skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Reducing the photocatalysis induced by hot electrons of plasmonic nanoparticles due to tradeoff of photothermal heating

Abstract

The photothermal heating by the plasmonic nanoparticles lowers their photocatalytic efficiency due to the desperation of the reacting materials.

Authors:
ORCiD logo [1]
  1. Chemical Engineering; Department of Biomedical Engineering; Department of Chemistry; Department of Physics and Astronomy; The University of Texas at San Antonio
Publication Date:
Research Org.:
Georgia Inst. of Technology, Atlanta, GA (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1539876
DOE Contract Number:  
SC0002232
Resource Type:
Journal Article
Journal Name:
Physical Chemistry Chemical Physics. PCCP (Print)
Additional Journal Information:
Journal Volume: 19; Journal Issue: 47; Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
Chemistry; Physics

Citation Formats

Mahmoud, Mahmoud A. Reducing the photocatalysis induced by hot electrons of plasmonic nanoparticles due to tradeoff of photothermal heating. United States: N. p., 2017. Web. doi:10.1039/c7cp03855k.
Mahmoud, Mahmoud A. Reducing the photocatalysis induced by hot electrons of plasmonic nanoparticles due to tradeoff of photothermal heating. United States. doi:10.1039/c7cp03855k.
Mahmoud, Mahmoud A. Sun . "Reducing the photocatalysis induced by hot electrons of plasmonic nanoparticles due to tradeoff of photothermal heating". United States. doi:10.1039/c7cp03855k.
@article{osti_1539876,
title = {Reducing the photocatalysis induced by hot electrons of plasmonic nanoparticles due to tradeoff of photothermal heating},
author = {Mahmoud, Mahmoud A.},
abstractNote = {The photothermal heating by the plasmonic nanoparticles lowers their photocatalytic efficiency due to the desperation of the reacting materials.},
doi = {10.1039/c7cp03855k},
journal = {Physical Chemistry Chemical Physics. PCCP (Print)},
issn = {1463-9076},
number = 47,
volume = 19,
place = {United States},
year = {2017},
month = {1}
}

Works referenced in this record:

Optical Studies of Dynamics in Noble Metal Nanostructures
journal, June 2011


Designing Plasmon Resonances
journal, April 2014

  • Hartland, Gregory
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 9
  • DOI: 10.1021/jz500703x

Surface raman spectroelectrochemistry: Part I. Heterocyclic, aromatic, and aliphatic amines adsorbed on the anodized silver electrode
journal, November 1977

  • Jeanmaire, David L.; Van Duyne, Richard P.
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 84, Issue 1, p. 1-20
  • DOI: 10.1016/S0022-0728(77)80224-6

Probing Single Molecules and Single Nanoparticles by Surface-Enhanced Raman Scattering
journal, February 1997


Gold Nanooctahedra with Tunable Size and Microfluidic-Induced 3D Assembly for Highly Uniform SERS-Active Supercrystals
journal, December 2015

  • Gómez-Graña, Sergio; Fernández-López, Cristina; Polavarapu, Lakshminarayana
  • Chemistry of Materials, Vol. 27, Issue 24
  • DOI: 10.1021/acs.chemmater.5b03620

Gold Nanorod–pNIPAM Hybrids with Reversible Plasmon Coupling: Synthesis, Modeling, and SERS Properties
journal, March 2015

  • Fernández-López, Cristina; Polavarapu, Lakshminarayana; Solís, Diego M.
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 23
  • DOI: 10.1021/am5087209

Ultrafast and nonlinear surface-enhanced Raman spectroscopy
journal, January 2016

  • Gruenke, Natalie L.; Cardinal, M. Fernanda; McAnally, Michael O.
  • Chemical Society Reviews, Vol. 45, Issue 8
  • DOI: 10.1039/C5CS00763A

Surface-plasmon field-enhanced fluorescence spectroscopy
journal, October 2000

  • Liebermann, Thorsten; Knoll, Wolfgang
  • Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 171, Issue 1-3
  • DOI: 10.1016/S0927-7757(99)00550-6

Single Ag Nanoparticle Spectroelectrochemistry via Dark-Field Scattering and Fluorescence Microscopies
journal, March 2015

  • Hill, Caleb M.; Bennett, Robert; Zhou, Chen
  • The Journal of Physical Chemistry C, Vol. 119, Issue 12
  • DOI: 10.1021/jp511637a

Resonant Optical Antennas
journal, June 2005


Surface enhanced sum frequency generation of carbon monoxide adsorbed on platinum nanoparticle arrays
journal, January 2000

  • Baldelli, Steve; Eppler, Aaron S.; Anderson, Erik
  • The Journal of Chemical Physics, Vol. 113, Issue 13
  • DOI: 10.1063/1.1290024

Surface plasmon subwavelength optics
journal, August 2003

  • Barnes, William L.; Dereux, Alain; Ebbesen, Thomas W.
  • Nature, Vol. 424, Issue 6950, p. 824-830
  • DOI: 10.1038/nature01937

Plasmonics for improved photovoltaic devices
journal, February 2010

  • Atwater, Harry A.; Polman, Albert
  • Nature Materials, Vol. 9, Issue 3, p. 205-213
  • DOI: 10.1038/nmat2629

Gold nanorod enhanced organic photovoltaics: The importance of morphology effects
journal, July 2014


Gold Nanoframes: Very High Surface Plasmon Fields and Excellent Near-Infrared Sensors
journal, September 2010

  • Mahmoud, Mahmoud A.; El-Sayed, Mostafa A.
  • Journal of the American Chemical Society, Vol. 132, Issue 36
  • DOI: 10.1021/ja104532z

Shape- and Size-Dependent Refractive Index Sensitivity of Gold Nanoparticles
journal, May 2008

  • Chen, Huanjun; Kou, Xiaoshan; Yang, Zhi
  • Langmuir, Vol. 24, Issue 10
  • DOI: 10.1021/la800305j

Trace detection of tetrabromobisphenol A by SERS with DMAP-modified magnetic gold nanoclusters
journal, January 2015

  • Kadasala, Naveen Reddy; Wei, Alexander
  • Nanoscale, Vol. 7, Issue 25
  • DOI: 10.1039/C4NR07658C

Effective Optoelectrical Switching by Using Pseudo-Single Crystal of Monolayer Array of 2D Polymer–Plasmonic Nanoparticles System
journal, December 2015


(Gold Nanorod Core)/(Polyaniline Shell) Plasmonic Switches with Large Plasmon Shifts and Modulation Depths
journal, March 2014


Tunable Electrochemical Switch of the Optical Properties of Metallic Nanoparticles
journal, April 2008

  • Leroux, Yann; Lacroix, Jean Christophe; Fave, Claire
  • ACS Nano, Vol. 2, Issue 4
  • DOI: 10.1021/nn700438a

Electrically Controlled Plasmonic Behavior of Gold Nanocube@Polyaniline Nanostructures: Transparent Plasmonic Aggregates
journal, April 2016


Polarized Optomechanical Response of Silver Nanodisc Monolayers on an Elastic Substrate Induced by Stretching
journal, August 2015


Femtosecond photoemission study of ultrafast electron dynamics in single-crystal Au(111) films
journal, October 1998


An autonomous photosynthetic device in which all charge carriers derive from surface plasmons
journal, February 2013

  • Mubeen, Syed; Lee, Joun; Singh, Nirala
  • Nature Nanotechnology, Vol. 8, Issue 4
  • DOI: 10.1038/nnano.2013.18

Evidence and implications of direct charge excitation as the dominant mechanism in plasmon-mediated photocatalysis
journal, January 2016

  • Boerigter, Calvin; Campana, Robert; Morabito, Matthew
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms10545

Spectroscopy and Dynamics of Nanometer-Sized Noble Metal Particles
journal, September 1998

  • Hodak, José H.; Martini, Ignacio; Hartland, Gregory V.
  • The Journal of Physical Chemistry B, Vol. 102, Issue 36
  • DOI: 10.1021/jp9809787

Shape and size dependence of radiative, non-radiative and photothermal properties of gold nanocrystals
journal, July 2000

  • Link, Stephan; El-Sayed, Mostafa A.
  • International Reviews in Physical Chemistry, Vol. 19, Issue 3
  • DOI: 10.1080/01442350050034180

Plasmon-induced hot carrier science and technology
journal, January 2015

  • Brongersma, Mark L.; Halas, Naomi J.; Nordlander, Peter
  • Nature Nanotechnology, Vol. 10, Issue 1
  • DOI: 10.1038/nnano.2014.311

Photochemistry on Metal Nanoparticles
journal, October 2006

  • Watanabe, Kazuo; Menzel, Dietrich; Nilius, Niklas
  • Chemical Reviews, Vol. 106, Issue 10
  • DOI: 10.1021/cr050167g

Hot Electrons Do the Impossible: Plasmon-Induced Dissociation of H 2 on Au
journal, December 2012

  • Mukherjee, Shaunak; Libisch, Florian; Large, Nicolas
  • Nano Letters, Vol. 13, Issue 1
  • DOI: 10.1021/nl303940z

Plasmonic hot electron enhanced MoS 2 photocatalysis in hydrogen evolution
journal, January 2015

  • Kang, Yimin; Gong, Yongji; Hu, Zhijian
  • Nanoscale, Vol. 7, Issue 10
  • DOI: 10.1039/C4NR07303G

Enhancing Colloidal Metallic Nanocatalysis: Sharp Edges and Corners for Solid Nanoparticles and Cage Effect for Hollow Ones
journal, February 2013

  • Mahmoud, Mahmoud A.; Narayanan, Radha; El-Sayed, Mostafa A.
  • Accounts of Chemical Research, Vol. 46, Issue 8
  • DOI: 10.1021/ar3002359

Polystyrene Microspheres: Inactive Supporting Material for Recycling and Recovering Colloidal Nanocatalysts in Solution
journal, November 2009

  • Mahmoud, M. A.; Snyder, B.; El-Sayed, M. A.
  • The Journal of Physical Chemistry Letters, Vol. 1, Issue 1
  • DOI: 10.1021/jz9000449

Sum Frequency Generation and Catalytic Reaction Studies of the Removal of Organic Capping Agents from Pt Nanoparticles by UV−Ozone Treatment
journal, February 2009

  • Aliaga, Cesar; Park, Jeong Y.; Yamada, Yusuke
  • The Journal of Physical Chemistry C, Vol. 113, Issue 15, p. 6150-6155
  • DOI: 10.1021/jp8108946

Controlling the Catalytic Efficiency on the Surface of Hollow Gold Nanoparticles by Introducing an Inner Thin Layer of Platinum or Palladium
journal, November 2014

  • Mahmoud, Mahmoud A.; Garlyyev, Batyr; El-Sayed, Mostafa A.
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 23
  • DOI: 10.1021/jz502071v

Fabrication of 2-dimensional platinum nanocatalyst arrays by electron beam lithography: ethylene hydrogenation and CO-poisoning reaction studies
journal, October 2006


Platinum Nanoparticle Shape Effects on Benzene Hydrogenation Selectivity
journal, October 2007

  • Bratlie, Kaitlin M.; Lee, Hyunjoo; Komvopoulos, Kyriakos
  • Nano Letters, Vol. 7, Issue 10
  • DOI: 10.1021/nl0716000

Wet Chemical Synthesis of High Aspect Ratio Cylindrical Gold Nanorods
journal, May 2001

  • Jana, Nikhil R.; Gearheart, Latha; Murphy, Catherine J.
  • The Journal of Physical Chemistry B, Vol. 105, Issue 19, p. 4065-4067
  • DOI: 10.1021/jp0107964

Shape-Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics?
journal, December 2008

  • Xia, Younan; Xiong, Yujie; Lim, Byungkwon
  • Angewandte Chemie International Edition, Vol. 48, Issue 1, p. 60-103
  • DOI: 10.1002/anie.200802248

Preparation and Growth Mechanism of Gold Nanorods (NRs) Using Seed-Mediated Growth Method
journal, May 2003

  • Nikoobakht, Babak; El-Sayed, Mostafa A.
  • Chemistry of Materials, Vol. 15, Issue 10
  • DOI: 10.1021/cm020732l

Hollow and Solid Metallic Nanoparticles in Sensing and in Nanocatalysis
journal, September 2013

  • Mahmoud, Mahmoud A.; O’Neil, Daniel; El-Sayed, Mostafa A.
  • Chemistry of Materials, Vol. 26, Issue 1
  • DOI: 10.1021/cm4020892

The effect of plasmon resonance coupling in P3HT-coated silver nanodisk monolayers on their optical sensitivity
journal, January 2016

  • Geldmeier, Jeffrey A.; Mahmoud, Mahmoud A.; Jeon, Ju-Won
  • Journal of Materials Chemistry C, Vol. 4, Issue 41
  • DOI: 10.1039/C6TC01999D

Overgrowth of Silver Nanodisks on a Substrate into Vertically Aligned Nanopillars for Chromatic Light Polarization
journal, August 2016


Stacking Faults in Formation of Silver Nanodisks
journal, August 2003

  • Germain, V.; Li, Jing; Ingert, D.
  • The Journal of Physical Chemistry B, Vol. 107, Issue 34
  • DOI: 10.1021/jp0303826

Solid-State Dewetting of Thin Films
journal, August 2012


Surface plasmon as a probe for melting of silver nanoparticles
journal, December 2009


The Optical Properties of Metal Nanoparticles:  The Influence of Size, Shape, and Dielectric Environment
journal, January 2003

  • Kelly, K. Lance; Coronado, Eduardo; Zhao, Lin Lin
  • The Journal of Physical Chemistry B, Vol. 107, Issue 3
  • DOI: 10.1021/jp026731y

Surface Catalytic Coupling Reaction of p -Mercaptoaniline Linking to Silver Nanostructures Responsible for Abnormal SERS Enhancement: A DFT Study
journal, September 2009

  • Wu, De-Yin; Liu, Xiu-Min; Huang, Yi-Fan
  • The Journal of Physical Chemistry C, Vol. 113, Issue 42
  • DOI: 10.1021/jp9050929

Wavelength-Selective Photocatalysis Using Gold–Platinum Nanorattles
journal, July 2015

  • Mahmoud, Mahmoud A.; Garlyyev, Batyr; El-Sayed, Mostafa A.
  • The Journal of Physical Chemistry C, Vol. 119, Issue 32
  • DOI: 10.1021/acs.jpcc.5b05967

Competition between Reaction and Degradation Pathways in Plasmon-Driven Photochemistry
journal, May 2016

  • Brooks, James L.; Frontiera, Renee R.
  • The Journal of Physical Chemistry C, Vol. 120, Issue 37
  • DOI: 10.1021/acs.jpcc.6b02314

Vibrational Response of Nanorods to Ultrafast Laser Induced Heating:  Theoretical and Experimental Analysis
journal, December 2003

  • Hu, Min; Wang, Xuan; Hartland, Gregory V.
  • Journal of the American Chemical Society, Vol. 125, Issue 48
  • DOI: 10.1021/ja037443y

Molecular Tilting Alignment on Ag@C Nanocubes Monitored by Temperature-Dependent Surface Enhanced Raman Scattering
journal, October 2017


Controlling Catalytic Selectivity on Metal Nanoparticles by Direct Photoexcitation of Adsorbate–Metal Bonds
journal, August 2014

  • Kale, Matthew J.; Avanesian, Talin; Xin, Hongliang
  • Nano Letters, Vol. 14, Issue 9
  • DOI: 10.1021/nl502571b

Enhancement of the Catalytic Activity of Supported Gold Nanoparticles for the Fenton Reaction by Light
journal, February 2011

  • Navalon, Sergio; de Miguel, Maykel; Martin, Roberto
  • Journal of the American Chemical Society, Vol. 133, Issue 7
  • DOI: 10.1021/ja108816p

A Real-Time Surface Enhanced Raman Spectroscopy Study of Plasmonic Photothermal Cell Death Using Targeted Gold Nanoparticles
journal, January 2016

  • Aioub, Mena; El-Sayed, Mostafa A.
  • Journal of the American Chemical Society, Vol. 138, Issue 4
  • DOI: 10.1021/jacs.5b10997

Plasmon-modulated photoluminescence from gold nanostructures and its dependence on plasmon resonance, excitation energy, and band structure
journal, January 2015

  • Ngoc, Loan Le Thi; Wiedemair, Justyna; van den Berg, Albert
  • Optics Express, Vol. 23, Issue 5
  • DOI: 10.1364/OE.23.005547