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Photocatalytic Methanol Oxidation by Supported Vanadium Oxide Species: Influence of Support and Degree of Oligomerization: Photocatalytic Methanol Oxidation by Supported Vanadium Oxide Species: Influence of Support and Degree of Oligomerization

Journal Article · · European Journal of Inorganic Chemistry
 [1];  [2];  [3];  [4];  [4];  [5];  [6]
  1. Heterogene Photokatalyse, Leibniz-Institut für Katalyse e. V. an der Universität Rostock, 18059 Rostock Germany; Lehrstuhl für Technische Chemie, Ruhr-Universität Bochum, 44801 Bochum Germany
  2. Operando Molecular Spectroscopy & Catalysis Lab, Lehigh University, 18015-3128 Bethlehem PA USA
  3. AG Nanobasierte Heterogene Katalysatoren, Max-Planck-Institut für Chemische Energiekonversion, 45470 Mülheim/Ruhr Germany
  4. Werkstoffe der Elektrotechnik, and, Center for Nanointegration Duisburg-Essen (CENIDE), Universität Duisburg-Essen, 47057 Duisburg Germany
  5. Lehrstuhl für Technische Chemie, Ruhr-Universität Bochum, 44801 Bochum Germany
  6. Heterogene Photokatalyse, Leibniz-Institut für Katalyse e. V. an der Universität Rostock, 18059 Rostock Germany

Not provided.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Center for Understanding and Control of Acid Gas-induced Evolution of Materials for Energy (UNCAGE-ME); Georgia Institute of Technology, Atlanta, GA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0012577
OSTI ID:
1537558
Journal Information:
European Journal of Inorganic Chemistry, Vol. 2018, Issue 33; ISSN 1434-1948
Publisher:
ChemPubSoc Europe
Country of Publication:
United States
Language:
English

References (76)

Oxidative dehydrogenation of propane over low-loaded vanadia catalysts: Impact of the support material on kinetics and selectivity June 2008
Anomalous reactivity of supported V2O5 nanoparticles for propane oxidative dehydrogenation: influence of the vanadium oxide precursor January 2013
Effect of Catalyst Structure on Oxidative Dehydrogenation of Ethane and Propane on Alumina-Supported Vanadia May 2002
Mechanistic Studies of Methanol Oxidation to Formaldehyde on Isolated Vanadate Sites Supported on MCM-48 January 2007
Mechanism of selective methanol oxidation over vanadium oxide-titanium oxide catalysts: a FT-IR and flow reactor study September 1987
An experimental and theoretical investigation of the structure and reactivity of bilayered VOx/TiOx/SiO2 catalysts for methanol oxidation March 2010
The dynamic states of silica-supported metal oxide catalysts during methanol oxidation September 1996
In situ IR, Raman, and UV-Vis DRS spectroscopy of supported vanadium oxide catalysts during methanol oxidation January 2000
The origin of the support effect in supported metal oxide catalysts: in situ infrared and kinetic studies during methanol oxidation March 1999
Reactivity of Supported Vanadium Oxide Catalysts: The Partial Oxidation of Methanol April 1994
Molecular structure–reactivity relationships for the oxidation of sulfur dioxide over supported metal oxide catalysts November 1999
Oxidation of sulfur dioxide over supported vanadia catalysts: molecular structure – reactivity relationships and reaction kinetics June 1999
Oxidation of sulfur dioxide over supported solid V2O5/SiO2 and supported molten salt V2O5?Cs2SO4/SiO2 catalysts: molecular structure and reactivity July 2004
Recent conceptual advances in the catalysis science of mixed metal oxide catalytic materials February 2005
Vibrational Spectroscopy of Oxide Overlayers August 2017
Combined Raman and IR study of MO x– V 2 O 5 /Al 2 O 3 (MO x = MoO 3 , WO 3 , NiO, CoO) catalysts under dehydrated conditions January 1996
Molecular structure and reactivity of vanadia-based catalysts for propane oxidative dehydrogenation studied by in situ Raman spectroscopy and catalytic activity measurements March 2004
Oxidative dehydrogenation of propane on V2O5/Al2O3 and V2O5/TiO2 catalysts: understanding the effect of support by parameter estimation June 2004
Mechanistic Studies of Methanol Oxidation to Formaldehyde on Isolated Vanadate Sites Supported on High Surface Area Zirconia March 2008
A Theoretical Investigation of the Selective Oxidation of Methanol to Formaldehyde on Isolated Vanadate Species Supported on Titania August 2008
Catalysis science of supported vanadium oxide catalysts January 2013
High-Visible-Light Photoactivity of Plasma-Promoted Vanadium Clusters on Nanozeolites for Partial Photooxidation of Methanol May 2017
Proof of Equivalent Catalytic Functionality upon Photon-Induced and Thermal Activation of Supported Isolated Vanadia Species in Methanol Oxidation April 2018
Effect of water vapor on the molecular structures of supported vanadium oxide catalysts at elevated temperatures July 1996
Acidic properties of alumina-supported metal oxide catalysts: an infrared spectroscopy study June 1992
Quantitative Determination of the Speciation of Surface Vanadium Oxides and Their Catalytic Activity May 2006
In Situ Spectroscopic Investigation of the Molecular and Electronic Structures of SiO 2 Supported Surface Metal Oxides October 2007
Hydrolysis of Metal Ions March 2016
Oxygen chemisorption and laser Raman spectroscopy of unsupported and silica-supported vanadium oxide catalysts September 1989
Structure and properties of vanadium oxide-zirconia catalysts for propane oxidative dehydrogenation July 1998
In Situ Spectroscopic Investigation of Molecular Structures of Highly Dispersed Vanadium Oxide on Silica under Various Conditions December 1998
Tuning the Acid/Base and Structural Properties of Titanate-Loaded Mesoporous Silica by Grafting of Zinc Oxide June 2012
Predicting molecular structures of surface metal oxide species on oxide supports under ambient conditions July 1991
Bonding states of surface vanadium(V) oxide phases on silica: structural characterization by vanadium-51 NMR and Raman spectroscopy August 1993
The mechanism for the controlled synthesis of highly dispersed vanadia supported on silica SBA-15 October 2006
Investigation of Silica-Supported Vanadium Oxide Catalysts by High-Field 51 V Magic-Angle Spinning NMR March 2017
Investigation of Surface Structures of Supported Vanadium Oxide Catalysts by UV−vis−NIR Diffuse Reflectance Spectroscopy February 2000
Structural Characteristics and Reactivity Properties of Highly Dispersed Al2O3/SiO2 and V2O5/Al2O3/SiO2 Catalysts May 2000
Oxidative dehydrogenation of propane over V/MCM-41 catalysts: comparison of O2 and N2O as oxidants August 2005
The influence of water on the dispersion of vanadia supported on silica SBA-15 December 2006
Structural Characteristics and Reactivity/Reducibility Properties of Dispersed and Bilayered V 2 O 5 /TiO 2 /SiO 2 Catalysts January 1999
Structure and Catalytic Properties of VOx/MCM Materials for the Partial Oxidation of Methane to Formaldehyde April 2000
The Influence of Water on the Dispersion of Vanadia Supported on Silica SBA-15:  A Combined XPS and Raman Study July 2007
Vanadium oxide nanostructures on another oxide: The viewpoint from model catalysts studies October 2015
Resolving the Atomic Structure of Vanadia Monolayer Catalysts: Monomers, Trimers, and Oligomers on Ceria October 2009
Resolving the Atomic Structure of Vanadia Monolayer Catalysts: Monomers, Trimers, and Oligomers on Ceria October 2009
Formaldehyde Formation on Vanadium Oxide Surfaces V 2 O 3 (0001) and V 2 O 5 (001): How does the Stable Methoxy Intermediate Form? May 2009
Formaldehydbildung auf den Vanadiumoxidoberflächen V 2 O 3 (0001) und V 2 O 5 (001): Wie bildet sich der stabile Methoxy-Zwischenzustand? May 2009
Study of the oxyvanadium constellation in transition-state-analog complexes of phosphoglucomutase and ribonuclease. Structural deductions from electron-transfer spectra March 1990
Spectroscopic Characterization of Highly Dispersed Vanadia Supported on SBA-15 July 2004
Structure of Isolated Vanadia and Titania: A Deep UV Raman, UV–Vis, and IR Spectroscopic Study January 2016
Supported Vanadium Oxide Catalysts: Quantitative Spectroscopy, Preferential Adsorption of V 4+/5+ , and Al 2 O 3 Coating of Zeolite Y October 1998
Structural Determination of Bulk and Surface Tungsten Oxides with UV−vis Diffuse Reflectance Spectroscopy and Raman Spectroscopy September 2007
Oxidative dehydrogenation of ethane to ethylene over alumina-supported vanadium oxide catalysts: Relationship between molecular structures and chemical reactivity December 2006
Influence of oxygen partial pressure on the optical properties of electron beam evaporated vanadium pentoxide thin films May 1998
The Origin of the Ligand Effect in Metal Oxide Catalysts: Novel Fixed-Bed in Situ Infrared and Kinetic Studies during Methanol Oxidation October 2001
Quantification of Active Sites for the Determination of Methanol Oxidation Turn-over Frequencies Using Methanol Chemisorption and in Situ Infrared Techniques. 1. Supported Metal Oxide Catalysts October 2001
Anharmonicity of CH3 deformation vibrations and Fermi resonance between the symmetrical CH3 stretching mode and overtones of CH3 deformation vibrations November 1972
Infrared studies of reactions on oxide surfaces. 6. Active sites on dehydroxylated silica for the chemisorption of ammonia and water August 1976
On the mechanism of methanol oxidation over vanadia-based catalysts: a FT-IR study of the adsorption of methanol, formaldehyde and formic acid on vanad March 1989
Monolayer V2O5/TiO2 and MoO3/TiO2 catalysts prepared by different methods January 1991
In situ laser Raman spectroscopy of supported metal oxides November 1984
Surface oxide-support interaction (SOSI) for surface redox sites May 1991
High resolution vibrational spectroscopy of CO on Ru(001): The importance of lateral interactions March 1980
The influence of lateral interactions on the vibrational spectrum of adsorbed CO March 1979
Reaction-Induced Spreading of Metal Oxides onto Surfaces of Oxide Supports during Alcohol Oxidation:  Phenomenon, Nature, and Mechanisms February 1999
In Situ Raman Spectroscopy of SiO 2 -Supported Transition Metal Oxide Catalysts:  An Isotopic 18 O− 16 O Exchange Study April 2008
Solid-state vanadium-51 NMR structural studies on supported vanadium(V) oxide catalysts: vanadium oxide surface layers on alumina and titania supports September 1989
Adsorption of alcohols on alumina. 1. Gravimetric and infrared spectroscopic investigation June 1978
Microcalorimetric and Fourier transform infrared spectroscopic studies of methanol adsorption on alumina December 1985
Infrared studies of the reactive adsorption of organic molecules over metal oxides and of the mechanisms of their heterogeneously-catalyzed oxidation February 1996
Infrared spectrometric studies of the surface basicity of metal oxides and zeolites using adsorbed probe molecules February 1996
Mechanistic aspects of the selective catalytic reduction of NOx by dimethyl ether and methanol over γ-Al2O3 December 2010
The Application of Diffuse Reflectance Infrared Spectroscopy and Temperature-Programmed Desorption To Investigate the Interaction of Methanol on η-Alumina November 2005
Infrared Study of the Adsorption of Methanol and Ethanol on Aluminum Oxide November 1962
Infrared spectroscopic identification of species arising from reactive adsorption of carbon oxides on metal oxide surfaces January 1982