A Scandium-Stabilized Diisophosphaethynolate Ligand: [OCPPCO] 4-

Grant, Lauren N.; Pinter, Balazs; Manor, Brian C.; Grützmacher, Hansjörg; Mindiola, Daniel J.

doi:10.1002/anie.201710757

A Scandium-Stabilized Diisophosphaethynolate Ligand: [OCPPCO] ^4-

Journal Article · 21 December 2017 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201710757· OSTI ID:1537464

^[1]; Pinter, Balazs ^[2]; Manor, Brian C. ^[1]; Grützmacher, Hansjörg ^[3]; ^[1]

Department of Chemistry, University of Pennsylvania, Philadelphia PA 19104 USA
Department of General Chemistry, Vrije Universiteit Brussel, Pleinlaan 2 1050 Brussels Belgium
Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog Weg 1, Hönggerberg 8093 Zürich Switzerland

Not provided.

Research Organization:: Indiana Univ., Bloomington, IN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: FG02-07ER15893

OSTI ID:: 1537464

Journal Information:: Angewandte Chemie (International Edition), Vol. 57, Issue 4; ISSN 1433-7851

Publisher:: Wiley

Country of Publication:: United States

Language:: English

References (22)

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Does Diisooxocyan (OCN−NCO) Exist? Schulz, Axel; Klapötke, Thomas M. Inorganic Chemistry, Vol. 35, Issue 16 https://doi.org/10.1021/ic960049z	journal	January 1996
The 2-Phosphaethynolate Anion: A Convenient Synthesis and [2+2] Cycloaddition Chemistry Jupp, Andrew R.; Goicoechea, Jose M. Angewandte Chemie International Edition, Vol. 52, Issue 38 https://doi.org/10.1002/anie.201305235	journal	August 2013
Phosphanierung von Kohlenmonoxid: eine einfache Synthese von Natriumphosphaethinolat (NaOCP) Puschmann, Florian Frank; Stein, Daniel; Heift, Dominikus Angewandte Chemie, Vol. 123, Issue 36 https://doi.org/10.1002/ange.201102930	journal	July 2011
Phosphideinbau in ein Cyclotrisilen Robinson, Thomas P.; Cowley, Michael J.; Scheschkewitz, David Angewandte Chemie, Vol. 127, Issue 2 https://doi.org/10.1002/ange.201409908	journal	November 2014
Unexpected Photodegradation of a Phosphaketenyl-Substituted Germyliumylidene Borate Complex Xiong, Yun; Yao, Shenglai; Szilvási, Tibor Angewandte Chemie, Vol. 129, Issue 15 https://doi.org/10.1002/ange.201701337	journal	March 2017
The 2-Phosphaethynolate Anion: A Convenient Synthesis and [2+2] Cycloaddition Chemistry Jupp, Andrew R.; Goicoechea, Jose M. Angewandte Chemie, Vol. 125, Issue 38 https://doi.org/10.1002/ange.201305235	journal	August 2013
Synthesis of P ₂ C ₂ O ₂ and P ₂ CO via NHC-mediated coupling of the phosphaethynolate anion Gilliard, Robert J.; Suter, Riccardo; Schrader, Erik Chemical Communications, Vol. 53, Issue 91 https://doi.org/10.1039/C7CC07654A	journal	January 2017
Spectroscopic Characterization, Computational Investigation, and Comparisons of ECX ^– (E = As, P, and N; X = S and O) Anions Hou, Gao-Lei; Chen, Bo; Transue, Wesley J. Journal of the American Chemical Society, Vol. 139, Issue 26 https://doi.org/10.1021/jacs.7b02984	journal	June 2017
A Planar Ti ₂ P ₂ Core Assembled by Reductive Decarbonylation of ⁻ O−C≡P and P−P Radical Coupling Grant, Lauren N.; Pinter, Balazs; Manor, Brian C. Chemistry - A European Journal, Vol. 23, Issue 26 https://doi.org/10.1002/chem.201701054	journal	April 2017
From a Phosphaketenyl-Functionalized Germylene to 1,3-Digerma-2,4-diphosphacyclobutadiene Yao, Shenglai; Xiong, Yun; Szilvási, Tibor Angewandte Chemie, Vol. 128, Issue 15 https://doi.org/10.1002/ange.201600701	journal	March 2016
Synthesis and Characterization of Terminal [Re(XCO)(CO) ₂ (triphos)] (X=N, P): Isocyanate versus Phosphaethynolate Complexes Alidori, Simone; Heift, Dominikus; Santiso-Quinones, Gustavo Chemistry - A European Journal, Vol. 18, Issue 46 https://doi.org/10.1002/chem.201202590	journal	September 2012
Uranium and thorium complexes of the phosphaethynolate ion Camp, Clément; Settineri, Nicholas; Lefèvre, Julia Chemical Science, Vol. 6, Issue 11 https://doi.org/10.1039/C5SC02150B	journal	January 2015
Phosphination of Carbon Monoxide: A Simple Synthesis of Sodium Phosphaethynolate (NaOCP) Puschmann, Florian Frank; Stein, Daniel; Heift, Dominikus Angewandte Chemie International Edition, Vol. 50, Issue 36 https://doi.org/10.1002/anie.201102930	journal	July 2011
Unexpected Photodegradation of a Phosphaketenyl-Substituted Germyliumylidene Borate Complex Xiong, Yun; Yao, Shenglai; Szilvási, Tibor Angewandte Chemie International Edition, Vol. 56, Issue 15 https://doi.org/10.1002/anie.201701337	journal	March 2017
Formation of a Uranium-Bound η ¹ -Cyaphide (CP ^– ) Ligand via Activation and C–O Bond Cleavage of Phosphaethynolate (OCP ^– ) Hoerger, Christopher J.; Heinemann, Frank W.; Louyriac, Elisa Organometallics, Vol. 36, Issue 22 https://doi.org/10.1021/acs.organomet.7b00590	journal	October 2017
A nucleophilic niobium(V) nitride prepared by isocyanate decarbonylation G. Fickes, Michael; L. Odom, Aaron; C. Cummins, Christopher Chemical Communications, Issue 20 https://doi.org/10.1039/a704253a	journal	January 1997
From a Phosphaketenyl-Functionalized Germylene to 1,3-Digerma-2,4-diphosphacyclobutadiene Yao, Shenglai; Xiong, Yun; Szilvási, Tibor Angewandte Chemie International Edition, Vol. 55, Issue 15 https://doi.org/10.1002/anie.201600701	journal	March 2016
Phosphide Delivery to a Cyclotrisilene Robinson, Thomas P.; Cowley, Michael J.; Scheschkewitz, David Angewandte Chemie International Edition, Vol. 54, Issue 2 https://doi.org/10.1002/anie.201409908	journal	November 2014
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Isolation of Au-, Co-η ¹ PCO and Cu-η ² PCO complexes, conversion of an Ir–η ¹ PCO complex into a dimetalladiphosphene, and an interaction-free PCO anion Liu, Liu; Ruiz, David A.; Dahcheh, Fatme Chemical Science, Vol. 7, Issue 3 https://doi.org/10.1039/C5SC04504E	journal	January 2016
Isolation of a Heavier Cyclobutadiene Analogue: 2,4-Digerma-1,3-diphosphacyclobutadiene Wu, Yile; Liu, Liu; Su, Jue Organometallics, Vol. 35, Issue 11 https://doi.org/10.1021/acs.organomet.6b00187	journal	May 2016

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