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Title: Selective C-H Bond Cleavage in Methane by Small Gold Clusters

Journal Article · · Angewandte Chemie (International Edition)
ORCiD logo [1];  [1];  [2]; ORCiD logo [2];  [3]; ORCiD logo [3]
  1. Institute of Surface Chemistry and Catalysis, University of Ulm, Albert-Einstein-Allee 47 89069 Ulm Germany
  2. Institute for Molecules and Materials, FELIX Laboratory, Radboud University, 6525 ED Nijmegen The Netherlands
  3. School of Physics, Georgia Institute of Technology, Atlanta GA 30332-0430 USA

Not provided.

Research Organization:
Georgia Institute of Technology, Atlanta, GA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
FG05-86ER45234
OSTI ID:
1537446
Journal Information:
Angewandte Chemie (International Edition), Vol. 56, Issue 43; ISSN 1433-7851
Publisher:
Wiley
Country of Publication:
United States
Language:
English

References (42)

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Additivity Effects in the Reactivities of Bimetallic Cluster Ions PtmAun+ journal November 2003
Organometallic alkane CH activation journal November 2004
Activation of methane by gold cations: Guided ion beam and theoretical studies journal October 2006
Catalytic Pt + -Mediated Oxidation of Methane by Molecular Oxygen in the Gas Phase journal June 1994
Size-Dependent Binding Energies of Methane to Small Gold Clusters journal May 2010
On the Origin of Room-temperature, Au + -mediated Coupling of a Methylene Ligand with H 2 . Implications for the Mechanism of Methane Dehydrogenation. journal March 2016
Structures of the Dehydrogenation Products of Methane Activation by 5d Transition Metal Cations journal May 2013
Bonding in Cu, Ag, and Au Clusters: Relativistic Effects, Trends, and Surprises journal June 2002
Selective Intermolecular Carbon-Hydrogen Bond Activation by Synthetic Metal Complexes in Homogeneous Solution journal March 1995
Unexpected Mechanistic Variants in the Thermal Gas-Phase Activation of Methane journal June 2016
Born-Oppenheimer molecular-dynamics simulations of finite systems: Structure and dynamics of ( H 2 O ) 2 journal July 1993
Activation of C–H Bonds in Pt + + x CH 4 Reactions, where x = 1–4: Identification of the Platinum Dimethyl Cation journal August 2016
Chemie mit Methan: Studieren geht über Probieren! journal June 2011
Gold clusters: reactions and deuterium uptake journal March 1991
Gasphasenkatalyse mit atomaren und Cluster-Metall-Ionen: ultimative “Single-Site”-Katalysatoren journal March 2005
Structure characterization of metal oxide clusters by vibrational spectroscopy: possibilities and prospects journal January 2012
Activation of Methane by Gas-Phase Rh+ journal July 1995
Methane Activation by 5 d Transition Metals: Energetics, Mechanisms, and Periodic Trends journal July 2016
Katalytische, PtI-vermittelte Oxidation von Methan mit molekularem Sauerstoff in der Gasphase journal June 1994
Intensity-resolved IR multiple photon ionization and fragmentation of C60 journal February 2010
Potential Energy Surface for Activation of Methane by Pt + :  A Combined Guided Ion Beam and DFT Study journal June 2001
Dehydrogenation of Simple Hydrocarbons on Platinum Cluster Ions journal November 2002
Complementary Active Sites Cause Size-Selective Reactivity of Aluminum Cluster Anions with Water journal January 2009
Bond Dissociation Energies of Organic Molecules journal April 2003
The Platinum Hydrido-Methyl Complex:  A Frozen Reaction Intermediate? journal October 1999
Temperature-Tunable Selective Methane Catalysis on Au 2 + : From Cryogenic Partial Oxidation Yielding Formaldehyde to Cold Ethylene Production journal March 2011
Reactions of Atomic Cations with Methane: Gas Phase Room-Temperature Kinetics and Periodicities in Reactivity journal May 2009
CH- and NH-activation by gaseous Rh2+ and PtRh+ cluster ions journal September 2004
Methanaktivierung und katalytische Ethylenbildung an freiem Au 2 + journal January 2010
Gas-Phase Catalysis by Atomic and Cluster Metal Ions: The Ultimate Single-Site Catalysts journal March 2005
Methane activation by rhodium cluster argon complexes journal April 1997
Chemistry with Methane: Concepts Rather than Recipes journal June 2011
Activation of methane and methane-d4 by ionic platinum clusters journal August 2006
Gas phase metal cluster model systems for heterogeneous catalysis journal January 2012
Methane activation by platinum cluster ions in the gas phase: effects of cluster charge on the Pt4 tetramer journal March 2000
Methane oligomerization in the gas phase by third-row transition-metal ions journal March 1991
Efficient pseudopotentials for plane-wave calculations journal January 1991
Pt+-mediated activation of methane: theory and experiment journal June 1995

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