Application of a mild hydrothermal method to the synthesis of mixed transition-metal( ii )/uranium( iv ) fluorides

Felder, Justin; Yeon, Jeongho; Smith, Mark; zur Loye, Hans-Conrad

doi:10.1039/c6qi00491a

Title: Application of a mild hydrothermal method to the synthesis of mixed transition-metal( ii )/uranium( iv ) fluorides

Journal Article · Sun Jan 01 00:00:00 EST 2017 · Inorganic Chemistry Frontiers (Online)

DOI:https://doi.org/10.1039/c6qi00491a· OSTI ID:1535157

Felder, Justin ^[1]; Yeon, Jeongho ^[1]; Smith, Mark ^[1]; zur Loye, Hans-Conrad ^[1]

Department of Chemistry and Biochemistry; University of South Carolina; Columbia; USA

The synthesis and properties of two families of mixed metal U(iv)/M(ii) fluoridesviaa mild hydrothermal method.

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Research Organization:: Univ. of South Carolina, Columbia, SC (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0008664

OSTI ID:: 1535157

Journal Information:: Inorganic Chemistry Frontiers (Online), Vol. 4, Issue 2; ISSN 2052-1553

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (36)

KNa3(UO2)2(Si4O10)2(H2O)4, a new compound formed during vapor hydration of an actinide-bearing borosilicate waste glass Burns, Peter C.; Olson, Rudolph A.; Finch, Robert J. Journal of Nuclear Materials, Vol. 278, Issue 2-3 https://doi.org/10.1016/S0022-3115(99)00247-0	journal	April 2000
A Re-Evaluation of the Structure of Weeksite, a Uranyl Silicate Framework Mineral Jackson, J. M.; Burns, P. C. The Canadian Mineralogist, Vol. 39, Issue 1 https://doi.org/10.2113/gscanmin.39.1.187	journal	February 2001
UO2/Zry-4 chemical interaction layers for intact and leak PWR fuel rods Kim, Kyu-Tae Journal of Nuclear Materials, Vol. 404, Issue 2 https://doi.org/10.1016/j.jnucmat.2010.07.013	journal	September 2010
Syntheses, Structures, and Characterization of Open-Framework Uranyl Germanates Ling, Jie; Morrison, Jessica M.; Ward, Matthew Inorganic Chemistry, Vol. 49, Issue 15 https://doi.org/10.1021/ic1010242	journal	August 2010
Design Study to Increase Plutonium Conversion Ratio of HC-FLWR Core Yamaji, Akifumi; Nakano, Yoshihiro; Uchikawa, Sadao Nuclear Technology, Vol. 179, Issue 3 https://doi.org/10.13182/NT12-A14165	journal	September 2012
Solid-state syntheses and single-crystal characterizations of three tetravalent thorium and uranium silicates Jin, Geng Bang; Soderholm, L. Journal of Solid State Chemistry, Vol. 221 https://doi.org/10.1016/j.jssc.2014.10.018	journal	January 2015
Synthesis, characterization and thermal study of Rb U(IV) Mo O and Rb U(VI) Mo O systems Keskar, Meera; Sali, S. K.; Krishnan, K. Journal of Nuclear Materials, Vol. 478 https://doi.org/10.1016/j.jnucmat.2016.06.021	journal	September 2016
Syntheses and characterization of the cubic uranium chalcogenides Rh2U6S15, Cs2Ti2U6Se15, Cs2Cr2U6Se15, and Cs2Ti2U6Te15 Ward, Matthew D.; Oh, George N.; Mesbah, Adel Journal of Solid State Chemistry, Vol. 228 https://doi.org/10.1016/j.jssc.2015.04.005	journal	August 2015
The [U ₂ (μ-S ₂ ) ₂ Cl ₈ ] ^4– Anion: Synthesis and Characterization of the Uranium Double Salt Cs ₅ [U ₂ (μ-S ₂ ) ₂ Cl ₈ ]I Ward, Matthew D.; Pozzi, Eric A.; Lee, Minseong Inorganic Chemistry, Vol. 54, Issue 6 https://doi.org/10.1021/acs.inorgchem.5b00234	journal	February 2015
Further Insight into Uranium and Thorium Metaphosphate Chemistry and the Effect of Nd ³⁺ Incorporation into Uranium(IV) Metaphosphate : Actinide Metaphosphate Chemistry Yu, Na; Klepov, Vladislav V.; Neumeier, Stefan European Journal of Inorganic Chemistry, Vol. 2015, Issue 9 https://doi.org/10.1002/ejic.201403098	journal	February 2015
Oleum and Sulfuric Acid as Reaction Media: The Actinide Examples UO2(S2O7)-lt (low temperature), UO2(S2O7)-ht (high temperature), UO2(HSO4)2, An(SO4)2 (An = Th, U), Th4(HSO4)2(SO4)7 and Th(HSO4)2(SO4) Betke, Ulf; Wickleder, Mathias S. European Journal of Inorganic Chemistry, Vol. 2012, Issue 2 https://doi.org/10.1002/ejic.201100975	journal	December 2011
[La(UO2)V2O7][(UO2)(VO4)] the first lanthanum uranyl-vanadate with structure built from two types of sheets based upon the uranophane anion-topology Mer, A.; Obbade, S.; Rivenet, M. Journal of Solid State Chemistry, Vol. 185 https://doi.org/10.1016/j.jssc.2011.10.042	journal	January 2012
Meisserite, Na ₅ (UO ₂ )(SO ₄ ) ₃ (SO ₃ OH)(H ₂ O), a new uranyl sulfate mineral from the Blue Lizard mine, San Juan County, Utah, USA Plášil, J.; Kampf, A. R.; Kasatkin, A. V. Mineralogical Magazine, Vol. 77, Issue 7 https://doi.org/10.1180/minmag.2013.077.7.07	journal	October 2013
A ₂ MnU ₃ O ₁₁ (A = K, Rb) and Li _3.2 Mn _1.8 U ₆ O ₂₂ : Three New Alkali-Metal Manganese Uranium(VI) Oxides Related to Natrotantite Read, Cory Michael; Morrison, Gregory; Yeon, Jeongho Inorganic Chemistry, Vol. 54, Issue 14 https://doi.org/10.1021/acs.inorgchem.5b01004	journal	July 2015
Crystal structure and phase transitions in the uranium perovskite, Ba2SrUO6 Reynolds, Emily; Kennedy, Brendan J.; Thorogood, Gordon J. Journal of Nuclear Materials, Vol. 433, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2012.08.034	journal	February 2013
Synthesis and structure of cesium-containing zippeite Serezhkina, L. B.; Grigor’ev, M. S.; Makarov, A. S. Radiochemistry, Vol. 57, Issue 1 https://doi.org/10.1134/S1066362215010038	journal	January 2015
Highly Distorted Uranyl Ion Coordination and One/Two-Dimensional Structural Relationship in the Ba ₂ [UO ₂ (TO ₄ ) ₂ ] (T = P, As) System: An Experimental and Computational Study Wu, Shijun; Kowalski, Piotr M.; Yu, Na Inorganic Chemistry, Vol. 53, Issue 14 https://doi.org/10.1021/ic500965v	journal	June 2014
Étude par diffractions X et neutronique d'un monocristal de UCr2O6 obtenu par synthèse hydrothermale sous très haute pression. Détermination des structures cristallographique et magnétique Collomb, A.; Gondrand, M.; Lehmann, M. S. Journal of Solid State Chemistry, Vol. 16, Issue 1-2 https://doi.org/10.1016/0022-4596(76)90005-0	journal	January 1976
U ₃ F ₁₂ (H ₂ O), a Noncentrosymmetric Uranium(IV) Fluoride Prepared via a Convenient In Situ Route That Creates U ⁴⁺ under Mild Hydrothermal Conditions Yeon, Jeongho; Smith, Mark D.; Sefat, Athena S. Inorganic Chemistry, Vol. 52, Issue 15 https://doi.org/10.1021/ic401412t	journal	July 2013
Crystal Growth, Structural Characterization, and Magnetic Properties of New Uranium(IV) Containing Mixed Metal Oxalates: Na ₂ U ₂ M(C ₂ O ₄ ) ₆ (H ₂ O) ₄ (M = Mn ²⁺ , Fe ²⁺ , Co ²⁺ , and Zn ²⁺ ) Yeon, Jeongho; Smith, Mark D.; Sefat, Athena S. Inorganic Chemistry, Vol. 52, Issue 4 https://doi.org/10.1021/ic3026733	journal	January 2013
Application of a Mild Hydrothermal Approach Containing an in Situ Reduction Step to the Growth of Single Crystals of the Quaternary U(IV)-Containing Fluorides Na ₄ MU ₆ F ₃₀ (M = Mn ²⁺ , Co ²⁺ , Ni ²⁺ , Cu ²⁺ , and Zn ²⁺ ) Crystal Growth, Structures, and Magnetic Properties Yeon, Jeongho; Smith, Mark D.; Tapp, Joshua Journal of the American Chemical Society, Vol. 136, Issue 10 https://doi.org/10.1021/ja412725r	journal	February 2014
Mild Hydrothermal Crystal Growth, Structure, and Magnetic Properties of Ternary U(IV) Containing Fluorides: LiUF ₅ , KU ₂ F ₉ , K ₇ U ₆ F ₃₁ , RbUF ₅ , RbU ₂ F ₉ , and RbU ₃ F ₁₃ Yeon, Jeongho; Smith, Mark D.; Tapp, Joshua Inorganic Chemistry, Vol. 53, Issue 12 https://doi.org/10.1021/ic5008507	journal	May 2014
Trivalent Cation-Controlled Phase Space of New U(IV) Fluorides, Na ₃ MU ₆ F ₃₀ (M = Al ³⁺ , Ga ³⁺ , Ti ³⁺ , V ³⁺ , Cr ³⁺ , Fe ³⁺ ): Mild Hydrothermal Synthesis Including an in Situ Reduction Step, Structures, Optical, and Magnetic Properties Yeon, Jeongho; Smith, Mark D.; Morrison, Gregory Inorganic Chemistry, Vol. 54, Issue 4 https://doi.org/10.1021/ic503034t	journal	January 2015
Mild hydrothermal crystal growth of new uranium(IV) fluorides, Na3.13Mg1.43U6F30 and Na2.50Mn1.75U6F30: Structures, optical and magnetic properties Yeon, Jeongho; Smith, Mark D.; Tapp, Joshua Journal of Solid State Chemistry, Vol. 236 https://doi.org/10.1016/j.jssc.2015.04.036	journal	April 2016
A short history of SHELX Sheldrick, George M. Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122 https://doi.org/10.1107/S0108767307043930	journal	December 2007
ShelXle : a Qt graphical user interface for SHELXL Hübschle, Christian B.; Sheldrick, George M.; Dittrich, Birger Journal of Applied Crystallography, Vol. 44, Issue 6 https://doi.org/10.1107/S0021889811043202	journal	November 2011
Hydrothermal Preparation of Nickel(II)/Uranium(IV) Fluorides with One-, Two-, and Three-Dimensional Topologies Bean, Amanda C.; Sullens, Tyler A.; Runde, Wolfgang Inorganic Chemistry, Vol. 42, Issue 8 https://doi.org/10.1021/ic0262076	journal	April 2003
Synthèse et étude structurale des composés CoNp2F10 · 8H2O ET CuNp2F10 · 6H2O Cousson, Alain; Abazli, Hicham; Jové, José Journal of the Less Common Metals, Vol. 109, Issue 1 https://doi.org/10.1016/0022-5088(85)90115-8	journal	July 1985
Simple correction for the sample shape and radial offset effects on SQUID magnetometers: Magnetic measurements on Ln2O3 (Ln=Gd, Dy, Er) standards Morrison, Gregory; zur Loye, Hans-Conrad Journal of Solid State Chemistry, Vol. 221 https://doi.org/10.1016/j.jssc.2014.10.026	journal	January 2015
Crystal Growth of Four Oxovanadium(IV) Tartrates Prepared via a Mild Two-Step Hydrothermal Method: Observation of Spin-Dimer Behavior and Second Harmonic Generation Cortese, Anthony J.; Wilkins, Branford; Smith, Mark D. Inorganic Chemistry, Vol. 54, Issue 8 https://doi.org/10.1021/acs.inorgchem.5b00275	journal	March 2015
Observation of Multiple Crystal-to-Crystal Transitions in a New Reduced Vanadium Oxalate Hybrid Material, Ba ₃ [(VO) ₂ (C ₂ O ₄ ) ₅ (H ₂ O) ₆ ]·(H ₂ O) ₃ , Prepared via a Mild, Two-Step Hydrothermal Method Abeysinghe, Dileka; Smith, Mark D.; Yeon, Jeongho Crystal Growth & Design, Vol. 14, Issue 9 https://doi.org/10.1021/cg500888u	journal	August 2014
Fluorure d'ammonium et d'uranium(IV): NH ₄ U ₃ F ₁₃ Abazli, H.; Cousson, A.; Tabuteau, A. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 36, Issue 11 https://doi.org/10.1107/S0567740880009946	journal	November 1980
Ferrimagnetic Fluorides Tressaud, Alain; Dance, Jean Michel Advances in Inorganic Chemistry and Radiochemistry https://doi.org/10.1016/S0065-2792(08)60039-4	book	January 1977
Hydrothermal Syntheses, Structures, and Magnetic Properties of the U(IV) Fluorides (C5H14N2)2U2F12·5H2O and (NH4)7U6F31 Almond, Philip M.; Deakin, Laura; Mar, Arthur Journal of Solid State Chemistry, Vol. 158, Issue 1 https://doi.org/10.1006/jssc.2001.9100	journal	April 2001
The First Organically Templated Tetravalent Uranium Phosphates with Dimer-Structured Topologies Lai, Yu-Lun; Chiang, Ray-Kuang; Lii, Kwang-Hwa Chemistry of Materials, Vol. 20, Issue 2 https://doi.org/10.1021/cm7027959	journal	January 2008
UF ₃ (H ₂ O)(C ₂ O ₄ ) _0.5 : A Fluorooxalate of Tetravalent Uranium with a Three-Dimensional Framework Structure Wang, Chih-Min; Liao, Chia-Hsien; Chen, Pei-Lin Inorganic Chemistry, Vol. 45, Issue 4 https://doi.org/10.1021/ic051960v	journal	February 2006