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Title: Metal–organic frameworks: functional luminescent and photonic materials for sensing applications

Journal Article · · Chemical Society Reviews
DOI:https://doi.org/10.1039/c6cs00930a· OSTI ID:1535129

This review summarizes the diverse routes to derive sensing applications from suitably functionalized and crystal-engineered metal–organic framework (MOF) materials, either by fluorometric responses, or based on photonic crystal-based signal transduction.

Research Organization:
Univ. of Texas at Dallas, Richardson, TX (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
FG02-08ER46491
OSTI ID:
1535129
Journal Information:
Chemical Society Reviews, Vol. 46, Issue 11; ISSN 0306-0012
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (312)

Coordination polymers, metal–organic frameworks and the need for terminology guidelines journal January 2012
Postsynthetic lanthanide functionalization of nanosized metal–organic frameworks for highly sensitive ratiometric luminescent thermometry journal January 2014
Recent Advances in Supramolecular Analytical Chemistry Using Optical Sensing journal February 2015
Fluorescence Sensing book January 2006
Generalized Förster-Dexter theory of photoinduced intramolecular energy transfer journal May 1993
Chemical Sensors Based on Amplifying Fluorescent Conjugated Polymers journal April 2007
Current developments in fluorescent PET (photoinduced electron transfer) sensors and switches journal January 2015
A dual-emitting 4d–4f nanocrystalline metal–organic framework as a self-calibrating luminescent sensor for indoor formaldehyde pollution journal January 2016
Energy transfer in solution of lanthanide complexes journal July 2002
Potential of microporous metal–organic frameworks for separation of hydrocarbon mixtures journal January 2016
Microporous metal–organic frameworks for storage and separation of small hydrocarbons journal January 2012
Applications of metal–organic frameworks in heterogeneous supramolecular catalysis journal January 2014
Metal organic frameworks for electrochemical applications journal January 2012
Luminescent metal–organic frameworks for chemical sensing and explosive detection journal January 2014
Photoluminescent Metal-Organic Frameworks for Gas Sensing journal March 2016
Facile fabrication of magnetic metal–organic framework nanocomposites for potential targeted drug delivery journal January 2011
Magnetic nanoscale metal organic frameworks for potential targeted anticancer drug delivery, imaging and as an MRI contrast agent journal January 2016
A polyrotaxane-like metal–organic framework exhibiting luminescent sensing of Eu 3+ cations and proton conductivity journal January 2014
Engineering metal-based luminescence in coordination polymers and metal–organic frameworks journal January 2013
MOF-based electronic and opto-electronic devices journal January 2014
Luminescent Chemodosimeters for Bioimaging journal June 2012
Hybrid nanomaterials for biomedical applications journal January 2010
Metal–organic frameworks for luminescence thermometry journal January 2015
Effective sensing of RDX via instant and selective detection of ketone vapors journal January 2014
Highly Stable Zr(IV)-Based Metal–Organic Frameworks for the Detection and Removal of Antibiotics and Organic Explosives in Water journal May 2016
Encapsulating Pyrene in a Metal–Organic Zeolite for Optical Sensing of Molecular Oxygen journal December 2015
Encapsulation of Ln III Ions/Dyes within a Microporous Anionic MOF by Post-synthetic Ionic Exchange Serving as a Ln III Ion Probe and Two-Color Luminescent Sensors journal May 2015
Host–guest interaction dictated selective adsorption and fluorescence quenching of a luminescent lightweight metal–organic framework toward liquid explosives journal January 2014
Pentiptycene-Based Luminescent Cu (II) MOF Exhibiting Selective Gas Adsorption and Unprecedentedly High-Sensitivity Detection of Nitroaromatic Compounds (NACs) journal February 2016
Discriminative detection of nitro aromatic explosives by a luminescent metal–organic framework journal January 2014
Stable Luminescent Metal–Organic Frameworks as Dual-Functional Materials To Encapsulate Ln 3+ Ions for White-Light Emission and To Detect Nitroaromatic Explosives journal March 2015
The vapour phase detection of explosive markers and derivatives using two fluorescent metal–organic frameworks journal January 2015
Visible detection of explosive nitroaromatics facilitated by a large stokes shift of luminescence using europium and terbium doped yttrium based MOFs journal January 2015
Three novel metal–organic frameworks based on an unsymmetrical rigid carboxylate ligand for luminescence sensing of nitrobenzene derivatives and magnetic properties journal January 2016
A Highly Symmetric Metal–Organic Framework Based on a Propeller-Like Ru-Organic Metalloligand for Photocatalysis and Explosives Detection journal November 2013
Aqueous- and vapor-phase detection of nitroaromatic explosives by a water-stable fluorescent microporous MOF directed by an ionic liquid journal January 2015
A highly stable dynamic fluorescent metal–organic framework for selective sensing of nitroaromatic explosives journal January 2013
Solvent-Induced Topological Diversity of Two Zn(II) Metal–Organic Frameworks and High Sensitivity in Recyclable Detection of Nitrobenzene journal June 2015
Assembly of Zn-metal organic frameworks based on a N-rich ligand: selective sorption for CO 2 and luminescence sensing of nitro explosives journal January 2015
A luminescent metal–organic framework for highly selective sensing of nitrobenzene and aniline journal January 2016
A luminescent Zr-based metal–organic framework for sensing/capture of nitrobenzene and high-pressure separation of CH 4 /C 2 H 6 journal January 2015
An unusual (4,4)-connected 3D porous cadmium metal–organic framework as a luminescent sensor for detection of nitrobenzene journal January 2016
2D Cd(II)–Lanthanide(III) Heterometallic–Organic Frameworks Based on Metalloligands for Tunable Luminescence and Highly Selective, Sensitive, and Recyclable Detection of Nitrobenzene journal July 2014
A luminescent europium MOF containing Lewis basic pyridyl site for highly selective sensing of o-, m- and p-nitrophenol journal January 2015
Modification of Extended Open Frameworks with Fluorescent Tags for Sensing Explosives: Competition between Size Selectivity and Electron Deficiency journal January 2014
A fluorescent metal–organic framework for highly selective detection of nitro explosives in the aqueous phase journal January 2014
Picogram sensing of trinitrophenol in aqueous medium through a water stable nanoscale coordination polymer journal January 2016
A Zn-MOF constructed from electron-rich π-conjugated ligands with an interpenetrated graphene-like net as an efficient nitroaromatic sensor journal January 2016
Exploitation of Guest Accessible Aliphatic Amine Functionality of a Metal–Organic Framework for Selective Detection of 2,4,6-Trinitrophenol (TNP) in Water journal August 2015
A thiadiazole-functionalized Zr( iv )-based metal–organic framework as a highly fluorescent probe for the selective detection of picric acid journal January 2016
3D Luminescent Amide-Functionalized Cadmium Tetrazolate Framework for Selective Detection of 2,4,6-Trinitrophenol journal January 2016
A Luminescent Microporous Metal–Organic Framework with Highly Selective CO 2 Adsorption and Sensing of Nitro Explosives journal August 2014
A Temperature-Responsive Smart Europium Metal-Organic Framework Switch for Reversible Capture and Release of Intrinsic Eu 3+ Ions journal March 2015
Tuning the Luminescence of Metal–Organic Frameworks for Detection of Energetic Heterocyclic Compounds journal October 2014
Selective Sensing of Fe 3+ and Al 3+ Ions and Detection of 2,4,6-Trinitrophenol by a Water-Stable Terbium-Based Metal-Organic Framework journal September 2015
Lanthanide–Potassium Biphenyl-3,3′-disulfonyl-4,4′-dicarboxylate Frameworks: Gas Sorption, Proton Conductivity, and Luminescent Sensing of Metal Ions journal June 2016
Highly Selective and Sensitive Luminescence Turn-On-Based Sensing of Al 3+ Ions in Aqueous Medium Using a MOF with Free Functional Sites journal June 2015
Heterometallic Alkaline Earth–Lanthanide Ba II –La III Microporous Metal–Organic Framework as Bifunctional Luminescent Probes of Al 3+ and MnO 4 journal April 2016
Metal–organic framework nanosheets for fast-response and highly sensitive luminescent sensing of Fe 3+ journal January 2016
Three new luminescent Cd( ii )-MOFs by regulating the tetracarboxylate and auxiliary co-ligands, displaying high sensitivity for Fe 3+ in aqueous solution journal January 2015
Turn-on and Ratiometric Luminescent Sensing of Hydrogen Sulfide Based on Metal–Organic Frameworks journal November 2016
A Highly Sensitive Luminescent Dye@MOF Composite for Probing Different Volatile Organic Compounds journal March 2016
A Metal-Organic Framework Containing Unusual Eight-Connected Zr-Oxo Secondary Building Units and Orthogonal Carboxylic Acids for Ultra-sensitive Metal Detection journal October 2014
Ligand Induced Anionic Cuprous Cyanide Framework for Cupric Ion Turn on Luminescence Sensing and Photocatalytic Degradation of Organic Dyes journal December 2015
Porphyrinic Metal–Organic Framework Catalyzed Heck-Reaction: Fluorescence “Turn-On” Sensing of Cu(II) Ion journal September 2016
A ratiometric and colorimetric luminescent thermometer over a wide temperature range based on a lanthanide coordination polymer journal January 2014
Luminescent MOF material based on cadmium( ii ) and mixed ligands: application for sensing volatile organic solvent molecules journal January 2015
Ag + -sensitized lanthanide luminescence in Ln 3+ post-functionalized metal–organic frameworks and Ag + sensing journal January 2015
A robust microporous metal–organic framework as a highly selective and sensitive, instantaneous and colorimetric sensor for Eu 3+ ions journal January 2015
A Series of Multifunctional Metal-Organic Frameworks Showing Excellent Luminescent Sensing, Sensitization, and Adsorbent Abilities journal July 2015
Highly Efficient Luminescent Metal–Organic Framework for the Simultaneous Detection and Removal of Heavy Metals from Water journal October 2016
Cadmium-Based Metal–Organic Framework as a Highly Selective and Sensitive Ratiometric Luminescent Sensor for Mercury(II) journal November 2015
A turn on fluorescent sensor based on lanthanide coordination polymer nanoparticles for the detection of mercury( ii ) in biological fluids journal January 2016
An electrodeposited lanthanide MOF thin film as a luminescent sensor for carbonate detection in aqueous solution journal January 2014
Dynamic Metal–Organic Framework with Anion-Triggered Luminescence Modulation Behavior journal November 2014
Selective Anion Exchange and Tunable Luminescent Behaviors of Metal–Organic Framework Based Supramolecular Isomers journal December 2014
Anion-Directed Assemblies of Cationic Metal–Organic Frameworks Based on 4,4′-Bis(1,2,4-triazole): Syntheses, Structures, Luminescent and Anion Exchange Properties journal October 2014
A Cationic Metal-Organic Framework Consisting of Nanoscale Cages: Capture, Separation, and Luminescent Probing of Cr 2 O 7 2− through a Single-Crystal to Single-Crystal Process journal October 2013
Unique Chiral Interpenetrating d–f Heterometallic MOFs as Luminescent Sensors journal May 2015
Heterometal–organic frameworks as highly sensitive and highly selective luminescent probes to detect I ions in aqueous solutions journal January 2015
Anhydrous Lanthanide MOFs and Direct Photoluminescent Sensing for Polyoxometalates in Aqueous Solution journal February 2014
High sensitive luminescence metal-organic framework sensor for hydrogen sulfide in aqueous solution: A trial of novel turn-on mechanism journal May 2017
Metal-organic framework based highly selective fluorescence turn-on probe for hydrogen sulphide journal November 2014
A Nitro-Functionalized Metal-Organic Framework as a Reaction-Based Fluorescence Turn-On Probe for Rapid and Selective H 2 S Detection journal June 2015
Cerium-based azide- and nitro-functionalized UiO-66 frameworks as turn-on fluorescent probes for the sensing of hydrogen sulphide journal January 2016
A Post-Synthetically Modified MOF for Selective and Sensitive Aqueous-Phase Detection of Highly Toxic Cyanide Ions journal December 2015
Metal–organic frameworks (MOFs) combined with ZnO quantum dots as a fluorescent sensing platform for phosphate journal July 2014
Solid state organic amine detection in a photochromic porous metal organic framework journal January 2015
Encapsulating Naphthalene in an Electron-Deficient MOF to Enhance Fluorescence for Organic Amines Sensing journal March 2016
Luminescent Coordination Polymer with Conjugated Lewis Acid Sites for the Detection of Organic Amines journal August 2015
Fluorescence Detection of Anilines and Photocatalytic Degradation of Rhodamine B by a Multifunctional Metal-Organic Framework: Fluorescence Detection of Anilines and Degradation of Rhodamine B journal November 2014
A ketone functionalized luminescent terbium metal–organic framework for sensing of small molecules journal January 2015
Sensitive chemosensing of nitro group containing organophosphate pesticides with MOF-5 journal September 2014
A luminescent nanocrystal metal organic framework for chemosensing of nitro group containing organophosphate pesticides journal January 2014
Lanthanide Ion Codoped Emitters for Tailoring Emission Trajectory and Temperature Sensing journal January 2015
Surface Modification and Functionalization of Nanoscale Metal-Organic Frameworks for Controlled Release and Luminescence Sensing journal August 2007
Highly sensitive detection of dipicolinic acid with a water-dispersible terbium-metal organic framework journal December 2016
Turn-On Luminescence Sensing and Real-Time Detection of Traces of Water in Organic Solvents by a Flexible Metal-Organic Framework journal December 2014
Highly Selective Chemical Sensing in a Luminescent Nanoporous Magnet journal August 2012
A Porous 4-Fold-Interpenetrated Chiral Framework Exhibiting Vapochromism, Single-Crystal-to-Single-Crystal Solvent Exchange, Gas Sorption, and a Poisoning Effect journal February 2013
Luminescent humidity sensors based on porous Ln3+-MOFs journal January 2012
Alkaline-earth phosphonate MOFs with reversible hydration-dependent fluorescence journal January 2016
A luminescent metal–organic framework for sensing methanol in ethanol solution journal January 2013
Tunable Two-color Luminescence and Host–guest Energy Transfer of Fluorescent Chromophores Encapsulated in Metal-Organic Frameworks journal March 2014
Postsynthetic Paddle-Wheel Cross-Linking and Functionalization of 1,3-Phenylenebis(azanetriyl)tetrabenzoate-Based MOFs journal March 2015
Metal–Organic Nanoporous Structures with Anisotropic Photoluminescence and Magnetic Properties and Their Use as Sensors journal January 2008
A pillar-layer MOF for detection of small molecule acetone and metal ions in dilute solution journal January 2015
Luminescent Open Metal Sites within a Metal–Organic Framework for Sensing Small Molecules journal July 2007
Insight into luminescence enhancement of coordinated water-containing lanthanide metal–organic frameworks by guest molecules journal January 2015
Real-Time Detection of Traces of Benzaldehyde in Benzyl Alcohol as a Solvent by a Flexible Lanthanide Microporous Metal-Organic Framework journal September 2015
A Bifunctional Metal-Organic Framework: Striking CO 2 -Selective Sorption Features along with Guest-Induced Tuning of Luminescence journal June 2016
Stable Multiresponsive Luminescent MOF for Colorimetric Detection of Small Molecules in Selective and Reversible Manner journal July 2015
Multifunctionality and Crystal Dynamics of a Highly Stable, Porous Metal−Organic Framework [Zn 4 O(NTB) 2 ] journal May 2005
Two-Dimensional Metal–Organic Framework with Wide Channels and Responsive Turn-On Fluorescence for the Chemical Sensing of Volatile Organic Compounds journal May 2014
Nanoscale UiO-MOF-based luminescent sensors for highly selective detection of cysteine and glutathione and their application in bioimaging journal January 2015
Vapochromic Luminescence of a Zirconium-Based Metal-Organic Framework for Sensing Applications: Vapochromic Luminescence of a Zirconium-Based Metal-Organic Framework for Sensing Applications journal June 2016
A Luminescent Dye@MOF Platform: Emission Fingerprint Relationships of Volatile Organic Molecules journal January 2014
A responsive MOF nanocomposite for decoding volatile organic compounds journal January 2016
A Luminescent Mixed-Lanthanide-Organic Framework Sensor for Decoding Different Volatile Organic Molecules journal June 2014
Mixed-Lanthanoid Metal–Organic Framework for Ratiometric Cryogenic Temperature Sensing journal November 2015
A lanthanide( iii ) metal–organic framework exhibiting ratiometric luminescent temperature sensing and tunable white light emission journal January 2016
Multimetal rare earth MOFs for lighting and thermometry: tailoring color and optimal temperature range through enhanced disulfobenzoic triplet phosphorescence journal January 2013
A Luminescent Metal-Organic Framework Thermometer with Intrinsic Dual Emission from Organic Lumophores journal February 2016
Cooperative Crystallization of Chiral Heterometallic Indium(III)–Potassium(I) Metal–Organic Frameworks as Photosensitizers in Luminescence Sensors and Dye-Sensitized Solar Cells journal January 2016
One-step growth of lanthanoid metal–organic framework (MOF) films under solvothermal conditions for temperature sensing journal January 2016
A near infrared luminescent metal–organic framework for temperature sensing in the physiological range journal January 2015
Dual-Emitting MOF⊃Dye Composite for Ratiometric Temperature Sensing journal January 2015
Design and Synthesis of an MOF Thermometer with High Sensitivity in the Physiological Temperature Range journal November 2015
Ratiometric Nanothermometer Based on an Emissive Ln 3+ -Organic Framework journal July 2013
An ideal detector composed of a 3D Gd-based coordination polymer for DNA and Hg 2+ ion journal January 2016
A Chiral Porous Metal–Organic Framework for Highly Sensitive and Enantioselective Fluorescence Sensing of Amino Alcohols journal May 2012
Remarkably selective and enantiodifferentiating sensing of histidine by a fluorescent homochiral Zn-MOF based on pyrene-tetralactic acid journal January 2016
A Mixed-Crystal Lanthanide Zeolite-like Metal–Organic Framework as a Fluorescent Indicator for Lysophosphatidic Acid, a Cancer Biomarker journal September 2015
Luminescent Metal–Organic Framework Films As Highly Sensitive and Fast-Response Oxygen Sensors journal April 2014
An amine-functionalized metal–organic framework as a sensing platform for DNA detection journal January 2014
Two luminescent metal–organic frameworks for the sensing of nitroaromatic explosives and DNA strands journal January 2014
Metal–organic framework (MOF): a novel sensing platform for biomolecules journal January 2013
Porous Cu(I) Triazolate Framework and Derived Hybrid Membrane with Exceptionally High Sensing Efficiency for Gaseous Oxygen journal July 2014
Nanoscale LnMOF-functionalized nonwoven fibers protected by a polydimethylsiloxane coating layer as a highly sensitive ratiometric oxygen sensor journal January 2016
Tandem MOF-Based Photonic Crystals for Enhanced Analyte-Specific Optical Detection journal March 2015
A malonitrile-functionalized metal-organic framework for hydrogen sulfide detection and selective amino acid molecular recognition journal March 2014
Tetrazine functionalized zirconium MOF as an optical sensor for oxidizing gases journal January 2015
Protonation effect on ligands in EuL: a luminescent switcher for fast naked-eye detection of HCl journal January 2015
A distinct reversible colorimetric and fluorescent low pH response on a water-stable zirconium–porphyrin metal–organic framework journal January 2014
A colloidal water-stable MOF as a broad-range fluorescent pH sensor via post-synthetic modification journal January 2014
An ultrastable porous metal–organic framework luminescent switch towards aromatic compounds journal January 2015
A Highly Chemically Stable Metal-Organic Framework as a Luminescent Probe for the Regenerable Ratiometric Sensing of pH journal August 2016
An efficient and sensitive fluorescent pH sensor based on amino functional metal–organic frameworks in aqueous environment journal January 2016
Photonic metal–organic framework composite spheres: a new kind of optical material with self-reporting molecular recognition journal January 2014
A ratiometric fluorescent pH sensor based on nanoscale metal–organic frameworks (MOFs) modified by europium( iii ) complexes journal January 2014
A multifunctional Eu MOF as a fluorescent pH sensor and exhibiting highly solvent-dependent adsorption and degradation of rhodamine B journal January 2015
Luminescent metal–organic frameworks journal January 2009
Luminescent Functional Metal–Organic Frameworks journal June 2011
Photoluminescent Metal−Organic Polymer Constructed from Trimetallic Clusters and Mixed Carboxylates journal February 2003
Photoinduced Charge-Transfer Processes on MOF-5 Nanoparticles: Elucidating Differences between Metal-Organic Frameworks and Semiconductor Metal Oxides journal August 2008
Principles of Fluorescence Spectroscopy book January 2006
Luminescent multifunctional lanthanides-based metal–organic frameworks journal January 2011
Luminescent metal–organic frameworks as explosive sensors journal January 2014
Sensing-functional luminescent metal–organic frameworks journal January 2016
Engineering the Optical Response of the Titanium-MIL-125 Metal–Organic Framework through Ligand Functionalization journal July 2013
MOF based luminescence tuning and chemical/physical sensing journal November 2015
From Antenna to Assay: Lessons Learned in Lanthanide Luminescence journal April 2009
Engineering metal–organic frameworks for aqueous phase 2,4,6-trinitrophenol (TNP) sensing journal January 2016
Pre-concentration and energy transfer enable the efficient luminescence sensing of transition metal ions by metal–organic frameworks journal January 2015
Parameterizing and grading hydrolytic stability in metal–organic frameworks journal January 2016
Chemical, thermal and mechanical stabilities of metal–organic frameworks journal February 2016
Structural stability of metal organic frameworks in aqueous media – Controlling factors and methods to improve hydrostability and hydrothermal cyclic stability journal January 2015
Water Stability and Adsorption in Metal–Organic Frameworks journal September 2014
Metal–Organic Framework Materials as Chemical Sensors journal September 2011
Chemical Sensors Based on Metal-Organic Frameworks journal June 2016
New Microporous Metal−Organic Framework Demonstrating Unique Selectivity for Detection of High Explosives and Aromatic Compounds journal March 2011
A luminescent nanoscale metal–organic framework for sensing of nitroaromatic explosives journal January 2011
A Luminescent Terbium MOF Containing Hydroxyl Groups Exhibits Selective Sensing of Nitroaromatic Compounds and Fe(III) Ions journal September 2016
Selective Turn-On Ammonia Sensing Enabled by High-Temperature Fluorescence in Metal–Organic Frameworks with Open Metal Sites journal August 2013
A blue luminescent MOF as a rapid turn-off/turn-on detector for H 2 O, O 2 and CH 2 Cl 2 , MeCN: 3∞[Ce(Im) 3 ImH]·ImH journal January 2015
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage journal January 2002
Metal−Organic Frameworks with Functional Pores for Recognition of Small Molecules journal August 2010
Pore Surface Engineering with Controlled Loadings of Functional Groups via Click Chemistry in Highly Stable Metal–Organic Frameworks journal August 2012
A π-electron deficient diaminotriazine functionalized MOF for selective sorption of benzene over cyclohexane journal January 2015
Stimulus-Responsive Metal-Organic Frameworks journal May 2014
Luminescent Metal-Organic Frameworks for Selectively Sensing Nitric Oxide in an Aqueous Solution and in Living Cells journal February 2012
Copper(i) coordination polymers of 2,2′-dipyridylamine derivatives: syntheses, structures, and luminescence journal January 2012
A novel ribbon-candy-like supramolecular architecture of cadmium(ii)–terephthalate polymer with giant rhombic channels: twofold interpenetration of the 3D 8210-a net journal December 2001
Understanding CO 2 Dynamics in Metal-Organic Frameworks with Open Metal Sites journal March 2013
Comprehensive study of carbon dioxide adsorption in the metal–organic frameworks M 2 (dobdc) (M = Mg, Mn, Fe, Co, Ni, Cu, Zn) journal January 2014
Harnessing Lewis acidic open metal sites of metal–organic frameworks: the foremost route to achieve highly selective benzene sorption over cyclohexane journal January 2016
A Systematic Study of Fluorescence-Based Detection of Nitroexplosives and Other Aromatics in the Vapor Phase by Microporous Metal-Organic Frameworks journal October 2013
Ionic metal-organic frameworks (iMOFs): Design principles and applications journal January 2016
Zinc-Adeninate Metal−Organic Framework for Aqueous Encapsulation and Sensitization of Near-infrared and Visible Emitting Lanthanide Cations journal February 2011
Dynamic Structural Behavior and Anion-Responsive Tunable Luminescence of a Flexible Cationic Metal-Organic Framework journal December 2012
Fabrication of metal nanoparticles in metal–organic frameworks journal January 2013
Inorganic nanoparticles in porous coordination polymers journal January 2016
Synthesis and applications of metal-organic framework–quantum dot (QD@MOF) composites journal January 2016
Metal–organic frameworks as hosts for nanoparticles journal January 2015
Water adsorption in MOFs: fundamentals and applications journal January 2014
Water-resistant porous coordination polymers for gas separation journal February 2017
Facile water-stability evaluation of metal–organic frameworks and the property of selective removal of dyes from aqueous solution journal January 2016
Stable porphyrin Zr and Hf metal–organic frameworks featuring 2.5 nm cages: high surface areas, SCSC transformations and catalyses journal January 2015
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
  • Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni
  • Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851 https://doi.org/10.1021/ja8057953
journal October 2008
Zr-based metal–organic frameworks: design, synthesis, structure, and applications journal January 2016
Conventional and Unconventional Metal–Organic Frameworks Based on Phosphonate Ligands: MOFs and UMOFs journal September 2011
Enhancing Water Stability of Metal–Organic Frameworks via Phosphonate Monoester Linkers journal August 2012
Phosphonate and sulfonate metal organic frameworks journal January 2009
New Porous Crystals of Extended Metal-Catecholates journal August 2012
Three-Dimensional Metal-Catecholate Frameworks and Their Ultrahigh Proton Conductivity journal December 2015
Pyrazolate-Based Porphyrinic Metal–Organic Framework with Extraordinary Base-Resistance journal January 2016
A Base-Resistant Metalloporphyrin Metal–Organic Framework for C–H Bond Halogenation journal December 2016
A Base-Resistant Zn II -Based Metal-Organic Framework: Synthesis, Structure, Postsynthetic Modification, and Gas Adsorption journal June 2016
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks journal June 2006
UiO-67-type Metal–Organic Frameworks with Enhanced Water Stability and Methane Adsorption Capacity journal February 2016
Metal−Organic Frameworks as Sensors: A ZIF-8 Based Fabry−Pérot Device as a Selective Sensor for Chemical Vapors and Gases journal June 2010
Facile Fabrication of Ultrathin Metal–Organic Framework-Coated Monolayer Colloidal Crystals for Highly Efficient Vapor Sensing journal November 2015
One-dimensional metal–organic framework photonic crystals used as platforms for vapor sorption journal January 2012
Facile fabrication of photonic MOF films through stepwise deposition on a colloid crystal substrate journal January 2011
Stacking the Nanochemistry Deck: Structural and Compositional Diversity in One-Dimensional Photonic Crystals journal April 2009
Selective and Sensitive Aqueous-Phase Detection of 2,4,6-Trinitrophenol (TNP) by an Amine-Functionalized Metal-Organic Framework journal November 2014
A Luminescent Microporous Metal-Organic Framework for the Fast and Reversible Detection of High Explosives journal January 2009
Site-selective cyclometalation of a metal–organic framework journal January 2013
Supramolecular Assembly of Calcium Metal−Organic Frameworks with Structural Transformations journal March 2011
Vapor phase detection of nitroaromatic and nitroaliphatic explosives by fluorescence active metal–organic frameworks journal January 2013
Selective, Sensitive, and Reversible Detection of Vapor-Phase High Explosives via Two-Dimensional Mapping: A New Strategy for MOF-Based Sensors journal August 2013
Porous material for absorption and luminescent detection of aromatic molecules in water journal January 2006
A robust near infrared luminescent ytterbium metal–organic framework for sensing of small molecules journal January 2011
In situ 2,5-pyrazinedicarboxylate and oxalate ligands synthesis leading to a microporous europium–organic framework capable of selective sensing of small molecules journal January 2010
Synthesis and Characterization of Three Ytterbium Coordination Polymers Featuring Various Cationic Species and a Luminescence Study of a Terbium Analogue With Open Channels journal March 2010
A Luminescent Metal-Organic Framework as a Turn-On Sensor for DMF Vapor journal November 2012
Lanthanide metal–organic frameworks containing a novel flexible ligand for luminescence sensing of small organic molecules and selective adsorption journal January 2015
What is Solvatochromism? journal December 2010
Colorimetric Sensor Arrays for Volatile Organic Compounds journal June 2006
Highly Sensitive Optical Detection of Humidity on Polymer/Metal Nanoparticle Hybrid Films journal March 2007
In situ growth of continuous thin metal–organic framework film for capacitive humidity sensing journal January 2011
Ultrasensitive Humidity Detection Using Metal–Organic Framework-Coated Microsensors journal August 2012
Two 3D Porous Lanthanide−Fumarate−Oxalate Frameworks Exhibiting Framework Dynamics and Luminescent Change upon Reversible De- and Rehydration journal February 2007
Cu( i )-MOF: naked-eye colorimetric sensor for humidity and formaldehyde in single-crystal-to-single-crystal fashion journal January 2014
Surface-modified CAU-10 MOF materials as humidity sensors: impedance spectroscopic study on water uptake journal January 2015
Insights on Capacitive Interdigitated Electrodes Coated with MOF Thin Films: Humidity and VOCs Sensing as a Case Study journal July 2015
A fiber optic sensor with a metal organic framework as a sensing material for trace levels of water in industrial gases journal July 2015
A novel humidity sensor based on NH2-MIL-125(Ti) metal organic framework with high responsiveness journal September 2013
Towards metal–organic framework based field effect chemical sensors: UiO-66-NH 2 for nerve agent detection journal January 2016
Human reactions to low concentrations of volatile organic compounds journal January 1986
Risk assessment of exposure to volatile organic compounds in different indoor environments journal January 2004
A Guest-Responsive Fluorescent 3D Microporous Metal−Organic Framework Derived from a Long-Lifetime Pyrene Core
  • Stylianou, Kyriakos C.; Heck, Romain; Chong, Samantha Y.
  • Journal of the American Chemical Society, Vol. 132, Issue 12, p. 4119-4130 https://doi.org/10.1021/ja906041f
journal March 2010
Highly Selective Sorption and Luminescent Sensing of Small Molecules Demonstrated in a Multifunctional Lanthanide Microporous Metal-Organic Framework Containing 1D Honeycomb-Type Channels journal January 2013
Luminescent Sensing and Catalytic Performances of a Multifunctional Lanthanide-Organic Framework Comprising a Triphenylamine Moiety journal May 2011
Lanthanide Metal-Organic Frameworks Showing Luminescence in the Visible and Near-Infrared Regions with Potential for Acetone Sensing journal November 2013
One-dimensional channel-structured Eu-MOF for sensing small organic molecules and Cu2+ ion journal January 2013
Dye Encapsulation Inside a New Mesoporous Metal-Organic Framework for Multifunctional Solvatochromic-Response Function journal September 2012
Molecular decoding using luminescence from an entangled porous framework journal January 2011
A luminescent metal–organic framework constructed using a tetraphenylethene-based ligand for sensing volatile organic compounds journal January 2015
Reversible Luminescence Vapochromism and Crystal-to-Amorphous-to-Crystal Transformations of Pseudopolymorphic Cu(I) Coordination Polymers journal October 2015
Vapochromic Luminescence and Flexibility Control of Porous Coordination Polymers by Substitution of Luminescent Multinuclear Cu(I) Cluster Nodes journal May 2015
Remarkable Vapochromic Behavior of Pure Organic Octahedron Embedded in Porous Frameworks journal May 2016
Chromophore-immobilized luminescent metal–organic frameworks as potential lighting phosphors and chemical sensors journal January 2016
Multifunctional amino-decorated metal–organic frameworks: nonlinear-optic, ferroelectric, fluorescence sensing and photocatalytic properties journal January 2012
Solvatochromic Behavior of Chiral Mesoporous Metal-Organic Frameworks and Their Applications for Sensing Small Molecules and Separating Cationic Dyes journal January 2013
A flexible metal azolate framework with drastic luminescence response toward solvent vapors and carbon dioxide journal January 2011
Two novel MOF-74 analogs exhibiting unique luminescent selectivity journal January 2013
Crystalline Structural Intermediates of a Breathing Metal-Organic Framework That Functions as a Luminescent Sensor and Gas Reservoir journal January 2013
A Multiresponsive Metal-Organic Framework: Direct Chemiluminescence, Photoluminescence, and Dual Tunable Sensing Applications journal December 2015
Zeolitic imidazolate framework-8 as a luminescent material for the sensing of metal ions and small molecules journal January 2011
Turn-On Fluorescence in Tetraphenylethylene-Based Metal–Organic Frameworks: An Alternative to Aggregation-Induced Emission journal December 2011
Highly Fluorescent Metal–Organic Framework for the Sensing of Volatile Organic Compounds journal May 2016
Highly selective acetone fluorescent sensors based on microporous Cd(ii) metal–organic frameworks journal January 2012
Two coordination polymers with enhanced ligand-centered luminescence and assembly imparted sensing ability for acetone journal January 2014
Copper(I) Metal–Organic Framework: Visual Sensor for Detecting Small Polar Aliphatic Volatile Organic Compounds journal December 2015
Adsorption and Separation of Reactive Aromatic Isomers and Generation and Stabilization of Their Radicals within Cadmium(II)−Triazole Metal−Organic Confined Space in a Single-Crystal-to-Single-Crystal Fashion journal May 2010
Solvatochromic Behavior of a Nanotubular Metal−Organic Framework for Sensing Small Molecules journal March 2011
Moisture-Stable Zn(II) Metal–Organic Framework as a Multifunctional Platform for Highly Efficient CO 2 Capture and Nitro Pollutant Vapor Detection journal July 2016
An Eu 3+ post-functionalized nanosized metal–organic framework for cation exchange-based Fe 3+ -sensing in an aqueous environment journal January 2014
Two Amino-Decorated Metal–Organic Frameworks for Highly Selective and Quantitatively Sensing of Hg II and Cr VI in Aqueous Solution journal July 2015
Optical properties of red, green and blue emitting rare earth benzenetricarboxylate compounds journal February 2010
Ligand-Directed Strategy for Zeolite-Type Metal–Organic Frameworks: Zinc(II) Imidazolates with Unusual Zeolitic Topologies journal February 2006
Mesoporous Metal–Organic Framework with Rare etb Topology for Hydrogen Storage and Dye Assembly journal September 2007
Bright blue emissions with temperature-dependent quantum yields from microporous metal–organic frameworks journal January 2012
Charge-transfer guest interactions in luminescent MOFs: implications for solid-state temperature and environmental sensing journal January 2012
A dual functional MOF as a luminescent sensor for quantitatively detecting the concentration of nitrobenzene and temperature journal January 2013
A Luminescent Mixed-Lanthanide Metal–Organic Framework Thermometer journal February 2012
A Highly Sensitive Mixed Lanthanide Metal–Organic Framework Self-Calibrated Luminescent Thermometer journal October 2013
Chameleon Luminophore for Sensing Temperatures: Control of Metal-to-Metal and Energy Back Transfer in Lanthanide Coordination Polymers journal May 2013
A Eu/Tb-codoped coordination polymer luminescent thermometer journal January 2014
A highly sensitive near-infrared luminescent metal–organic framework thermometer in the physiological range journal January 2016
Ratiometric Thermometer Based on a Lanthanoid Coordination Polymer: Ratiometric Thermometer Based on a Lanthanoid Coordination Polymer journal May 2016
Synthesis, Structure, White-Light Emission, and Temperature Recognition Properties of Eu/Tb Mixed Coordination Polymers journal November 2015
A luminescent nanoscale metal–organic framework with controllable morphologies for spore detection journal January 2012
Metal–organic frameworks-based biosensor for sequence-specific recognition of double-stranded DNA journal January 2013
Chemistry, Nutrition, and Microbiology of d -Amino Acids journal September 1999
Presence of d-alanine in proteins of normal and Alzheimer human brain journal October 1992
Protease Amperometric Sensor journal September 2006
Luminescent nanocrystal metal organic framework based biosensor for molecular recognition journal May 2014
Aqueous phase nitric oxide detection by an amine-decorated metal–organic framework journal January 2015
A metal–organic framework for selectively sensing of PO43− anion in aqueous solution journal February 2011
Fast response and highly selective sensing of amine vapors using a luminescent coordination polymer journal January 2014
A 1D crystalline organic polyrotaxane formed via hydrogen bond-mediated self-assembly of a conformationally flexible tri-carboxylic acid journal January 2009
Postsynthetic modification of metal–organic framework for hydrogen sulfide detection journal November 2015
Metal−Organic Framework Thin Film for Enhanced Localized Surface Plasmon Resonance Gas Sensing journal October 2010
Fabrication of Metal-Organic Framework-Containing Silica-Colloidal Crystals for Vapor Sensing journal August 2011
A Chemically Functionalizable Nanoporous Material [Cu3(TMA)2(H2O)3]n journal February 1999
Engineering ZIF-8 Thin Films for Hybrid MOF-Based Devices journal June 2012
Fabrication of an NH 2 -MIL-88B photonic film for naked-eye sensing of organic vapors journal January 2014
Novel Route to Size-Controlled Fe–MIL-88B–NH 2 Metal–Organic Framework Nanocrystals journal December 2011
Flexible metal–organic framework-based one-dimensional photonic crystals journal January 2015
Analyte Detection with Cu-BTC Metal–Organic Framework Thin Films by Means of Mass-Sensitive and Work-Function-Based Readout journal July 2014
Hydrogen Storage in the Giant-Pore Metal–Organic Frameworks MIL-100 and MIL-101 journal December 2006
MOF Thin Film-Coated Metal Oxide Nanowire Array: Significantly Improved Chemiresistor Sensor Performance journal May 2016
High Performance Hollow Metal-Organic Framework Nanoshell-Based Etalons for Volatile Organic Compounds Detection journal August 2016
Nanoimprinted, Submicrometric, MOF-Based 2D Photonic Structures: Toward Easy Selective Vapors Sensing by a Smartphone Camera journal November 2015
Metal–organic framework thin films: electrochemical fabrication techniques and corresponding applications & perspectives journal January 2016
Metal–organic frameworks for membrane-based separations journal November 2016
Applications of water stable metal–organic frameworks journal January 2016
“Green” Synthesis of Metal-Organic Frameworks: “Green” Synthesis of Metal-Organic Frameworks journal June 2016
Synthesis of metal–organic frameworks in water at room temperature: salts as linker sources journal January 2015
Green synthesis of zirconium-MOFs journal January 2015