Electrochemical Validation of In-Cell Chromium Getters to Mitigate Chromium Poisoning in SOFC Stack

Uddin, Md Aman; Aphale, Ashish; Hu, Boxun; Heo, Su Jeong; Pasaogullari, Ugur; Singh, Prabhakar

doi:10.1149/2.0421713jes

Title: Electrochemical Validation of In-Cell Chromium Getters to Mitigate Chromium Poisoning in SOFC Stack

Journal Article · Sun Jan 01 00:00:00 EST 2017 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.0421713jes· OSTI ID:1536960

Uddin, Md Aman; Aphale, Ashish; Hu, Boxun; Heo, Su Jeong; Pasaogullari, Ugur; Singh, Prabhakar

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Research Organization:: Univ. of Connecticut, Storrs, CT (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE)

DOE Contract Number:: FE0023385

OSTI ID:: 1536960

Journal Information:: Journal of the Electrochemical Society, Vol. 164, Issue 13; ISSN 0013-4651

Publisher:: The Electrochemical Society

Country of Publication:: United States

Language:: English

References (38)

Engineered cathodes for high performance SOFCs Williford, R. Journal of Power Sources, Vol. 128, Issue 1 https://doi.org/10.1016/j.jpowsour.2003.09.055	journal	March 2004
Fuel cells: The expectations for an environmental-friendly and sustainable source of energy Stambouli, A. Boudghene Renewable and Sustainable Energy Reviews, Vol. 15, Issue 9 https://doi.org/10.1016/j.rser.2011.07.100	journal	December 2011
Recent Advances in Materials for Fuel Cells Brandon, N. P.; Skinner, S.; Steele, B. C. H. Annual Review of Materials Research, Vol. 33, Issue 1 https://doi.org/10.1146/annurev.matsci.33.022802.094122	journal	August 2003
Solid Oxide Fuel Cells: Technology Status Singh, Prabhakar; Minh, Nguyen Q. International Journal of Applied Ceramic Technology, Vol. 1, Issue 1 https://doi.org/10.1111/j.1744-7402.2004.tb00149.x	journal	January 2004
Chromium deposition and poisoning of cathodes of solid oxide fuel cells – A review Jiang, San Ping; Chen, Xinbing International Journal of Hydrogen Energy, Vol. 39, Issue 1 https://doi.org/10.1016/j.ijhydene.2013.10.042	journal	January 2014
The oxidation behaviour of metals and alloys at high temperatures in atmospheres containing water vapour: A review Saunders, S. R. J.; Monteiro, M.; Rizzo, F. Progress in Materials Science, Vol. 53, Issue 5 https://doi.org/10.1016/j.pmatsci.2007.11.001	journal	July 2008
Chromium vaporisation from Fe,Cr base alloys used as interconnect in fuel cells Gindorf, Christian; Singheiser, Lorenz; Hilpert, Klaus Steel Research, Vol. 72, Issue 11-12 https://doi.org/10.1002/srin.200100163	journal	November 2001
Water Vapor–Mediated Volatilization of High-Temperature Materials Meschter, Peter J.; Opila, Elizabeth J.; Jacobson, Nathan S. Annual Review of Materials Research, Vol. 43, Issue 1 https://doi.org/10.1146/annurev-matsci-071312-121636	journal	July 2013
Study on the Cr deposition and poisoning phenomenon at (La 0.6 Sr 0.4 )(Co 0.2 Fe 0.8 )O 3−δ electrode of solid oxide fuel cells by transmission X-ray microscopy Chen, Xinbing; Jin, Chan; Zhao, Ling International Journal of Hydrogen Energy, Vol. 39, Issue 28 https://doi.org/10.1016/j.ijhydene.2014.07.112	journal	September 2014
Characterization of Cr Poisoning in a Solid Oxide Fuel Cell Cathode Using a High Energy X-ray Microbeam Liu, Di-Jia; Almer, Jonathan; Cruse, Terry Journal of The Electrochemical Society, Vol. 157, Issue 5 https://doi.org/10.1149/1.3358262	journal	January 2010
Experimental and thermodynamic evaluation of La1−xSrxMnO3±δ and La1−xSrxCo1−yFeyO3−δ cathodes in Cr-containing humidified air Hu, Boxun; Krishnan, Sridevi; Liang, Chiying International Journal of Hydrogen Energy, Vol. 42, Issue 15 https://doi.org/10.1016/j.ijhydene.2017.01.040	journal	April 2017
Low-Temperature Chromium Poisoning of SOFC Cathode Heo, Su Jeong; Hu, Boxun; Aphale, Ashish N. ECS Transactions, Vol. 78, Issue 1 https://doi.org/10.1149/07801.1055ecst	journal	May 2017
Electrochemical properties of A-site deficient SOFC cathodes under Cr poisoning conditions Fu, C. J.; Sun, K. N.; Chen, X. B. Electrochimica Acta, Vol. 54, Issue 28 https://doi.org/10.1016/j.electacta.2009.07.055	journal	December 2009
Adhesion of oxide scales grown on ferritic stainless steels in solid oxide fuel cells temperature and atmosphere conditions Chandra-Ambhorn, S.; Wouters, Y.; Antoni, L. Journal of Power Sources, Vol. 171, Issue 2 https://doi.org/10.1016/j.jpowsour.2007.06.058	journal	September 2007
Potassium-Assisted Chromium Transport in Solid Oxide Fuel Cells Ingram, B. J.; Cruse, T. A.; Krumpelt, M. Journal of The Electrochemical Society, Vol. 154, Issue 11 https://doi.org/10.1149/1.2781117	journal	January 2007
Electrochemical properties of a SOFC cathode in contact with a chromium-containing alloy separator Matsuzaki, Y. Solid State Ionics, Vol. 132, Issue 3-4 https://doi.org/10.1016/S0167-2738(00)00654-8	journal	July 2000
Metallic interconnects for solid oxide fuel cell: A review on protective coating and deposition techniques Mah, Joelle C. W.; Muchtar, Andanastuti; Somalu, Mahendra R. International Journal of Hydrogen Energy, Vol. 42, Issue 14 https://doi.org/10.1016/j.ijhydene.2016.03.195	journal	April 2017
Oxide Scale Morphology and Chromium Evaporation Characteristics of Alloys for Balance of Plant Applications in Solid Oxide Fuel Cells Ge, Le; Verma, Atul; Goettler, Richard Metallurgical and Materials Transactions A, Vol. 44, Issue S1 https://doi.org/10.1007/s11661-012-1492-y	journal	November 2012
Highly Dense Mn-Co Spinel Coating for Protection of Metallic Interconnect of Solid Oxide Fuel Cells Lee, Sung-Il; Hong, Jongsup; Kim, Hyoungchul Journal of The Electrochemical Society, Vol. 161, Issue 14 https://doi.org/10.1149/2.0541414jes	journal	January 2014
Development of MnCoO coating with new aluminizing process for planar SOFC stacks Choi, Jung Pyung; Scott Weil, K.; Matt Chou, Y. International Journal of Hydrogen Energy, Vol. 36, Issue 7 https://doi.org/10.1016/j.ijhydene.2010.04.110	journal	April 2011
La(Ni,Fe)O3 as a cathode material with high tolerance to chromium poisoning for solid oxide fuel cells Zhen, Y. D.; Tok, A. I. Y.; Jiang, S. P. Journal of Power Sources, Vol. 170, Issue 1 https://doi.org/10.1016/j.jpowsour.2007.03.079	journal	June 2007
Formation of spinel reaction layers in manganese cobaltite – coated Crofer22 APU for solid oxide fuel cell interconnects Magdefrau, Neal J.; Chen, Lei; Sun, Ellen Y. Journal of Power Sources, Vol. 227 https://doi.org/10.1016/j.jpowsour.2012.07.091	journal	April 2013
Interactions Between SOFC Interconnect Coating Materials and Chromia Wang, Kangli; Liu, Yingjia; Fergus, Jeffrey W. Journal of the American Ceramic Society, Vol. 94, Issue 12 https://doi.org/10.1111/j.1551-2916.2011.04749.x	journal	July 2011
Reduction of chromium vaporization from SOFC interconnectors by highly effective coatings Stanislowski, M.; Froitzheim, J.; Niewolak, L. Journal of Power Sources, Vol. 164, Issue 2 https://doi.org/10.1016/j.jpowsour.2006.08.013	journal	February 2007
Characterization and performance of (La,Ba)(Co,Fe)O3 cathode for solid oxide fuel cells with iron–chromium metallic interconnect Zhen, Yongda; Jiang, San Ping Journal of Power Sources, Vol. 180, Issue 2 https://doi.org/10.1016/j.jpowsour.2008.02.093	journal	June 2008
Chromium Deposition and Poisoning at Ba0.5Sr0.5Co0.8Fe0.2O3−δ Cathode of Solid Oxide Fuel Cells Kim, Yu−Mi; Chen, Xinbing; Jiang, San Ping Electrochemical and Solid-State Letters, Vol. 14, Issue 4 https://doi.org/10.1149/1.3549169	journal	January 2011
Effects of chromium poisoning on the long-term oxygen exchange kinetics of the solid oxide fuel cell cathode materials La0.6Sr0.4CoO3 and Nd2NiO4 Yang, Min; Bucher, Edith; Sitte, Werner Journal of Power Sources, Vol. 196, Issue 17 https://doi.org/10.1016/j.jpowsour.2010.10.064	journal	September 2011
Highly active and stable (La0.24Sr0.16Ba0.6)(Co0.5Fe0.44Nb0.06)O3−δ (LSBCFN) cathodes for solid oxide fuel cells prepared by a novel mixing synthesis method Chen, Xinbing; Jiang, San Ping Journal of Materials Chemistry A, Vol. 1, Issue 15 https://doi.org/10.1039/c3ta10230k	journal	January 2013
Mitigating Cr Contamination by Hot Air Filtering in Solid Oxide Fuel Cells Schuler, J. Andreas; Schuler, Albert J.; Penner, Dirk Electrochemical and Solid-State Letters, Vol. 14, Issue 12, p. B132-B134 https://doi.org/10.1149/2.002112esl	journal	January 2011
Mitigation of Chromium Assisted Degradation of LSM Cathode in SOFC Liang, Chiying; Hu, Boxun; Aphale, Ashish ECS Transactions, Vol. 75, Issue 28 https://doi.org/10.1149/07528.0057ecst	journal	January 2017
Design and Optimization of Chromium Getter for SOFC Systems through Computational Modeling Uddin, Md Aman; Banas, Charles Joseph; Liang, Chiying ECS Transactions, Vol. 78, Issue 1 https://doi.org/10.1149/07801.1063ecst	journal	May 2017
Chemical and Structural Stability of Sr _x Ni _y O _z Chromium Getter for Application in SOFC Systems Aphale, Ashish N.; Uddin, Md Aman; Hu, Boxun ECS Transactions, Vol. 78, Issue 1 https://doi.org/10.1149/07801.1073ecst	journal	May 2017
Structure, electrical conducting and thermal expansion properties of La0.6Sr0.4Co0.8Fe0.2O3−δ–Ce0.8Sm0.2O2−δ composite cathodes Xu, Qing; Huang, Duan-ping; Zhang, Feng Journal of Alloys and Compounds, Vol. 454, Issue 1-2 https://doi.org/10.1016/j.jallcom.2006.12.132	journal	April 2008
In situ study of activation and de-activation of LSM fuel cell cathodes – Electrochemistry and surface analysis of thin-film electrodes Huber, Anne-Katrin; Falk, Mareike; Rohnke, Marcus Journal of Catalysis, Vol. 294 https://doi.org/10.1016/j.jcat.2012.07.010	journal	October 2012
New Insights into the Strain Coupling to Surface Chemistry, Electronic Structure, and Reactivity of La _0.7 Sr _0.3 MnO ₃ Jalili, Helia; Han, Jeong Woo; Kuru, Yener The Journal of Physical Chemistry Letters, Vol. 2, Issue 7 https://doi.org/10.1021/jz200160b	journal	March 2011
Stability of strontium-doped lanthanum manganite cathode in humidified air Hu, Boxun; Keane, Michael; Mahapatra, Manoj K. Journal of Power Sources, Vol. 248 https://doi.org/10.1016/j.jpowsour.2013.08.098	journal	February 2014
Cation self-diffusion in strontium oxide (SrO) Murarka, S. P.; Swalin, R. A. Journal of Physics and Chemistry of Solids, Vol. 32, Issue 6 https://doi.org/10.1016/S0022-3697(71)80185-3	journal	January 1971
About the Role of Chromium and Oxygen Ion Diffusion on the Growth Mechanism of Oxidation Films of the AISI 304 Austenitic Stainless Steel Sabioni, Antônio Claret Soares; Ramos, Roberto Paulo Barbosa; Ji, Vincent Oxidation of Metals, Vol. 78, Issue 3-4 https://doi.org/10.1007/s11085-012-9301-y	journal	May 2012

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