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Title: Solvent-dependent photo-induced dynamics in a non-rigidly linked zinc phthalocyanine–perylenediimide dyad probed using ultrafast spectroscopy

Abstract

A solvent dependent pump–probe study on an artificial light harvesting dyad reveals static and dynamic system-bath interactions observed in ultrafast photoinduced energy and electron transfer.

Authors:
 [1]; ORCiD logo [1];  [2];  [2]; ORCiD logo [2]; ORCiD logo [1]
  1. Department of Chemistry; Princeton University; Princeton; USA
  2. Área de Química Orgánica; Instituto de Bioingeniería; Universidad Miguel Hernández; Elche 03202; Spain
Publication Date:
Research Org.:
Princeton Univ., NJ (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1535200
DOE Contract Number:  
SC0015429
Resource Type:
Journal Article
Journal Name:
Physical Chemistry Chemical Physics. PCCP (Print)
Additional Journal Information:
Journal Volume: 19; Journal Issue: 31; Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
Chemistry; Physics

Citation Formats

Kudisch, Bryan, Maiuri, Margherita, Blas-Ferrando, Vicente M., Ortiz, Javier, Sastre-Santos, Ángela, and Scholes, Gregory D. Solvent-dependent photo-induced dynamics in a non-rigidly linked zinc phthalocyanine–perylenediimide dyad probed using ultrafast spectroscopy. United States: N. p., 2017. Web. doi:10.1039/c7cp02143g.
Kudisch, Bryan, Maiuri, Margherita, Blas-Ferrando, Vicente M., Ortiz, Javier, Sastre-Santos, Ángela, & Scholes, Gregory D. Solvent-dependent photo-induced dynamics in a non-rigidly linked zinc phthalocyanine–perylenediimide dyad probed using ultrafast spectroscopy. United States. doi:10.1039/c7cp02143g.
Kudisch, Bryan, Maiuri, Margherita, Blas-Ferrando, Vicente M., Ortiz, Javier, Sastre-Santos, Ángela, and Scholes, Gregory D. Sun . "Solvent-dependent photo-induced dynamics in a non-rigidly linked zinc phthalocyanine–perylenediimide dyad probed using ultrafast spectroscopy". United States. doi:10.1039/c7cp02143g.
@article{osti_1535200,
title = {Solvent-dependent photo-induced dynamics in a non-rigidly linked zinc phthalocyanine–perylenediimide dyad probed using ultrafast spectroscopy},
author = {Kudisch, Bryan and Maiuri, Margherita and Blas-Ferrando, Vicente M. and Ortiz, Javier and Sastre-Santos, Ángela and Scholes, Gregory D.},
abstractNote = {A solvent dependent pump–probe study on an artificial light harvesting dyad reveals static and dynamic system-bath interactions observed in ultrafast photoinduced energy and electron transfer.},
doi = {10.1039/c7cp02143g},
journal = {Physical Chemistry Chemical Physics. PCCP (Print)},
issn = {1463-9076},
number = 31,
volume = 19,
place = {United States},
year = {2017},
month = {1}
}

Works referenced in this record:

Fullerene–porphyrin architectures; photosynthetic antenna and reaction center models
journal, December 2001

  • Guldi, Dirk M.
  • Chemical Society Reviews, Vol. 31, Issue 1
  • DOI: 10.1039/b106962b

Molecular mimicry of photosynthetic energy and electron transfer
journal, April 1993

  • Gust, Devens; Moore, Thomas A.; Moore, Ana L.
  • Accounts of Chemical Research, Vol. 26, Issue 4
  • DOI: 10.1021/ar00028a010

Charge Photogeneration in Neat Conjugated Polymers
journal, September 2013

  • Reid, Obadiah G.; Pensack, Ryan D.; Song, Yin
  • Chemistry of Materials, Vol. 26, Issue 1
  • DOI: 10.1021/cm4027144

Photoinduced Electron Transfer in Organic Solar Cells
journal, February 2016


Photoinduced electron transfer in supramolecular systems for artificial photosynthesis
journal, May 1992

  • Wasielewski, Michael R.
  • Chemical Reviews, Vol. 92, Issue 3, p. 435-461
  • DOI: 10.1021/cr00011a005

Towards artificial photosynthesis: Supramolecular, donor–acceptor, porphyrin- and phthalocyanine/carbon nanostructure ensembles
journal, November 2012

  • Bottari, Giovanni; Trukhina, Olga; Ince, Mine
  • Coordination Chemistry Reviews, Vol. 256, Issue 21-22
  • DOI: 10.1016/j.ccr.2012.03.011

Covalent and Noncovalent Phthalocyanine−Carbon Nanostructure Systems: Synthesis, Photoinduced Electron Transfer, and Application to Molecular Photovoltaics
journal, November 2010

  • Bottari, Giovanni; de la Torre, Gema; Guldi, Dirk M.
  • Chemical Reviews, Vol. 110, Issue 11
  • DOI: 10.1021/cr900254z

Phthalocyanines: From outstanding electronic properties to emerging applications
journal, January 2008

  • Claessens, Christian G.; Hahn, Uwe; Torres, Tomás
  • The Chemical Record, Vol. 8, Issue 2
  • DOI: 10.1002/tcr.20139

Rylene and Related Diimides for Organic Electronics
journal, December 2010

  • Zhan, Xiaowei; Facchetti, Antonio; Barlow, Stephen
  • Advanced Materials, Vol. 23, Issue 2, p. 268-284
  • DOI: 10.1002/adma.201001402

Perylene Bisimide Dye Assemblies as Archetype Functional Supramolecular Materials
journal, August 2015


Porphyrins XXIV. Energy, oscillator strength, and Zeeman splitting calculations (SCMO-CI) for phthalocyanine, porphyrins, and related ring systems
journal, December 1972

  • McHugh, A. J.; Gouterman, Martin; Weiss, Charles
  • Theoretica Chimica Acta, Vol. 24, Issue 4
  • DOI: 10.1007/BF01007552

Helical Ribbons for Molecular Electronics
journal, May 2014

  • Zhong, Yu; Kumar, Bharat; Oh, Seokjoon
  • Journal of the American Chemical Society, Vol. 136, Issue 22
  • DOI: 10.1021/ja503533y

Perylenediimides as non-fullerene acceptors in bulk-heterojunction solar cells (BHJSCs)
journal, January 2016

  • Fernández-Lázaro, Fernando; Zink-Lorre, Nathalie; Sastre-Santos, Ángela
  • Journal of Materials Chemistry A, Vol. 4, Issue 24
  • DOI: 10.1039/C6TA02045C

Industrial applications of phthalocyanines
journal, June 2000


Direct Observation of Excimer-Mediated Intramolecular Electron Transfer in a Cofacially-Stacked Perylene Bisimide Pair
journal, July 2016

  • Sung, Jooyoung; Nowak-Król, Agnieszka; Schlosser, Felix
  • Journal of the American Chemical Society, Vol. 138, Issue 29
  • DOI: 10.1021/jacs.6b04591

Macrocyclic Dyads Based on C 60 and Perylenediimides Connected by Click Chemistry
journal, January 2014

  • Pla, Sara; Martín-Gomis, Luis; Ohkubo, Kei
  • Asian Journal of Organic Chemistry, Vol. 3, Issue 2
  • DOI: 10.1002/ajoc.201300235

Phthalocyanine–Perylenediimide Cart Wheels
journal, September 2016

  • Fernández-Ariza, Javier; Krick Calderón, Rafael M.; Rodríguez-Morgade, M. Salomé
  • Journal of the American Chemical Society, Vol. 138, Issue 39
  • DOI: 10.1021/jacs.6b07432

A simple artificial light-harvesting dyad as a model for excess energy dissipation in oxygenic photosynthesis
journal, March 2006

  • Berera, R.; Herrero, C.; van Stokkum, I. H. M.
  • Proceedings of the National Academy of Sciences, Vol. 103, Issue 14
  • DOI: 10.1073/pnas.0508530103

Formation of a long-lived charge-separated state of a zinc phthalocyanine-perylenediimide dyad by complexation with magnesium ion
journal, January 2005

  • Fukuzumi, Shunichi; Ohkubo, Kei; Ortiz, Javier
  • Chemical Communications, Issue 30
  • DOI: 10.1039/b506412k

Control of Photoinduced Electron Transfer in Zinc Phthalocyanine−Perylenediimide Dyad and Triad by the Magnesium Ion
journal, October 2008

  • Fukuzumi, Shunichi; Ohkubo, Kei; Ortiz, Javier
  • The Journal of Physical Chemistry A, Vol. 112, Issue 43
  • DOI: 10.1021/jp805464e

Rational design of a phthalocyanine–perylenediimide dyad with a long-lived charge-separated state
journal, January 2012

  • Blas-Ferrando, Vicente M.; Ortiz, Javier; Bouissane, Latifa
  • Chemical Communications, Vol. 48, Issue 50
  • DOI: 10.1039/c2cc31087b

Electron transfers in chemistry and biology
journal, August 1985

  • Marcus, R. A.; Sutin, Norman
  • Biochimica et Biophysica Acta (BBA) - Reviews on Bioenergetics, Vol. 811, Issue 3
  • DOI: 10.1016/0304-4173(85)90014-X

Energy transfer from Förster–Dexter theory to quantum coherent light-harvesting
journal, January 2011

  • Olaya-Castro, Alexandra; Scholes, Gregory D.
  • International Reviews in Physical Chemistry, Vol. 30, Issue 1
  • DOI: 10.1080/0144235X.2010.537060

Synthesis and Photophysical Properties of Conjugated and Nonconjugated Phthalocyanine–Perylenediimide Systems
journal, November 2016

  • Follana-Berná, Jorge; Inan, Damla; Blas-Ferrando, Vicente M.
  • The Journal of Physical Chemistry C, Vol. 120, Issue 46
  • DOI: 10.1021/acs.jpcc.6b07160

Observation of Two Triplet-Pair Intermediates in Singlet Exciton Fission
journal, June 2016

  • Pensack, Ryan D.; Ostroumov, Evgeny E.; Tilley, Andrew J.
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 13
  • DOI: 10.1021/acs.jpclett.6b00947

Global and target analysis of time-resolved spectra
journal, July 2004

  • van Stokkum, Ivo H. M.; Larsen, Delmar S.; van Grondelle, Rienk
  • Biochimica et Biophysica Acta (BBA) - Bioenergetics, Vol. 1657, Issue 2-3
  • DOI: 10.1016/j.bbabio.2004.04.011

Glotaran : A Java -Based Graphical User Interface for the R Package TIMP
journal, January 2012

  • Snellenburg, Joris J.; Laptenok, Sergey P.; Seger, Ralf
  • Journal of Statistical Software, Vol. 49, Issue 3
  • DOI: 10.18637/jss.v049.i03

Photophysical and quantum chemical study on a J-aggregate forming perylene bisimide monomer
journal, January 2011

  • Ambrosek, David; Marciniak, Henning; Lochbrunner, Stefan
  • Physical Chemistry Chemical Physics, Vol. 13, Issue 39
  • DOI: 10.1039/c1cp21624d

Trends in the TD-DFT calculations of porphyrin and phthalocyanine analogs
journal, August 2014

  • Mack, John; Stone, Justin; Nyokong, Tebello
  • Journal of Porphyrins and Phthalocyanines, Vol. 18, Issue 08n09
  • DOI: 10.1142/S108842461450045X

Magnetic circular dichroism and absorption spectrum of zinc phthalocyanine in an argon matrix between 14700 and 74000 cm-1
journal, April 1989

  • Van Cott, Thomas C.; Rose, Janna L.; Misener, G. Christian
  • The Journal of Physical Chemistry, Vol. 93, Issue 8
  • DOI: 10.1021/j100345a028

Solvent effects on the photochemical and fluorescence properties of zinc phthalocyanine derivatives
journal, May 2003


Characterizing the functional dynamics of zinc phthalocyanine from femtoseconds to nanoseconds
journal, April 2008

  • Savolainen, Janne; van der Linden, Dennis; Dijkhuizen, Niels
  • Journal of Photochemistry and Photobiology A: Chemistry, Vol. 196, Issue 1
  • DOI: 10.1016/j.jphotochem.2007.11.018

Excited state dynamics in phthalocyanines studied using degenerate four wave mixing with incoherent light
journal, March 2002

  • Rao, S. Venugopal; Rao, D. Narayana
  • Journal of Porphyrins and Phthalocyanines, Vol. 06, Issue 03
  • DOI: 10.1142/S1088424602000270

Coherence in Energy Transfer and Photosynthesis
journal, April 2015


Photochemical hole-burning spectroscopy of a photosynthetic reaction center mutant with altered charge separation kinetics: properties and decay of the initially excited state
journal, November 1991

  • Middendorf, Thomas R.; Mazzola, Laura T.; Gaul, Dale F.
  • The Journal of Physical Chemistry, Vol. 95, Issue 24
  • DOI: 10.1021/j100177a093

Broadband dielectric response of dichloromethane
journal, March 2009


Structural study of aqueous solutions of tetrahydrofuran and acetone mixtures using dielectric relaxation technique
journal, February 1996

  • Kumbharkhane, A. C.; Helambe, S. N.; Lokhande, M. P.
  • Pramana, Vol. 46, Issue 2
  • DOI: 10.1007/BF02848226

Interplay of solvent motion and vibrational excitation in electron-transfer kinetics: experiment and theory
journal, April 1992

  • Walker, Gilbert C.; Aakesson, Eva; Johnson, Alan E.
  • The Journal of Physical Chemistry, Vol. 96, Issue 9
  • DOI: 10.1021/j100188a032

Activationless solvent‐controlled electron transfer
journal, January 1988

  • Rips, Ilya; Jortner, Joshua
  • The Journal of Chemical Physics, Vol. 88, Issue 2
  • DOI: 10.1063/1.454160

Excited State Electron and Proton Transfers
journal, October 1986


Dynamic solvent effects on intramolecular electron-transfer reactions: fluctuation time scales and population decays
journal, May 1988

  • Simon, John D.; Su, Shyh Gang
  • The Journal of Physical Chemistry, Vol. 92, Issue 9
  • DOI: 10.1021/j100320a001

Transient solvation of polar dye molecules in polar aprotic solvents
journal, February 1988

  • Kahlow, Michael A.; Kang, Tai Jong; Barbara, Paul F.
  • The Journal of Chemical Physics, Vol. 88, Issue 4
  • DOI: 10.1063/1.454020

Charge-Transfer and Energy-Transfer Processes in π-Conjugated Oligomers and Polymers:  A Molecular Picture
journal, November 2004

  • Brédas, Jean-Luc; Beljonne, David; Coropceanu, Veaceslav
  • Chemical Reviews, Vol. 104, Issue 11
  • DOI: 10.1021/cr040084k

Effect of Mutual Position of Electron Donor and Acceptor on Photoinduced Electron Transfer in Supramolecular Chlorophyll–Fullerene Dyads
journal, February 2014

  • Stranius, Kati; Iashin, Vladimir; Nikkonen, Taru
  • The Journal of Physical Chemistry A, Vol. 118, Issue 8
  • DOI: 10.1021/jp412442t

Ultrafast electron transfer in a porphyrin-amino naphthalene diimide dyad
journal, January 2013

  • Robotham, Benjamin; Lastman, Katrina A.; Langford, Steven J.
  • Journal of Photochemistry and Photobiology A: Chemistry, Vol. 251
  • DOI: 10.1016/j.jphotochem.2012.11.002

Linkage and Solvent Dependence of Photoinduced Electron Transfer in Zincporphyrin-C 60 Dyads
journal, January 1996

  • Imahori, Hiroshi; Hagiwara, Kiyoshi; Aoki, Masanori
  • Journal of the American Chemical Society, Vol. 118, Issue 47
  • DOI: 10.1021/ja9628415

Spacer controlled photo-induced intramolecular electron transfer in a series of phenothiazine-boron dipyrromethene donor–acceptor dyads
journal, November 2015