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Title: Controlling nucleation, growth, and orientation of metal halide perovskite thin films with rationally selected additives

Abstract

Impact of rationally selected additives in precursor solutions on the nucleation and growth of hybrid perovskite thin films is investigated.

Authors:
 [1];  [1];  [2];  [1];  [1];  [1];  [3];  [4];  [2];  [5];  [1]
  1. Department of Chemical Engineering; University of Virginia; Charlottesville; USA
  2. School of Chemical and Biomolecular Engineering; Cornell University; Ithaca; USA
  3. Department of Physics; Wake Forest University; Winston-Salem; USA
  4. Cornell High Energy Synchrotron Source; Cornell University; Ithaca; USA
  5. Department of Mechanical Engineering and Materials Science; University of Pittsburgh; Pittsburgh; USA
Publication Date:
Research Org.:
Univ. of Virginia, Charlottesville, VA (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1535165
DOE Contract Number:  
SC0016144
Resource Type:
Journal Article
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Volume: 5; Journal Issue: 1; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
Chemistry; Energy & Fuels; Materials Science

Citation Formats

Foley, Benjamin J., Girard, Justin, Sorenson, Blaire A., Chen, Alexander Z., Scott Niezgoda, J., Alpert, Matthew R., Harper, Angela F., Smilgies, Detlef-M., Clancy, Paulette, Saidi, Wissam A., and Choi, Joshua J. Controlling nucleation, growth, and orientation of metal halide perovskite thin films with rationally selected additives. United States: N. p., 2017. Web. doi:10.1039/c6ta07671h.
Foley, Benjamin J., Girard, Justin, Sorenson, Blaire A., Chen, Alexander Z., Scott Niezgoda, J., Alpert, Matthew R., Harper, Angela F., Smilgies, Detlef-M., Clancy, Paulette, Saidi, Wissam A., & Choi, Joshua J. Controlling nucleation, growth, and orientation of metal halide perovskite thin films with rationally selected additives. United States. doi:10.1039/c6ta07671h.
Foley, Benjamin J., Girard, Justin, Sorenson, Blaire A., Chen, Alexander Z., Scott Niezgoda, J., Alpert, Matthew R., Harper, Angela F., Smilgies, Detlef-M., Clancy, Paulette, Saidi, Wissam A., and Choi, Joshua J. Sun . "Controlling nucleation, growth, and orientation of metal halide perovskite thin films with rationally selected additives". United States. doi:10.1039/c6ta07671h.
@article{osti_1535165,
title = {Controlling nucleation, growth, and orientation of metal halide perovskite thin films with rationally selected additives},
author = {Foley, Benjamin J. and Girard, Justin and Sorenson, Blaire A. and Chen, Alexander Z. and Scott Niezgoda, J. and Alpert, Matthew R. and Harper, Angela F. and Smilgies, Detlef-M. and Clancy, Paulette and Saidi, Wissam A. and Choi, Joshua J.},
abstractNote = {Impact of rationally selected additives in precursor solutions on the nucleation and growth of hybrid perovskite thin films is investigated.},
doi = {10.1039/c6ta07671h},
journal = {Journal of Materials Chemistry. A},
issn = {2050-7488},
number = 1,
volume = 5,
place = {United States},
year = {2017},
month = {1}
}

Works referenced in this record:

High Performance of Planar Perovskite Solar Cells Produced from PbI 2 (DMSO) and PbI 2 (NMP) Complexes by Intramolecular Exchange
journal, February 2016

  • Jo, Yimhyun; Oh, Kyoung Suk; Kim, Minjin
  • Advanced Materials Interfaces, Vol. 3, Issue 10
  • DOI: 10.1002/admi.201500768

Lewis Acid–Base Adduct Approach for High Efficiency Perovskite Solar Cells
journal, January 2016


Branched methoxydiphenylamine-substituted fluorene derivatives as hole transporting materials for high-performance perovskite solar cells
journal, January 2016

  • Malinauskas, Tadas; Saliba, Michael; Matsui, Taisuke
  • Energy & Environmental Science, Vol. 9, Issue 5
  • DOI: 10.1039/C5EE03911H

Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency
journal, January 2016

  • Saliba, Michael; Matsui, Taisuke; Seo, Ji-Youn
  • Energy & Environmental Science, Vol. 9, Issue 6
  • DOI: 10.1039/C5EE03874J

Hysteresis-free low-temperature-processed planar perovskite solar cells with 19.1% efficiency
journal, January 2016

  • Yoon, Heetae; Kang, Seong Min; Lee, Jong-Kwon
  • Energy & Environmental Science, Vol. 9, Issue 7
  • DOI: 10.1039/C6EE01037G

High-performance photovoltaic perovskite layers fabricated through intramolecular exchange
journal, May 2015


Highly Reproducible Perovskite Solar Cells with Average Efficiency of 18.3% and Best Efficiency of 19.7% Fabricated via Lewis Base Adduct of Lead(II) Iodide
journal, July 2015

  • Ahn, Namyoung; Son, Dae-Yong; Jang, In-Hyuk
  • Journal of the American Chemical Society, Vol. 137, Issue 27
  • DOI: 10.1021/jacs.5b04930

Interface engineering of highly efficient perovskite solar cells
journal, July 2014


A vacuum flash–assisted solution process for high-efficiency large-area perovskite solar cells
journal, June 2016


Microstructures of Organometal Trihalide Perovskites for Solar Cells: Their Evolution from Solutions and Characterization
journal, November 2015

  • Zhou, Yuanyuan; Game, Onkar S.; Pang, Shuping
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 23
  • DOI: 10.1021/acs.jpclett.5b01843

Relationships between Lead Halide Perovskite Thin-Film Fabrication, Morphology, and Performance in Solar Cells
journal, November 2015

  • Sharenko, Alexander; Toney, Michael F.
  • Journal of the American Chemical Society, Vol. 138, Issue 2
  • DOI: 10.1021/jacs.5b10723

Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites
journal, October 2012


Morphological Control for High Performance, Solution-Processed Planar Heterojunction Perovskite Solar Cells
journal, September 2013

  • Eperon, Giles E.; Burlakov, Victor M.; Docampo, Pablo
  • Advanced Functional Materials, Vol. 24, Issue 1, p. 151-157
  • DOI: 10.1002/adfm.201302090

Mesoscopic CH3NH3PbI3/TiO2 Heterojunction Solar Cells
journal, October 2012

  • Etgar, Lioz; Gao, Peng; Xue, Zhaosheng
  • Journal of the American Chemical Society, Vol. 134, Issue 42, p. 17396-17399
  • DOI: 10.1021/ja307789s

Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber
journal, October 2013

  • Stranks, S. D.; Eperon, G. E.; Grancini, G.
  • Science, Vol. 342, Issue 6156, p. 341-344
  • DOI: 10.1126/science.1243982

Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells
journal, July 2014

  • Jeon, Nam Joong; Noh, Jun Hong; Kim, Young Chan
  • Nature Materials, Vol. 13, Issue 9, p. 897-903
  • DOI: 10.1038/nmat4014

Solvent engineering towards controlled grain growth in perovskite planar heterojunction solar cells
journal, January 2015

  • Rong, Yaoguang; Tang, Zhongjia; Zhao, Yufeng
  • Nanoscale, Vol. 7, Issue 24
  • DOI: 10.1039/C5NR02866C

Fabrication of metal-oxide-free CH 3 NH 3 PbI 3 perovskite solar cells processed at low temperature
journal, January 2015

  • Ryu, Seungchan; Seo, Jangwon; Shin, Seong Sik
  • Journal of Materials Chemistry A, Vol. 3, Issue 7
  • DOI: 10.1039/C5TA00011D

A Fast Deposition-Crystallization Procedure for Highly Efficient Lead Iodide Perovskite Thin-Film Solar Cells
journal, July 2014

  • Xiao, Manda; Huang, Fuzhi; Huang, Wenchao
  • Angewandte Chemie International Edition, Vol. 53, Issue 37
  • DOI: 10.1002/anie.201405334

Room-temperature crystallization of hybrid-perovskite thin films via solvent–solvent extraction for high-performance solar cells
journal, January 2015

  • Zhou, Yuanyuan; Yang, Mengjin; Wu, Wenwen
  • Journal of Materials Chemistry A, Vol. 3, Issue 15
  • DOI: 10.1039/C5TA00477B

Impact of the organic halide salt on final perovskite composition for photovoltaic applications
journal, August 2014

  • Moore, David T.; Sai, Hiroaki; Wee Tan, Kwan
  • APL Materials, Vol. 2, Issue 8
  • DOI: 10.1063/1.4886275

Direct Crystallization Route to Methylammonium Lead Iodide Perovskite from an Ionic Liquid
journal, April 2015

  • Moore, David T.; Tan, Kwan W.; Sai, Hiroaki
  • Chemistry of Materials, Vol. 27, Issue 9
  • DOI: 10.1021/cm5047484

High efficiency methylammonium lead triiodide perovskite solar cells: the relevance of non-stoichiometric precursors
journal, January 2015

  • Roldán-Carmona, C.; Gratia, P.; Zimmermann, I.
  • Energy & Environmental Science, Vol. 8, Issue 12
  • DOI: 10.1039/C5EE02555A

Ultrasmooth organic–inorganic perovskite thin-film formation and crystallization for efficient planar heterojunction solar cells
journal, January 2015

  • Zhang, Wei; Saliba, Michael; Moore, David T.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7142

Non-Thermal Annealing Fabrication of Efficient Planar Perovskite Solar Cells with Inclusion of NH 4 Cl
journal, February 2015


The roles of alkyl halide additives in enhancing perovskite solar cell performance
journal, January 2015

  • Chueh, Chu-Chen; Liao, Chien-Yi; Zuo, Fan
  • Journal of Materials Chemistry A, Vol. 3, Issue 17
  • DOI: 10.1039/C4TA05012F

Easily accessible polymer additives for tuning the crystal-growth of perovskite thin-films for highly efficient solar cells
journal, January 2016

  • Dong, Qingqing; Wang, Zhaowei; Zhang, Kaicheng
  • Nanoscale, Vol. 8, Issue 10
  • DOI: 10.1039/C6NR00206D

Formamidinium lead trihalide: a broadly tunable perovskite for efficient planar heterojunction solar cells
journal, January 2014

  • Eperon, Giles E.; Stranks, Samuel D.; Menelaou, Christopher
  • Energy & Environmental Science, Vol. 7, Issue 3
  • DOI: 10.1039/c3ee43822h

Planar CH 3 NH 3 PbI 3 Perovskite Solar Cells with Constant 17.2% Average Power Conversion Efficiency Irrespective of the Scan Rate
journal, April 2015


High-performance and high-durability perovskite photovoltaic devices prepared using ethylammonium iodide as an additive
journal, January 2015

  • Hsu, Hsiang-Lin; Chang, Ching-Chih; Chen, Chih-Ping
  • Journal of Materials Chemistry A, Vol. 3, Issue 17
  • DOI: 10.1039/C5TA01563D

Hydrobromic acid assisted crystallization of MAPbI 3−x Cl x for enhanced power conversion efficiency in perovskite solar cells
journal, January 2016

  • Huang, Jin; Wang, Minqiang; Ding, Lei
  • RSC Advances, Vol. 6, Issue 61
  • DOI: 10.1039/C6RA07536C

Planar heterojunction perovskite solar cells with superior reproducibility
journal, November 2014

  • Jeon, Ye-Jin; Lee, Sehyun; Kang, Rira
  • Scientific Reports, Vol. 4, Issue 1
  • DOI: 10.1038/srep06953

Hydrochloric acid accelerated formation of planar CH 3 NH 3 PbI 3 perovskite with high humidity tolerance
journal, January 2015

  • Li, Ge; Zhang, Taiyang; Zhao, Yixin
  • Journal of Materials Chemistry A, Vol. 3, Issue 39
  • DOI: 10.1039/C5TA06172E

Improved performance and stability of perovskite solar cells by crystal crosslinking with alkylphosphonic acid ω-ammonium chlorides
journal, August 2015

  • Li, Xiong; Ibrahim Dar, M.; Yi, Chenyi
  • Nature Chemistry, Vol. 7, Issue 9
  • DOI: 10.1038/nchem.2324

Additive Enhanced Crystallization of Solution-Processed Perovskite for Highly Efficient Planar-Heterojunction Solar Cells
journal, March 2014

  • Liang, Po-Wei; Liao, Chien-Yi; Chueh, Chu-Chen
  • Advanced Materials, Vol. 26, Issue 22, p. 3748-3754
  • DOI: 10.1002/adma.201400231

Effects of 4-tert-butylpyridine on perovskite formation and performance of solution-processed perovskite solar cells
journal, January 2015

  • Shi, Yantao; Wang, Xiangyuan; Zhang, Hong
  • Journal of Materials Chemistry A, Vol. 3, Issue 44
  • DOI: 10.1039/C5TA05988G

Additive-Modulated Evolution of HC(NH 2 ) 2 PbI 3 Black Polymorph for Mesoscopic Perovskite Solar Cells
journal, October 2015


An 80.11% FF record achieved for perovskite solar cells by using the NH 4 Cl additive
journal, January 2014


One-step, low-temperature deposited perovskite solar cell utilizing small molecule additive
journal, January 2015

  • Chen, Chun-Chao; Hong, Zirou; Li, Gang
  • Journal of Photonics for Energy, Vol. 5, Issue 1
  • DOI: 10.1117/1.JPE.5.057405

Sequential deposition as a route to high-performance perovskite-sensitized solar cells
journal, July 2013

  • Burschka, Julian; Pellet, Norman; Moon, Soo-Jin
  • Nature, Vol. 499, Issue 7458, p. 316-319
  • DOI: 10.1038/nature12340

Growth of CH3NH3PbI3 cuboids with controlled size for high-efficiency perovskite solar cells
journal, August 2014

  • Im, Jeong-Hyeok; Jang, In-Hyuk; Pellet, Norman
  • Nature Nanotechnology, Vol. 9, Issue 11
  • DOI: 10.1038/nnano.2014.181

Efficient, high yield perovskite photovoltaic devices grown by interdiffusion of solution-processed precursor stacking layers
journal, January 2014

  • Xiao, Zhengguo; Bi, Cheng; Shao, Yuchuan
  • Energy Environ. Sci., Vol. 7, Issue 8
  • DOI: 10.1039/C4EE01138D

A Closer Look into Two-Step Perovskite Conversion with X-ray Scattering
journal, March 2015

  • Schlipf, Johannes; Docampo, Pablo; Schaffer, Christoph J.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 7
  • DOI: 10.1021/acs.jpclett.5b00329

Crystallization Dynamics of Organolead Halide Perovskite by Real-Time X-ray Diffraction
journal, July 2015


Enhancing the crystallization and optimizing the orientation of perovskite films via controlling nucleation dynamics
journal, January 2016

  • Liang, Qiuju; Liu, Jiangang; Cheng, Zhongkai
  • Journal of Materials Chemistry A, Vol. 4, Issue 1
  • DOI: 10.1039/C5TA08015K

Influence of Thermal Processing Protocol upon the Crystallization and Photovoltaic Performance of Organic–Inorganic Lead Trihalide Perovskites
journal, April 2014

  • Saliba, Michael; Tan, Kwan Wee; Sai, Hiroaki
  • The Journal of Physical Chemistry C, Vol. 118, Issue 30
  • DOI: 10.1021/jp500717w

Thermally Induced Structural Evolution and Performance of Mesoporous Block Copolymer-Directed Alumina Perovskite Solar Cells
journal, April 2014

  • Tan, Kwan Wee; Moore, David T.; Saliba, Michael
  • ACS Nano, Vol. 8, Issue 5
  • DOI: 10.1021/nn500526t

Monitoring the Phase Formation of Coevaporated Lead Halide Perovskite Thin Films by in Situ X-ray Diffraction
journal, September 2014

  • Pistor, Paul; Borchert, Juliane; Fränzel, Wolfgang
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 19
  • DOI: 10.1021/jz5017312

In situ X-ray scattering of perovskite solar cell active layers roll-to-roll coated on flexible substrates
journal, January 2016

  • Rossander, Lea H.; Larsen-Olsen, Thue T.; Dam, Henrik F.
  • CrystEngComm, Vol. 18, Issue 27
  • DOI: 10.1039/C6CE00382F

Facet-dependent photovoltaic efficiency variations in single grains of hybrid halide perovskite
journal, July 2016


Hybrid Halide Perovskite Solar Cell Precursors: Colloidal Chemistry and Coordination Engineering behind Device Processing for High Efficiency
journal, March 2015

  • Yan, Keyou; Long, Mingzhu; Zhang, Tiankai
  • Journal of the American Chemical Society, Vol. 137, Issue 13
  • DOI: 10.1021/jacs.5b00321

Compositional engineering of perovskite materials for high-performance solar cells
journal, January 2015

  • Jeon, Nam Joong; Noh, Jun Hong; Yang, Woon Seok
  • Nature, Vol. 517, Issue 7535
  • DOI: 10.1038/nature14133

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu
journal, April 2010

  • Grimme, Stefan; Antony, Jens; Ehrlich, Stephan
  • The Journal of Chemical Physics, Vol. 132, Issue 15
  • DOI: 10.1063/1.3382344

A thorough benchmark of density functional methods for general main group thermochemistry, kinetics, and noncovalent interactions
journal, January 2011

  • Goerigk, Lars; Grimme, Stefan
  • Physical Chemistry Chemical Physics, Vol. 13, Issue 14
  • DOI: 10.1039/c0cp02984j

PACKMOL: A package for building initial configurations for molecular dynamics simulations
journal, October 2009

  • Martínez, L.; Andrade, R.; Birgin, E. G.
  • Journal of Computational Chemistry, Vol. 30, Issue 13
  • DOI: 10.1002/jcc.21224

Evaluation and Reparametrization of the OPLS-AA Force Field for Proteins via Comparison with Accurate Quantum Chemical Calculations on Peptides
journal, July 2001

  • Kaminski, George A.; Friesner, Richard A.; Tirado-Rives, Julian
  • The Journal of Physical Chemistry B, Vol. 105, Issue 28
  • DOI: 10.1021/jp003919d

Accurate Coulomb-fitting basis sets for H to Rn
journal, January 2006

  • Weigend, Florian
  • Physical Chemistry Chemical Physics, Vol. 8, Issue 9
  • DOI: 10.1039/b515623h

Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996


Ab initiomolecular dynamics for liquid metals
journal, January 1993


Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996


Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

Coordination Chemistry Study of Hydrated and Solvated Lead(II) Ions in Solution and Solid State
journal, February 2011

  • Persson, Ingmar; Lyczko, Krzysztof; Lundberg, Daniel
  • Inorganic Chemistry, Vol. 50, Issue 3
  • DOI: 10.1021/ic1017714

Controllable Grain Morphology of Perovskite Absorber Film by Molecular Self-Assembly toward Efficient Solar Cell Exceeding 17%
journal, August 2015

  • Li, Wenzhe; Fan, Jiandong; Li, Jiangwei
  • Journal of the American Chemical Society, Vol. 137, Issue 32
  • DOI: 10.1021/jacs.5b06444

Two different mechanisms of CH 3 NH 3 PbI 3 film formation in one-step deposition and its effect on photovoltaic properties of OPV-type perovskite solar cells
journal, January 2015

  • Bae, Seunghwan; Han, Seung Jin; Shin, Tae Joo
  • Journal of Materials Chemistry A, Vol. 3, Issue 47
  • DOI: 10.1039/C5TA06870C

Critical kinetic control of non-stoichiometric intermediate phase transformation for efficient perovskite solar cells
journal, January 2016

  • Rong, Yaoguang; Venkatesan, Swaminathan; Guo, Rui
  • Nanoscale, Vol. 8, Issue 26
  • DOI: 10.1039/C6NR00488A

Bonding Power of Electrons and Theory of Valence.
journal, December 1931


Controllable Perovskite Crystallization at a Gas–Solid Interface for Hole Conductor-Free Solar Cells with Steady Power Conversion Efficiency over 10%
journal, November 2014

  • Hao, Feng; Stoumpos, Constantinos C.; Liu, Zhao
  • Journal of the American Chemical Society, Vol. 136, Issue 46
  • DOI: 10.1021/ja509245x

Identification and characterization of the intermediate phase in hybrid organic–inorganic MAPbI 3 perovskite
journal, January 2016

  • Guo, Xin; McCleese, Christopher; Kolodziej, Charles
  • Dalton Transactions, Vol. 45, Issue 9
  • DOI: 10.1039/C5DT04420K

Large Grained Perovskite Solar Cells Derived from Single-Crystal Perovskite Powders with Enhanced Ambient Stability
journal, June 2016

  • Yen, Hung-Ju; Liang, Po-Wei; Chueh, Chu-Chen
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 23
  • DOI: 10.1021/acsami.6b02169

High-efficiency solution-processed perovskite solar cells with millimeter-scale grains
journal, January 2015


Methylamine-Gas-Induced Defect-Healing Behavior of CH 3 NH 3 PbI 3 Thin Films for Perovskite Solar Cells
journal, June 2015

  • Zhou, Zhongmin; Wang, Zaiwei; Zhou, Yuanyuan
  • Angewandte Chemie International Edition, Vol. 54, Issue 33
  • DOI: 10.1002/anie.201504379

Square-Centimeter Solution-Processed Planar CH 3 NH 3 PbI 3 Perovskite Solar Cells with Efficiency Exceeding 15%
journal, September 2015

  • Yang, Mengjin; Zhou, Yuanyuan; Zeng, Yining
  • Advanced Materials, Vol. 27, Issue 41
  • DOI: 10.1002/adma.201502586

Controlled orientation of perovskite films through mixed cations toward high performance perovskite solar cells
journal, September 2016


Efficient planar heterojunction perovskite solar cells by vapour deposition
journal, September 2013

  • Liu, Mingzhen; Johnston, Michael B.; Snaith, Henry J.
  • Nature, Vol. 501, Issue 7467, p. 395-398
  • DOI: 10.1038/nature12509

Crystallization of Methyl Ammonium Lead Halide Perovskites: Implications for Photovoltaic Applications
journal, September 2014

  • Tidhar, Yaron; Edri, Eran; Weissman, Haim
  • Journal of the American Chemical Society, Vol. 136, Issue 38
  • DOI: 10.1021/ja505556s

Abnormal crystal growth in CH 3 NH 3 PbI 3−x Cl x using a multi-cycle solution coating process
journal, January 2015

  • Dong, Qingfeng; Yuan, Yongbo; Shao, Yuchuan
  • Energy & Environmental Science, Vol. 8, Issue 8
  • DOI: 10.1039/C5EE01179E

Interface-Induced Nucleation, Orientational Alignment and Symmetry Transformations in Nanocube Superlattices
journal, January 2012

  • Choi, Joshua J.; Bian, Kaifu; Baumgardner, William J.
  • Nano Letters, Vol. 12, Issue 9
  • DOI: 10.1021/nl3026289

Ligand-Directed Assembly of Preformed Titania Nanocrystals into Highly Anisotropic Nanostructures
journal, March 2004


Ultrathin PbS Sheets by Two-Dimensional Oriented Attachment
journal, July 2010


General Synthesis of Semiconductor Chalcogenide Nanorods by Using the Monodentate Ligandn-Butylamine as a Shape Controller
journal, December 2002

  • Yang, Jian; Xue, Can; Yu, Shu-Hong
  • Angewandte Chemie International Edition, Vol. 41, Issue 24
  • DOI: 10.1002/anie.200290020

Preferential Facet Growth of Methylammonium Lead Halide Single Crystals Promoted by Halide Coordination
journal, August 2016

  • Zhang, Yi; Huang, Fuqiang; Mi, Qixi
  • Chemistry Letters, Vol. 45, Issue 8
  • DOI: 10.1246/cl.160419

First-Principles Atomistic Thermodynamics for Oxidation Catalysis: Surface Phase Diagrams and Catalytically Interesting Regions
journal, January 2003


Ab initio atomistic thermodynamics study of the early stages of Cu(100) oxidation
journal, December 2012


Strong Reciprocal Interaction between Polarization and Surface Stoichiometry in Oxide Ferroelectrics
journal, October 2014

  • Saidi, Wissam A.; Martirez, John Mark P.; Rappe, Andrew M.
  • Nano Letters, Vol. 14, Issue 11
  • DOI: 10.1021/nl5035013

Termination Dependence of Tetragonal CH 3 NH 3 PbI 3 Surfaces for Perovskite Solar Cells
journal, August 2014

  • Haruyama, Jun; Sodeyama, Keitaro; Han, Liyuan
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 16
  • DOI: 10.1021/jz501510v

Efficient planar heterojunction mixed-halide perovskite solar cells deposited via spray-deposition
journal, January 2014

  • Barrows, Alexander T.; Pearson, Andrew J.; Kwak, Chan Kyu
  • Energy Environ. Sci., Vol. 7, Issue 9
  • DOI: 10.1039/C4EE01546K

Understanding the formation and evolution of interdiffusion grown organolead halide perovskite thin films by thermal annealing
journal, January 2014

  • Bi, Cheng; Shao, Yuchuan; Yuan, Yongbo
  • J. Mater. Chem. A, Vol. 2, Issue 43
  • DOI: 10.1039/C4TA04007D

Mixed solvents for the optimization of morphology in solution-processed, inverted-type perovskite/fullerene hybrid solar cells
journal, January 2014

  • Kim, Hak-Beom; Choi, Hyosung; Jeong, Jaeki
  • Nanoscale, Vol. 6, Issue 12
  • DOI: 10.1039/c4nr00130c

The origin of high efficiency in low-temperature solution-processable bilayer organometal halide hybrid solar cells
journal, January 2014

  • Sun, Shuangyong; Salim, Teddy; Mathews, Nripan
  • Energy Environ. Sci., Vol. 7, Issue 1
  • DOI: 10.1039/C3EE43161D

Fermi level, work function and vacuum level
journal, January 2016


Energy Level Modification in Lead Sulfide Quantum Dot Thin Films through Ligand Exchange
journal, May 2014

  • Brown, Patrick R.; Kim, Donghun; Lunt, Richard R.
  • ACS Nano, Vol. 8, Issue 6
  • DOI: 10.1021/nn500897c