skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Construction of Au–Pd alloy shells for enhanced catalytic performance toward alkyne semihydrogenation reactions

Abstract

Au–Pd alloy surfaces have been fabricated on preformed Pd nanocrystals for highly active and selective alkyne semihydrogenation reactions.

Authors:
 [1];  [1]; ORCiD logo [1];  [1]; ORCiD logo [1];  [1]; ORCiD logo [2]
  1. Frontier Institute of Science and Technology and School of Chemical Engineering and Technology; State Key Laboratory of Multiphase Flow in Power Engineering; Xi'an Jiaotong University; Xi'an; China
  2. Department of Chemistry; and UCR Center for Catalysis; University of California; Riverside; USA
Publication Date:
Research Org.:
Univ. of California, Riverside, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1535142
DOE Contract Number:  
SC0002247
Resource Type:
Journal Article
Journal Name:
Materials Horizons
Additional Journal Information:
Journal Volume: 4; Journal Issue: 4; Journal ID: ISSN 2051-6347
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
Chemistry; Materials Science

Citation Formats

Li, Xiang, Wang, Zhenni, Zhang, Zhaorui, Yang, Guang, Jin, Mingshang, Chen, Qiang, and Yin, Yadong. Construction of Au–Pd alloy shells for enhanced catalytic performance toward alkyne semihydrogenation reactions. United States: N. p., 2017. Web. doi:10.1039/c6mh00478d.
Li, Xiang, Wang, Zhenni, Zhang, Zhaorui, Yang, Guang, Jin, Mingshang, Chen, Qiang, & Yin, Yadong. Construction of Au–Pd alloy shells for enhanced catalytic performance toward alkyne semihydrogenation reactions. United States. doi:10.1039/c6mh00478d.
Li, Xiang, Wang, Zhenni, Zhang, Zhaorui, Yang, Guang, Jin, Mingshang, Chen, Qiang, and Yin, Yadong. Sun . "Construction of Au–Pd alloy shells for enhanced catalytic performance toward alkyne semihydrogenation reactions". United States. doi:10.1039/c6mh00478d.
@article{osti_1535142,
title = {Construction of Au–Pd alloy shells for enhanced catalytic performance toward alkyne semihydrogenation reactions},
author = {Li, Xiang and Wang, Zhenni and Zhang, Zhaorui and Yang, Guang and Jin, Mingshang and Chen, Qiang and Yin, Yadong},
abstractNote = {Au–Pd alloy surfaces have been fabricated on preformed Pd nanocrystals for highly active and selective alkyne semihydrogenation reactions.},
doi = {10.1039/c6mh00478d},
journal = {Materials Horizons},
issn = {2051-6347},
number = 4,
volume = 4,
place = {United States},
year = {2017},
month = {1}
}

Works referenced in this record:

High-performance transition metal-doped Pt3Ni octahedra for oxygen reduction reaction
journal, June 2015


Shaping binary metal nanocrystals through epitaxial seeded growth
journal, July 2007

  • Habas, Susan E.; Lee, Hyunjoo; Radmilovic, Velimir
  • Nature Materials, Vol. 6, Issue 9
  • DOI: 10.1038/nmat1957

Biphasic Pd−Au Alloy Catalyst for Low-Temperature CO Oxidation
journal, August 2010

  • Xu, Jing; White, Tim; Li, Ping
  • Journal of the American Chemical Society, Vol. 132, Issue 30
  • DOI: 10.1021/ja102617r

Cu 2+ -Assisted Synthesis of Hexoctahedral Au–Pd Alloy Nanocrystals with High-Index Facets
journal, November 2011

  • Zhang, Lei; Zhang, Jiawei; Kuang, Qin
  • Journal of the American Chemical Society, Vol. 133, Issue 43
  • DOI: 10.1021/ja2063617

Composition-Dependent Catalytic Activity of Bimetallic Nanocrystals: AgPd-Catalyzed Hydrodechlorination of 4-Chlorophenol
journal, June 2013

  • Rong, Hongpan; Cai, Shuangfei; Niu, Zhiqiang
  • ACS Catalysis, Vol. 3, Issue 7
  • DOI: 10.1021/cs400282a

Atomic Ensemble and Electronic Effects in Ag-Rich AgPd Nanoalloy Catalysts for Oxygen Reduction in Alkaline Media
journal, May 2012

  • Slanac, Daniel A.; Hardin, William G.; Johnston, Keith P.
  • Journal of the American Chemical Society, Vol. 134, Issue 23
  • DOI: 10.1021/ja303580b

Synthesis and Characterization of Pt–Ag Alloy Nanocages with Enhanced Activity and Durability toward Oxygen Reduction
journal, September 2016


Aerobic Oxidation of Cyclohexane on Catalysts Based on Twinned and Single-Crystal Au 75 Pd 25 Bimetallic Nanocrystals
journal, April 2015

  • Wang, Liangbing; Zhao, Songtao; Liu, Chenxuan
  • Nano Letters, Vol. 15, Issue 5
  • DOI: 10.1021/nl5045132

New Approach to Fully Ordered fct-FePt Nanoparticles for Much Enhanced Electrocatalysis in Acid
journal, March 2015


Asymmetric Synthesis of Chiral Bimetallic [Ag 28 Cu 12 (SR) 24 ] 4– Nanoclusters via Ion Pairing
journal, September 2016

  • Yan, Juanzhu; Su, Haifeng; Yang, Huayan
  • Journal of the American Chemical Society, Vol. 138, Issue 39
  • DOI: 10.1021/jacs.6b08100

Unique Excavated Rhombic Dodecahedral PtCu 3 Alloy Nanocrystals Constructed with Ultrathin Nanosheets of High-Energy {110} Facets
journal, February 2014

  • Jia, Yanyan; Jiang, Yaqi; Zhang, Jiawei
  • Journal of the American Chemical Society, Vol. 136, Issue 10
  • DOI: 10.1021/ja413209q

Surface Polarization Matters: Enhancing the Hydrogen-Evolution Reaction by Shrinking Pt Shells in Pt-Pd-Graphene Stack Structures
journal, August 2014

  • Bai, Song; Wang, Chengming; Deng, Mingsen
  • Angewandte Chemie International Edition, Vol. 53, Issue 45
  • DOI: 10.1002/anie.201406468

Ag–Pt Compositional Intermetallics Made from Alloy Nanoparticles
journal, September 2016


Bimetallic Nanocrystals: Syntheses, Properties, and Applications
journal, July 2016


Screw Thread-Like Platinum–Copper Nanowires Bounded with High-Index Facets for Efficient Electrocatalysis
journal, July 2016


Synthesis of CuPt Nanorod Catalysts with Tunable Lengths
journal, April 2009

  • Liu, Qingsheng; Yan, Zhen; Henderson, Nathaniel L.
  • Journal of the American Chemical Society, Vol. 131, Issue 16
  • DOI: 10.1021/ja810151r

Solution-Based Evolution and Enhanced Methanol Oxidation Activity of Monodisperse Platinum-Copper Nanocubes
journal, May 2009

  • Xu, Dan; Liu, Zhaoping; Yang, Hongzhou
  • Angewandte Chemie International Edition, Vol. 48, Issue 23
  • DOI: 10.1002/anie.200900293

Shape-Selective Synthesis and Facet-Dependent Enhanced Electrocatalytic Activity and Durability of Monodisperse Sub-10 nm Pt−Pd Tetrahedrons and Cubes
journal, March 2011

  • Yin, An-Xiang; Min, Xiao-Quan; Zhang, Ya-Wen
  • Journal of the American Chemical Society, Vol. 133, Issue 11
  • DOI: 10.1021/ja200329p

Twin-Induced Growth of Palladium-Platinum Alloy Nanocrystals
journal, July 2009

  • Lim, Byungkwon; Wang, Jinguo; Camargo, Pedro H. C.
  • Angewandte Chemie International Edition, Vol. 48, Issue 34
  • DOI: 10.1002/anie.200902235

Designed Synthesis of Atom-Economical Pd/Ni Bimetallic Nanoparticle-Based Catalysts for Sonogashira Coupling Reactions
journal, April 2004

  • Son, Seung Uk; Jang, Youngjin; Park, Jongnam
  • Journal of the American Chemical Society, Vol. 126, Issue 16
  • DOI: 10.1021/ja039757r

Formation of FePt Nanoparticles Having High Coercivity
journal, November 2006

  • Rutledge, Ryan D.; Morris, William H.; Wellons, Matthew S.
  • Journal of the American Chemical Society, Vol. 128, Issue 44
  • DOI: 10.1021/ja0633868

Recent Advances in Chemical Synthesis, Self-Assembly, and Applications of FePt Nanoparticles
journal, February 2006


Synthesis of FePt Nanocubes and Their Oriented Self-Assembly
journal, June 2006

  • Chen, Min; Kim, Jaemin; Liu, J. P.
  • Journal of the American Chemical Society, Vol. 128, Issue 22
  • DOI: 10.1021/ja061704x

Formation of Hollow Ni 2 P Nanoparticles Based on the Nanoscale Kirkendall Effect
journal, January 2007

  • Chiang, Ray-Kuang; Chiang, Ray-Tung
  • Inorganic Chemistry, Vol. 46, Issue 2
  • DOI: 10.1021/ic061846s

Hollow Nanocrystals through the Nanoscale Kirkendall Effect
journal, December 2012

  • Wang, Wenshou; Dahl, Michael; Yin, Yadong
  • Chemistry of Materials, Vol. 25, Issue 8
  • DOI: 10.1021/cm3030928

Thermodynamic controlled synthesis of intermetallic Au 3 Cu alloy nanocrystals from Cu microparticles
journal, January 2014

  • Zhao, Wengao; Yang, Lini; Yin, Yadong
  • J. Mater. Chem. A, Vol. 2, Issue 4
  • DOI: 10.1039/C3TA13921B

Controlled Synthesis of Pd–Pt Alloy Hollow Nanostructures with Enhanced Catalytic Activities for Oxygen Reduction
journal, February 2012

  • Hong, Jong Wook; Kang, Shin Wook; Choi, Bu-Seo
  • ACS Nano, Vol. 6, Issue 3
  • DOI: 10.1021/nn2046828

Anisotropic phase segregation and migration of Pt in nanocrystals en route to nanoframe catalysts
journal, August 2016

  • Niu, Zhiqiang; Becknell, Nigel; Yu, Yi
  • Nature Materials, Vol. 15, Issue 11
  • DOI: 10.1038/nmat4724

Highly Crystalline Multimetallic Nanoframes with Three-Dimensional Electrocatalytic Surfaces
journal, February 2014


Synthesis of Pd−Pt Bimetallic Nanocrystals with a Concave Structure through a Bromide-Induced Galvanic Replacement Reaction
journal, April 2011

  • Zhang, Hui; Jin, Mingshang; Wang, Jinguo
  • Journal of the American Chemical Society, Vol. 133, Issue 15
  • DOI: 10.1021/ja201156s

Gold Nanocages for Biomedical Applications
journal, October 2007


Facile Synthesis of Gold−Silver Nanocages with Controllable Pores on the Surface
journal, November 2006

  • Chen, Jingyi; McLellan, Joseph M.; Siekkinen, Andrew
  • Journal of the American Chemical Society, Vol. 128, Issue 46
  • DOI: 10.1021/ja066023g

Interfacial electronic effects control the reaction selectivity of platinum catalysts
journal, January 2016

  • Chen, Guangxu; Xu, Chaofa; Huang, Xiaoqing
  • Nature Materials, Vol. 15, Issue 5
  • DOI: 10.1038/nmat4555

Platinum-based nanocages with subnanometer-thick walls and well-defined, controllable facets
journal, July 2015


Ultrathin Icosahedral Pt-Enriched Nanocage with Excellent Oxygen Reduction Reaction Activity
journal, January 2016

  • He, Dong Sheng; He, Daping; Wang, Jing
  • Journal of the American Chemical Society, Vol. 138, Issue 5
  • DOI: 10.1021/jacs.5b12530

Pd@Pt Core–Shell Concave Decahedra: A Class of Catalysts for the Oxygen Reduction Reaction with Enhanced Activity and Durability
journal, November 2015

  • Wang, Xue; Vara, Madeline; Luo, Ming
  • Journal of the American Chemical Society, Vol. 137, Issue 47
  • DOI: 10.1021/jacs.5b10059

Palladium–platinum core-shell icosahedra with substantially enhanced activity and durability towards oxygen reduction
journal, July 2015

  • Wang, Xue; Choi, Sang-Il; Roling, Luke T.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8594

On the role of surface diffusion in determining the shape or morphology of noble-metal nanocrystals
journal, April 2013

  • Xia, X.; Xie, S.; Liu, M.
  • Proceedings of the National Academy of Sciences, Vol. 110, Issue 17
  • DOI: 10.1073/pnas.1222109110

Atomic Layer-by-Layer Deposition of Platinum on Palladium Octahedra for Enhanced Catalysts toward the Oxygen Reduction Reaction
journal, February 2015

  • Park, Jinho; Zhang, Lei; Choi, Sang-Il
  • ACS Nano, Vol. 9, Issue 3
  • DOI: 10.1021/nn506387w

Ru–Pt core–shell nanoparticles for preferential oxidation of carbon monoxide in hydrogen
journal, March 2008

  • Alayoglu, Selim; Nilekar, Anand U.; Mavrikakis, Manos
  • Nature Materials, Vol. 7, Issue 4, p. 333-338
  • DOI: 10.1038/nmat2156

Coherency Strain Effects on the Optical Response of Core/Shell Heteronanostructures
journal, June 2003

  • Chen, Xiaobo; Lou, Yongbing; Samia, Anna C.
  • Nano Letters, Vol. 3, Issue 6
  • DOI: 10.1021/nl034243b

Synthesis of Pd nanocrystals enclosed by {100} facets and with sizes <10 nm for application in CO oxidation
journal, October 2010


Formation and characterization of Au/Pd surface alloys on Pd(111)
journal, April 2007


Vegard’s law
journal, March 1991


Epitaxial Growth of Twinned Au–Pt Core–Shell Star-Shaped Decahedra as Highly Durable Electrocatalysts
journal, November 2015


Quantitative Analysis of the Coverage Density of Br Ions on Pd{100} Facets and Its Role in Controlling the Shape of Pd Nanocrystals
journal, March 2013

  • Peng, Hsin-Chieh; Xie, Shuifen; Park, Jinho
  • Journal of the American Chemical Society, Vol. 135, Issue 10
  • DOI: 10.1021/ja400301k

UV–Ozone Cleaning of Supported Poly(vinylpyrrolidone)-Stabilized Palladium Nanocubes: Effect of Stabilizer Removal on Morphology and Catalytic Behavior
journal, June 2011

  • Crespo-Quesada, Micaela; Andanson, Jean-Michel; Yarulin, Artur
  • Langmuir, Vol. 27, Issue 12
  • DOI: 10.1021/la201007m

Evaluating the ozone cleaning treatment in shape-controlled Pt nanoparticles: Evidences of atomic surface disordering
journal, May 2011


The Role of Organic Capping Layers of Platinum Nanoparticles in Catalytic Activity of CO Oxidation
journal, February 2009


Chemicals from Alkynes with Palladium Catalysts
journal, June 2013

  • Chinchilla, Rafael; Nájera, Carmen
  • Chemical Reviews, Vol. 114, Issue 3
  • DOI: 10.1021/cr400133p

The Roles of Subsurface Carbon and Hydrogen in Palladium-Catalyzed Alkyne Hydrogenation
journal, April 2008


Understanding Palladium Hydrogenation Catalysts: When the Nature of the Reactive Molecule Controls the Nature of the Catalyst Active Phase
journal, August 2008

  • Teschner, Detre; Révay, Zsolt; Borsodi, János
  • Angewandte Chemie International Edition, Vol. 47, Issue 48
  • DOI: 10.1002/anie.200802134

Isolated Metal Atom Geometries as a Strategy for Selective Heterogeneous Hydrogenations
journal, March 2012

  • Kyriakou, Georgios; Boucher, Matthew B.; Jewell, April D.
  • Science, Vol. 335, Issue 6073
  • DOI: 10.1126/science.1215864

A Palladium Nanoparticle-Nanomicelle Combination for the Stereoselective Semihydrogenation of Alkynes in Water at Room Temperature
journal, October 2014

  • Slack, Eric D.; Gabriel, Christopher M.; Lipshutz, Bruce H.
  • Angewandte Chemie International Edition, Vol. 53, Issue 51
  • DOI: 10.1002/anie.201407723

New environmentally friendly catalysts containing Pd–interstitial carbon made from Pd–glucose precursors for ultraselective hydrogenations in the liquid phase
journal, January 2011

  • Chan, Chun Wong Aaron; Xie, Yaling; Cailuo, Nick
  • Chemical Communications, Vol. 47, Issue 28
  • DOI: 10.1039/c1cc12681d

Highly Efficient Pd/SiO 2 –Dimethyl Sulfoxide Catalyst System for Selective Semihydrogenation of Alkynes
journal, April 2011

  • Takahashi, Yusuke; Hashimoto, Norifumi; Hara, Takayoshi
  • Chemistry Letters, Vol. 40, Issue 4
  • DOI: 10.1246/cl.2011.405

A Pd–Cu 2 O nanocomposite as an effective synergistic catalyst for selective semi-hydrogenation of the terminal alkynes only
journal, January 2016

  • Yang, Shuliang; Cao, Changyan; Peng, Li
  • Chemical Communications, Vol. 52, Issue 18
  • DOI: 10.1039/C6CC00143B

cis-Semihydrogenation of alkynes with amine borane complexes catalyzed by gold nanoparticles under mild conditions
journal, January 2015

  • Vasilikogiannaki, Eleni; Titilas, Ioannis; Vassilikogiannakis, Georgios
  • Chemical Communications, Vol. 51, Issue 12
  • DOI: 10.1039/C4CC08163C

Green semi-hydrogenation of alkynes by Pd@borate monolith catalysts under continuous flow
journal, March 2014


Palladium nanoparticles supported on mpg-C3N4 as active catalyst for semihydrogenation of phenylacetylene under mild conditions
journal, January 2013

  • Deng, Dongshun; Yang, Yang; Gong, Yutong
  • Green Chemistry, Vol. 15, Issue 9
  • DOI: 10.1039/c3gc40779a

Metal-Ligand Core-Shell Nanocomposite Catalysts for the Selective Semihydrogenation of Alkynes
journal, December 2012

  • Mitsudome, Takato; Takahashi, Yusuke; Ichikawa, Satoshi
  • Angewandte Chemie International Edition, Vol. 52, Issue 5
  • DOI: 10.1002/anie.201207845

Pd-Pb Alloy Nanocrystals with Tailored Composition for Semihydrogenation: Taking Advantage of Catalyst Poisoning
journal, May 2015


A density functional theory study of the ‘mythic’ Lindlar hydrogenation catalyst
journal, September 2010

  • García-Mota, M.; Gómez-Díaz, J.; Novell-Leruth, G.
  • Theoretical Chemistry Accounts, Vol. 128, Issue 4-6
  • DOI: 10.1007/s00214-010-0800-0

Poisoning and deactivation of palladium catalysts
journal, September 2001

  • Albers, Peter; Pietsch, Jörg; Parker, Stewart F.
  • Journal of Molecular Catalysis A: Chemical, Vol. 173, Issue 1-2
  • DOI: 10.1016/S1381-1169(01)00154-6

Pd−Ga Intermetallic Compounds as Highly Selective Semihydrogenation Catalysts
journal, October 2010

  • Armbrüster, Marc; Kovnir, Kirill; Behrens, Malte
  • Journal of the American Chemical Society, Vol. 132, Issue 42
  • DOI: 10.1021/ja106568t

The Influence of Catalyst Restructuring on the Selective Hydrogenation of Acetylene to Ethylene
journal, October 2001

  • Jin, Yaming; Datye, Abhaya K.; Rightor, Ed
  • Journal of Catalysis, Vol. 203, Issue 2
  • DOI: 10.1006/jcat.2001.3347

Acetylene hydrogenation selectivity control on PdCu/Al2O3 catalysts
journal, July 1984


Promoters in the hydrogenation of alkynes in mixtures: insights from density functional theory
journal, January 2012

  • López, Núria; Vargas-Fuentes, Crisa
  • Chem. Commun., Vol. 48, Issue 10
  • DOI: 10.1039/C1CC14922A

A Convenient Synthesis of Ethynylarenes and Diethynylarenes
journal, January 1980

  • Takahashi, S.; Kuroyama, Y.; Sonogashira, K.
  • Synthesis, Vol. 1980, Issue 08
  • DOI: 10.1055/s-1980-29145