E. M.; Petitto, S. C.; Harbison, G. S.
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 23, Issue 4 https://doi.org/10.1116/1.1863972
journal July 2005
Surface composition of CoxNi1−xO solid solutions by X-ray photoelectron and Auger spectroscopies journal May 1999
Surface composition of MnxCo1−xO solid solutions by X-ray photoelectron and Auger spectroscopies journal January 2000
Valence-band electronic structure of Co 3 O 4 epitaxy on CoO(100) journal February 1999
Analysis of the NiCo2O4 spinel surface with Auger and X-ray photoelectron spectroscopy journal September 2000
Epitaxial growth of Co 3 O 4 on CoO(100)
  • Carson, G. A.; Nassir, M. H.; Langell, M. A.
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 14, Issue 3 https://doi.org/10.1116/1.580310
journal May 1996