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Title: Structural elucidation of a mononuclear titanium methylidene


The first example of a structurally characterized titanium methylidene, (PN) 2TiCH 2, has been preparedviaone-electron oxidation of (PN) 2Ti(CH 3) followed by deprotonation with an ylide or by H-atom abstraction using an aryloxyl radical.

 [1];  [2];  [1];  [2]; ORCiD logo [1]
  1. Department of Chemistry; University of Pennsylvania; Philadelphia PA; USA
  2. Department of Chemistry; Korea Advanced Institute of Science and Technology; Daejeon; South Korea; Institute for Basic Science
Publication Date:
Research Org.:
Indiana Univ., Bloomington, IN (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
DOE Contract Number:  
Resource Type:
Journal Article
Journal Name:
Additional Journal Information:
Journal Volume: 53; Journal Issue: 24; Journal ID: ISSN 1359-7345
Royal Society of Chemistry
Country of Publication:
United States

Citation Formats

Grant, Lauren N., Ahn, Seihwan, Manor, Brian C., Baik, Mu-Hyun, and Mindiola, Daniel J. Structural elucidation of a mononuclear titanium methylidene. United States: N. p., 2017. Web. doi:10.1039/c7cc00654c.
Grant, Lauren N., Ahn, Seihwan, Manor, Brian C., Baik, Mu-Hyun, & Mindiola, Daniel J. Structural elucidation of a mononuclear titanium methylidene. United States. doi:10.1039/c7cc00654c.
Grant, Lauren N., Ahn, Seihwan, Manor, Brian C., Baik, Mu-Hyun, and Mindiola, Daniel J. Sun . "Structural elucidation of a mononuclear titanium methylidene". United States. doi:10.1039/c7cc00654c.
title = {Structural elucidation of a mononuclear titanium methylidene},
author = {Grant, Lauren N. and Ahn, Seihwan and Manor, Brian C. and Baik, Mu-Hyun and Mindiola, Daniel J.},
abstractNote = {The first example of a structurally characterized titanium methylidene, (PN)2TiCH2, has been preparedviaone-electron oxidation of (PN)2Ti(CH3) followed by deprotonation with an ylide or by H-atom abstraction using an aryloxyl radical.},
doi = {10.1039/c7cc00654c},
journal = {ChemComm},
issn = {1359-7345},
number = 24,
volume = 53,
place = {United States},
year = {2017},
month = {1}

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