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Title: Macroscopically aligned nanowire arrays of π-conjugated polymers via shear-enhanced crystallization

Abstract

The nanoscale structure and macroscopic morphology of π-conjugated polymers are very important for their electronic application.

Authors:
 [1]; ORCiD logo [2];  [2]; ORCiD logo [1]; ORCiD logo [3]
  1. MOE Key Laboratory of Macromolecular Synthesis and Functionalization; Department of Polymer Science & Engineering; Zhejiang University; Hangzhou 310027; China
  2. Department of Chemical Engineering; University of Washington; Seattle; USA
  3. Materials Science & Engineering Department; University of Washington; Seattle; USA; Department of Chemistry
Publication Date:
Research Org.:
Univ. of Washington, Seattle, WA (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1535267
DOE Contract Number:  
SC0010282
Resource Type:
Journal Article
Journal Name:
Journal of Materials Chemistry C
Additional Journal Information:
Journal Volume: 5; Journal Issue: 21; Journal ID: ISSN 2050-7526
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
Materials Science; Physics

Citation Formats

Li, Jun-Huan, Xi, Yuyin, Pozzo, Lilo D., Xu, Jun-Ting, and Luscombe, Christine K. Macroscopically aligned nanowire arrays of π-conjugated polymers via shear-enhanced crystallization. United States: N. p., 2017. Web. doi:10.1039/c7tc01419h.
Li, Jun-Huan, Xi, Yuyin, Pozzo, Lilo D., Xu, Jun-Ting, & Luscombe, Christine K. Macroscopically aligned nanowire arrays of π-conjugated polymers via shear-enhanced crystallization. United States. doi:10.1039/c7tc01419h.
Li, Jun-Huan, Xi, Yuyin, Pozzo, Lilo D., Xu, Jun-Ting, and Luscombe, Christine K. Sun . "Macroscopically aligned nanowire arrays of π-conjugated polymers via shear-enhanced crystallization". United States. doi:10.1039/c7tc01419h.
@article{osti_1535267,
title = {Macroscopically aligned nanowire arrays of π-conjugated polymers via shear-enhanced crystallization},
author = {Li, Jun-Huan and Xi, Yuyin and Pozzo, Lilo D. and Xu, Jun-Ting and Luscombe, Christine K.},
abstractNote = {The nanoscale structure and macroscopic morphology of π-conjugated polymers are very important for their electronic application.},
doi = {10.1039/c7tc01419h},
journal = {Journal of Materials Chemistry C},
issn = {2050-7526},
number = 21,
volume = 5,
place = {United States},
year = {2017},
month = {1}
}

Works referenced in this record:

Designing π-conjugated polymers for organic electronics
journal, December 2013


The path to ubiquitous and low-cost organic electronic appliances on plastic
journal, April 2004


Low-Bandgap Near-IR Conjugated Polymers/Molecules for Organic Electronics
journal, August 2015


Toward Printed Integrated Circuits based on Unipolar or Ambipolar Polymer Semiconductors
journal, June 2013

  • Baeg, Kang-Jun; Caironi, Mario; Noh, Yong-Young
  • Advanced Materials, Vol. 25, Issue 31
  • DOI: 10.1002/adma.201205361

Semiconducting π-Conjugated Systems in Field-Effect Transistors: A Material Odyssey of Organic Electronics
journal, November 2011

  • Wang, Chengliang; Dong, Huanli; Hu, Wenping
  • Chemical Reviews, Vol. 112, Issue 4
  • DOI: 10.1021/cr100380z

A general relationship between disorder, aggregation and charge transport in conjugated polymers
journal, August 2013

  • Noriega, Rodrigo; Rivnay, Jonathan; Vandewal, Koen
  • Nature Materials, Vol. 12, Issue 11
  • DOI: 10.1038/nmat3722

Ordering of Poly(3-hexylthiophene) in Solutions and Films: Effects of Fiber Length and Grain Boundaries on Anisotropy and Mobility
journal, May 2016


Controlling Polymorphism in Poly(3-Hexylthiophene) through Addition of Ferrocene for Enhanced Charge Mobilities in Thin-Film Transistors
journal, December 2014

  • Smith, Brandon H.; Clark, Michael B.; Kuang, Hao
  • Advanced Functional Materials, Vol. 25, Issue 4
  • DOI: 10.1002/adfm.201403089

Effect of Regioregularity on Charge Transport and Structural and Excitonic Coherence in Poly(3-hexylthiophene) Nanowires
journal, June 2015

  • Mazzio, Katherine A.; Rice, Andrew H.; Durban, Mathew M.
  • The Journal of Physical Chemistry C, Vol. 119, Issue 27
  • DOI: 10.1021/acs.jpcc.5b02914

Rational Design of High-Mobility Semicrystalline Conjugated Polymers with Tunable Charge Polarity: Beyond Benzobisthiadiazole-Based Polymers
journal, October 2016

  • Wang, Yang; Hasegawa, Tsukasa; Matsumoto, Hidetoshi
  • Advanced Functional Materials, Vol. 27, Issue 2
  • DOI: 10.1002/adfm.201604608

Record High Hole Mobility in Polymer Semiconductors via Side-Chain Engineering
journal, September 2013

  • Kang, Il; Yun, Hui-Jun; Chung, Dae Sung
  • Journal of the American Chemical Society, Vol. 135, Issue 40
  • DOI: 10.1021/ja405112s

Fabrication and processing of polymer solar cells: A review of printing and coating techniques
journal, April 2009


Solubility-driven polythiophene nanowires and their electrical characteristics
journal, January 2011

  • Park, Yeong Don; Lee, Seung Goo; Lee, Hwa Sung
  • J. Mater. Chem., Vol. 21, Issue 7
  • DOI: 10.1039/C0JM03114C

Controlled Assembly of Poly(3-hexylthiophene): Managing the Disorder to Order Transition on the Nano- through Meso-Scales
journal, December 2014

  • Choi, Dalsu; Chang, Mincheol; Reichmanis, Elsa
  • Advanced Functional Materials, Vol. 25, Issue 6
  • DOI: 10.1002/adfm.201403708

Photoinduced Anisotropic Supramolecular Assembly and Enhanced Charge Transport of Poly(3-hexylthiophene) Thin Films
journal, April 2014

  • Chang, Mincheol; Lee, Jiho; Kleinhenz, Nabil
  • Advanced Functional Materials, Vol. 24, Issue 28
  • DOI: 10.1002/adfm.201400523

Tunable Crystallinity in Regioregular Poly(3-Hexylthiophene) Thin Films and Its Impact on Field Effect Mobility
journal, May 2011

  • Aiyar, Avishek R.; Hong, Jung-Il; Nambiar, Rakesh
  • Advanced Functional Materials, Vol. 21, Issue 14
  • DOI: 10.1002/adfm.201002729

Controllable Growth and Field-Effect Property of Monolayer to Multilayer Microstripes of an Organic Semiconductor
journal, July 2010

  • Li, Liqiang; Gao, Peng; Schuermann, Klaus C.
  • Journal of the American Chemical Society, Vol. 132, Issue 26, p. 8807-8809
  • DOI: 10.1021/ja1017267

High-Mobility Aligned Pentacene Films Grown by Zone-Casting
journal, December 2008

  • Duffy, Claudia M.; Andreasen, Jens W.; Breiby, Dag W.
  • Chemistry of Materials, Vol. 20, Issue 23
  • DOI: 10.1021/cm801689f

Contact-Induced Nucleation in High-Performance Bottom-Contact Organic Thin Film Transistors Manufactured by Large-Area Compatible Solution Processing
journal, September 2015

  • Niazi, Muhammad R.; Li, Ruipeng; Abdelsamie, Maged
  • Advanced Functional Materials, Vol. 26, Issue 14
  • DOI: 10.1002/adfm.201502428

Macroscopic Alignment of One-Dimensional Conjugated Polymer Nanocrystallites for High-Mobility Organic Field-Effect Transistors
journal, May 2016

  • Chang, Mincheol; Choi, Dalsu; Egap, Eilaf
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 21
  • DOI: 10.1021/acsami.6b02216

Direct Uniaxial Alignment of a Donor–Acceptor Semiconducting Polymer Using Single-Step Solution Shearing
journal, March 2016

  • Shaw, Leo; Hayoz, Pascal; Diao, Ying
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 14
  • DOI: 10.1021/acsami.6b01607

Conjugated Polymer Alignment: Synergisms Derived from Microfluidic Shear Design and UV Irradiation
journal, September 2016

  • Wang, Gang; Chu, Ping-Hsun; Fu, Boyi
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 37
  • DOI: 10.1021/acsami.6b07548

2D Versus 3D Crystalline Order in Thin Films of Regioregular Poly(3-hexylthiophene) Oriented by Mechanical Rubbing and Epitaxy
journal, September 2011

  • Hartmann, Lucia; Tremel, Kim; Uttiya, Sureeporn
  • Advanced Functional Materials, Vol. 21, Issue 21
  • DOI: 10.1002/adfm.201101139

Anisotropic Structure and Charge Transport in Highly Strain-Aligned Regioregular Poly(3-hexylthiophene)
journal, August 2011

  • O'Connor, Brendan; Kline, R. Joseph; Conrad, Brad R.
  • Advanced Functional Materials, Vol. 21, Issue 19
  • DOI: 10.1002/adfm.201100904

A Physicochemical Approach Toward Extending Conjugation and the Ordering of Solution-Processable Semiconducting Polymers
journal, February 2016

  • Lee, Minjung; Jeon, Hyeonyeol; Jang, Mi
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 7
  • DOI: 10.1021/acsami.5b12552

Toward Precision Control of Nanofiber Orientation in Conjugated Polymer Thin Films: Impact on Charge Transport
journal, December 2016


Nucleation, Growth, and Alignment of Poly(3-hexylthiophene) Nanofibers for High-Performance OFETs
journal, February 2017


Solution coating of large-area organic semiconductor thin films with aligned single-crystalline domains
journal, June 2013

  • Diao, Ying; Tee, Benjamin C-K.; Giri, Gaurav
  • Nature Materials, Vol. 12, Issue 7
  • DOI: 10.1038/nmat3650

General Strategy for Self-Assembly of Highly Oriented Nanocrystalline Semiconducting Polymers with High Mobility
journal, April 2014

  • Luo, Chan; Kyaw, Aung Ko Ko; Perez, Louis A.
  • Nano Letters, Vol. 14, Issue 5
  • DOI: 10.1021/nl500758w

Anisotropy of Charge Transport in a Uniaxially Aligned and Chain-Extended, High-Mobility, Conjugated Polymer Semiconductor
journal, January 2011

  • Lee, Mi Jung; Gupta, Dhritiman; Zhao, Ni
  • Advanced Functional Materials, Vol. 21, Issue 5
  • DOI: 10.1002/adfm.201001781

Template-Guided Solution-Shearing Method for Enhanced Charge Carrier Mobility in Diketopyrrolopyrrole-Based Polymer Field-Effect Transistors
journal, June 2014

  • Shin, Jicheol; Hong, Tae Ryang; Lee, Tae Wan
  • Advanced Materials, Vol. 26, Issue 34
  • DOI: 10.1002/adma.201401179

Solution-processable pentacene microcrystal arrays for high performance organic field-effect transistors
journal, March 2007

  • Lee, Wi Hyoung; Kim, Do Hwan; Jang, Yunseok
  • Applied Physics Letters, Vol. 90, Issue 13
  • DOI: 10.1063/1.2717087

Ultra-flexible solution-processed organic field-effect transistors
journal, January 2012

  • Yi, Hee Taek; Payne, Marcia M.; Anthony, John E.
  • Nature Communications, Vol. 3, Issue 1
  • DOI: 10.1038/ncomms2263

Control of the Morphology and Structural Development of Solution-Processed Functionalized Acenes for High-Performance Organic Transistors
journal, May 2009

  • Lim, Jung Ah; Lee, Hwa Sung; Lee, Wi Hyoung
  • Advanced Functional Materials, Vol. 19, Issue 10
  • DOI: 10.1002/adfm.200801135

Very High Mobility in Solution-Processed Organic Thin-Film Transistors of Highly Ordered [1]Benzothieno[3,2-b]benzothiophene Derivatives
journal, November 2009

  • Uemura, Takafumi; Hirose, Yuri; Uno, Mayumi
  • Applied Physics Express, Vol. 2, Issue 11, Article No. 111501
  • DOI: 10.1143/APEX.2.111501

High-Mobility Field-Effect Transistors from Large-Area Solution-Grown Aligned C60 Single Crystals
journal, January 2012

  • Li, Hanying; Tee, Benjamin C-K.; Cha, Judy J.
  • Journal of the American Chemical Society, Vol. 134, Issue 5, p. 2760-2765
  • DOI: 10.1021/ja210430b

Alignment and Patterning of Ordered Small-Molecule Organic Semiconductor Micro-/Nanocrystals for Device Applications
journal, January 2016


About Supramolecular Assemblies of π-Conjugated Systems
journal, April 2005

  • Hoeben, Freek J. M.; Jonkheijm, Pascal; Meijer, E. W.
  • Chemical Reviews, Vol. 105, Issue 4
  • DOI: 10.1021/cr030070z

Liquid Crystalline Poly(3-hexylthiophene) Solutions Revisited: Role of Time-Dependent Self-Assembly
journal, March 2015


Patterned deposition at moving contact lines
journal, April 2014


Morphology control for high performance organic thin film transistors
journal, January 2011

  • Shao, Wei; Dong, Huanli; Jiang, Lang
  • Chem. Sci., Vol. 2, Issue 4
  • DOI: 10.1039/C0SC00502A

Controlling the Field-Effect Mobility of Regioregular Polythiophene by Changing the Molecular Weight
journal, September 2003

  • Kline, R. J.; McGehee, M. D.; Kadnikova, E. N.
  • Advanced Materials, Vol. 15, Issue 18
  • DOI: 10.1002/adma.200305275

The impact of molecular weight on microstructure and charge transport in semicrystalline polymer semiconductors–poly(3-hexylthiophene), a model study
journal, December 2013


Aligned Polythiophene and its Blend Film by Direct-Writing for Anisotropic Charge Transport
journal, May 2014

  • Lu, Guanghao; Chen, Jiayue; Xu, Wentao
  • Advanced Functional Materials, Vol. 24, Issue 31
  • DOI: 10.1002/adfm.201400699

Oriented Poly(3-hexylthiophene) Nanofibril with the π−π Stacking Growth Direction by Solvent Directional Evaporation
journal, April 2011

  • Liu, Jiangang; Sun, Yue; Gao, Xiang
  • Langmuir, Vol. 27, Issue 7
  • DOI: 10.1021/la105109t

Two-dimensional charge transport in self-organized, high-mobility conjugated polymers
journal, October 1999

  • Sirringhaus, H.; Brown, P. J.; Friend, R. H.
  • Nature, Vol. 401, Issue 6754, p. 685-688
  • DOI: 10.1038/44359

Highly anisotropic P3HT films with enhanced thermoelectric performance via organic small molecule epitaxy
journal, July 2016

  • Qu, Sanyin; Yao, Qin; Wang, Liming
  • NPG Asia Materials, Vol. 8, Issue 7
  • DOI: 10.1038/am.2016.97

Inkjet-Assisted Nanotransfer Printing for Large-Scale Integrated Nanopatterns of Various Single-Crystal Organic Materials
journal, February 2016

  • Park, Kyung Sun; Baek, Jangmi; Park, Yoonkyung
  • Advanced Materials, Vol. 28, Issue 15
  • DOI: 10.1002/adma.201505594