CO 2 reduction or HCO 2 - oxidation? Solvent-dependent thermochemistry of a nickel hydride complex

Ceballos, Bianca M.; Tsay, Charlene; Yang, Jenny Y.

doi:10.1039/c7cc02511d

Title: CO ₂ reduction or HCO ₂ ^- oxidation? Solvent-dependent thermochemistry of a nickel hydride complex

Journal Article · Sun Jan 01 00:00:00 EST 2017 · ChemComm

DOI:https://doi.org/10.1039/c7cc02511d· OSTI ID:1535177

^[1]; Tsay, Charlene ^[1];

^[1]

Department of Chemistry; University of California; Irvine; USA

The hydricity (ΔG_H-) of a newly synthesized nickel hydride was experimentally determined in acetonitrile (50.6 kcal mol^-1), dimethyl sulfoxide (47.1 kcal mol^-1), and water (22.8 kcal mol^-1).

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Research Organization:: Univ. of California, Irvine, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0012150

OSTI ID:: 1535177

Journal Information:: ChemComm, Vol. 53, Issue 53; ISSN 1359-7345

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

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