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Title: Oxidatively-Stable Linear Poly(propylenimine)-Containing Adsorbents for CO 2 Capture from Ultradilute Streams

Abstract

Not provided.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]
  1. School of Chemical &, Biomolecular EngineeringGeorgia Institute of Technology 311 Ferst Drive Atlanta GA 30332 USA
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Understanding and Control of Acid Gas-induced Evolution of Materials for Energy (UNCAGE-ME); Georgia Inst. of Technology, Atlanta, GA (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1537543
DOE Contract Number:  
SC0012577
Resource Type:
Journal Article
Journal Name:
ChemSusChem
Additional Journal Information:
Journal Volume: 11; Journal Issue: 15; Journal ID: ISSN 1864-5631
Publisher:
ChemPubSoc Europe
Country of Publication:
United States
Language:
English
Subject:
Chemistry; Science & Technology - Other Topics

Citation Formats

Pang, Simon H., Lively, Ryan P., and Jones, Christopher W. Oxidatively-Stable Linear Poly(propylenimine)-Containing Adsorbents for CO 2 Capture from Ultradilute Streams. United States: N. p., 2018. Web. doi:10.1002/cssc.201800438.
Pang, Simon H., Lively, Ryan P., & Jones, Christopher W. Oxidatively-Stable Linear Poly(propylenimine)-Containing Adsorbents for CO 2 Capture from Ultradilute Streams. United States. doi:10.1002/cssc.201800438.
Pang, Simon H., Lively, Ryan P., and Jones, Christopher W. Mon . "Oxidatively-Stable Linear Poly(propylenimine)-Containing Adsorbents for CO 2 Capture from Ultradilute Streams". United States. doi:10.1002/cssc.201800438.
@article{osti_1537543,
title = {Oxidatively-Stable Linear Poly(propylenimine)-Containing Adsorbents for CO 2 Capture from Ultradilute Streams},
author = {Pang, Simon H. and Lively, Ryan P. and Jones, Christopher W.},
abstractNote = {Not provided.},
doi = {10.1002/cssc.201800438},
journal = {ChemSusChem},
issn = {1864-5631},
number = 15,
volume = 11,
place = {United States},
year = {2018},
month = {7}
}

Works referenced in this record:

Study of Carbon Dioxide Adsorption on Mesoporous Aminopropylsilane-Functionalized Silica and Titania Combining Microcalorimetry and in Situ Infrared Spectroscopy
journal, December 2009

  • Knöfel, Christina; Martin, Céline; Hornebecq, Virginie
  • The Journal of Physical Chemistry C, Vol. 113, Issue 52
  • DOI: 10.1021/jp907054h

Design of Aminopolymer Structure to Enhance Performance and Stability of CO 2 Sorbents: Poly(propylenimine) vs Poly(ethylenimine)
journal, March 2017

  • Pang, Simon H.; Lee, Li-Chen; Sakwa-Novak, Miles A.
  • Journal of the American Chemical Society, Vol. 139, Issue 10
  • DOI: 10.1021/jacs.7b00235

Degradation of amine-supported CO2 adsorbents in the presence of oxygen-containing gases
journal, November 2011

  • Heydari-Gorji, Aliakbar; Belmabkhout, Youssef; Sayari, Abdelhamid
  • Microporous and Mesoporous Materials, Vol. 145, Issue 1-3
  • DOI: 10.1016/j.micromeso.2011.05.010

New Amines for CO 2 Capture. I. Mechanisms of Amine Degradation in the Presence of CO 2
journal, October 2009

  • Lepaumier, Helene; Picq, Dominique; Carrette, Pierre-Louis
  • Industrial & Engineering Chemistry Research, Vol. 48, Issue 20
  • DOI: 10.1021/ie900472x

New Amines for CO 2 Capture. II. Oxidative Degradation Mechanisms
journal, October 2009

  • Lepaumier, Helene; Picq, Dominique; Carrette, Pierre-Louis
  • Industrial & Engineering Chemistry Research, Vol. 48, Issue 20
  • DOI: 10.1021/ie9004749

Carbon Dioxide Capture from the Air Using a Polyamine Based Regenerable Solid Adsorbent
journal, December 2011

  • Goeppert, Alain; Czaun, Miklos; May, Robert B.
  • Journal of the American Chemical Society, Vol. 133, Issue 50, p. 20164-20167
  • DOI: 10.1021/ja2100005

Preparation and characterization of novel CO2 “molecular basket” adsorbents based on polymer-modified mesoporous molecular sieve MCM-41
journal, August 2003


On thermodynamic separation efficiency: Adsorption processes
journal, April 2016

  • Lively, Ryan P.; Realff, Matthew J.
  • AIChE Journal, Vol. 62, Issue 10
  • DOI: 10.1002/aic.15269

Ising Models of Polyprotic Acids and Bases
journal, June 1994

  • Borkovec, Michal; Koper, Ger J. M.
  • The Journal of Physical Chemistry, Vol. 98, Issue 23
  • DOI: 10.1021/j100074a034

Novel Polyethylenimine-Modified Mesoporous Molecular Sieve of MCM-41 Type as High-Capacity Adsorbent for CO2 Capture
journal, November 2002

  • Xu, Xiaochun; Song, Chunshan; Andresen, John M.
  • Energy & Fuels, Vol. 16, Issue 6, p. 1463-1469
  • DOI: 10.1021/ef020058u

Microwave Accelerated Polymerization of 2-Phenyl-5,6-dihydro-4H-1,3-oxazine: Kinetics and Influence of End-Groups on Glass Transition Temperature
journal, August 2006

  • Sinnwell, Sebastian; Ritter, Helmut
  • Macromolecular Rapid Communications, Vol. 27, Issue 16
  • DOI: 10.1002/marc.200600231

Inhibitors of Monoethanolamine Oxidation in CO 2 Capture Processes
journal, October 2014

  • Voice, Alexander K.; Rochelle, Gary T.
  • Industrial & Engineering Chemistry Research, Vol. 53, Issue 42
  • DOI: 10.1021/ie500996z

CO2 capture by solid adsorbents and their applications: current status and new trends
journal, January 2011

  • Wang, Qiang; Luo, Jizhong; Zhong, Ziyi
  • Energy Environ. Sci., Vol. 4, Issue 1
  • DOI: 10.1039/C0EE00064G

New Amines for CO 2 Capture. III. Effect of Alkyl Chain Length between Amine Functions on Polyamines Degradation
journal, May 2010

  • Lepaumier, Helene; Martin, Sandrine; Picq, Dominique
  • Industrial & Engineering Chemistry Research, Vol. 49, Issue 10
  • DOI: 10.1021/ie902006a

Oxidative Degradation of Aminosilica Adsorbents Relevant to Postcombustion CO 2 Capture
journal, May 2011

  • Bollini, Praveen; Choi, Sunho; Drese, Jeffrey H.
  • Energy & Fuels, Vol. 25, Issue 5
  • DOI: 10.1021/ef200140z

Easily Regenerable Solid Adsorbents Based on Polyamines for Carbon Dioxide Capture from the Air
journal, March 2014


Oxidative Degradation of Monoethanolamine
journal, August 2002

  • Chi, Susan; Rochelle, Gary T.
  • Industrial & Engineering Chemistry Research, Vol. 41, Issue 17
  • DOI: 10.1021/ie010697c

Applicability of linear polyethylenimine supported on nano-silica for the adsorption of CO 2 from various sources including dry air
journal, January 2015

  • Zhang, Hang; Goeppert, Alain; Prakash, G. K. Surya
  • RSC Advances, Vol. 5, Issue 65
  • DOI: 10.1039/C5RA05428A

Thermal, Oxidative and CO 2 Induced Degradation of Primary Amines Used for CO 2 Capture: Effect of Alkyl Linker on Stability
journal, May 2014

  • Didas, Stephanie A.; Zhu, Rongshun; Brunelli, Nicholas A.
  • The Journal of Physical Chemistry C, Vol. 118, Issue 23
  • DOI: 10.1021/jp5025137

Oxidative Stability of Amino Polymer–Alumina Hybrid Adsorbents for Carbon Dioxide Capture
journal, March 2013

  • Bali, Sumit; Chen, Thomas T.; Chaikittisilp, Watcharop
  • Energy & Fuels, Vol. 27, Issue 3
  • DOI: 10.1021/ef4001067

Linear poly(propylenimine)/lithium triflate as a polymer electrolyte system
journal, May 2008


Preparation, characterization, and antimicrobial property of cotton cellulose fabric grafted with poly (propylene imine) dendrimer
journal, July 2012


Thermal stability of polyethylenimine based carbon dioxide adsorbents and its influence on selection of regeneration strategies
journal, December 2008


Enhanced Adsorption Efficiency through Materials Design for Direct Air Capture over Supported Polyethylenimine
journal, September 2016


Amine-Tethered Solid Adsorbents Coupling High Adsorption Capacity and Regenerability for CO2 Capture From Ambient Air
journal, May 2011

  • Choi, Sunho; Gray, McMahan L.; Jones, Christopher W.
  • ChemSusChem, Vol. 4, Issue 5
  • DOI: 10.1002/cssc.201000355

Direct Capture of CO2 from Ambient Air
journal, August 2016

  • Sanz-Pérez, Eloy S.; Murdock, Christopher R.; Didas, Stephanie A.
  • Chemical Reviews, Vol. 116, Issue 19, p. 11840-11876
  • DOI: 10.1021/acs.chemrev.6b00173

Applications of Pore-Expanded Mesoporous Silica. 2. Development of a High-Capacity, Water-Tolerant Adsorbent for CO 2
journal, October 2005

  • Franchi, Robert S.; Harlick, Peter J. E.; Sayari, Abdelhamid
  • Industrial & Engineering Chemistry Research, Vol. 44, Issue 21
  • DOI: 10.1021/ie0504194

Linking CO 2 Sorption Performance to Polymer Morphology in Aminopolymer/Silica Composites through Neutron Scattering
journal, September 2015

  • Holewinski, Adam; Sakwa-Novak, Miles A.; Jones, Christopher W.
  • Journal of the American Chemical Society, Vol. 137, Issue 36
  • DOI: 10.1021/jacs.5b06823

PIM-1 as a Solution-Processable “Molecular Basket” for CO 2 Capture from Dilute Sources
journal, November 2015


Oxidative degradation of silica-supported polyethylenimine for CO 2 adsorption: insights into the nature of deactivated species
journal, January 2014

  • Ahmadalinezhad, Asieh; Sayari, Abdelhamid
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 4
  • DOI: 10.1039/C3CP53928H

Probing Intramolecular versus Intermolecular CO 2 Adsorption on Amine-Grafted SBA-15
journal, November 2015


Poly(allylamine)–Mesoporous Silica Composite Materials for CO 2 Capture from Simulated Flue Gas or Ambient Air
journal, December 2011

  • Chaikittisilp, Watcharop; Khunsupat, Ratayakorn; Chen, Thomas T.
  • Industrial & Engineering Chemistry Research, Vol. 50, Issue 24
  • DOI: 10.1021/ie201584t

Adsorptive removal of carbon dioxide using polyethyleneimine-loaded mesoporous silica materials
journal, August 2008


Application of Amine-Tethered Solid Sorbents for Direct CO 2 Capture from the Ambient Air
journal, March 2011

  • Choi, Sunho; Drese, Jeffrey H.; Eisenberger, Peter M.
  • Environmental Science & Technology, Vol. 45, Issue 6
  • DOI: 10.1021/es102797w

Role of Amine Structure on Carbon Dioxide Adsorption from Ultradilute Gas Streams such as Ambient Air
journal, July 2012

  • Didas, Stephanie A.; Kulkarni, Ambarish R.; Sholl, David S.
  • ChemSusChem, Vol. 5, Issue 10, p. 2058-2064
  • DOI: 10.1002/cssc.201200196

Thermal, Oxidative, and CO 2 -Induced Degradation of Supported Polyethylenimine Adsorbents
journal, May 2012

  • Heydari-Gorji, Aliakbar; Sayari, Abdelhamid
  • Industrial & Engineering Chemistry Research, Vol. 51, Issue 19
  • DOI: 10.1021/ie3003446

Mesoporous Alumina-Supported Amines as Potential Steam-Stable Adsorbents for Capturing CO 2 from Simulated Flue Gas and Ambient Air
journal, November 2011

  • Chaikittisilp, Watcharop; Kim, Hyung-Ju; Jones, Christopher W.
  • Energy & Fuels, Vol. 25, Issue 11
  • DOI: 10.1021/ef201224v

Post-Grafting Amination of Alkyl Halide-Functionalized Silica for Applications in Catalysis, Adsorption, and 15 N NMR Spectroscopy
journal, February 2015

  • Moschetta, Eric G.; Sakwa-Novak, Miles A.; Greenfield, Jake L.
  • Langmuir, Vol. 31, Issue 7
  • DOI: 10.1021/la5046817

Air as the renewable carbon source of the future: an overview of CO2 capture from the atmosphere
journal, January 2012

  • Goeppert, Alain; Czaun, Miklos; Surya Prakash, G. K.
  • Energy & Environmental Science, Vol. 5, Issue 7
  • DOI: 10.1039/c2ee21586a

Oxidation-stable amine-containing adsorbents for carbon dioxide capture
journal, February 2018


CO 2 Adsorption on Polyethylenimine-Functionalized SBA-15 Mesoporous Silica: Isotherms and Modeling
journal, February 2014

  • Gargiulo, Nicola; Peluso, Antonio; Aprea, Paolo
  • Journal of Chemical & Engineering Data, Vol. 59, Issue 3
  • DOI: 10.1021/je401075p

Adsorbent Materials for Carbon Dioxide Capture from Large Anthropogenic Point Sources
journal, September 2009

  • Choi, Sunho; Drese, Jeffrey H.; Jones, Christopher W.
  • ChemSusChem, Vol. 2, Issue 9, p. 796-854
  • DOI: 10.1002/cssc.200900036

Amine-bearing mesoporous silica for CO2 removal from dry and humid air
journal, June 2010

  • Belmabkhout, Youssef; Serna-Guerrero, Rodrigo; Sayari, Abdelhamid
  • Chemical Engineering Science, Vol. 65, Issue 11
  • DOI: 10.1016/j.ces.2010.02.044

Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011

  • Sumida, Kenji; Rogow, David L.; Mason, Jarad A.
  • Chemical Reviews, Vol. 112, Issue 2, p. 724-781
  • DOI: 10.1021/cr2003272

Mechanisms and Kinetics for Sorption of CO 2 on Bicontinuous Mesoporous Silica Modified with n -Propylamine
journal, September 2011

  • Bacsik, Zoltán; Ahlsten, Nanna; Ziadi, Asraa
  • Langmuir, Vol. 27, Issue 17
  • DOI: 10.1021/la202033p

Adsorption Microcalorimetry of CO 2 in Confined Aminopolymers
journal, December 2016


Modeling adsorption of CO2 on amine-functionalized mesoporous silica. 2: Kinetics and breakthrough curves
journal, July 2010

  • Serna-Guerrero, Rodrigo; Sayari, Abdelhamid
  • Chemical Engineering Journal, Vol. 161, Issue 1-2
  • DOI: 10.1016/j.cej.2010.04.042

CO 2 -Induced Degradation of Amine-Containing Adsorbents: Reaction Products and Pathways
journal, August 2012

  • Sayari, Abdelhamid; Heydari-Gorji, Aliakbar; Yang, Yong
  • Journal of the American Chemical Society, Vol. 134, Issue 33
  • DOI: 10.1021/ja304888a

Mechanism and Kinetics of CO 2 Adsorption on Surface Bonded Amines
journal, February 2015

  • Hahn, Maximilian W.; Steib, Matthias; Jentys, Andreas
  • The Journal of Physical Chemistry C, Vol. 119, Issue 8
  • DOI: 10.1021/jp512001t

Temperature-programmed desorption of CO2 from polyethylenimine-loaded SBA-15 as molecular basket sorbents
journal, October 2012


Influence of Drying Conditions on Amine-Functionalized SBA-15 as Adsorbent of CO2
journal, January 2011


Evaluation of CO2 adsorption dynamics of polymer/silica supported poly(ethylenimine) hollow fiber sorbents in rapid temperature swing adsorption
journal, February 2014

  • Fan, Yanfang; Lively, Ryan P.; Labreche, Ying
  • International Journal of Greenhouse Gas Control, Vol. 21
  • DOI: 10.1016/j.ijggc.2013.11.021

Adsorption of CO 2 on a micro-/mesoporous polyimine modified with tris(2-aminoethyl)amine
journal, January 2015

  • Xu, Chao; Bacsik, Zoltán; Hedin, Niklas
  • Journal of Materials Chemistry A, Vol. 3, Issue 31
  • DOI: 10.1039/C5TA01321F

Important Roles of Enthalpic and Entropic Contributions to CO 2 Capture from Simulated Flue Gas and Ambient Air Using Mesoporous Silica Grafted Amines
journal, September 2014

  • Alkhabbaz, Mustafa A.; Bollini, Praveen; Foo, Guo Shiou
  • Journal of the American Chemical Society, Vol. 136, Issue 38
  • DOI: 10.1021/ja507655x

Metal−Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room Temperature
journal, December 2005

  • Millward, Andrew R.; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 127, Issue 51, p. 17998-17999
  • DOI: 10.1021/ja0570032

Epoxide-functionalization of polyethyleneimine for synthesis of stable carbon dioxide adsorbent in temperature swing adsorption
journal, August 2016

  • Choi, Woosung; Min, Kyungmin; Kim, Chaehoon
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms12640

Elucidation of Surface Species through in Situ FTIR Spectroscopy of Carbon Dioxide Adsorption on Amine-Grafted SBA-15
journal, August 2016


Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg2(dobpdc)
journal, April 2012

  • McDonald, Thomas M.; Lee, Woo Ram; Mason, Jarad A.
  • Journal of the American Chemical Society, Vol. 134, Issue 16, p. 7056-7065
  • DOI: 10.1021/ja300034j

Infrared Study of Strongly and Weakly Adsorbed CO 2 on Fresh and Oxidatively Degraded Amine Sorbents
journal, April 2013

  • Srikanth, Chakravartula S.; Chuang, Steven S. C.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 18
  • DOI: 10.1021/jp311232f

Performance and Properties of a Solid Amine Sorbent for Carbon Dioxide Removal in Space Life Support Applications
journal, March 2001

  • Satyapal, Sunita; Filburn, Tom; Trela, John
  • Energy & Fuels, Vol. 15, Issue 2
  • DOI: 10.1021/ef0002391

Spectroscopic Investigation into Oxidative Degradation of Silica-Supported Amine Sorbents for CO2 Capture
journal, June 2012


Hollow Fiber Adsorbents for CO 2 Removal from Flue Gas
journal, August 2009

  • Lively, Ryan P.; Chance, Ronald R.; Kelley, B. T.
  • Industrial & Engineering Chemistry Research, Vol. 48, Issue 15
  • DOI: 10.1021/ie9005244

Steam Induced Structural Changes of a Poly(ethylenimine) Impregnated γ-Alumina Sorbent for CO 2 Extraction from Ambient Air
journal, June 2014

  • Sakwa-Novak, Miles A.; Jones, Christopher W.
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 12
  • DOI: 10.1021/am501500q

Comprehensive Study of the Impact of Steam on Polyethyleneimine on Silica for CO 2 Capture
journal, October 2013

  • Hammache, Sonia; Hoffman, James S.; Gray, McMahan L.
  • Energy & Fuels, Vol. 27, Issue 11
  • DOI: 10.1021/ef401562w

Thermoresponsive Poly(2-oxazine)s
journal, November 2011

  • Bloksma, Meta M.; Paulus, Renzo M.; van Kuringen, Huub P. C.
  • Macromolecular Rapid Communications, Vol. 33, Issue 1
  • DOI: 10.1002/marc.201100587