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Title: In situ identification of kinetic factors that expedite inorganic crystal formation and discovery

Abstract

In situX-ray diffraction reveals key processes that can be utilized to direct the synthesis of complex inorganic crystals.

Authors:
ORCiD logo [1];  [1]; ORCiD logo [1]
  1. Department of Materials Science and Engineering; Frederick Seitz Materials Research Laboratory; University of Illinois at Urbana-Champaign; Urbana; USA
Publication Date:
Research Org.:
Univ. of Illinois at Urbana-Champaign, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1535171
DOE Contract Number:  
SC0013897
Resource Type:
Journal Article
Journal Name:
Journal of Materials Chemistry C
Additional Journal Information:
Journal Volume: 5; Journal Issue: 23; Journal ID: ISSN 2050-7526
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
Materials Science; Physics

Citation Formats

Jiang, Zhelong, Ramanathan, Arun, and Shoemaker, Daniel P. In situ identification of kinetic factors that expedite inorganic crystal formation and discovery. United States: N. p., 2017. Web. doi:10.1039/c6tc04931a.
Jiang, Zhelong, Ramanathan, Arun, & Shoemaker, Daniel P. In situ identification of kinetic factors that expedite inorganic crystal formation and discovery. United States. doi:10.1039/c6tc04931a.
Jiang, Zhelong, Ramanathan, Arun, and Shoemaker, Daniel P. Sun . "In situ identification of kinetic factors that expedite inorganic crystal formation and discovery". United States. doi:10.1039/c6tc04931a.
@article{osti_1535171,
title = {In situ identification of kinetic factors that expedite inorganic crystal formation and discovery},
author = {Jiang, Zhelong and Ramanathan, Arun and Shoemaker, Daniel P.},
abstractNote = {In situX-ray diffraction reveals key processes that can be utilized to direct the synthesis of complex inorganic crystals.},
doi = {10.1039/c6tc04931a},
journal = {Journal of Materials Chemistry C},
issn = {2050-7526},
number = 23,
volume = 5,
place = {United States},
year = {2017},
month = {1}
}

Works referenced in this record:

The Materials Genome Initiative, the interplay of experiment, theory and computation
journal, April 2014

  • de Pablo, Juan J.; Jones, Barbara; Kovacs, Cora Lind
  • Current Opinion in Solid State and Materials Science, Vol. 18, Issue 2
  • DOI: 10.1016/j.cossms.2014.02.003

The high-throughput highway to computational materials design
journal, February 2013

  • Curtarolo, Stefano; Hart, Gus L. W.; Nardelli, Marco Buongiorno
  • Nature Materials, Vol. 12, Issue 3
  • DOI: 10.1038/nmat3568

In situ studies of a platform for metastable inorganic crystal growth and materials discovery
journal, July 2014

  • Shoemaker, D. P.; Hu, Y. -J.; Chung, D. Y.
  • Proceedings of the National Academy of Sciences, Vol. 111, Issue 30
  • DOI: 10.1073/pnas.1406211111

Atomic displacements in the charge ice pyrochlore Bi 2 Ti 2 O 6 O studied by neutron total scattering
journal, April 2010


Magnetic Frustration in Iridium Spinel Compound CuIr 2 S 4
journal, February 2014


Highly Stable and Imperceptible Electronics Utilizing Photoactivated Heterogeneous Sol-Gel Metal-Oxide Dielectrics and Semiconductors
journal, January 2015

  • Jo, Jeong-Wan; Kim, Jaekyun; Kim, Kyung-Tae
  • Advanced Materials, Vol. 27, Issue 7
  • DOI: 10.1002/adma.201404296

Ultrafast Phase Transition via Catastrophic Phonon Collapse Driven by Plasmonic Hot-Electron Injection
journal, January 2014

  • Appavoo, Kannatassen; Wang, Bin; Brady, Nathaniel F.
  • Nano Letters, Vol. 14, Issue 3
  • DOI: 10.1021/nl4044828

Unexpected High-Temperature Stability of β-Zn 4 Sb 3 Opens the Door to Enhanced Thermoelectric Performance
journal, January 2014

  • Lin, Jianping; Li, Xudong; Qiao, Guanjun
  • Journal of the American Chemical Society, Vol. 136, Issue 4
  • DOI: 10.1021/ja410605f

β-NaMnO 2 : A High-Performance Cathode for Sodium-Ion Batteries
journal, November 2014

  • Billaud, Juliette; Clément, Raphaële J.; Armstrong, A. Robert
  • Journal of the American Chemical Society, Vol. 136, Issue 49
  • DOI: 10.1021/ja509704t

High-Temperature Ferrimagnetism Driven by Lattice Distortion in Double Perovskite Ca 2 FeOsO 6
journal, February 2014

  • Feng, Hai L.; Arai, Masao; Matsushita, Yoshitaka
  • Journal of the American Chemical Society, Vol. 136, Issue 9
  • DOI: 10.1021/ja411713q

Evidence of Charge-Transfer Ferromagnetism in Transparent Diluted Magnetic Oxide Nanocrystals: Switching the Mechanism of Magnetic Interactions
journal, May 2014

  • Farvid, Shokouh S.; Sabergharesou, Tahereh; Hutfluss, Lisa N.
  • Journal of the American Chemical Society, Vol. 136, Issue 21
  • DOI: 10.1021/ja501888a

Preparation and characterization of Ba2Co2Fe12O22 ferrite via glucose sol–gel method
journal, September 2011

  • Xia, Haiyan; Ye, Yunzhe; Yan, Longgang
  • Journal of Sol-Gel Science and Technology, Vol. 61, Issue 1
  • DOI: 10.1007/s10971-011-2587-4

Giant Negative Electrocaloric Effect in Antiferroelectric La-Doped Pb(ZrTi)O 3 Thin Films Near Room Temperature
journal, April 2015


Understanding the Role of Nanostructures for Efficient Hydrogen Generation on Immobilized Photocatalysts
journal, June 2013

  • Jiang, Zhelong; Tang, Yuxin; Tay, Qiuling
  • Advanced Energy Materials, Vol. 3, Issue 10
  • DOI: 10.1002/aenm.201300380

Capturing Phase Evolution during Solvothermal Synthesis of Metastable Cu 4 O 3
journal, April 2016


Mechanical Force-Driven Growth of Elongated Bending TiO 2 -based Nanotubular Materials for Ultrafast Rechargeable Lithium Ion Batteries
journal, July 2014


Colloidal Synthesis of Single-Layer MSe 2 (M = Mo, W) Nanosheets via Anisotropic Solution-Phase Growth Approach
journal, June 2015

  • Jung, Wonil; Lee, Sujeong; Yoo, Dongwon
  • Journal of the American Chemical Society, Vol. 137, Issue 23
  • DOI: 10.1021/jacs.5b02772

Colloidal Synthesis of an Exotic Phase of Silicon: The BC8 Structure
journal, January 2014

  • Ganguly, Shreyashi; Kazem, Nasrin; Carter, Danielle
  • Journal of the American Chemical Society, Vol. 136, Issue 4
  • DOI: 10.1021/ja412213q

Materials Discovery by Flux Crystal Growth: Quaternary and Higher Order Oxides
journal, January 2012

  • Bugaris, Daniel E.; zur Loye, Hans-Conrad
  • Angewandte Chemie International Edition, Vol. 51, Issue 16
  • DOI: 10.1002/anie.201102676

Probing Molten Salt Flux Reactions Using Time-Resolved in Situ High-Temperature Powder X-ray Diffraction:  A New Synthesis Route to the Mixed-Valence NaTi 2 O 4
journal, March 2004

  • Geselbracht, Margret J.; Noailles, Liam D.; Ngo, Lien T.
  • Chemistry of Materials, Vol. 16, Issue 6
  • DOI: 10.1021/cm034770w

Multiferroic Iron Oxide Thin Films at Room Temperature
journal, May 2014

  • Gich, Martí; Fina, Ignasi; Morelli, Alessio
  • Advanced Materials, Vol. 26, Issue 27
  • DOI: 10.1002/adma.201400990

Intrinsic exchange bias in Zn x Mn 3 x O 4 ( x 1 ) solid solutions
journal, October 2009


Bulk synthesis of iron-based superconductors
journal, April 2013


Synthesis of Cu2ZnSnSe4 compound powders by solid state reaction using elemental powders
journal, December 2010

  • Adhi Wibowo, Rachmat; Hwa Jung, Woon; Kim, Kyoo Ho
  • Journal of Physics and Chemistry of Solids, Vol. 71, Issue 12
  • DOI: 10.1016/j.jpcs.2010.08.012

High Performance Na-doped PbTe–PbS Thermoelectric Materials: Electronic Density of States Modification and Shape-Controlled Nanostructures
journal, October 2011

  • Girard, Steven N.; He, Jiaqing; Zhou, Xiaoyuan
  • Journal of the American Chemical Society, Vol. 133, Issue 41
  • DOI: 10.1021/ja206380h

Tellurium substitution effect on superconductivity of the α-phase iron selenide
journal, October 2008


A Planning Strategy for Diversity-Oriented Synthesis
journal, January 2004

  • Burke, Martin D.; Schreiber, Stuart L.
  • Angewandte Chemie International Edition, Vol. 43, Issue 1
  • DOI: 10.1002/anie.200300626

Discovery of 1,2,4-Triazine Derivatives as Adenosine A 2A Antagonists using Structure Based Drug Design
journal, January 2012

  • Congreve, Miles; Andrews, Stephen P.; Doré, Andrew S.
  • Journal of Medicinal Chemistry, Vol. 55, Issue 5
  • DOI: 10.1021/jm201376w

A Two-Component Small Molecule System for Activity-Based Detection and Signal Amplification: Application to the Visual Detection of Threshold Levels of Pd(II)
journal, April 2011

  • Baker, Matthew S.; Phillips, Scott T.
  • Journal of the American Chemical Society, Vol. 133, Issue 14
  • DOI: 10.1021/ja108347d

Design and Synthesis of Donor–Acceptor Stenhouse Adducts: A Visible Light Photoswitch Derived from Furfural
journal, November 2014

  • Helmy, Sameh; Oh, Saemi; Leibfarth, Frank A.
  • The Journal of Organic Chemistry, Vol. 79, Issue 23
  • DOI: 10.1021/jo502206g

Pyrite Formation via Kinetic Intermediates through Low-Temperature Solid-State Metathesis
journal, October 2014

  • Martinolich, Andrew J.; Neilson, James R.
  • Journal of the American Chemical Society, Vol. 136, Issue 44
  • DOI: 10.1021/ja5081647

Polymorph Selectivity of Superconducting CuSe 2 Through Kinetic Control of Solid-State Metathesis
journal, March 2015

  • Martinolich, Andrew J.; Kurzman, Joshua A.; Neilson, James R.
  • Journal of the American Chemical Society, Vol. 137, Issue 11
  • DOI: 10.1021/ja512520z

Computational Design and Prediction of Interesting Not-Yet-Synthesized Structures of Inorganic Materials by Using Building Unit Concepts
journal, September 2002


Combinatorial solid-state chemistry of inorganic materials
journal, July 2004

  • Koinuma, Hideomi; Takeuchi, Ichiro
  • Nature Materials, Vol. 3, Issue 7
  • DOI: 10.1038/nmat1157

Crystal structure prediction from first principles
journal, December 2008

  • Woodley, Scott M.; Catlow, Richard
  • Nature Materials, Vol. 7, Issue 12
  • DOI: 10.1038/nmat2321

Photovoltaic output limitation of n ‐FeS 2 (pyrite) Schottky barriers: A temperature‐dependent characterization
journal, December 1992

  • Büker, K.; Alonso‐Vante, N.; Tributsch, H.
  • Journal of Applied Physics, Vol. 72, Issue 12
  • DOI: 10.1063/1.351925

Iron disulfide for solar energy conversion
journal, May 1993


Iron Chalcogenide Photovoltaic Absorbers
journal, August 2011

  • Yu, Liping; Lany, Stephan; Kykyneshi, Robert
  • Advanced Energy Materials, Vol. 1, Issue 5
  • DOI: 10.1002/aenm.201100351

Polyhedral deformations in olivine-type compounds and the crystal structure of Fe 2 SiS 4 and Fe 2 GeS 4
journal, June 1976

  • Vincent, H.; Bertaut, E. F.; Baur, W. H.
  • Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 32, Issue 6
  • DOI: 10.1107/S056774087600633X

Neutron powder diffraction study of the crystal and magnetic structures of Fe2SiS4
journal, April 1999


VESTA : a three-dimensional visualization system for electronic and structural analysis
journal, May 2008


Thermodynamic modeling of the Fe-S system
journal, February 2005


Reaction Synthesis of Ti<SUB>3</SUB>SiC<SUB>2</SUB> from Mixture of Elemental Powders
journal, January 2000


Understanding Fluxes as Media for Directed Synthesis: In Situ Local Structure of Molten Potassium Polysulfides
journal, May 2012

  • Shoemaker, Daniel P.; Chung, Duck Young; Mitchell, J. F.
  • Journal of the American Chemical Society, Vol. 134, Issue 22
  • DOI: 10.1021/ja303047e

Principles of crystal growth of intermetallic and oxide compounds from molten solutions
journal, July 2012


Materials discovery by crystal growth: Lanthanide metal containing oxides of the platinum group metals (Ru, Os, Ir, Rh, Pd, Pt) from molten alkali metal hydroxides
journal, July 2009

  • Mugavero, Samuel J.; Gemmill, William R.; Roof, Irina P.
  • Journal of Solid State Chemistry, Vol. 182, Issue 7
  • DOI: 10.1016/j.jssc.2009.05.006

On the defect structure and diffusion kinetics in transition metal sulphides and oxides
journal, August 1988


Alloy degradation under oxidizing-sulfidizing conditions at elevated temperatures
journal, March 2004


Sulfidation Kinetics of Iron and Ferritic Iron-Cobalt Alloys
journal, January 1976

  • Young, D. J.
  • Journal of The Electrochemical Society, Vol. 123, Issue 2
  • DOI: 10.1149/1.2132792

Sulfidation of iron at high temperatures and diffusion kinetics in ferrous sulfide
journal, February 1982

  • Danielewski, M.; Mrowec, S.; Stołosa, A.
  • Oxidation of Metals, Vol. 17, Issue 1-2
  • DOI: 10.1007/BF00606194

Kinetics and mechanism of high-temperature sulfur corrosion of Fe-Cr-Al alloys
journal, December 1979

  • Mrowec, S.; Wedrychowska, M.
  • Oxidation of Metals, Vol. 13, Issue 6
  • DOI: 10.1007/BF00812774

Chemical Diffusion and Point Defect Properties of Iron Sulfide (Fe[sub 1−δ]S) at Temperatures 600°–1000°C
journal, January 1979

  • Fryt, E. M.
  • Journal of The Electrochemical Society, Vol. 126, Issue 4
  • DOI: 10.1149/1.2129108

The sulfidation and oxidation behavior of sputter-deposited amorphous Al-Nb-Si alloys at high temperatures
journal, January 1997


Dealloying Silver/Gold Alloys in Neutral Silver Nitrate Solution: Porosity Evolution, Surface Composition, and Surface Oxides
journal, January 2008

  • Snyder, J.; Livi, K.; Erlebacher, J.
  • Journal of The Electrochemical Society, Vol. 155, Issue 8, p. C464-C473
  • DOI: 10.1149/1.2940319