Realizing Efficient Lead-Free Formamidinium Tin Triiodide Perovskite Solar Cells via a Sequential Deposition Route

Zhu, Zonglong; Chueh, Chu-Chen; Li, Nan; Mao, Chengyi; Jen, Alex K. -Y.

doi:10.1002/adma.201703800

Realizing Efficient Lead-Free Formamidinium Tin Triiodide Perovskite Solar Cells via a Sequential Deposition Route

Journal Article · 18 December 2017 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201703800· OSTI ID:1537363

^[1]; Chueh, Chu-Chen ^[2]; Li, Nan ^[3]; Mao, Chengyi ^[4]; Jen, Alex K. -Y. ^[5]

Department of Materials Science and Engineering and Department of Chemistry, University of Washington, Seattle WA 98195-2120 USA; DOE/OSTI
Department of Materials Science and Engineering and Department of Chemistry, University of Washington, Seattle WA 98195-2120 USA; Department of Chemical Engineering, National Taiwan University, Taipei 106 Taiwan
Department of Materials Science and Engineering and Department of Chemistry, University of Washington, Seattle WA 98195-2120 USA; Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084 China
Department of Materials Science and Engineering and Department of Chemistry, University of Washington, Seattle WA 98195-2120 USA
Department of Materials Science and Engineering and Department of Chemistry, University of Washington, Seattle WA 98195-2120 USA; Department of Chemistry, City University of Hong Kong, Kowloon Hong Kong

Not provided.

Research Organization:: Univ. of Washington, Seattle, WA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

DOE Contract Number:: EE0006710;

OSTI ID:: 1537363

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 6 Vol. 30; ISSN 0935-9648

Publisher:: Wiley

Country of Publication:: United States

Language:: English

References (66)

Control of Ambipolar and Unipolar Transport in Organic Transistors by Selective Inkjet-Printed Chemical Doping for High Performance Complementary Circuits Khim, Dongyoon; Baeg, Kang-Jun; Caironi, Mario Advanced Functional Materials, Vol. 24, Issue 40 https://doi.org/10.1002/adfm.201400850	journal	August 2014
Organic Cation-Dependent Degradation Mechanism of Organotin Halide Perovskites Wang, Feng; Ma, Jiale; Xie, Fangyan Advanced Functional Materials, Vol. 26, Issue 20 https://doi.org/10.1002/adfm.201505127	journal	March 2016
High Mobility N-Type Transistors Based on Solution-Sheared Doped 6,13-Bis(triisopropylsilylethynyl)pentacene Thin Films Naab, Benjamin D.; Himmelberger, Scott; Diao, Ying Advanced Materials, Vol. 25, Issue 33 https://doi.org/10.1002/adma.201205098	journal	July 2013
Doping of Fullerenes via Anion-Induced Electron Transfer and Its Implication for Surfactant Facilitated High Performance Polymer Solar Cells Li, Chang-Zhi; Chueh, Chu-Chen; Ding, Feizhi Advanced Materials, Vol. 25, Issue 32 https://doi.org/10.1002/adma.201300580	journal	June 2013
Additive Enhanced Crystallization of Solution-Processed Perovskite for Highly Efficient Planar-Heterojunction Solar Cells Liang, Po-Wei; Liao, Chien-Yi; Chueh, Chu-Chen Advanced Materials, Vol. 26, Issue 22, p. 3748-3754 https://doi.org/10.1002/adma.201400231	journal	March 2014
Binary-Metal Perovskites Toward High-Performance Planar-Heterojunction Hybrid Solar Cells Zuo, Fan; Williams, Spencer T.; Liang, Po-Wei Advanced Materials, Vol. 26, Issue 37 https://doi.org/10.1002/adma.201401641	journal	August 2014
Lead-Free Halide Perovskite Solar Cells with High Photocurrents Realized Through Vacancy Modulation Kumar, Mulmudi Hemant; Dharani, Sabba; Leong, Wei Lin Advanced Materials, Vol. 26, Issue 41 https://doi.org/10.1002/adma.201401991	journal	September 2014
Suppressed Charge Recombination in Inverted Organic Photovoltaics via Enhanced Charge Extraction by Using a Conductive Fullerene Electron Transport Layer Li, Chang-Zhi; Chang, Chih-Yu; Zang, Yue Advanced Materials, Vol. 26, Issue 36 https://doi.org/10.1002/adma.201402276	journal	August 2014
Toward Large Scale Roll-to-Roll Production of Fully Printed Perovskite Solar Cells Hwang, Kyeongil; Jung, Yen-Sook; Heo, Youn-Jung Advanced Materials, Vol. 27, Issue 7 https://doi.org/10.1002/adma.201404598	journal	January 2015
Enhanced Efficiency and Stability of Inverted Perovskite Solar Cells Using Highly Crystalline SnO ₂ Nanocrystals as the Robust Electron-Transporting Layer Zhu, Zonglong; Bai, Yang; Liu, Xiao Advanced Materials, Vol. 28, Issue 30 https://doi.org/10.1002/adma.201600619	journal	May 2016
Solution-Processed Tin-Based Perovskite for Near-Infrared Lasing Xing, Guichuan; Kumar, Mulmudi Hemant; Chong, Wee Kiang Advanced Materials, Vol. 28, Issue 37 https://doi.org/10.1002/adma.201601418	journal	July 2016
Stable Low-Bandgap Pb-Sn Binary Perovskites for Tandem Solar Cells Yang, Zhibin; Rajagopal, Adharsh; Chueh, Chu-Chen Advanced Materials, Vol. 28, Issue 40 https://doi.org/10.1002/adma.201602696	journal	August 2016
Lead-Free Inverted Planar Formamidinium Tin Triiodide Perovskite Solar Cells Achieving Power Conversion Efficiencies up to 6.22% Liao, Weiqiang; Zhao, Dewei; Yu, Yue Advanced Materials, Vol. 28, Issue 42 https://doi.org/10.1002/adma.201602992	journal	August 2016
Multichannel Interdiffusion Driven FASnI ₃ Film Formation Using Aqueous Hybrid Salt/Polymer Solutions toward Flexible Lead-Free Perovskite Solar Cells Xi, Jun; Wu, Zhaoxin; Jiao, Bo Advanced Materials, Vol. 29, Issue 23 https://doi.org/10.1002/adma.201606964	journal	April 2017
Stability of Metal Halide Perovskite Solar Cells Leijtens, Tomas; Eperon, Giles E.; Noel, Nakita K. Advanced Energy Materials, Vol. 5, Issue 20 https://doi.org/10.1002/aenm.201500963	journal	September 2015
Heterojunction-Depleted Lead-Free Perovskite Solar Cells with Coarse-Grained B-γ-CsSnI ₃ Thin Films Wang, Ning; Zhou, Yuanyuan; Ju, Ming-Gang Advanced Energy Materials, Vol. 6, Issue 24 https://doi.org/10.1002/aenm.201601130	journal	September 2016
Mixed Cation FA _x PEA _1- _x PbI ₃ with Enhanced Phase and Ambient Stability toward High-Performance Perovskite Solar Cells Li, Nan; Zhu, Zonglong; Chueh, Chu-Chen Advanced Energy Materials, Vol. 7, Issue 1 https://doi.org/10.1002/aenm.201601307	journal	September 2016
50% Sn-Based Planar Perovskite Solar Cell with Power Conversion Efficiency up to 13.6% Li, Yunlong; Sun, Weihai; Yan, Weibo Advanced Energy Materials, Vol. 6, Issue 24 https://doi.org/10.1002/aenm.201601353	journal	August 2016
Formation of Hybrid Perovskite Tin Iodide Single Crystals by Top-Seeded Solution Growth Dang, Yangyang; Zhou, Yian; Liu, Xiaolong Angewandte Chemie International Edition, Vol. 55, Issue 10 https://doi.org/10.1002/anie.201511792	journal	February 2016
Perovskite Solar Cells: From Materials to Devices Jung, Hyun Suk; Park, Nam-Gyu Small, Vol. 11, Issue 1 https://doi.org/10.1002/smll.201402767	journal	October 2014
Thermal change of SnI2 thin films. Part 3. Isothermal change under light radiation Sawada, Y.; Suzuki, M. Thermochimica Acta, Vol. 243, Issue 1 https://doi.org/10.1016/0040-6031(94)85042-9	journal	September 1994
The Renaissance of Halide Perovskites and Their Evolution as Emerging Semiconductors Stoumpos, Constantinos C.; Kanatzidis, Mercouri G. Accounts of Chemical Research, Vol. 48, Issue 10 https://doi.org/10.1021/acs.accounts.5b00229	journal	September 2015
Hybrid Perovskites for Photovoltaics: Charge-Carrier Recombination, Diffusion, and Radiative Efficiencies Johnston, Michael B.; Herz, Laura M. Accounts of Chemical Research, Vol. 49, Issue 1 https://doi.org/10.1021/acs.accounts.5b00411	journal	December 2015
Lewis Acid–Base Adduct Approach for High Efficiency Perovskite Solar Cells Lee, Jin-Wook; Kim, Hui-Seon; Park, Nam-Gyu Accounts of Chemical Research, Vol. 49, Issue 2 https://doi.org/10.1021/acs.accounts.5b00440	journal	January 2016
Making and Breaking of Lead Halide Perovskites Manser, Joseph S.; Saidaminov, Makhsud I.; Christians, Jeffrey A. Accounts of Chemical Research, Vol. 49, Issue 2 https://doi.org/10.1021/acs.accounts.5b00455	journal	January 2016
A Long-Term View on Perovskite Optoelectronics Docampo, Pablo; Bein, Thomas Accounts of Chemical Research, Vol. 49, Issue 2 https://doi.org/10.1021/acs.accounts.5b00465	journal	January 2016
Current Challenges and Prospective Research for Upscaling Hybrid Perovskite Photovoltaics Williams, Spencer T.; Rajagopal, Adharsh; Chueh, Chu-Chen The Journal of Physical Chemistry Letters, Vol. 7, Issue 5 https://doi.org/10.1021/acs.jpclett.5b02651	journal	February 2016
Overcoming Short-Circuit in Lead-Free CH ₃ NH ₃ SnI ₃ Perovskite Solar Cells via Kinetically Controlled Gas–Solid Reaction Film Fabrication Process Yokoyama, Takamichi; Cao, Duyen H.; Stoumpos, Constantinos C. The Journal of Physical Chemistry Letters, Vol. 7, Issue 5 https://doi.org/10.1021/acs.jpclett.6b00118	journal	February 2016
Effect of Structural Phase Transition on Charge-Carrier Lifetimes and Defects in CH ₃ NH ₃ SnI ₃ Perovskite Parrott, Elizabeth S.; Milot, Rebecca L.; Stergiopoulos, Thomas The Journal of Physical Chemistry Letters, Vol. 7, Issue 7 https://doi.org/10.1021/acs.jpclett.6b00322	journal	March 2016
Doping Versatile n-Type Organic Semiconductors via Room Temperature Solution-Processable Anionic Dopants Chueh, Chu-Chen; Li, Chang-Zhi; Ding, Feizhi ACS Applied Materials & Interfaces, Vol. 9, Issue 1 https://doi.org/10.1021/acsami.6b14375	journal	December 2016
CsSnBr ₃ , A Lead-Free Halide Perovskite for Long-Term Solar Cell Application: Insights on SnF ₂ Addition Gupta, Satyajit; Bendikov, Tatyana; Hodes, Gary ACS Energy Letters, Vol. 1, Issue 5 https://doi.org/10.1021/acsenergylett.6b00402	journal	October 2016
Excited-State Properties of C ₆₀ Fullerene Derivatives Guldi, Dirk M.; Prato, Maurizio Accounts of Chemical Research, Vol. 33, Issue 10 https://doi.org/10.1021/ar990144m	journal	October 2000
The Synthesis, Characterization, and Lewis Acidity of SnI2 and SnI4 Yoder, Carolyn S.; Shenk, Stephanie; Schaeffer, Richard W. Journal of Chemical Education, Vol. 74, Issue 5 https://doi.org/10.1021/ed074p575	journal	May 1997
Synthesis and studies of trimethylamine adducts with tin(II) halides Hsu, C. C.; Geanangel, R. A. Inorganic Chemistry, Vol. 16, Issue 10 https://doi.org/10.1021/ic50176a022	journal	October 1977
Controllable Grain Morphology of Perovskite Absorber Film by Molecular Self-Assembly toward Efficient Solar Cell Exceeding 17% Li, Wenzhe; Fan, Jiandong; Li, Jiangwei Journal of the American Chemical Society, Vol. 137, Issue 32 https://doi.org/10.1021/jacs.5b06444	journal	August 2015
Solvent-Mediated Crystallization of CH₃NH₃SnI₃ Films for Heterojunction Depleted Perovskite Solar Cells Hao, Feng; Stoumpos, Constantinos C.; Guo, Peijun Journal of the American Chemical Society, Vol. 137, Issue 35, p. 11445-11452 https://doi.org/10.1021/jacs.5b06658	journal	August 2015
Synthesis and Optical Properties of Lead-Free Cesium Tin Halide Perovskite Nanocrystals Jellicoe, Tom C.; Richter, Johannes M.; Glass, Hugh F. J. Journal of the American Chemical Society, Vol. 138, Issue 9 https://doi.org/10.1021/jacs.5b13470	journal	February 2016
Fabrication of Efficient Formamidinium Tin Iodide Perovskite Solar Cells through SnF ₂ –Pyrazine Complex Lee, Seon Joo; Shin, Seong Sik; Kim, Young Chan Journal of the American Chemical Society, Vol. 138, Issue 12 https://doi.org/10.1021/jacs.6b00142	journal	March 2016
Rational Design of Dipolar Chromophore as an Efficient Dopant-Free Hole-Transporting Material for Perovskite Solar Cells Li, Zhong’an; Zhu, Zonglong; Chueh, Chu-Chen Journal of the American Chemical Society, Vol. 138, Issue 36 https://doi.org/10.1021/jacs.6b06291	journal	August 2016
Carrier Diffusion Lengths of over 500 nm in Lead-Free Perovskite CH ₃ NH ₃ SnI ₃ Films Ma, Lin; Hao, Feng; Stoumpos, Constantinos C. Journal of the American Chemical Society, Vol. 138, Issue 44 https://doi.org/10.1021/jacs.6b09257	journal	October 2016
Highly Oriented Low-Dimensional Tin Halide Perovskites with Enhanced Stability and Photovoltaic Performance Liao, Yuqin; Liu, Hefei; Zhou, Wenjia Journal of the American Chemical Society, Vol. 139, Issue 19 https://doi.org/10.1021/jacs.7b01815	journal	May 2017
Enhanced Photoluminescence and Solar Cell Performance via Lewis Base Passivation of Organic–Inorganic Lead Halide Perovskites Noel, Nakita K.; Abate, Antonio; Stranks, Samuel D. ACS Nano, Vol. 8, Issue 10 https://doi.org/10.1021/nn5036476	journal	September 2014
All-solid-state dye-sensitized solar cells with high efficiency Chung, In; Lee, Byunghong; He, Jiaqing Nature, Vol. 485, Issue 7399, p. 486-489 https://doi.org/10.1038/nature11067	journal	May 2012
Sequential deposition as a route to high-performance perovskite-sensitized solar cells Burschka, Julian; Pellet, Norman; Moon, Soo-Jin Nature, Vol. 499, Issue 7458, p. 316-319 https://doi.org/10.1038/nature12340	journal	July 2013
Metal-halide perovskites for photovoltaic and light-emitting devices Stranks, Samuel D.; Snaith, Henry J. Nature Nanotechnology, Vol. 10, Issue 5 https://doi.org/10.1038/nnano.2015.90	journal	May 2015
The emergence of perovskite solar cells Green, Martin A.; Ho-Baillie, Anita; Snaith, Henry J. Nature Photonics, Vol. 8, Issue 7, p. 506-514 https://doi.org/10.1038/nphoton.2014.134	journal	July 2014
Lead-free solid-state organic–inorganic halide perovskite solar cells Hao, Feng; Stoumpos, Constantinos C.; Cao, Duyen Hanh Nature Photonics, Vol. 8, Issue 6 https://doi.org/10.1038/nphoton.2014.82	journal	May 2014
Highly Efficient Perovskite Solar Cells with Substantial Reduction of Lead Content Liu, Chong; Fan, Jiandong; Li, Hongliang Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep35705	journal	October 2016
Organic–inorganic hybrid lead halide perovskites for optoelectronic and electronic applications Zhao, Yixin; Zhu, Kai Chemical Society Reviews, Vol. 45, Issue 3 https://doi.org/10.1039/C4CS00458B	journal	January 2016
Organohalide lead perovskites for photovoltaic applications Gao, Peng; Grätzel, Michael; Nazeeruddin, Mohammad K. Energy Environ. Sci., Vol. 7, Issue 8 https://doi.org/10.1039/C4EE00942H	journal	January 2014
Lead-free organic–inorganic tin halide perovskites for photovoltaic applications Noel, Nakita K.; Stranks, Samuel D.; Abate, Antonio Energy Environ. Sci., Vol. 7, Issue 9 https://doi.org/10.1039/C4EE01076K	journal	January 2014
Efficient, high yield perovskite photovoltaic devices grown by interdiffusion of solution-processed precursor stacking layers Xiao, Zhengguo; Bi, Cheng; Shao, Yuchuan Energy Environ. Sci., Vol. 7, Issue 8 https://doi.org/10.1039/C4EE01138D	journal	January 2014
Halide perovskite materials for solar cells: a theoretical review Yin, Wan-Jian; Yang, Ji-Hui; Kang, Joongoo Journal of Materials Chemistry A, Vol. 3, Issue 17 https://doi.org/10.1039/C4TA05033A	journal	January 2015
Formamidinium tin-based perovskite with low E _g for photovoltaic applications Koh, Teck Ming; Krishnamoorthy, Thirumal; Yantara, Natalia Journal of Materials Chemistry A, Vol. 3, Issue 29 https://doi.org/10.1039/C5TA00190K	journal	January 2015
Organometal halide perovskite thin films and solar cells by vapor deposition Ono, Luis K.; Leyden, Matthew R.; Wang, Shenghao Journal of Materials Chemistry A, Vol. 4, Issue 18 https://doi.org/10.1039/C5TA08963H	journal	January 2016
Recent advancements in perovskite solar cells: flexibility, stability and large scale Ye, Meidan; Hong, Xiaodan; Zhang, Fayin Journal of Materials Chemistry A, Vol. 4, Issue 18 https://doi.org/10.1039/C5TA09661H	journal	January 2016
Strategic improvement of the long-term stability of perovskite materials and perovskite solar cells Xu, Tingting; Chen, Lixin; Guo, Zhanhu Physical Chemistry Chemical Physics, Vol. 18, Issue 39 https://doi.org/10.1039/C6CP04553G	journal	January 2016
Efficient n-type dopants with extremely low doping ratios for high performance inverted perovskite solar cells Bin, Zhengyang; Li, Jiangwei; Wang, Liduo Energy & Environmental Science, Vol. 9, Issue 11 https://doi.org/10.1039/C6EE01987K	journal	January 2016
Effective interfacial layer to enhance efficiency of polymer solar cells via solution-processed fullerene-surfactants Li, Chang-Zhi; Chueh, Chu-Chen; Yip, Hin-Lap Journal of Materials Chemistry, Vol. 22, Issue 17 https://doi.org/10.1039/c2jm30755c	journal	January 2012
Tin(ii) fluoride vs. tin(ii) chloride – a comparison of their coordination chemistry with neutral ligands Gurnani, Chitra; Hector, Andrew L.; Jager, Edward Dalton Transactions, Vol. 42, Issue 23 https://doi.org/10.1039/c3dt50743b	journal	January 2013
Organic-Inorganic Hybrid Materials as Semiconducting Channels in Thin-Film Field-Effect Transistors Kagan, C. R.; Mitzi, D. B.; Dimitrakopoulos, C. D. Science, Vol. 286, Issue 5441, p. 945-947 https://doi.org/10.1126/science.286.5441.945	journal	October 1999
High-performance photovoltaic perovskite layers fabricated through intramolecular exchange Yang, W. S.; Noh, J. H.; Jeon, N. J. Science, Vol. 348, Issue 6240 https://doi.org/10.1126/science.aaa9272	journal	May 2015
A vacuum flash–assisted solution process for high-efficiency large-area perovskite solar cells Li, Xiong; Bi, Dongqin; Yi, Chenyi Science, Vol. 353, Issue 6294 https://doi.org/10.1126/science.aaf8060	journal	June 2016
Perovskite-perovskite tandem photovoltaics with optimized band gaps Eperon, Giles E.; Leijtens, Tomas; Bush, Kevin A. Science, Vol. 354, Issue 6314 https://doi.org/10.1126/science.aaf9717	journal	October 2016
Incorporation of rubidium cations into perovskite solar cells improves photovoltaic performance Saliba, M.; Matsui, T.; Domanski, K. Science, Vol. 354, Issue 6309 https://doi.org/10.1126/science.aah5557	journal	September 2016
Iodide management in formamidinium-lead-halide–based perovskite layers for efficient solar cells Yang, Woon Seok; Park, Byung-Wook; Jung, Eui Hyuk Science, Vol. 356, Issue 6345 https://doi.org/10.1126/science.aan2301	journal	June 2017

Similar Records

Lead-free inverted planar formamidinium tin triiodide perovskite solar cells achieving power conversion efficiencies up to 6.22%

Journal Article · 2016 · Advanced Materials · OSTI ID:1331968

Formamidinium + cesium lead triiodide perovskites: Discrepancies between thin film optical absorption and solar cell efficiency

Journal Article · 2018 · Solar Energy Materials and Solar Cells · OSTI ID:1636892

Related Subjects

Chemistry
Materials Science
Physics
Science & Technology - Other Topics

Realizing Efficient Lead-Free Formamidinium Tin Triiodide Perovskite Solar Cells via a Sequential Deposition Route

Citation Formats

References (66)

Similar Records

Related Subjects