skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Photoelectrochemical ion concentration polarization: membraneless ion filtration based on light-driven electrochemical reactions

Abstract

A membrane-free photoelectrochemical device is able to partially desalinate water.

Authors:
 [1];  [1];  [1]; ORCiD logo [1]
  1. Department of Chemistry; The University of Texas at Austin; Austin; USA
Publication Date:
Research Org.:
Univ. of Texas, Austin, TX (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1535232
DOE Contract Number:  
FG02-06ER15758
Resource Type:
Journal Article
Journal Name:
Lab on a chip (Print)
Additional Journal Information:
Journal Volume: 17; Journal Issue: 14; Journal ID: ISSN 1473-0197
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
Biochemistry & Molecular Biology; Chemistry; Science & Technology - Other Topics

Citation Formats

Yoon, Eunsoo, Davies, Collin D., Hooper, Tim A., and Crooks, Richard M. Photoelectrochemical ion concentration polarization: membraneless ion filtration based on light-driven electrochemical reactions. United States: N. p., 2017. Web. doi:10.1039/c7lc00455a.
Yoon, Eunsoo, Davies, Collin D., Hooper, Tim A., & Crooks, Richard M. Photoelectrochemical ion concentration polarization: membraneless ion filtration based on light-driven electrochemical reactions. United States. doi:10.1039/c7lc00455a.
Yoon, Eunsoo, Davies, Collin D., Hooper, Tim A., and Crooks, Richard M. Sun . "Photoelectrochemical ion concentration polarization: membraneless ion filtration based on light-driven electrochemical reactions". United States. doi:10.1039/c7lc00455a.
@article{osti_1535232,
title = {Photoelectrochemical ion concentration polarization: membraneless ion filtration based on light-driven electrochemical reactions},
author = {Yoon, Eunsoo and Davies, Collin D. and Hooper, Tim A. and Crooks, Richard M.},
abstractNote = {A membrane-free photoelectrochemical device is able to partially desalinate water.},
doi = {10.1039/c7lc00455a},
journal = {Lab on a chip (Print)},
issn = {1473-0197},
number = 14,
volume = 17,
place = {United States},
year = {2017},
month = {1}
}

Works referenced in this record:

Recent advancements in ion concentration polarization
journal, January 2016


Theory and experiments of concentration polarization and ion focusing at microchannel and nanochannel interfaces
journal, January 2010

  • Zangle, Thomas A.; Mani, Ali; Santiago, Juan G.
  • Chemical Society Reviews, Vol. 39, Issue 3
  • DOI: 10.1039/b902074h

Nanofluidic concentration devices for biomolecules utilizing ion concentration polarization: theory, fabrication, and applications
journal, January 2010

  • Kim, Sung Jae; Song, Yong-Ak; Han, Jongyoon
  • Chemical Society Reviews, Vol. 39, Issue 3, p. 912-922
  • DOI: 10.1039/b822556g

Electrokinetic Trapping and Concentration Enrichment of DNA in a Microfluidic Channel
journal, October 2003

  • Dai, Jinhua; Ito, Takashi; Sun, Li
  • Journal of the American Chemical Society, Vol. 125, Issue 43
  • DOI: 10.1021/ja0374776

Ion-Enrichment and Ion-Depletion Effect of Nanochannel Structures
journal, June 2004

  • Pu, Qiaosheng; Yun, Jongsin; Temkin, Henryk
  • Nano Letters, Vol. 4, Issue 6
  • DOI: 10.1021/nl0494811

Million-fold Preconcentration of Proteins and Peptides by Nanofluidic Filter
journal, July 2005

  • Wang, Ying-Chih; Stevens, Anna L.; Han, Jongyoon
  • Analytical Chemistry, Vol. 77, Issue 14
  • DOI: 10.1021/ac050321z

Induced Electrokinetic Transport in Micro−Nanofluidic Interconnect Devices
journal, December 2007

  • Jin, Xiaozhong; Joseph, Sony; Gatimu, Enid N.
  • Langmuir, Vol. 23, Issue 26
  • DOI: 10.1021/la702326v

Transient Effects on Microchannel Electrokinetic Filtering with an Ion-Permselective Membrane
journal, February 2008

  • Dhopeshwarkar, Rahul; Crooks, Richard M.; Hlushkou, Dzmitry
  • Analytical Chemistry, Vol. 80, Issue 4
  • DOI: 10.1021/ac7019927

Bipolar Electrochemistry
journal, July 2013

  • Fosdick, Stephen E.; Knust, Kyle N.; Scida, Karen
  • Angewandte Chemie International Edition, Vol. 52, Issue 40
  • DOI: 10.1002/anie.201300947

Bipolar Electrochemistry: From Materials Science to Motion and Beyond
journal, May 2013

  • Loget, Gabriel; Zigah, Dodzi; Bouffier, Laurent
  • Accounts of Chemical Research, Vol. 46, Issue 11
  • DOI: 10.1021/ar400039k

Bipolar Electrode Focusing: Faradaic Ion Concentration Polarization
journal, March 2011

  • Anand, Robbyn K.; Sheridan, Eoin; Knust, Kyle N.
  • Analytical Chemistry, Vol. 83, Issue 6, p. 2351-2358
  • DOI: 10.1021/ac103302j

Bipolar Electrodes: A Useful Tool for Concentration, Separation, and Detection of Analytes in Microelectrochemical Systems
journal, November 2010

  • Mavré, François; Anand, Robbyn K.; Laws, Derek R.
  • Analytical Chemistry, Vol. 82, Issue 21
  • DOI: 10.1021/ac101262v

Counter-flow gradient electrofocusing
journal, February 2007


Exploring Gradients in Electrophoretic Separation and Preconcentration on Miniaturized Devices
journal, April 2016


Direct seawater desalination by ion concentration polarization
journal, March 2010

  • Kim, Sung Jae; Ko, Sung Hee; Kang, Kwan Hyoung
  • Nature Nanotechnology, Vol. 5, Issue 4, p. 297-301
  • DOI: 10.1038/nnano.2010.34

Out-of-plane ion concentration polarization for scalable water desalination
journal, January 2014

  • MacDonald, Brendan D.; Gong, Max M.; Zhang, Pei
  • Lab Chip, Vol. 14, Issue 4
  • DOI: 10.1039/C3LC51255J

Electrochemically Mediated Seawater Desalination
journal, June 2013

  • Knust, Kyle N.; Hlushkou, Dzmitry; Anand, Robbyn K.
  • Angewandte Chemie International Edition, Vol. 52, Issue 31
  • DOI: 10.1002/anie.201302577

Continuous-Flow Biomolecule and Cell Concentrator by Ion Concentration Polarization
journal, October 2011

  • Kwak, Rhokyun; Kim, Sung Jae; Han, Jongyoon
  • Analytical Chemistry, Vol. 83, Issue 19, p. 7348-7355
  • DOI: 10.1021/ac2012619

Microfluidic paper-based biomolecule preconcentrator based on ion concentration polarization
journal, January 2016

  • Han, Sung Il; Hwang, Kyo Seon; Kwak, Rhokyun
  • Lab on a Chip, Vol. 16, Issue 12
  • DOI: 10.1039/C6LC00499G

Direct DNA Analysis with Paper-Based Ion Concentration Polarization
journal, October 2015

  • Gong, Max M.; Nosrati, Reza; San Gabriel, Maria C.
  • Journal of the American Chemical Society, Vol. 137, Issue 43
  • DOI: 10.1021/jacs.5b08523

Continuous Signal Enhancement for Sensitive Aptamer Affinity Probe Electrophoresis Assay Using Electrokinetic Concentration
journal, September 2011

  • Cheow, Lih Feng; Han, Jongyoon
  • Analytical Chemistry, Vol. 83, Issue 18
  • DOI: 10.1021/ac201307d

Sample pre-concentration with high enrichment factors at a fixed location in paper-based microfluidic devices
journal, January 2016

  • Yeh, Shih-Hao; Chou, Kuang-Hua; Yang, Ruey-Jen
  • Lab on a Chip, Vol. 16, Issue 5
  • DOI: 10.1039/C5LC01365H

Bipolar Electrode Focusing: Simultaneous Concentration Enrichment and Separation in a Microfluidic Channel Containing a Bipolar Electrode
journal, November 2009

  • Laws, Derek R.; Hlushkou, Dzmitry; Perdue, Robbyn K.
  • Analytical Chemistry, Vol. 81, Issue 21, p. 8923-8929
  • DOI: 10.1021/ac901545y

A polymeric high-throughput pressure-driven micromixer using a nanoporous membrane
journal, September 2010


Non-equilibrium electrokinetic micromixer with 3D nanochannel networks
journal, January 2015

  • Choi, Eunpyo; Kwon, Kilsung; Lee, Seung Jun
  • Lab on a Chip, Vol. 15, Issue 8
  • DOI: 10.1039/C4LC01435A

Diagnostics for the Developing World: Microfluidic Paper-Based Analytical Devices
journal, January 2010

  • Martinez, Andres W.; Phillips, Scott T.; Whitesides, George M.
  • Analytical Chemistry, Vol. 82, Issue 1
  • DOI: 10.1021/ac9013989

New Functionalities for Paper-Based Sensors Lead to Simplified User Operation, Lower Limits of Detection, and New Applications
journal, June 2016


Faradaic Ion Concentration Polarization on a Paper Fluidic Platform
journal, March 2017


Fabrication of microfluidic systems in poly(dimethylsiloxane)
journal, January 2000


Preparation and characterization of TiO2 thin film by thermal oxidation of sputtered Ti film
journal, April 2013

  • Zhou, Bing; Jiang, Xiaohong; liu, Zhubo
  • Materials Science in Semiconductor Processing, Vol. 16, Issue 2
  • DOI: 10.1016/j.mssp.2012.05.001

Bipolar electrode focusing: tuning the electric field gradient
journal, January 2011

  • Anand, Robbyn K.; Sheridan, Eoin; Hlushkou, Dzmitry
  • Lab Chip, Vol. 11, Issue 3
  • DOI: 10.1039/C0LC00351D

Label-Free Electrochemical Monitoring of Concentration Enrichment during Bipolar Electrode Focusing
journal, September 2011

  • Sheridan, Eoin; Hlushkou, Dzmitry; Anand, Robbyn K.
  • Analytical Chemistry, Vol. 83, Issue 17
  • DOI: 10.1021/ac201402n

Multichannel Microchip Electrophoresis Device Fabricated in Polycarbonate with an Integrated Contact Conductivity Sensor Array
journal, February 2007

  • Shadpour, Hamed; Hupert, Mateusz L.; Patterson, Donald
  • Analytical Chemistry, Vol. 79, Issue 3
  • DOI: 10.1021/ac0612168

Bipolar Electrode Focusing: The Effect of Current and Electric Field on Concentration Enrichment
journal, December 2009

  • Perdue, Robbyn K.; Laws, Derek R.; Hlushkou, Dzmitry
  • Analytical Chemistry, Vol. 81, Issue 24, p. 10149-10155
  • DOI: 10.1021/ac901913r

Electrokinetics in Microfluidic Channels Containing a Floating Electrode
journal, August 2008

  • Dhopeshwarkar, Rahul; Hlushkou, Dzmitry; Nguyen, Mark
  • Journal of the American Chemical Society, Vol. 130, Issue 32, p. 10480-10481
  • DOI: 10.1021/ja8036405

Electrochemically-gated delivery of analyte bands in microfluidic devices using bipolar electrodes
journal, January 2013

  • Scida, Karen; Sheridan, Eoin; Crooks, Richard M.
  • Lab on a Chip, Vol. 13, Issue 12
  • DOI: 10.1039/c3lc50321f

Photoelectrochemical cells
journal, November 2001


Titanium dioxide photocatalysis
journal, June 2000

  • Fujishima, Akira; Rao, Tata N.; Tryk, Donald A.
  • Journal of Photochemistry and Photobiology C: Photochemistry Reviews, Vol. 1, Issue 1
  • DOI: 10.1016/S1389-5567(00)00002-2

Kinetic Approach to the Photocurrent Transients in Water Photoelectrolysis at n-TiO[sub 2] Electrodes
journal, January 1990

  • Tafalla, D.
  • Journal of The Electrochemical Society, Vol. 137, Issue 6
  • DOI: 10.1149/1.2086809

Green and low-cost synthesis of PANI–TiO 2 nanocomposite mesoporous films for photoelectrochemical water splitting
journal, January 2015

  • Hidalgo, D.; Bocchini, S.; Fontana, M.
  • RSC Advances, Vol. 5, Issue 61
  • DOI: 10.1039/C5RA06734K

Electrocatalytic Oxygen Evolution Reaction (OER) on Ru, Ir, and Pt Catalysts: A Comparative Study of Nanoparticles and Bulk Materials
journal, July 2012

  • Reier, Tobias; Oezaslan, Mehtap; Strasser, Peter
  • ACS Catalysis, Vol. 2, Issue 8
  • DOI: 10.1021/cs3003098

Bipolar electrode depletion: membraneless filtration of charged species using an electrogenerated electric field gradient
journal, January 2011

  • Sheridan, Eoin; Knust, Kyle N.; Crooks, Richard M.
  • The Analyst, Vol. 136, Issue 20, p. 4134-4137
  • DOI: 10.1039/c1an15510e

Dual-channel bipolar electrode focusing: simultaneous separation and enrichment of both anions and cations
journal, January 2012

  • Knust, Kyle N.; Sheridan, Eoin; Anand, Robbyn K.
  • Lab on a Chip, Vol. 12, Issue 20, p. 4107-4114
  • DOI: 10.1039/c2lc40660h

Enrichment of Cations via Bipolar Electrode Focusing
journal, August 2012

  • Sheridan, Eoin; Hlushkou, Dzmitry; Knust, Kyle N.
  • Analytical Chemistry, Vol. 84, Issue 17, p. 7393-7399
  • DOI: 10.1021/ac301101b

Transport of barrel and spherical shaped colloids in unsaturated porous media
journal, September 2015


Electrocatalysis and Chlorine Evolution Reaction at Ruthenium Dioxide Deposited on Conductive Diamond
journal, March 2002

  • Ferro, Sergio; De Battisti, Achille
  • The Journal of Physical Chemistry B, Vol. 106, Issue 9
  • DOI: 10.1021/jp012195i

Ti atoms in Ru0.3Ti0.7O2 mixed oxides form active and selective sites for electrochemical chlorine evolution
journal, November 2014