Ta-Doped SrCoO 3-δ as a promising bifunctional oxygen electrode for reversible solid oxide fuel cells: a focused study on stability

Wang, Jie; Yang, Tianrang; Lei, Libin; Huang, Kevin

doi:10.1039/c7ta02003a

Title: Ta-Doped SrCoO _3-δ as a promising bifunctional oxygen electrode for reversible solid oxide fuel cells: a focused study on stability

Journal Article · Sun Jan 01 00:00:00 EST 2017 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/c7ta02003a· OSTI ID:1535254

Wang, Jie ^[1]; Yang, Tianrang ^[1]; Lei, Libin ^[1];

^[1]

Department of Mechanical Engineering; University of South Carolina; Columbia; USA

The present work reports a thorough investigation into the structural, thermal, electrical and electrochemical properties of 10 mol% Ta-doped SrCoO_3-δ(denoted as SCT10) as a promising bifunctional oxygen electrode for intermediate-temperature reversible solid oxide fuel cells.

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Research Organization:: Univ. of South Carolina, Columbia, SC (United States); Univ. of Pennsylvania, Philadelphia, PA (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

DOE Contract Number:: AR0000492; FE0023317

OSTI ID:: 1535254

Journal Information:: Journal of Materials Chemistry. A, Vol. 5, Issue 19; ISSN 2050-7488

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (58)

A New Family of Mo-Doped SrCoO _3−δ Perovskites for Application in Reversible Solid State Electrochemical Cells Aguadero, A.; Pérez-Coll, D.; Alonso, J. A. Chemistry of Materials, Vol. 24, Issue 14 https://doi.org/10.1021/cm300255r	journal	July 2012
Thermal expansion of Gd-doped ceria and reduced ceria Hayashi, H. Solid State Ionics, Vol. 132, Issue 3-4 https://doi.org/10.1016/S0167-2738(00)00646-9	journal	July 2000
Novel SrCo1−yNbyO3−δ cathodes for intermediate-temperature solid oxide fuel cells Wang, Fang; Zhou, Qingjun; He, Tianmin Journal of Power Sources, Vol. 195, Issue 12 https://doi.org/10.1016/j.jpowsour.2009.12.081	journal	June 2010
Time-Resolved in Situ Studies of Oxygen Intercalation into SrCoO_2.5, Performed by Neutron Diffraction and X-ray Absorption Spectroscopy Le Toquin, Ronan; Paulus, Werner; Cousson, Alain Journal of the American Chemical Society, Vol. 128, Issue 40, p. 13161-13174 https://doi.org/10.1021/ja063207m	journal	October 2006
Oxygen-Deficient Perovskite Sr _0.7 Y _0.3 CoO _2.65−δ as a Cathode for Intermediate-Temperature Solid Oxide Fuel Cells Li, Yan; Kim, Young N.; Cheng, Jinguang Chemistry of Materials, Vol. 23, Issue 22 https://doi.org/10.1021/cm202542q	journal	November 2011
Bulk Properties of the Oxygen Reduction Catalyst SrCo _0.9 Nb _0.1 O _3−δ Usiskin, Robert E.; Davenport, Timothy C.; Wang, Richard Y. Chemistry of Materials, Vol. 28, Issue 8 https://doi.org/10.1021/acs.chemmater.5b04783	journal	April 2016
LnBaCo[sub 2]O[sub 5+δ] Oxides as Cathodes for Intermediate-Temperature Solid Oxide Fuel Cells Kim, J. -H.; Manthiram, A. Journal of The Electrochemical Society, Vol. 155, Issue 4 https://doi.org/10.1149/1.2839028	journal	January 2008
Reversible redox reactions in an epitaxially stabilized SrCoOx oxygen sponge Jeen, Hyoungjeen; Choi, Woo Seok; Biegalski, Michael D. Nature Materials, Vol. 12, Issue 11 https://doi.org/10.1038/nmat3736	journal	August 2013
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Defect Chemistry and Catalysis in Oxidation and Reduction over Perovskite-Type Oxides Voorhoeve, R. J. H.; Remeika, J. P.; Trimble, L. E. Annals of the New York Academy of Sciences, Vol. 272, Issue 1 Catalitic Che https://doi.org/10.1111/j.1749-6632.1976.tb34221.x	journal	April 1976
A novel efficient oxide electrode for electrocatalytic oxygen reduction at 400–600 °C Zhou, Wei; Shao, Zongping; Ran, Ran Chemical Communications, Issue 44 https://doi.org/10.1039/b813327a	journal	January 2008
A comparative study of SrCo _0.8 Nb _0.2 O _3−δ and SrCo _0.8 Ta _0.2 O _3−δ as low-temperature solid oxide fuel cell cathodes: effect of non-geometry factors on the oxygen reduction reaction Li, Mengran; Zhou, Wei; Peterson, Vanessa K. Journal of Materials Chemistry A, Vol. 3, Issue 47 https://doi.org/10.1039/C5TA07178J	journal	January 2015
Metal–Insulator Transition and Crystal Structure of La1−xSrxCoO3as Functions of Sr-Content, Temperature, and Oxygen Partial Pressure Mineshige, Atsushi; Kobune, Masafumi; Fujii, Satoshi Journal of Solid State Chemistry, Vol. 142, Issue 2 https://doi.org/10.1006/jssc.1998.8051	journal	February 1999
Effect of DC current polarization on the electrochemical behaviour of La2NiO4+δ and La3Ni2O7+δ-based systems Pérez-Coll, D.; Aguadero, A.; Escudero, M. J. Journal of Power Sources, Vol. 192, Issue 1 https://doi.org/10.1016/j.jpowsour.2008.10.073	journal	July 2009
Comparative Studies of SrCo _{1− x} Ta _x O _{3− δ} ( x =0.05-0.4) Oxides as Cathodes for Low-Temperature Solid-Oxide Fuel Cells Li, Mengran; Zhou, Wei; Zhu, Zhonghua ChemElectroChem, Vol. 2, Issue 9 https://doi.org/10.1002/celc.201500157	journal	June 2015
A Highly Active Perovskite Electrode for the Oxygen Reduction Reaction Below 600 °C Zhou, Wei; Sunarso, Jaka; Zhao, Mingwen Angewandte Chemie International Edition, Vol. 52, Issue 52 https://doi.org/10.1002/anie.201307305	journal	November 2013
Comparison of Oxygen Permeability and Stability of Perovskite Type La _0.2 A _0.8 Co _0.2 Fe _0.8 O _3- _δ (A = Sr, Ba, Ca) Membranes Li, Shiguang; Jin, Wanqin; Huang, Pei Industrial & Engineering Chemistry Research, Vol. 38, Issue 8 https://doi.org/10.1021/ie9900014	journal	August 1999
Thermal expansion coefficient of yttria stabilized zirconia for various yttria contents Hayashi, H.; Saitou, T.; Maruyama, N. Solid State Ionics, Vol. 176, Issue 5-6 https://doi.org/10.1016/j.ssi.2004.08.021	journal	February 2005
Atomic Resolution Analysis of the Defect Chemistry and Microdomain Structure of Brownmillerite-Type Strontium Cobaltite Ito, Yasuo; Klie, Robert F.; Browning, Nigel D. Journal of the American Ceramic Society, Vol. 85, Issue 4 https://doi.org/10.1111/j.1151-2916.2002.tb00201.x	journal	April 2002
A niobium and tantalum co-doped perovskite cathode for solid oxide fuel cells operating below 500 °C Li, Mengran; Zhao, Mingwen; Li, Feng Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms13990	journal	January 2017
Intermediate-temperature electrochemical performance of a polycrystalline PrBaCo2O5+δ cathode on samarium-doped ceria electrolyte Chen, Dengjie; Ran, Ran; Zhang, Kun Journal of Power Sources, Vol. 188, Issue 1 https://doi.org/10.1016/j.jpowsour.2008.11.045	journal	March 2009
Electrochemical investigation of mixed ionic/electronic cathodes for SOFCs Barbucci, A.; Carpanese, P.; Cerisola, G. Solid State Ionics, Vol. 176, Issue 19-22 https://doi.org/10.1016/j.ssi.2005.04.027	journal	June 2005
Recent advances in Perovskite-type materials for solid oxide fuel cell cathodes Skinner, Stephen J. International Journal of Inorganic Materials, Vol. 3, Issue 2 https://doi.org/10.1016/S1466-6049(01)00004-6	journal	March 2001
Improving La0.6Sr0.4Co0.2Fe0.8O3−δ cathode performance by infiltration of a Sm0.5Sr0.5CoO3−δ coating Lou, Xiaoyuan; Wang, Shizhong; Liu, Ze Solid State Ionics, Vol. 180, Issue 23-25 https://doi.org/10.1016/j.ssi.2009.06.014	journal	October 2009
Defect chemistry and surface properties of LaCoO3 Read, Mark S. D.; Saiful Islam, M.; Watson, Graeme W. Journal of Materials Chemistry, Vol. 10, Issue 10 https://doi.org/10.1039/b002168g	journal	January 2000
Thermal and Electrical Stability of Sr _0.9 Y _0.1 CoO _2.5+δ as a Promising Cathode for Intermediate-Temperature Solid Oxide Fuel Cells Jiang, Long; Wang, Jie; Xiong, Xiaolei Journal of The Electrochemical Society, Vol. 163, Issue 5 https://doi.org/10.1149/2.0361605jes	journal	January 2016
A Broad Stability Investigation of Nb-Doped SrCoO _2.5+δ as a Reversible Oxygen Electrode for Intermediate-Temperature Solid Oxide Fuel Cells Wang, Jie; Jiang, Long; Xiong, Xiaolei Journal of The Electrochemical Society, Vol. 163, Issue 8 https://doi.org/10.1149/2.1121608jes	journal	January 2016
A kinetic study of oxygen reduction reaction on La2NiO4 cathodes by means of impedance spectroscopy Escudero, M. J.; Aguadero, A.; Alonso, J. A. Journal of Electroanalytical Chemistry, Vol. 611, Issue 1-2 https://doi.org/10.1016/j.jelechem.2007.08.006	journal	December 2007
Electrical properties of GdBaCo2O5+x for ITSOFC applications Chang, A.; Skinner, S.; Kilner, J. Solid State Ionics, Vol. 177, Issue 19-25 https://doi.org/10.1016/j.ssi.2006.05.047	journal	October 2006
Sr- and Ni-Doped LaCoO[sub 3] and LaFeO[sub 3] Perovskites Huang, Keqin Journal of The Electrochemical Society, Vol. 145, Issue 9 https://doi.org/10.1149/1.1838789	journal	January 1998
Crystal structure, thermal expansion and conductivity of anisotropic La1−xSrxGa1−2xMg2xO3−y (x=0.05, 0.1) single crystals Vasylechko, L.; Vashook, V.; Savytskii, D. Journal of Solid State Chemistry, Vol. 172, Issue 2 https://doi.org/10.1016/S0022-4596(03)00016-1	journal	May 2003
Pauling's Electronegativity Equation and a New Corollary Accurately Predict Bond Dissociation Enthalpies and Enhance Current Understanding of the Nature of the Chemical Bond Matsunaga, Nikita; Rogers, Donald W.; Zavitsas, Andreas A. The Journal of Organic Chemistry, Vol. 68, Issue 8 https://doi.org/10.1021/jo020650g	journal	April 2003
Long term behaviors of La0.8Sr0.2MnO3 and La0.6Sr0.4Co0.2Fe0.8O3 as cathodes for solid oxide fuel cells Lu, Kathy; Shen, Fengyu International Journal of Hydrogen Energy, Vol. 39, Issue 15 https://doi.org/10.1016/j.ijhydene.2014.03.046	journal	May 2014
Preparation and characterization of Fully stoichiometric SrCoO₃ by electrochemical oxidation Bezdicka, P.; Wattiaux, A.; Grenier, J. Zeitschrift fur anorganische und allgemeine Chemie, Vol. 619, Issue 1, p. 7-12 https://doi.org/10.1002/zaac.19936190104	journal	January 1993
Synthesis of silicon doped SrMO3 (M = Mn, Co): stabilization of the cubic perovskite and enhancement in conductivity Hancock, Cathryn A.; Slater, Peter R. Dalton Transactions, Vol. 40, Issue 20 https://doi.org/10.1039/c1dt10253b	journal	January 2011
Investigation of Mixed Conductor BaCo_0.7Fe_0.3−xY_xO_3−δ with High Oxygen Permeability Zhao, Hailei; Xu, Nansheng; Cheng, Yunfei The Journal of Physical Chemistry C, Vol. 114, Issue 41, p. 17975-17981 https://doi.org/10.1021/jp106220z	journal	September 2010
A powder neutron diffraction determination of the structure of Sr ₆ Co ₅ O ₁₅ , formerly described as the low-temperature hexagonal form of SrCoO _3–x Harrison, William T. A.; Hegwood, Steven L.; Jacobson, Allan J. J. Chem. Soc., Chem. Commun., Issue 19 https://doi.org/10.1039/C39950001953	journal	January 1995
A new defect chemistry model for Nb-doped SrCoO2.5+δ: The role of oxygen interstitials and delocalized-to-localized electron holes Wang, Jie; Jin, Xinfang; Huang, Kevin Journal of Solid State Chemistry, Vol. 246 https://doi.org/10.1016/j.jssc.2016.11.008	journal	February 2017
EXPGUI , a graphical user interface for GSAS Toby, Brian H. Journal of Applied Crystallography, Vol. 34, Issue 2 https://doi.org/10.1107/S0021889801002242	journal	April 2001
Rapid oxygen ion diffusion and surface exchange kinetics in PrBaCo2O5+x with a perovskite related structure and ordered A cations Kim, G.; Wang, S.; Jacobson, A. J. Journal of Materials Chemistry, Vol. 17, Issue 24 https://doi.org/10.1039/b618345j	journal	January 2007
Impedance of Solid Oxide Fuel Cell LSM/YSZ Composite Cathodes Jørgensen, M. J.; Mogensen, M. Journal of The Electrochemical Society, Vol. 148, Issue 5 https://doi.org/10.1149/1.1360203	journal	January 2001
Phase relation and oxygen-non-stoichiometry of Perovskite-like Compound SrCoOx (2.29 < x > 2.80) Takeda, Y.; Kanno, R.; Takada, T. Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 540, Issue 9-10 https://doi.org/10.1002/zaac.19865400929	journal	September 1986
Optimization of La1−Sr CoO3− perovskite cathodes for intermediate temperature solid oxide fuel cells through the analysis of crystal structure and electrical properties Gwon, Ohhun; Yoo, Seonyoung; Shin, Jeeyoung International Journal of Hydrogen Energy, Vol. 39, Issue 35 https://doi.org/10.1016/j.ijhydene.2014.07.137	journal	December 2014
Influence of constituent metal cations in substituted LaCoO3 on mixed conductivity and oxygen permeability Teraoka, Y.; Nobunaga, T.; Okamoto, K. Solid State Ionics, Vol. 48, Issue 3-4 https://doi.org/10.1016/0167-2738(91)90034-9	journal	November 1991
Evaluation of pulsed laser deposited SrNb0.1Co0.9O3−δ thin films as promising cathodes for intermediate-temperature solid oxide fuel cells Chen, Dengjie; Chen, Chi; Gao, Yang Journal of Power Sources, Vol. 295 https://doi.org/10.1016/j.jpowsour.2015.07.003	journal	November 2015
Characterization of Sr-Doped LaMnO[sub 3] and LaCoO[sub 3] as Cathode Materials for a Doped LaGaO[sub 3] Ceramic Fuel Cell Huang, Keqin Journal of The Electrochemical Society, Vol. 143, Issue 11 https://doi.org/10.1149/1.1837262	journal	January 1996
SrCo _0.95 Sb _0.05 O _3−δ as Cathode Material for High Power Density Solid Oxide Fuel Cells ^† Aguadero, Ainara; Alonso, José Antonio; Pérez-Coll, Domingo Chemistry of Materials, Vol. 22, Issue 3 https://doi.org/10.1021/cm901423g	journal	February 2010
Cathodic Polarization Phenomena of Perovskite Oxide Electrodes with Stabilized Zirconia Takeda, Y. Journal of The Electrochemical Society, Vol. 134, Issue 11 https://doi.org/10.1149/1.2100267	journal	January 1987
Topotactic Electrochemical Redox Reactions of the Defect Perovskite SrCoO_2.5+x Nemudry, A.; Rudolf, P.; Schollhorn, R. Chemistry of Materials, Vol. 8, Issue 9, p. 2232-2238 https://doi.org/10.1021/cm950504+		September 1996
New families of Mn+-doped SrCo1−xMxO3−δ perovskites performing as cathodes in solid-oxide fuel cells Cascos, V.; Troncoso, L.; Alonso, J. A. International Journal of Hydrogen Energy, Vol. 40, Issue 34 https://doi.org/10.1016/j.ijhydene.2015.03.134	journal	September 2015
Influence of M cations on structural, thermal and electrical properties of new oxygen selective membranes based on SrCo0.95M0.05O3−δ perovskite Zeng, Pingying; Shao, Zongping; Liu, Shaomin Separation and Purification Technology, Vol. 67, Issue 3 https://doi.org/10.1016/j.seppur.2009.03.047	journal	June 2009
SrCo1−yTiyO3−δ as potential cathode materials for intermediate-temperature solid oxide fuel cells Shen, Yu; Wang, Fang; Ma, Xin Journal of Power Sources, Vol. 196, Issue 18 https://doi.org/10.1016/j.jpowsour.2011.04.025	journal	September 2011
Characteristics of SrCo1−xSnxO3−δ cathode materials for use in solid oxide fuel cells Wang, Sea-Fue; Hsu, Yung-Fu; Yeh, Chun-Ting Solid State Ionics, Vol. 227 https://doi.org/10.1016/j.ssi.2012.08.020	journal	October 2012
Electrochemical Investigation of Composite Cathodes with SmBa _0.5 Sr _0.5 Co ₂ O _5+δ Cathodes for Intermediate Temperature-Operating Solid Oxide Fuel Cell ^† Kim, Jung Hyun; Cassidy, Mark; Irvine, John T. S. Chemistry of Materials, Vol. 22, Issue 3 https://doi.org/10.1021/cm901720w	journal	February 2010
Relationship between cation substitution and stability of perovskite structure in SrCoO3–δ-based mixed conductors Nagai, T.; Ito, W.; Sakon, T. Solid State Ionics, Vol. 177, Issue 39-40 https://doi.org/10.1016/j.ssi.2006.10.022	journal	January 2007
A computational modelling study of oxygen vacancies at LaCoO3 perovskite surfaces Khan, S.; Oldman, R. J.; Cor?, F. Physical Chemistry Chemical Physics, Vol. 8, Issue 44 https://doi.org/10.1039/b602753a	journal	January 2006
Comparison of Ln[sub 0.6]Sr[sub 0.4]CoO[sub 3−δ] (Ln=La, Pr, Nd, Sm, and Gd) as Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells Lee, K. T.; Manthiram, A. Journal of The Electrochemical Society, Vol. 153, Issue 4 https://doi.org/10.1149/1.2172572	journal	January 2006
An A-Site-Deficient Perovskite offers High Activity and Stability for Low-Temperature Solid-Oxide Fuel Cells Zhu, Yinlong; Chen, Zhi-Gang; Zhou, Wei ChemSusChem, Vol. 6, Issue 12 https://doi.org/10.1002/cssc.201300694	journal	October 2013

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