skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: The Influence of Chemical Modification on Linker Rotational Dynamics in Metal-Organic Frameworks

Journal Article · · Angewandte Chemie (International Edition)
 [1];  [1];  [2];  [2];  [3]; ORCiD logo [4]
  1. Department of Chemistry, University of Michigan, 930 N. University Ave. Ann Arbor MI 48109-1055 USA
  2. Institut für Physik-NMR, Halle/Saale Germany
  3. Department of Chemistry, University of Michigan, 930 N. University Ave. Ann Arbor MI 48109-1055 USA; Macromolecular Science and Engineering, University of Michigan, 2300 Hayward Avenue Ann Arbor MI 48109-1055 USA
  4. Department of Chemistry, University of Michigan, 930 N. University Ave. Ann Arbor MI 48109-1055 USA; Biophysics Program, University of Michigan, 930 N. University Ave. Ann Arbor MI 48109-1055 USA

Not provided.

Research Organization:
Univ. of Michigan, Ann Arbor, MI (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0004888
OSTI ID:
1537489
Journal Information:
Angewandte Chemie (International Edition), Vol. 57, Issue 28; ISSN 1433-7851
Publisher:
Wiley
Country of Publication:
United States
Language:
English

References (35)

Flexible Metal-Organic Frameworks: Recent Advances and Potential Applications journal August 2015
Control of Molecular Rotor Rotational Frequencies in Porous Coordination Polymers Using a Solid-Solution Approach journal September 2015
Soft porous crystals journal November 2009
Dynamic Motion of Building Blocks in Porous Coordination Polymers journal November 2006
Dynamic Motion of Building Blocks in Porous Coordination Polymers journal November 2006
Enhanced stability and CO2 affinity of a UiO-66 type metal–organic framework decorated with dimethyl groups journal January 2012
Targeted Manipulation of Metal-Organic Frameworks To Direct Sorption Properties journal March 2014
How Linker’s Modification Controls Swelling Properties of Highly Flexible Iron(III) Dicarboxylates MIL-88 journal November 2011
Understanding Intrinsic Light Absorption Properties of UiO-66 Frameworks: A Combined Theoretical and Experimental Study journal November 2015
Flexible metal–organic frameworks journal January 2014
Large breathing effects in three-dimensional porous hybrid matter: facts, analyses, rules and consequences journal January 2009
A Switchable Molecular Rotator: Neutron Spectroscopy Study on a Polymeric Spin-Crossover Compound
  • Rodríguez-Velamazán, J. Alberto; González, Miguel A.; Real, José A.
  • Journal of the American Chemical Society, Vol. 134, Issue 11 https://doi.org/10.1021/ja206228n
journal March 2012
Responsive Metal–Organic Frameworks and Framework Materials: Under Pressure, Taking the Heat, in the Spotlight, with Friends journal February 2015
Thermal modulation of birefringence observed in a crystalline molecular gyrotop journal May 2012
Supramolecular ferroelectrics journal March 2015
Tailoring porosity and rotational dynamics in a series of octacarboxylate metal-organic frameworks journal March 2017
A metal-organic framework-based splitter for separating propylene from propane journal July 2016
Hybrid porous solids past, present, future journal January 2008
Function-led design of new porous materials journal May 2015
Dynamics of Benzene Rings in MIL-53(Cr) and MIL-47(V) Frameworks Studied by 2H NMR Spectroscopy journal May 2010
Dynamics of Benzene Rings in MIL-53(Cr) and MIL-47(V) Frameworks Studied by 2H NMR Spectroscopy journal May 2010
Probing the Dynamics of the Porous Zr Terephthalate UiO-66 Framework Using 2 H NMR and Neutron Scattering journal May 2012
Guest Controlled Rotational Dynamics of Terephthalate Phenylenes in Metal–Organic Framework MIL-53(Al): Effect of Different Xylene Loadings journal July 2014
Fast Molecular Rotor Dynamics Modulated by Guest Inclusion in a Highly Organized Nanoporous Organosilica journal March 2010
Fast Molecular Rotor Dynamics Modulated by Guest Inclusion in a Highly Organized Nanoporous Organosilica journal March 2010
Solid-state NMR: A powerful tool for characterization of metal–organic frameworks journal February 2013
Metal-Cation-Independent Dynamics of Phenylene Ring in Microporous MOFs: A 2 H Solid-State NMR Study journal December 2015
Separated Local Field Spectra in NMR: Determination of Structure of Solids journal May 1976
Site-Resolved Determination of Peptide Torsion Angle φ from the Relative Orientations of Backbone N−H and C−H Bonds by Solid-State NMR journal July 1997
Two-dimensional rotational spin-echo nuclear magnetic resonance in solids: correlation of chemical shift and dipolar interactions journal May 1981
Intermediate motions as studied by solid-state separated local field NMR experiments journal March 2008
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
  • Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni
  • Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851 https://doi.org/10.1021/ja8057953
journal October 2008
A simple analytical model to describe dynamic magic-angle spinning experiments journal January 2006
Amphidynamic Character of Crystalline MOF-5: Rotational Dynamics of Terephthalate Phenylenes in a Free-Volume, Sterically Unhindered Environment
  • Gould, Stephanie L.; Tranchemontagne, David; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 130, Issue 11, p. 3246-3247 https://doi.org/10.1021/ja077122c
journal March 2008
Reticular synthesis and the design of new materials journal June 2003

Similar Records

Solvent Choice in Metal–Organic Framework Linker Exchange Permits Microstructural Control
Journal Article · Wed Nov 25 00:00:00 EST 2020 · Journal of the American Chemical Society · OSTI ID:1537489

Reagent Reactivity and Solvent Choice Determine Metal–Organic Framework Microstructure during Postsynthetic Modification
Journal Article · Thu Dec 31 00:00:00 EST 2020 · Journal of the American Chemical Society · OSTI ID:1537489

Cooperative Sieving and Functionalization of Zr Metal–Organic Frameworks through Insertion and Post-Modification of Auxiliary Linkers
Journal Article · Tue Apr 30 00:00:00 EDT 2019 · ACS Applied Materials and Interfaces · OSTI ID:1537489

Related Subjects