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Title: Role of Ionic Functional Groups on Ion Transport at Perovskite Interfaces

Abstract

Not provided.

Authors:
 [1];  [2];  [2];  [1];  [1];  [3];  [4];  [2];  [1]
  1. Department of Polymer Science & Engineering, Conte Center for Polymer Research, University of Massachusetts, 120 Governors Drive Amherst MA 01003 USA
  2. Department of Chemistry, University of Massachusetts, 710 North Pleasant Street Amherst MA 0100-9303 USA
  3. Department of Chemistry, University of Massachusetts, 710 North Pleasant Street Amherst MA 0100-9303 USA; Department of Physics, University of Massachusetts, 710 North Pleasant Street Amherst Massachusetts 01003-9303 USA
  4. Department of Physics, Indian Institute of Technology Roorkee, Roorkee 247667 Uttarakhand India
Publication Date:
Research Org.:
Gordon Research Conferences, Kingston, RI (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1537227
DOE Contract Number:  
FG02-08ER15965
Resource Type:
Journal Article
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Volume: 7; Journal Issue: 21; Journal ID: ISSN 1614-6832
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
Chemistry; Energy & Fuels; Materials Science; Physics

Citation Formats

Liu, Yao, Renna, Lawrence A., Thompson, Hilary B., Page, Zachariah A., Emrick, Todd, Barnes, Michael D., Bag, Monojit, Venkataraman, D., and Russell, Thomas P. Role of Ionic Functional Groups on Ion Transport at Perovskite Interfaces. United States: N. p., 2017. Web. doi:10.1002/aenm.201701235.
Liu, Yao, Renna, Lawrence A., Thompson, Hilary B., Page, Zachariah A., Emrick, Todd, Barnes, Michael D., Bag, Monojit, Venkataraman, D., & Russell, Thomas P. Role of Ionic Functional Groups on Ion Transport at Perovskite Interfaces. United States. doi:10.1002/aenm.201701235.
Liu, Yao, Renna, Lawrence A., Thompson, Hilary B., Page, Zachariah A., Emrick, Todd, Barnes, Michael D., Bag, Monojit, Venkataraman, D., and Russell, Thomas P. Mon . "Role of Ionic Functional Groups on Ion Transport at Perovskite Interfaces". United States. doi:10.1002/aenm.201701235.
@article{osti_1537227,
title = {Role of Ionic Functional Groups on Ion Transport at Perovskite Interfaces},
author = {Liu, Yao and Renna, Lawrence A. and Thompson, Hilary B. and Page, Zachariah A. and Emrick, Todd and Barnes, Michael D. and Bag, Monojit and Venkataraman, D. and Russell, Thomas P.},
abstractNote = {Not provided.},
doi = {10.1002/aenm.201701235},
journal = {Advanced Energy Materials},
issn = {1614-6832},
number = 21,
volume = 7,
place = {United States},
year = {2017},
month = {8}
}

Works referenced in this record:

The emergence of perovskite solar cells
journal, July 2014

  • Green, Martin A.; Ho-Baillie, Anita; Snaith, Henry J.
  • Nature Photonics, Vol. 8, Issue 7, p. 506-514
  • DOI: 10.1038/nphoton.2014.134

The light and shade of perovskite solar cells
journal, August 2014


Recent Advances in the Inverted Planar Structure of Perovskite Solar Cells
journal, December 2015


Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
journal, May 2009

  • Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo
  • Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051
  • DOI: 10.1021/ja809598r

Efficient planar heterojunction perovskite solar cells by vapour deposition
journal, September 2013

  • Liu, Mingzhen; Johnston, Michael B.; Snaith, Henry J.
  • Nature, Vol. 501, Issue 7467, p. 395-398
  • DOI: 10.1038/nature12509

Sequential deposition as a route to high-performance perovskite-sensitized solar cells
journal, July 2013

  • Burschka, Julian; Pellet, Norman; Moon, Soo-Jin
  • Nature, Vol. 499, Issue 7458, p. 316-319
  • DOI: 10.1038/nature12340

Interface engineering of highly efficient perovskite solar cells
journal, July 2014


Compositional engineering of perovskite materials for high-performance solar cells
journal, January 2015

  • Jeon, Nam Joong; Noh, Jun Hong; Yang, Woon Seok
  • Nature, Vol. 517, Issue 7535
  • DOI: 10.1038/nature14133

High-efficiency solution-processed perovskite solar cells with millimeter-scale grains
journal, January 2015


A hole-conductor-free, fully printable mesoscopic perovskite solar cell with high stability
journal, July 2014


Solvent Annealing of Perovskite-Induced Crystal Growth for Photovoltaic-Device Efficiency Enhancement
journal, August 2014


Additive Enhanced Crystallization of Solution-Processed Perovskite for Highly Efficient Planar-Heterojunction Solar Cells
journal, March 2014

  • Liang, Po-Wei; Liao, Chien-Yi; Chueh, Chu-Chen
  • Advanced Materials, Vol. 26, Issue 22, p. 3748-3754
  • DOI: 10.1002/adma.201400231

General Working Principles of CH 3 NH 3 PbX 3 Perovskite Solar Cells
journal, January 2014

  • Gonzalez-Pedro, Victoria; Juarez-Perez, Emilio J.; Arsyad, Waode-Sukmawati
  • Nano Letters, Vol. 14, Issue 2
  • DOI: 10.1021/nl404252e

Defect migration in methylammonium lead iodide and its role in perovskite solar cell operation
journal, January 2015

  • Azpiroz, Jon M.; Mosconi, Edoardo; Bisquert, Juan
  • Energy & Environmental Science, Vol. 8, Issue 7
  • DOI: 10.1039/C5EE01265A

Ionic transport in hybrid lead iodide perovskite solar cells
journal, June 2015

  • Eames, Christopher; Frost, Jarvist M.; Barnes, Piers R. F.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8497

First-Principles Study of Ion Diffusion in Perovskite Solar Cell Sensitizers
journal, August 2015

  • Haruyama, Jun; Sodeyama, Keitaro; Han, Liyuan
  • Journal of the American Chemical Society, Vol. 137, Issue 32
  • DOI: 10.1021/jacs.5b03615

Principles of Chemical Bonding and Band Gap Engineering in Hybrid Organic–Inorganic Halide Perovskites
journal, February 2015

  • Walsh, Aron
  • The Journal of Physical Chemistry C, Vol. 119, Issue 11
  • DOI: 10.1021/jp512420b

Giant switchable photovoltaic effect in organometal trihalide perovskite devices
journal, December 2014

  • Xiao, Zhengguo; Yuan, Yongbo; Shao, Yuchuan
  • Nature Materials, Vol. 14, Issue 2
  • DOI: 10.1038/nmat4150

Photon recycling in lead iodide perovskite solar cells
journal, March 2016


Impedance Spectroscopic Analysis of Lead Iodide Perovskite-Sensitized Solid-State Solar Cells
journal, December 2013

  • Dualeh, Amalie; Moehl, Thomas; Tétreault, Nicolas
  • ACS Nano, Vol. 8, Issue 1, p. 362-373
  • DOI: 10.1021/nn404323g

Anomalous Hysteresis in Perovskite Solar Cells
journal, April 2014

  • Snaith, Henry J.; Abate, Antonio; Ball, James M.
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 9
  • DOI: 10.1021/jz500113x

Slow Dynamic Processes in Lead Halide Perovskite Solar Cells. Characteristic Times and Hysteresis
journal, June 2014

  • Sanchez, Rafael S.; Gonzalez-Pedro, Victoria; Lee, Jin-Wook
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 13
  • DOI: 10.1021/jz5011187

Hysteresis and transient behavior in current–voltage measurements of hybrid-perovskite absorber solar cells
journal, January 2014

  • Unger, E. L.; Hoke, E. T.; Bailie, C. D.
  • Energy Environ. Sci., Vol. 7, Issue 11
  • DOI: 10.1039/C4EE02465F

Best Practices in Perovskite Solar Cell Efficiency Measurements. Avoiding the Error of Making Bad Cells Look Good
journal, February 2015

  • Christians, Jeffrey A.; Manser, Joseph S.; Kamat, Prashant V.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 5
  • DOI: 10.1021/acs.jpclett.5b00289

Ion Migration in Organometal Trihalide Perovskite and Its Impact on Photovoltaic Efficiency and Stability
journal, January 2016


Kinetics of Ion Transport in Perovskite Active Layers and Its Implications for Active Layer Stability
journal, September 2015

  • Bag, Monojit; Renna, Lawrence A.; Adhikari, Ramesh Y.
  • Journal of the American Chemical Society, Vol. 137, Issue 40
  • DOI: 10.1021/jacs.5b08535

Origin of JV Hysteresis in Perovskite Solar Cells
journal, February 2016


Ionic polarization-induced current–voltage hysteresis in CH3NH3PbX3 perovskite solar cells
journal, February 2016

  • Meloni, Simone; Moehl, Thomas; Tress, Wolfgang
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms10334

Can slow-moving ions explain hysteresis in the current–voltage curves of perovskite solar cells?
journal, January 2016

  • Richardson, Giles; O'Kane, Simon E. J.; Niemann, Ralf G.
  • Energy & Environmental Science, Vol. 9, Issue 4
  • DOI: 10.1039/C5EE02740C

Modeling Anomalous Hysteresis in Perovskite Solar Cells
journal, September 2015

  • van Reenen, Stephan; Kemerink, Martijn; Snaith, Henry J.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 19
  • DOI: 10.1021/acs.jpclett.5b01645

Origin and elimination of photocurrent hysteresis by fullerene passivation in CH3NH3PbI3 planar heterojunction solar cells
journal, December 2014

  • Shao, Yuchuan; Xiao, Zhengguo; Bi, Cheng
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms6784

High efficiency stable inverted perovskite solar cells without current hysteresis
journal, January 2015

  • Wu, Chun-Guey; Chiang, Chien-Hung; Tseng, Zong-Liang
  • Energy & Environmental Science, Vol. 8, Issue 9
  • DOI: 10.1039/C5EE00645G

Perovskite–fullerene hybrid materials suppress hysteresis in planar diodes
journal, May 2015

  • Xu, Jixian; Buin, Andrei; Ip, Alexander H.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8081

Sulfamic Acid-Catalyzed Lead Perovskite Formation for Solar Cell Fabrication on Glass or Plastic Substrates
journal, January 2016

  • Guo, Yunlong; Sato, Wataru; Shoyama, Kazutaka
  • Journal of the American Chemical Society, Vol. 138, Issue 16
  • DOI: 10.1021/jacs.6b02130

Unbroken Perovskite: Interplay of Morphology, Electro-optical Properties, and Ionic Movement
journal, April 2016

  • Correa-Baena, Juan-Pablo; Anaya, Miguel; Lozano, Gabriel
  • Advanced Materials, Vol. 28, Issue 25
  • DOI: 10.1002/adma.201600624

The Significance of Ion Conduction in a Hybrid Organic-Inorganic Lead-Iodide-Based Perovskite Photosensitizer
journal, May 2015

  • Yang, Tae-Youl; Gregori, Giuliano; Pellet, Norman
  • Angewandte Chemie International Edition, Vol. 54, Issue 27
  • DOI: 10.1002/anie.201500014

Grain boundary dominated ion migration in polycrystalline organic–inorganic halide perovskite films
journal, January 2016

  • Shao, Yuchuan; Fang, Yanjun; Li, Tao
  • Energy & Environmental Science, Vol. 9, Issue 5
  • DOI: 10.1039/C6EE00413J

Interface-Dependent Ion Migration/Accumulation Controls Hysteresis in MAPbI 3 Solar Cells
journal, July 2016

  • Levine, Igal; Nayak, Pabitra K.; Wang, Jacob Tse-Wei
  • The Journal of Physical Chemistry C, Vol. 120, Issue 30
  • DOI: 10.1021/acs.jpcc.6b04233

Heterojunction Modification for Highly Efficient Organic–Inorganic Perovskite Solar Cells
journal, November 2014

  • Wojciechowski, Konrad; Stranks, Samuel D.; Abate, Antonio
  • ACS Nano, Vol. 8, Issue 12
  • DOI: 10.1021/nn505723h

Electro-optics of perovskite solar cells
journal, December 2014

  • Lin, Qianqian; Armin, Ardalan; Nagiri, Ravi Chandra Raju
  • Nature Photonics, Vol. 9, Issue 2
  • DOI: 10.1038/nphoton.2014.284

Multifunctional Fullerene Derivative for Interface Engineering in Perovskite Solar Cells
journal, December 2015

  • Li, Yaowen; Zhao, Yue; Chen, Qi
  • Journal of the American Chemical Society, Vol. 137, Issue 49
  • DOI: 10.1021/jacs.5b10614

Understanding Interface Engineering for High-Performance Fullerene/Perovskite Planar Heterojunction Solar Cells
journal, November 2015

  • Liu, Yao; Bag, Monojit; Renna, Lawrence A.
  • Advanced Energy Materials, Vol. 6, Issue 2
  • DOI: 10.1002/aenm.201501606

Efficient, high yield perovskite photovoltaic devices grown by interdiffusion of solution-processed precursor stacking layers
journal, January 2014

  • Xiao, Zhengguo; Bi, Cheng; Shao, Yuchuan
  • Energy Environ. Sci., Vol. 7, Issue 8
  • DOI: 10.1039/C4EE01138D

High-efficiency robust perovskite solar cells on ultrathin flexible substrates
journal, January 2016

  • Li, Yaowen; Meng, Lei; Yang, Yang
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms10214

Hydrophilic Conjugated Polymers Prepared by Aqueous Horner–Wadsworth–Emmons Coupling
journal, March 2016


A Polymer Hole Extraction Layer for Inverted Perovskite Solar Cells from Aqueous Solutions
journal, July 2016

  • Liu, Yao; Renna, Lawrence A.; Page, Zachariah A.
  • Advanced Energy Materials, Vol. 6, Issue 20
  • DOI: 10.1002/aenm.201600664

Topographic distance and watershed lines
journal, July 1994


Finely Tuned Polymer Interlayers Enhance Solar Cell Efficiency
journal, July 2015

  • Liu, Yao; Page, Zachariah A.; Russell, Thomas P.
  • Angewandte Chemie International Edition, Vol. 54, Issue 39
  • DOI: 10.1002/anie.201503933

Charge Separation in Semicrystalline Polymeric Semiconductors by Photoexcitation: Is the Mechanism Intrinsic or Extrinsic?
journal, May 2011


Directional charge separation in isolated organic semiconductor crystalline nanowires
journal, February 2016

  • Labastide, J. A.; Thompson, H. B.; Marques, S. R.
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms10629

Specific cation interactions as the cause of slow dynamics and hysteresis in dye and perovskite solar cells: a small-perturbation study
journal, January 2016

  • Contreras, Lidia; Idígoras, Jesús; Todinova, Anna
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 45
  • DOI: 10.1039/C6CP05851E

Photovoltaic behaviour of lead methylammonium triiodide perovskite solar cells down to 80 K
journal, January 2015

  • Zhang, Hua; Qiao, Xianfeng; Shen, Yan
  • Journal of Materials Chemistry A, Vol. 3, Issue 22
  • DOI: 10.1039/C5TA02206A

New generation perovskite solar cells with solution-processed amino-substituted perylene diimide derivative as electron-transport layer
journal, January 2016

  • Zhang, Hua; Xue, Lingwei; Han, Junbo
  • Journal of Materials Chemistry A, Vol. 4, Issue 22
  • DOI: 10.1039/C6TA03119F

Evidence for reduced charge recombination in carbon nanotube/perovskite-based active layers
journal, October 2016


Application of A-C Techniques to the Study of Lithium Diffusion in Tungsten Trioxide Thin Films
journal, January 1980

  • Ho, C.
  • Journal of The Electrochemical Society, Vol. 127, Issue 2
  • DOI: 10.1149/1.2129668

Ionic and Optical Properties of Methylammonium Lead Iodide Perovskite across the Tetragonal-Cubic Structural Phase Transition
journal, September 2016


Surface Recombination and Collection Efficiency in Perovskite Solar Cells from Impedance Analysis
journal, November 2016

  • Zarazua, Isaac; Han, Guifang; Boix, Pablo P.
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 24
  • DOI: 10.1021/acs.jpclett.6b02193

Impedance Studies of Diffusion Phenomena and Ionic and Electronic Conductivity of Cerium Oxide
journal, January 2005

  • Jasinski, Piotr; Petrovsky, Vladimir; Suzuki, Toshio
  • Journal of The Electrochemical Society, Vol. 152, Issue 4
  • DOI: 10.1149/1.1861174

Properties of Contact and Bulk Impedances in Hybrid Lead Halide Perovskite Solar Cells Including Inductive Loop Elements
journal, April 2016

  • Guerrero, Antonio; Garcia-Belmonte, Germà; Mora-Sero, Ivan
  • The Journal of Physical Chemistry C, Vol. 120, Issue 15
  • DOI: 10.1021/acs.jpcc.6b01728

Recombination in Perovskite Solar Cells: Significance of Grain Boundaries, Interface Traps, and Defect Ions
journal, April 2017


Scanning Kelvin probe study of metal/polymer interfaces
journal, July 2004


Kelvin Probe Force Microscopy on Surfaces:  Investigation of the Surface Potential of Self-Assembled Monolayers on Gold
journal, November 1999

  • Lü, J.; Delamarche, E.; Eng, L.
  • Langmuir, Vol. 15, Issue 23
  • DOI: 10.1021/la9904861

Hydrogenation-Induced Surface Polarity Recognition and Proton Memory Behavior at Protic-Ionic-Liquid/Oxide Electric-Double-Layer Interfaces
journal, May 2010

  • Yuan, Hongtao; Shimotani, Hidekazu; Tsukazaki, Atsushi
  • Journal of the American Chemical Society, Vol. 132, Issue 19
  • DOI: 10.1021/ja909110s

Energy-Efficient Hybrid Perovskite Memristors and Synaptic Devices
journal, May 2016


The missing memristor found
journal, May 2008

  • Strukov, Dmitri B.; Snider, Gregory S.; Stewart, Duncan R.
  • Nature, Vol. 453, Issue 7191
  • DOI: 10.1038/nature06932

Electrocoloration in SrTi O 3 : Vacancy Drift and Oxidation-Reduction of Transition Metals
journal, November 1971


Fulleropyrrolidine interlayers: Tailoring electrodes to raise organic solar cell efficiency
journal, September 2014


Computation of Minkowski Measures on 2d and 3d Binary Images
journal, June 2007

  • Legland, David; Kiêu, Kiên; Devaux, Marie-Françoise
  • Image Analysis & Stereology, Vol. 26, Issue 2
  • DOI: 10.5566/ias.v26.p83-92