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Title: Ethane and ethylene aromatization on zinc-containing zeolites

Abstract

The importance of balance between the number of Zn and Brønsted acid sites for aromatization of ethane and ethylene on Zn-ZSM-5 is discussed.

Authors:
ORCiD logo [1]; ORCiD logo [1]
  1. Center for Catalytic Science and Technology; Department of Chemical and Biomolecular Engineering; University of Delaware; Newark; USA
Publication Date:
Research Org.:
Univ. of Delaware, Newark, DE (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1535218
DOE Contract Number:  
SC0014436
Resource Type:
Journal Article
Journal Name:
Catalysis Science and Technology
Additional Journal Information:
Journal Volume: 7; Journal Issue: 16; Journal ID: ISSN 2044-4753
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
Chemistry

Citation Formats

Mehdad, Ali, and Lobo, Raul F. Ethane and ethylene aromatization on zinc-containing zeolites. United States: N. p., 2017. Web. doi:10.1039/c7cy00890b.
Mehdad, Ali, & Lobo, Raul F. Ethane and ethylene aromatization on zinc-containing zeolites. United States. doi:10.1039/c7cy00890b.
Mehdad, Ali, and Lobo, Raul F. Sun . "Ethane and ethylene aromatization on zinc-containing zeolites". United States. doi:10.1039/c7cy00890b.
@article{osti_1535218,
title = {Ethane and ethylene aromatization on zinc-containing zeolites},
author = {Mehdad, Ali and Lobo, Raul F.},
abstractNote = {The importance of balance between the number of Zn and Brønsted acid sites for aromatization of ethane and ethylene on Zn-ZSM-5 is discussed.},
doi = {10.1039/c7cy00890b},
journal = {Catalysis Science and Technology},
issn = {2044-4753},
number = 16,
volume = 7,
place = {United States},
year = {2017},
month = {1}
}

Works referenced in this record:

Aromatization of short chain alkanes on zeolite catalysts
journal, September 1992


Dehydrocyclodimerization IV. The reactions of butenes
journal, June 1970


Conversion of light alkanes into aromatic hydrocarbons: 1-dehydrocyclodimerization of propane on PtHZSM-5 catalysts
journal, November 1987


Structure and function of metal cations in light alkane reactions catalyzed by modified H-ZSM5
journal, December 1996


Transformation of Lower Alkanes into Aromatic Hydrocarbons over ZSM-5 Zeolites
journal, August 1992


Ethane to Aromatic Hydrocarbons: Past, Present, Future
journal, November 2000


M2 forming - a process for aromatization of light hydrocarbons
journal, January 1986

  • Chen, Nai Y.; Yan, Tsoung Y.
  • Industrial & Engineering Chemistry Process Design and Development, Vol. 25, Issue 1
  • DOI: 10.1021/i200032a023

Converting light hydrocarbons containing olefins to aromatics (Alpha Process)
journal, May 1998


Impact of Zeolites on the Petroleum and Petrochemical Industry
journal, May 2009


Activation of C2–C4 alkanes over acid and bifunctional zeolite catalysts
journal, August 2006


On two alternative mechanisms of ethane activation over ZSM-5 zeolite modified by Zn2+ and Ga1+ cations
journal, January 2005

  • Kazansky, V. B.; Subbotina, I. R.; Rane, N.
  • Physical Chemistry Chemical Physics, Vol. 7, Issue 16
  • DOI: 10.1039/b506782k

Structure and Reactivity of Zn-Modified ZSM-5 Zeolites: The Importance of Clustered Cationic Zn Complexes
journal, December 2011

  • Almutairi, Sami M. T.; Mezari, Brahim; Magusin, Pieter C. M. M.
  • ACS Catalysis, Vol. 2, Issue 1
  • DOI: 10.1021/cs200441e

Structure and Density of Active Zn Species in Zn/H-ZSM5 Propane Aromatization Catalysts
journal, October 1998

  • Biscardi, Joseph A.; Meitzner, George D.; Iglesia, Enrique
  • Journal of Catalysis, Vol. 179, Issue 1
  • DOI: 10.1006/jcat.1998.2177

Generation of active sites for ethane aromatization in ZSM-5 zeolites by a solid-state reaction of zinc metal with Brønsted acid sites of the zeolite
journal, August 2001


Introduction of Zn, Ga, and Fe into HZSM-5 Cavities by Sublimation:  Identification of Acid Sites
journal, June 1999

  • El-Malki, El-M.; van Santen, R. A.; Sachtler, W. M. H.
  • The Journal of Physical Chemistry B, Vol. 103, Issue 22
  • DOI: 10.1021/jp990116l

A new charge alternating model of localization of bivalent cations in high silica zeolites with distantly placed aluminum atoms in the framework
journal, May 2004


Initial stages of propane activation over Zn/MFI catalyst studied by in situ NMR and IR spectroscopic techniques
journal, February 2006


Recent Advances in the Synthesis, Characterization and Application of Zn + -containing Heterogeneous Catalysts
journal, February 2016


Activation of ethane in Zn-exchanged zeolites: a theoretical study
journal, January 2000

  • Frash, Maxim V.; van Santen, Rutger A.
  • Physical Chemistry Chemical Physics, Vol. 2, Issue 5
  • DOI: 10.1039/a909426a

Study of the Activation of C−H and H−H Chemical Bonds by the [ZnOZn] 2+ Oxycation:  Influence of the Zeolite Framework Geometry
journal, December 2003

  • Barbosa, Luis Antonio M. M.; van Santen, Rutger A.
  • The Journal of Physical Chemistry B, Vol. 107, Issue 51
  • DOI: 10.1021/jp030394r

Activation of Light Alkanes over Zinc Species Stabilized in ZSM-5 Zeolite:  A Comprehensive DFT Study
journal, February 2007

  • Pidko, Evgeny A.; van Santen, Rutger A.
  • The Journal of Physical Chemistry C, Vol. 111, Issue 6
  • DOI: 10.1021/jp065911v

Conversion of light alkanes to aromatic hydrocarbons
journal, January 1988


Kinetic modeling of propane aromatization reaction over HZSM-5 and GaHZSM-5
journal, February 1995

  • Lukyanov, Dmitri B.; Gnep, N. Suor; Guisnet, Michel R.
  • Industrial & Engineering Chemistry Research, Vol. 34, Issue 2
  • DOI: 10.1021/ie00041a012

The reaction of propane over ZSM-5-H and ZSM-5-Zn zeolite catalysts
journal, July 1985


Reaction Pathways and Rate-Determining Steps in Reactions of Alkanes on H-ZSM5 and Zn/H-ZSM5 Catalysts
journal, February 1999


Kinetic coupling and hydrogen surface fugacities in heterogeneous catalysis: I. Alkane reactions on Te/NaX, H-ZSM5, and Ga/H-ZSM5
journal, April 1992


Zn-promoted hydrogen exchange for methane and ethane on Zn/H-BEA zeolite: In situ 1H MAS NMR kinetic study
journal, January 2008


Significant Influence of Zn on Activation of the C-H Bonds of Small Alkanes by Brønsted Acid Sites of Zeolite
journal, December 2008

  • Stepanov, Alexander G.; Arzumanov, Sergei S.; Gabrienko, Anton A.
  • ChemPhysChem, Vol. 9, Issue 17
  • DOI: 10.1002/cphc.200800569

Propane Aromatization on Zn-Modified Zeolite BEA Studied by Solid-State NMR in Situ
journal, June 2010

  • Gabrienko, Anton A.; Arzumanov, Sergei S.; Freude, Dieter
  • The Journal of Physical Chemistry C, Vol. 114, Issue 29
  • DOI: 10.1021/jp103580f

Propene aromatization over alkali-exchanged ZSM-5 zeolites
journal, April 1993


On the Mechanism of Propane Dehydrocyclization over Cation-Containing, Proton-Poor MFI Zeolite
journal, January 1998

  • Price, Geoffrey L.; Kanazirev, Vladislav; Dooley, Kerry M.
  • Journal of Catalysis, Vol. 173, Issue 1
  • DOI: 10.1006/jcat.1997.1891

Transformation of but-1-ene into aromatic hydrocarbons over ZSM-5 zeolites
journal, January 1987

  • Ono, Yoshio; Kitagawa, Hiroyoshi; Sendoda, Yoko
  • Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 83, Issue 9
  • DOI: 10.1039/f19878302913

Anionic Oligomerization of Ethylene over Ga/ZSM-5 Zeolite: A Theoretical Study
journal, November 2008

  • Pidko, Evgeny A.; Hensen, Emiel J. M.; van Santen, Rutger A.
  • The Journal of Physical Chemistry C, Vol. 112, Issue 49
  • DOI: 10.1021/jp8069767

Cracking and aromatization properties of some metal modified ZSM-5 catalysts for light alkane conversions
journal, December 2004

  • Viswanadham, N.; Muralidhar, G.; Rao, T. S. R. Prasada
  • Journal of Molecular Catalysis A: Chemical, Vol. 223, Issue 1-2
  • DOI: 10.1016/j.molcata.2003.11.045

The conversion of ethene and propene to higher hydrocarbons over ZSM-5
journal, May 1987


Effect of the metal promoter on the performances of H-ZSM5 in ethylene aromatization
journal, July 2017


Influence of Zn species in HZSM-5 on ethylene aromatization
journal, June 2015


Silver‐Promoted Dehydroaromatization of Ethylene over ZSM‐5 Catalysts
journal, March 2017


Carbon Dioxide and Nitrogen Adsorption on Cation-Exchanged SSZ-13 Zeolites
journal, December 2012

  • Pham, Trong D.; Liu, Qingling; Lobo, Raul F.
  • Langmuir, Vol. 29, Issue 2
  • DOI: 10.1021/la304138z

Zn-Promoted H-ZSM-5 for Endothermic Reforming of n -Hexane at High Pressures
journal, March 2016

  • Yeh, Yu-Hao; Zhu, Shiyu; Staiber, Patrick
  • Industrial & Engineering Chemistry Research, Vol. 55, Issue 14
  • DOI: 10.1021/acs.iecr.6b00639

ZnO Clusters Encapsulated inside Micropores of Zeolites Studied by UV Raman and Laser-Induced Luminescence Spectroscopies
journal, August 2004

  • Chen, Jun; Feng, Zhaochi; Ying, Pinliang
  • The Journal of Physical Chemistry B, Vol. 108, Issue 34
  • DOI: 10.1021/jp048746x

Controlling the Distribution of Supported Nanoparticles by Aqueous Synthesis
journal, March 2013

  • Eggenhuisen, Tamara M.; Friedrich, Heiner; Nudelman, Fabio
  • Chemistry of Materials, Vol. 25, Issue 6
  • DOI: 10.1021/cm3037845

Zinc promoted H-ZSM-5 catalysts for conversion of propane to aromatics II. Nature of the active sites and their activation
journal, November 1996


Non-oxidative reactions of propane on Zn/Na-ZSM5
journal, January 1999

  • Biscardi, Joseph A.; Iglesia, Enrique
  • Physical Chemistry Chemical Physics, Vol. 1, Issue 24
  • DOI: 10.1039/a906550d

Propylene Hydrogenation and Propane Dehydrogenation by a Single-Site Zn 2+ on Silica Catalyst
journal, March 2014

  • Schweitzer, Neil M.; Hu, Bo; Das, Ujjal
  • ACS Catalysis, Vol. 4, Issue 4
  • DOI: 10.1021/cs401116p

Reaction kinetics of propane dehydrogenation over partially reduced zinc oxide supported on silicalite
journal, January 1992

  • Wan, Ben-Zu; Chu, Hui Min
  • Journal of the Chemical Society, Faraday Transactions, Vol. 88, Issue 19
  • DOI: 10.1039/ft9928802943

β-Scission of Olefins on Acidic Zeolites: A Periodic PBE-D Study in H-ZSM-5
journal, October 2013

  • Mazar, Mark N.; Al-Hashimi, Saleh; Cococcioni, Matteo
  • The Journal of Physical Chemistry C, Vol. 117, Issue 45
  • DOI: 10.1021/jp403504n

Kinetics and Thermochemistry of C 4 –C 6 Olefin Cracking on H-ZSM-5
journal, May 2014

  • Chen, Cha-Jung; Rangarajan, Srinivas; Hill, Ian M.
  • ACS Catalysis, Vol. 4, Issue 7
  • DOI: 10.1021/cs500119n

Mechanistic Considerations in Acid-Catalyzed Cracking of Olefins
journal, January 1996

  • Buchanan, J. S.; Santiesteban, J. G.; Haag, W. O.
  • Journal of Catalysis, Vol. 158, Issue 1
  • DOI: 10.1006/jcat.1996.0027