skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Synthesis and characterization of a dipyriamethyrin–uranyl complex

Abstract

A bench stable uranyl complex of a hexaazadipyriamethryin macrocyclic ligand has been prepared and characterized.

Authors:
ORCiD logo [1];  [1];  [1]; ORCiD logo [1]; ORCiD logo [1];  [1]; ORCiD logo [1]
  1. Department of Chemistry, The University of Texas at Austin, 105 East 24th, Street-Stop A5300; Austin; USA
Publication Date:
Research Org.:
Univ. of Texas, Austin, TX (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1535176
DOE Contract Number:  
FG02-01ER15186
Resource Type:
Journal Article
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 53; Journal Issue: 36; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
Chemistry

Citation Formats

Brewster, James T., He, Qing, Anguera, Gonzalo, Moore, Matthew D., Ke, Xian-Sheng, Lynch, Vincent M., and Sessler, Jonathan L. Synthesis and characterization of a dipyriamethyrin–uranyl complex. United States: N. p., 2017. Web. doi:10.1039/c7cc01674c.
Brewster, James T., He, Qing, Anguera, Gonzalo, Moore, Matthew D., Ke, Xian-Sheng, Lynch, Vincent M., & Sessler, Jonathan L. Synthesis and characterization of a dipyriamethyrin–uranyl complex. United States. doi:10.1039/c7cc01674c.
Brewster, James T., He, Qing, Anguera, Gonzalo, Moore, Matthew D., Ke, Xian-Sheng, Lynch, Vincent M., and Sessler, Jonathan L. Sun . "Synthesis and characterization of a dipyriamethyrin–uranyl complex". United States. doi:10.1039/c7cc01674c.
@article{osti_1535176,
title = {Synthesis and characterization of a dipyriamethyrin–uranyl complex},
author = {Brewster, James T. and He, Qing and Anguera, Gonzalo and Moore, Matthew D. and Ke, Xian-Sheng and Lynch, Vincent M. and Sessler, Jonathan L.},
abstractNote = {A bench stable uranyl complex of a hexaazadipyriamethryin macrocyclic ligand has been prepared and characterized.},
doi = {10.1039/c7cc01674c},
journal = {ChemComm},
issn = {1359-7345},
number = 36,
volume = 53,
place = {United States},
year = {2017},
month = {1}
}

Works referenced in this record:

Transition-Metal Complexes of Expanded Porphyrins
journal, May 2007

  • Sessler, Jonathan L.; Tomat, Elisa
  • Accounts of Chemical Research, Vol. 40, Issue 5
  • DOI: 10.1021/ar600006n

Expanded Porphyrins and Their Heterologs
journal, October 1997

  • Jasat, Ayub; Dolphin, David
  • Chemical Reviews, Vol. 97, Issue 6
  • DOI: 10.1021/cr950078b

Hexaalkyl Terpyrrole: A New Building Block for the Preparation of Expanded Porphyrins
journal, April 1995

  • Sessler, Jonathan L.; Weghorn, Steven J.; Hiseada, Yoshio
  • Chemistry - A European Journal, Vol. 1, Issue 1
  • DOI: 10.1002/chem.19950010110

Synthesis and X-ray Crystallography of Rh(I) Carbonyl Complexes of Amethyrin
journal, April 1998

  • Sessler, Jonathan L.; Gebauer, Andreas; Guba, Anka
  • Inorganic Chemistry, Vol. 37, Issue 8
  • DOI: 10.1021/ic971018m

The shell structure of ? ring currents in the expanded porphyrin amethyrin
journal, January 2006

  • Steiner, Erich; Fowler, Patrick W.
  • Organic & Biomolecular Chemistry, Vol. 4, Issue 12
  • DOI: 10.1039/b602426b

Hexaphyrin(1.0.1.0.0.0). A new colorimetric actinide sensor
journal, November 2004


Hexaphyrin(1.0.1.0.0.0): An Expanded Porphyrin Ligand for the Actinide Cations Uranyl (UO22+) and Neptunyl (NpO2+)
journal, January 2001


New chemistry of amethyrin
journal, May 2001


A new synthesis of isoamethyrins: A 4+2 route
journal, August 2016

  • Anguera, Gonzalo; Borrós, Salvador; Borrell, José I.
  • Journal of Porphyrins and Phthalocyanines, Vol. 20, Issue 08n11
  • DOI: 10.1142/S1088424616500553

Immobilization of a hexaphyrin(1.0.1.0.0.0) derivative onto a tentagel-amino resin and its use in uranyl cation detection
journal, January 2008

  • Melfi, Patricia J.; Camiolo, Salvatore; Lee, Jeong Tae
  • Dalton Transactions, Issue 12
  • DOI: 10.1039/b718627d

Bis[(μ-chloro)copper(II)] Amethyrin:  A Bimetallic Copper(II) Complex of an Expanded Porphyrin
journal, January 1996

  • Weghorn, Steven J.; Sessler, Jonathan L.; Lynch, Vincent
  • Inorganic Chemistry, Vol. 35, Issue 5
  • DOI: 10.1021/ic9509692

Octaethylporphyrin and expanded porphyrin complexes containing coordinated BF 2 groups
journal, January 2004

  • Köhler, Thomas; Hodgson, Michael C.; Seidel, Daniel
  • Chem. Commun., Issue 9
  • DOI: 10.1039/B400596A

A facile synthesis of new tetrapyrrole macrocyclic derivatives. Formation of bimetallic transition metal complexes
journal, January 1991

  • Corriu, Robert J. P.; Bolin, Geng; Moreau, Jo�l J. E.
  • Journal of the Chemical Society, Chemical Communications, Issue 4
  • DOI: 10.1039/c39910000211

Highly reactive meso-like positions of dipyrihexaphyrin
journal, January 2012

  • Setsune, Jun-ichiro; Yamato, Kyohei
  • Chemical Communications, Vol. 48, Issue 37
  • DOI: 10.1039/c2cc30981e

Self-Assembled Pyridine-Dipyrrolate Cages
journal, March 2016

  • Zhang, Huacheng; Lee, Juhoon; Lammer, Aaron D.
  • Journal of the American Chemical Society, Vol. 138, Issue 13
  • DOI: 10.1021/jacs.6b00564

A Luminescent Zirconium(IV) Complex as a Molecular Photosensitizer for Visible Light Photoredox Catalysis
journal, September 2016

  • Zhang, Yu; Petersen, Jeffrey L.; Milsmann, Carsten
  • Journal of the American Chemical Society, Vol. 138, Issue 40
  • DOI: 10.1021/jacs.6b05934

An Unusual Cobalt Azide Adduct That Produces a Nitrene Species for Carbon–Hydrogen Insertion Chemistry
journal, July 2016


A cis -Divacant Octahedral and Mononuclear Iron(IV) Imide
journal, October 2014

  • Searles, Keith; Fortier, Skye; Khusniyarov, Marat M.
  • Angewandte Chemie, Vol. 126, Issue 51
  • DOI: 10.1002/ange.201407156

Probing the Steric and Electronic Characteristics of a New Bis-Pyrrolide Pincer Ligand
journal, January 2014

  • Komine, Nobuyuki; Buell, René W.; Chen, Chun-Hsing
  • Inorganic Chemistry, Vol. 53, Issue 3
  • DOI: 10.1021/ic402120r

A Hybrid Macrocycle with a Pyridine Subunit Displays Aromatic Character upon Uranyl Cation Complexation
journal, March 2014

  • Ho, I-Ting; Zhang, Zhan; Ishida, Masatoshi
  • Journal of the American Chemical Society, Vol. 136, Issue 11
  • DOI: 10.1021/ja412520g

Cryptand-like Porphyrinoid Assembled with Three Dipyrrylpyridine Chains:  Synthesis, Structure, and Homotropic Positive Allosteric Binding of Carboxylic Acids
journal, February 2008

  • Setsune, Jun-ichiro; Watanabe, Keigo
  • Journal of the American Chemical Society, Vol. 130, Issue 8
  • DOI: 10.1021/ja710424n

Expanded Porphyrin-Anion Supramolecular Assemblies: Environmentally Responsive Sensors for Organic Solvents and Anions
journal, May 2015

  • Zhang, Zhan; Kim, Dong Sub; Lin, Chung-Yon
  • Journal of the American Chemical Society, Vol. 137, Issue 24
  • DOI: 10.1021/jacs.5b03131

The development of artificial porphyrinoids embedded with functional building blocks
journal, January 2015

  • Zhou, Zhikuan; Shen, Zhen
  • Journal of Materials Chemistry C, Vol. 3, Issue 14
  • DOI: 10.1039/C5TC00115C

Multiporphyrinic Cages: Architectures and Functions
journal, January 2014

  • Durot, Stéphanie; Taesch, Julien; Heitz, Valérie
  • Chemical Reviews, Vol. 114, Issue 17
  • DOI: 10.1021/cr400673y

A Self-Assembled Porphyrin-Based Dimeric Capsule Constructed by a Pd(II)−Pyridine Interaction Which Shows Efficient Guest Inclusion
journal, November 2000

  • Ikeda, Atsushi; Ayabe, Masatsugu; Shinkai, Seiji
  • Organic Letters, Vol. 2, Issue 23
  • DOI: 10.1021/ol006620m

Equipping metallo-supramolecular macrocycles with functional groups: assemblies of pyridine-substituted urea ligands
journal, January 2012

  • Troff, Ralf W.; Hovorka, Rainer; Weilandt, Torsten
  • Dalton Transactions, Vol. 41, Issue 27
  • DOI: 10.1039/c2dt30190c

Directly Pd(II)-Bridged Porphyrin Belts with Remarkable Curvatures
journal, September 2010

  • Song, Jianxin; Aratani, Naoki; Heo, Ji Haeng
  • Journal of the American Chemical Society, Vol. 132, Issue 34
  • DOI: 10.1021/ja1046654

Fe–Pt Twisted Heterometallic Bicyclic Supramolecules via Multicomponent Self-Assembly
journal, February 2017

  • Sepehrpour, Hajar; Saha, Manik Lal; Stang, Peter J.
  • Journal of the American Chemical Society, Vol. 139, Issue 7
  • DOI: 10.1021/jacs.6b11860

Convenient access to the anhydrous thorium tetrachloride complexes ThCl4(DME)2, ThCl4(1,4-dioxane)2 and ThCl4(THF)3.5 using commercially available and inexpensive starting materials
journal, January 2010

  • Cantat, Thibault; Scott, Brian L.; Kiplinger, Jaqueline L.
  • Chemical Communications, Vol. 46, Issue 6
  • DOI: 10.1039/b923558b

A Trigonal Bipyramidal Uranyl Amido Complex:  Synthesis and Structural Characterization of [Na(THF) 2 ][UO 2 (N(SiMe 3 ) 2 ) 3 ]
journal, November 2000

  • Burns, Carol J.; Clark, David L.; Donohoe, Robert J.
  • Inorganic Chemistry, Vol. 39, Issue 24
  • DOI: 10.1021/ic0003168

meso-Substituted expanded porphyrins: new and stable hexaphyrins
journal, January 1999

  • Neves, Maria G. P. M. S.; Martins, Rosália M.; Tomé, Augusto C.
  • Chemical Communications, Issue 4
  • DOI: 10.1039/a808952c

m eso -Aryl-Substituted Expanded Porphyrins
journal, July 2001

  • Shin, Ji-Young; Furuta, Hiroyuki; Yoza, Kenji
  • Journal of the American Chemical Society, Vol. 123, Issue 29
  • DOI: 10.1021/ja0106624

A new mixing of Hartree–Fock and local density‐functional theories
journal, January 1993

  • Becke, Axel D.
  • The Journal of Chemical Physics, Vol. 98, Issue 2
  • DOI: 10.1063/1.464304