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Title: A binary metal organic framework derived hierarchical hollow Ni 3 S 2 /Co 9 S 8 /N-doped carbon composite with superior sodium storage performance

Abstract

The carbonization and sulfurization of a hierarchical hollow MOF leads to anode materials with exceptional performance in Na +batteries with high cycle stability and rate performance.

Authors:
 [1];  [1];  [1];  [2];  [1];  [1]; ORCiD logo [2]; ORCiD logo [1]
  1. Department of Polymer Science; University of Akron; Akron; USA
  2. Department of Polymer Engineering; University of Akron; Akron; USA
Publication Date:
Research Org.:
pH Matter, LLC, Columbus, OH (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1535249
DOE Contract Number:  
SC0013831
Resource Type:
Journal Article
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Volume: 5; Journal Issue: 23; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
Chemistry; Energy & Fuels; Materials Science

Citation Formats

Liu, Xinye, Zou, Feng, Liu, Kewei, Qiang, Zhe, Taubert, Clinton J., Ustriyana, Putu, Vogt, Bryan D., and Zhu, Yu. A binary metal organic framework derived hierarchical hollow Ni 3 S 2 /Co 9 S 8 /N-doped carbon composite with superior sodium storage performance. United States: N. p., 2017. Web. doi:10.1039/c7ta00201g.
Liu, Xinye, Zou, Feng, Liu, Kewei, Qiang, Zhe, Taubert, Clinton J., Ustriyana, Putu, Vogt, Bryan D., & Zhu, Yu. A binary metal organic framework derived hierarchical hollow Ni 3 S 2 /Co 9 S 8 /N-doped carbon composite with superior sodium storage performance. United States. doi:10.1039/c7ta00201g.
Liu, Xinye, Zou, Feng, Liu, Kewei, Qiang, Zhe, Taubert, Clinton J., Ustriyana, Putu, Vogt, Bryan D., and Zhu, Yu. Sun . "A binary metal organic framework derived hierarchical hollow Ni 3 S 2 /Co 9 S 8 /N-doped carbon composite with superior sodium storage performance". United States. doi:10.1039/c7ta00201g.
@article{osti_1535249,
title = {A binary metal organic framework derived hierarchical hollow Ni 3 S 2 /Co 9 S 8 /N-doped carbon composite with superior sodium storage performance},
author = {Liu, Xinye and Zou, Feng and Liu, Kewei and Qiang, Zhe and Taubert, Clinton J. and Ustriyana, Putu and Vogt, Bryan D. and Zhu, Yu},
abstractNote = {The carbonization and sulfurization of a hierarchical hollow MOF leads to anode materials with exceptional performance in Na+batteries with high cycle stability and rate performance.},
doi = {10.1039/c7ta00201g},
journal = {Journal of Materials Chemistry. A},
issn = {2050-7488},
number = 23,
volume = 5,
place = {United States},
year = {2017},
month = {1}
}

Works referenced in this record:

Building better batteries
journal, February 2008

  • Armand, M.; Tarascon, J.-M.
  • Nature, Vol. 451, Issue 7179, p. 652-657
  • DOI: 10.1038/451652a

Tin and Tin Compounds for Sodium Ion Battery Anodes: Phase Transformations and Performance
journal, May 2015


Na-Ion Battery Anodes: Materials and Electrochemistry
journal, January 2016


Lithium-ion batteries. A look into the future
journal, January 2011

  • Scrosati, Bruno; Hassoun, Jusef; Sun, Yang-Kook
  • Energy & Environmental Science, Vol. 4, Issue 9
  • DOI: 10.1039/c1ee01388b

Recent Advances and Prospects of Cathode Materials for Sodium-Ion Batteries
journal, August 2015


Recent developments in electrode materials for sodium-ion batteries
journal, January 2015

  • Wang, Luyuan Paul; Yu, Linghui; Wang, Xin
  • Journal of Materials Chemistry A, Vol. 3, Issue 18
  • DOI: 10.1039/C4TA06467D

3D Porous γ-Fe 2 O 3 @C Nanocomposite as High-Performance Anode Material of Na-Ion Batteries
journal, November 2014

  • Zhang, Ning; Han, Xiaopeng; Liu, Yongchang
  • Advanced Energy Materials, Vol. 5, Issue 5
  • DOI: 10.1002/aenm.201401123

Transition metal oxides for high performance sodium ion battery anodes
journal, April 2014


Cobalt sulfides/dodecahedral porous carbon as anode materials for Na-ion batteries
journal, January 2015

  • Zhang, Zhian; Gan, Yongqing; Lai, Yanqing
  • RSC Advances, Vol. 5, Issue 125
  • DOI: 10.1039/C5RA21589G

Few-Layered SnS 2 on Few-Layered Reduced Graphene Oxide as Na-Ion Battery Anode with Ultralong Cycle Life and Superior Rate Capability
journal, November 2014

  • Zhang, Yandong; Zhu, Peiyi; Huang, Liliang
  • Advanced Functional Materials, Vol. 25, Issue 3
  • DOI: 10.1002/adfm.201402833

Metal organic frameworks-derived Co 3 O 4 hollow dodecahedrons with controllable interiors as outstanding anodes for Li storage
journal, January 2014

  • Shao, Jie; Wan, Zhongming; Liu, Hongmei
  • J. Mater. Chem. A, Vol. 2, Issue 31
  • DOI: 10.1039/C4TA01966K

MOF-Derived Porous ZnO/ZnFe 2 O 4 /C Octahedra with Hollow Interiors for High-Rate Lithium-Ion Batteries
journal, August 2014


Preparation and Exceptional Lithium Anodic Performance of Porous Carbon-Coated ZnO Quantum Dots Derived from a Metal–Organic Framework
journal, May 2013

  • Yang, Seung Jae; Nam, Seunghoon; Kim, Taehoon
  • Journal of the American Chemical Society, Vol. 135, Issue 20
  • DOI: 10.1021/ja311550t

Metal Organic Frameworks Derived Hierarchical Hollow NiO/Ni/Graphene Composites for Lithium and Sodium Storage
journal, November 2015


Porous cubes constructed by cobalt oxide nanocrystals with graphene sheet coatings for enhanced lithium storage properties
journal, January 2016

  • Geng, Hongbo; Guo, Yuanyuan; Ding, Xianguang
  • Nanoscale, Vol. 8, Issue 14
  • DOI: 10.1039/C6NR01024E

Rational design of Co 3 O 4 /Co/carbon nanocages composites from metal organic frameworks as an advanced lithium-ion battery anode
journal, May 2017


Synthesis and Lithium Storage Properties of Co3O4 Nanosheet-Assembled Multishelled Hollow Spheres
journal, May 2010

  • Wang, Xi; Wu, Xing-Long; Guo, Yu-Guo
  • Advanced Functional Materials, Vol. 20, Issue 10
  • DOI: 10.1002/adfm.200902295

Coral-like α-MnS composites with N-doped carbon as anode materials for high-performance lithium-ion batteries
journal, January 2012

  • Liu, Yang; Qiao, Yun; Zhang, Wu-Xing
  • Journal of Materials Chemistry, Vol. 22, Issue 45
  • DOI: 10.1039/c2jm35227c

Formation of Uniform Fe 3 O 4 Hollow Spheres Organized by Ultrathin Nanosheets and Their Excellent Lithium Storage Properties
journal, June 2015


Cobalt Hydroxide/Oxide Hexagonal Ring–Graphene Hybrids through Chemical Etching of Metal Hydroxide Platelets by Graphene Oxide: Energy Storage Applications
journal, February 2014

  • Nethravathi, C.; Rajamathi, Catherine R.; Rajamathi, Michael
  • ACS Nano, Vol. 8, Issue 3
  • DOI: 10.1021/nn406480g

Graphene Anchored with Co3O4 Nanoparticles as Anode of Lithium Ion Batteries with Enhanced Reversible Capacity and Cyclic Performance
journal, June 2010

  • Wu, Zhong-Shuai; Ren, Wencai; Wen, Lei
  • ACS Nano, Vol. 4, Issue 6, p. 3187-3194
  • DOI: 10.1021/nn100740x

Nitrogen-doped, carbon-rich, highly photoluminescent carbon dots from ammonium citrate
journal, January 2014


Enhancing Electrocatalytic Oxygen Reduction on Nitrogen-Doped Graphene by Active Sites Implantation
journal, November 2013

  • Feng, Leiyu; Yang, Lanqin; Huang, Zujing
  • Scientific Reports, Vol. 3, Issue 1
  • DOI: 10.1038/srep03306

Microwave-Induced In Situ Synthesis of Zn 2 GeO 4 /N-Doped Graphene Nanocomposites and Their Lithium-Storage Properties
journal, March 2013

  • Zou, Feng; Hu, Xianluo; Sun, Yongming
  • Chemistry - A European Journal, Vol. 19, Issue 19
  • DOI: 10.1002/chem.201204588

Update on anode materials for Na-ion batteries
journal, January 2015

  • Kang, Hongyan; Liu, Yongchang; Cao, Kangzhe
  • Journal of Materials Chemistry A, Vol. 3, Issue 35
  • DOI: 10.1039/C5TA03181H

Improved electrochemical performance of CoS 2 –MWCNT nanocomposites for sodium-ion batteries
journal, January 2015

  • Shadike, Zulipiya; Cao, Ming-Hui; Ding, Fei
  • Chemical Communications, Vol. 51, Issue 52
  • DOI: 10.1039/C5CC02564H

Nickel Disulfide–Graphene Nanosheets Composites with Improved Electrochemical Performance for Sodium Ion Battery
journal, March 2016

  • Wang, Tianshi; Hu, Pu; Zhang, Chuanjian
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 12
  • DOI: 10.1021/acsami.6b00179

MoS 2 /Graphene Composite Paper for Sodium-Ion Battery Electrodes
journal, January 2014

  • David, Lamuel; Bhandavat, Romil; Singh, Gurpreet
  • ACS Nano, Vol. 8, Issue 2
  • DOI: 10.1021/nn406156b

Pyrite FeS 2 for high-rate and long-life rechargeable sodium batteries
journal, January 2015

  • Hu, Zhe; Zhu, Zhiqiang; Cheng, Fangyi
  • Energy & Environmental Science, Vol. 8, Issue 4
  • DOI: 10.1039/C4EE03759F