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Title: A conversion-based highly energy dense Cu 2+ intercalated Bi-birnessite/Zn alkaline battery

Abstract

A conversion-based highly energy dense Cu 2+intercalated Bi-birnessite/Zn battery with a cycle life of 900 cycles is reported.

Authors:
ORCiD logo [1];  [1];  [1];  [1]; ORCiD logo [1];  [1];  [2];  [1]
  1. The CUNY Energy Institute at the City College of New York; Department of Chemical Engineering; New York; USA
  2. Department of Physics; The City College of New York; CUNY; New York; USA
Publication Date:
Research Org.:
City Univ. of New York (CUNY), NY (United States)
Sponsoring Org.:
USDOE Advanced Research Projects Agency - Energy (ARPA-E)
OSTI Identifier:
1535262
DOE Contract Number:  
AR0000150
Resource Type:
Journal Article
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Volume: 5; Journal Issue: 30; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
Chemistry; Energy & Fuels; Materials Science

Citation Formats

Yadav, Gautam G., Wei, Xia, Huang, Jinchao, Gallaway, Joshua W., Turney, Damon E., Nyce, Michael, Secor, Jeff, and Banerjee, Sanjoy. A conversion-based highly energy dense Cu 2+ intercalated Bi-birnessite/Zn alkaline battery. United States: N. p., 2017. Web. doi:10.1039/c7ta05347a.
Yadav, Gautam G., Wei, Xia, Huang, Jinchao, Gallaway, Joshua W., Turney, Damon E., Nyce, Michael, Secor, Jeff, & Banerjee, Sanjoy. A conversion-based highly energy dense Cu 2+ intercalated Bi-birnessite/Zn alkaline battery. United States. doi:10.1039/c7ta05347a.
Yadav, Gautam G., Wei, Xia, Huang, Jinchao, Gallaway, Joshua W., Turney, Damon E., Nyce, Michael, Secor, Jeff, and Banerjee, Sanjoy. Sun . "A conversion-based highly energy dense Cu 2+ intercalated Bi-birnessite/Zn alkaline battery". United States. doi:10.1039/c7ta05347a.
@article{osti_1535262,
title = {A conversion-based highly energy dense Cu 2+ intercalated Bi-birnessite/Zn alkaline battery},
author = {Yadav, Gautam G. and Wei, Xia and Huang, Jinchao and Gallaway, Joshua W. and Turney, Damon E. and Nyce, Michael and Secor, Jeff and Banerjee, Sanjoy},
abstractNote = {A conversion-based highly energy dense Cu2+intercalated Bi-birnessite/Zn battery with a cycle life of 900 cycles is reported.},
doi = {10.1039/c7ta05347a},
journal = {Journal of Materials Chemistry. A},
issn = {2050-7488},
number = 30,
volume = 5,
place = {United States},
year = {2017},
month = {1}
}

Works referenced in this record:

Progress in electrical energy storage system: A critical review
journal, March 2009


Rechargeability and economic aspects of alkaline zinc–manganese dioxide cells for electrical storage and load leveling
journal, February 2015


Hetaerolite Profiles in Alkaline Batteries Measured by High Energy EDXRD
journal, November 2014

  • Gallaway, Joshua W.; Menard, Melissa; Hertzberg, Benjamin
  • Journal of The Electrochemical Society, Vol. 162, Issue 1
  • DOI: 10.1149/2.0811501jes

Operando identification of the point of [Mn2]O4 spinel formation during γ-MnO2 discharge within batteries
journal, July 2016


Rechargeable Zinc Alkaline Anodes for Long-Cycle Energy Storage
journal, May 2017


Electrochemical reactions in batteries. Emphasizing the MnO2 cathode of dry cells
journal, September 1972

  • Kozawa, Akiya; Powers, R. A.
  • Journal of Chemical Education, Vol. 49, Issue 9
  • DOI: 10.1021/ed049p587

The rechargeability of manganese dioxide in alkaline electrolyte
journal, October 1981


Impact of cathode additives on the cycling performance of rechargeable alkaline manganese dioxide–zinc batteries for energy storage applications
journal, December 2016

  • Mehta, Sean A.; Bonakdarpour, Arman; Wilkinson, David P.
  • Journal of Applied Electrochemistry, Vol. 47, Issue 2
  • DOI: 10.1007/s10800-016-1034-1

Rechargeable Cells with Modified MnO[sub 2] Cathodes
journal, January 1988

  • Dzieciuch, M. A.
  • Journal of The Electrochemical Society, Vol. 135, Issue 10
  • DOI: 10.1149/1.2095349

Rechargeable manganese oxide electrodes
journal, December 1987

  • Wroblowa, H. S.; Gupta, N.
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 238, Issue 1-2
  • DOI: 10.1016/0022-0728(87)85167-7

Rechargeable manganese oxide electrodes
journal, May 1987

  • Yao, Yung Fang; Gupta, N.; Wroblowa, H. S.
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 223, Issue 1-2
  • DOI: 10.1016/0022-0728(87)85254-3

Effect of Multiple Cation Electrolyte Mixtures on Rechargeable Zn–MnO 2 Alkaline Battery
journal, June 2016


Regenerable Cu-intercalated MnO2 layered cathode for highly cyclable energy dense batteries
journal, March 2017

  • Yadav, Gautam G.; Gallaway, Joshua W.; Turney, Damon E.
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms14424

Redox Processes at the Manganese Dioxide Electrode
journal, January 1997

  • Donne, Scott W.
  • Journal of The Electrochemical Society, Vol. 144, Issue 9
  • DOI: 10.1149/1.1837944

Redox Processes at the Manganese Dioxide Electrode
journal, January 1997

  • Donne, Scott W.
  • Journal of The Electrochemical Society, Vol. 144, Issue 9
  • DOI: 10.1149/1.1837943

Rechargeability of MnO[sub 2] in KOH Media Produced by Decomposition of Dissolved KMnO[sub 4] and Bi(NO[sub 3])[sub 3] Mixtures
journal, January 1997

  • Bodé, M.
  • Journal of The Electrochemical Society, Vol. 144, Issue 3
  • DOI: 10.1149/1.1837491

Rechargeability of MnO[sub 2] in KOH Media Produced by Decomposition of Dissolved KMnO[sub 4] and Bi(NO[sub 3])[sub 3] Mixtures
journal, January 1997

  • Yu, L. T.
  • Journal of The Electrochemical Society, Vol. 144, Issue 3
  • DOI: 10.1149/1.1837492

Electrodeposition of preferentially oriented zinc for flow-assisted alkaline batteries
journal, June 2014


An indicator of zinc morphology transition in flowing alkaline electrolyte
journal, August 2012


Development and testing of an economic grid-scale flow-assisted zinc/nickel-hydroxide alkaline battery
journal, October 2014


Life-cycle analysis of flow-assisted nickel zinc-, manganese dioxide-, and valve-regulated lead-acid batteries designed for demand-charge reduction
journal, March 2015

  • Spanos, Constantine; Turney, Damon E.; Fthenakis, Vasilis
  • Renewable and Sustainable Energy Reviews, Vol. 43
  • DOI: 10.1016/j.rser.2014.10.072

Impact of anode substrates on electrodeposited zinc over cycling in zinc-anode rechargeable alkaline batteries
journal, September 2016


The Cathodic Reduction Mechanism of Electrolytic Manganese Dioxide in Alkaline Electrolyte
journal, January 1965

  • Kozawa, A.; Yeager, J. F.
  • Journal of The Electrochemical Society, Vol. 112, Issue 10
  • DOI: 10.1149/1.2423350

Rechargeability of a Chemically Modified MnO[sub 2]∕Zn Battery System at Practically Favorable Power Levels
journal, January 1993

  • Bai, L.
  • Journal of The Electrochemical Society, Vol. 140, Issue 4
  • DOI: 10.1149/1.2056222

Raman spectroscopy of AMn2O4 (A = Mn, Mg and Zn) spinels
journal, June 2002

  • Malavasi, Lorenzo; Galinetto, Pietro; Mozzati, Maria C.
  • Physical Chemistry Chemical Physics, Vol. 4, Issue 15
  • DOI: 10.1039/b203520k

First-Order Raman Effect in Wurtzite-Type Crystals
journal, May 1969


Electrochemically-induced reversible transition from the tunneled to layered polymorphs of manganese dioxide
journal, August 2014

  • Lee, Boeun; Yoon, Chong Seung; Lee, Hae Ri
  • Scientific Reports, Vol. 4, Issue 1
  • DOI: 10.1038/srep06066

Elucidating the intercalation mechanism of zinc ions into α-MnO 2 for rechargeable zinc batteries
journal, January 2015

  • Lee, Boeun; Lee, Hae Ri; Kim, Haesik
  • Chemical Communications, Vol. 51, Issue 45
  • DOI: 10.1039/C5CC02585K

A calcium hydroxide interlayer as a selective separator for rechargeable alkaline Zn/MnO2 batteries
journal, August 2017


Development of long-lived high-performance zinc-calcium/nickel oxide cells
journal, November 1992

  • Jain, R.; Adler, T. C.; McLarnon, F. R.
  • Journal of Applied Electrochemistry, Vol. 22, Issue 11
  • DOI: 10.1007/BF01029582

Formation and Decomposition Kinetic Studies of Calcium Zincate in 20 w∕o KOH
journal, January 1986

  • Wang, Yar-Ming
  • Journal of The Electrochemical Society, Vol. 133, Issue 9
  • DOI: 10.1149/1.2109037

Effect of KOH Concentration on the Formation and Decomposition Kinetics of Calcium Zincate
journal, January 1990

  • Wang, Yar-Ming
  • Journal of The Electrochemical Society, Vol. 137, Issue 9
  • DOI: 10.1149/1.2087076

Rechargeable nickel–3D zinc batteries: An energy-dense, safer alternative to lithium-ion
journal, April 2017

  • Parker, Joseph F.; Chervin, Christopher N.; Pala, Irina R.
  • Science, Vol. 356, Issue 6336
  • DOI: 10.1126/science.aak9991