Amine-functionalized (Al) MIL-53/VTEC™ mixed-matrix membranes for H2/CO2 mixture separations at high pressure and high temperature

Perez, Edson V.; Kalaw, Grace J.D.; Ferraris, John P.; Balkus, Kenneth J.; Musselman, Inga H.

doi:10.1016/j.memsci.2017.02.003

Title: Amine-functionalized (Al) MIL-53/VTEC™ mixed-matrix membranes for H₂/CO₂ mixture separations at high pressure and high temperature

Journal Article · Thu Feb 02 00:00:00 EST 2017 · Journal of Membrane Science

DOI:https://doi.org/10.1016/j.memsci.2017.02.003· OSTI ID:1534104

Perez, Edson V. ^[1]; Kalaw, Grace J.D. ^[1]; Ferraris, John P. ^[1]; Balkus, Kenneth J. ^[1]; Musselman, Inga H. ^[1]

University of Texas at Dallas, Richardson, TX (United States)

In this report VTEC™ PI-1388 and 20 wt% (Al) NH₂-MIL-53/VTEC™ PI-1388 mixed-matrix membranes (MMMs) with different thicknesses were tested for gas permeation of H2 and CO₂ from 5 to 30 bar and from 35 to 300 °C. 50/50 H₂/CO₂ mixtures were also tested at 30 bar and 250 °C with stage cuts that ranged from 0.05 to 1. Gas permeation data show that the affinity of (Al) NH₂-MIL-53 for VTEC™ PI-1388 is strong enough to perform gas separations under these conditions. At 30 bar and at temperatures above 200 °C, the performance of the MMMs for H₂/CO₂ separation improved significantly with increasing temperature. Specifically, the H₂ permeability of the MMM at 300 °C increased by 70% with respect to that of VTEC™ PI-1388 (VTEC™ PI-1388: H₂ = 85 Barrer, H₂/CO₂ = 4.0; MMM: H₂ = 144 Barrer, H₂/CO₂ = 5.8). Gas mixture separations using VTEC™ PI-1388 and the MMM depended on the stage cut and reached a maximum H₂/CO₂ separation of 7.2 for VTEC™ PI-1388 and 7.5 for the MMM at a stage cut of 0.05.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Univ. of Texas at Dallas, Richardson, TX (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE); National Science Foundation (NSF)

Grant/Contract Number:: FE0001293; NT0007636; CBET-0933563; CBET-1403950

OSTI ID:: 1534104

Alternate ID(s):: OSTI ID: 1426304

Journal Information:: Journal of Membrane Science, Vol. 530, Issue C; ISSN 0376-7388

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 20 works

Citation information provided by
Web of Science

References (69)

Thermal imidization optimization of polyimide thin films using Fourier transform infrared spectroscopy and electrical measurements Diaham, S.; Locatelli, M. L.; Lebey, T. Thin Solid Films, Vol. 519, Issue 6 https://doi.org/10.1016/j.tsf.2010.10.031	journal	January 2011
Hydrogen from coal: Production and utilisation technologies Shoko, E.; McLellan, B.; Dicks, A. L. International Journal of Coal Geology, Vol. 65, Issue 3-4 https://doi.org/10.1016/j.coal.2005.05.004	journal	January 2006
An Amine-Functionalized MIL-53 Metal−Organic Framework with Large Separation Power for CO ₂ and CH ₄ Couck, Sarah; Denayer, Joeri F. M.; Baron, Gino V. Journal of the American Chemical Society, Vol. 131, Issue 18 https://doi.org/10.1021/ja900555r	journal	May 2009
Effect of Pressure on High-Temperature Water Gas Shift Reaction in Microporous Zeolite Membrane Reactor Kim, Seok-Jhin; Xu, Zhi; Reddy, Gunugunuri K. Industrial & Engineering Chemistry Research, Vol. 51, Issue 3 https://doi.org/10.1021/ie201452y	journal	January 2012
Corrigendum to “Influence of temperature on the upper bound: Theoretical considerations and comparison with experimental results” [J. Membr. Sci. 360 (2010) 58–69] Rowe, Brandon W.; Robeson, Lloyd M.; Freeman, Benny D. Journal of Membrane Science, Vol. 366, Issue 1-2 https://doi.org/10.1016/j.memsci.2010.10.008	journal	January 2011
Gas Separation Membrane Materials: A Perspective Baker, Richard W.; Low, Bee Ting Macromolecules, Vol. 47, Issue 20 https://doi.org/10.1021/ma501488s	journal	September 2014
Amino-based metal-organic frameworks as stable, highly active basic catalysts Gascon, J.; Aktay, U.; Hernandezalonso, M. Journal of Catalysis, Vol. 261, Issue 1 https://doi.org/10.1016/j.jcat.2008.11.010	journal	January 2009
Zeolite membranes – a review and comparison with MOFs Rangnekar, N.; Mittal, N.; Elyassi, B. Chemical Society Reviews, Vol. 44, Issue 20 https://doi.org/10.1039/C5CS00292C	journal	January 2015
Zeolitic imidazolate framework (ZIF-8) based polymer nanocomposite membranes for gas separation Song, Qilei; Nataraj, S. K.; Roussenova, Mina V. Energy & Environmental Science, Vol. 5, Issue 8 https://doi.org/10.1039/c2ee21996d	journal	January 2012
Inorganic microporous membranes for H2 and CO2 separation—Review of experimental and modeling progress Li, H.; Haas-Santo, K.; Schygulla, U. Chemical Engineering Science, Vol. 127 https://doi.org/10.1016/j.ces.2015.01.022	journal	May 2015
A study on catalytic membrane reactors for water gas shift reaction Basile, A.; Drioli, E.; Santell, F. Gas Separation & Purification, Vol. 10, Issue 1 https://doi.org/10.1016/0950-4214(95)00023-2	journal	January 1996
Hydrogen production from coal-derived syngas using a catalytic membrane reactor based process Abdollahi, Mitra; Yu, Jiang; Liu, Paul K. T. Journal of Membrane Science, Vol. 363, Issue 1-2 https://doi.org/10.1016/j.memsci.2010.07.023	journal	November 2010
Water–gas shift reaction in a Pd membrane reactor over Pt/Ce0.6Zr0.4O2 catalyst Bi, Yadong; Xu, Hengyong; Li, Wenzhao International Journal of Hydrogen Energy, Vol. 34, Issue 7 https://doi.org/10.1016/j.ijhydene.2009.01.046	journal	April 2009
Mixed-matrix membranes containing MOF-5 for gas separations Perez, Edson V.; Balkus, Kenneth J.; Ferraris, John P. Journal of Membrane Science, Vol. 328, Issue 1-2, p. 165-173 https://doi.org/10.1016/j.memsci.2008.12.006	journal	February 2009
Inorganic membranes for hydrogen production and purification: A critical review and perspective Lu, G. Q.; Diniz da Costa, J. C.; Duke, M. Journal of Colloid and Interface Science, Vol. 314, Issue 2, p. 589-603 https://doi.org/10.1016/j.jcis.2007.05.067	journal	October 2007
An innovative configuration of a Pd-based membrane reactor for the production of pure hydrogen Barbieri, G.; Brunetti, A.; Tricoli, G. Journal of Power Sources, Vol. 182, Issue 1 https://doi.org/10.1016/j.jpowsour.2008.03.086	journal	July 2008
Membrane reactor for water gas shift reaction Basile, A.; Criscuoli, A.; Santella, F. Gas Separation & Purification, Vol. 10, Issue 4 https://doi.org/10.1016/S0950-4214(96)00024-2	journal	January 1996
Gas Sorption and Transport in Glassy Polymers Paul, D. R. Berichte der Bunsengesellschaft für physikalische Chemie, Vol. 83, Issue 4 https://doi.org/10.1002/bbpc.19790830403	journal	April 1979
Synthesis of soluble aluminium carboxylates directly from aluminium hydroxide Narayanan, Ramasubramanian; Laine, Richard M. Journal of Materials Chemistry, Vol. 10, Issue 9 https://doi.org/10.1039/b000724m	journal	January 2000
Origins and Evolution of Inorganic-Based and MOF-Based Mixed-Matrix Membranes for Gas Separations Perez, Edson; Karunaweera, Chamaal; Musselman, Inga Processes, Vol. 4, Issue 3 https://doi.org/10.3390/pr4030032	journal	September 2016
The rheology of Torlon® solutions and its role in the formation of ultra-thin defect-free Torlon® hollow fiber membranes for gas separation Peng, Na; Chung, Tai-Shung; Lai, Juin-Yih Journal of Membrane Science, Vol. 326, Issue 2 https://doi.org/10.1016/j.memsci.2008.10.038	journal	January 2009
Adsorption and Separation of Light Gases on an Amino-Functionalized Metal-Organic Framework: An Adsorption and In Situ XRD Study Couck, Sarah; Gobechiya, Elena; Kirschhock, Christine E. A. ChemSusChem, Vol. 5, Issue 4 https://doi.org/10.1002/cssc.201100378	journal	February 2012
Visualizing MOF Mixed Matrix Membranes at the Nanoscale: Towards Structure-Performance Relationships in CO ₂ /CH ₄ Separation Over NH ₂ -MIL-53(Al)@PI Rodenas, Tania; van Dalen, Marion; García-Pérez, Elena Advanced Functional Materials, Vol. 24, Issue 2 https://doi.org/10.1002/adfm.201203462	journal	March 2013
A model for diffusion in a glassy polymer Vieth, W. R.; Sladek, K. J. Journal of Colloid Science, Vol. 20, Issue 9 https://doi.org/10.1016/0095-8522(65)90071-1	journal	December 1965
Thermodynamic analysis of the breathing of amino-functionalized MIL-53(Al) upon CO2 adsorption Boutin, Anne; Couck, Sarah; Coudert, François-Xavier Microporous and Mesoporous Materials, Vol. 140, Issue 1-3 https://doi.org/10.1016/j.micromeso.2010.07.009	journal	April 2011
Hybrid membranes of metal–organic molecule nanocages for aromatic/aliphatic hydrocarbon separation by pervaporation Zhao, Cui; Wang, Naixin; Wang, Lin Chem. Commun., Vol. 50, Issue 90 https://doi.org/10.1039/C4CC05279J	journal	January 2014
Thermal optimization of polybenzimidazole meniscus membranes for the separation of hydrogen, methane, and carbon dioxide Pesiri, David R.; Jorgensen, Betty; Dye, Robert C. Journal of Membrane Science, Vol. 218, Issue 1-2 https://doi.org/10.1016/S0376-7388(03)00129-7	journal	July 2003
From minerals to materials: synthesis of alumoxanes from the reaction of boehmite with carboxylic acids Landry, Christopher C.; Pappé, Nina; Mason, Mark R. J. Mater. Chem., Vol. 5, Issue 2 https://doi.org/10.1039/JM9950500331	journal	January 1995
Mixed-matrix membranes containing functionalized porous metal–organic polyhedrons for the effective separation of CO ₂ –CH ₄ mixture Ma, Jing; Ying, Yunpan; Yang, Qingyuan Chemical Communications, Vol. 51, Issue 20 https://doi.org/10.1039/C5CC00384A	journal	January 2015
Membrane Gas Separation: A Review/State of the Art Bernardo, P.; Drioli, E.; Golemme, G. Industrial & Engineering Chemistry Research, Vol. 48, Issue 10 https://doi.org/10.1021/ie8019032	journal	May 2009
Model for sorption of mixed gases in glassy polymers Koros, W. J. Journal of Polymer Science: Polymer Physics Edition, Vol. 18, Issue 5 https://doi.org/10.1002/pol.1980.180180506	journal	May 1980
Recent advances on membranes and membrane reactors for hydrogen production Gallucci, Fausto; Fernandez, Ekain; Corengia, Pablo Chemical Engineering Science, Vol. 92 https://doi.org/10.1016/j.ces.2013.01.008	journal	April 2013
Carbon dioxide sorption and transport in polycarbonate Koros, W. J.; Paul, D. R.; Rocha, A. A. Journal of Polymer Science: Polymer Physics Edition, Vol. 14, Issue 4 https://doi.org/10.1002/pol.1976.180140410	journal	April 1976
Observations concerning the temperature dependence of the langmuir sorption capacity of glassy polymers Koros, W. J.; Paul, D. R. Journal of Polymer Science: Polymer Physics Edition, Vol. 19, Issue 10 https://doi.org/10.1002/pol.1981.180191014	journal	October 1981
Hydrogen Selective NH2-MIL-53(Al) MOF Membranes with High Permeability Zhang, Feng; Zou, Xiaoqin; Gao, Xue Advanced Functional Materials, Vol. 22, Issue 17 https://doi.org/10.1002/adfm.201200084	journal	May 2012
A pulse chromatographic study of the adsorption properties of the amino-MIL-53 (Al) metal–organic framework Couck, Sarah; Rémy, Tom; Baron, Gino V. Physical Chemistry Chemical Physics, Vol. 12, Issue 32 https://doi.org/10.1039/b927115e	journal	January 2010
Hydrothermal stability of cobalt silica membranes in a water gas shift membrane reactor Battersby, Scott; Smart, Simon; Ladewig, Bradley Separation and Purification Technology, Vol. 66, Issue 2 https://doi.org/10.1016/j.seppur.2008.12.020	journal	April 2009
Fabrication of mixed matrix hollow fibers with intimate polymer–zeolite interface for gas separation Jiang, Lan Ying; Chung, Tai Shung; Kulprathipanja, Santi AIChE Journal, Vol. 52, Issue 8 https://doi.org/10.1002/aic.10909	journal	January 2006
FT-IR, UV spectroscopic and DFT quantum chemical study on the molecular conformation, vibrational and electronic transitions of 2-aminoterephthalic acid Karabacak, Mehmet; Cinar, Mehmet; Unal, Zeliha Journal of Molecular Structure, Vol. 982, Issue 1-3 https://doi.org/10.1016/j.molstruc.2010.07.033	journal	October 2010
The Water-Gas Shift Reaction Newsome, David S. Catalysis Reviews, Vol. 21, Issue 2, p. 275-318 https://doi.org/10.1080/03602458008067535	journal	January 1980
Metal-organic polyhedra 18 mixed-matrix membranes for gas separation Perez, Edson V.; Balkus, Kenneth J.; Ferraris, John P. Journal of Membrane Science, Vol. 463 https://doi.org/10.1016/j.memsci.2014.03.045	journal	August 2014
Gas sorption in polymers, molecular sieves, and mixed matrix membranes Moore, Theodore T.; Koros, William J. Journal of Applied Polymer Science, Vol. 104, Issue 6 https://doi.org/10.1002/app.25653	journal	January 2007
Reversible diamine cross-linking of polyimide membranes Powell, Clem E.; Duthie, Xavier J.; Kentish, Sandra E. Journal of Membrane Science, Vol. 291, Issue 1-2 https://doi.org/10.1016/j.memsci.2007.01.016	journal	March 2007
Pd–Ag membrane reactors for water gas shift reaction Tosti, S.; Basile, A.; Chiappetta, G. Chemical Engineering Journal, Vol. 93, Issue 1 https://doi.org/10.1016/S1385-8947(02)00113-4	journal	May 2003
“High Temperature Gas Separation Membranes in Coal Gasification” Diniz da Costa, J. C.; Reed, G. P.; Thambimuthu, K. Energy Procedia, Vol. 1, Issue 1 https://doi.org/10.1016/j.egypro.2009.01.041	journal	February 2009
Functionalized flexible MOFs as fillers in mixed matrix membranes for highly selective separation of CO2 from CH4 at elevated pressures Zornoza, Beatriz; Martinez-Joaristi, Alberto; Serra-Crespo, Pablo Chemical Communications, Vol. 47, Issue 33 https://doi.org/10.1039/c1cc13431k	journal	January 2011
Instrument for gas permeation measurements at high pressure and high temperature Perez, Edson V.; Balkus, Kenneth J.; Ferraris, John P. Review of Scientific Instruments, Vol. 84, Issue 6 https://doi.org/10.1063/1.4808285	journal	June 2013
Polybenzimidazole (PBI)/zeolitic imidazolate frameworks (ZIF-8) mixed matrix membranes for pervaporation dehydration of alcohols Shi, Gui Min; Yang, Tingxu; Chung, Tai Shung Journal of Membrane Science, Vol. 415-416 https://doi.org/10.1016/j.memsci.2012.05.052	journal	October 2012
Influence of temperature on the upper bound: Theoretical considerations and comparison with experimental results Rowe, Brandon W.; Robeson, Lloyd M.; Freeman, Benny D. Journal of Membrane Science, Vol. 360, Issue 1-2 https://doi.org/10.1016/j.memsci.2010.04.047	journal	September 2010
Synthesis and Modification of a Functionalized 3D Open-Framework Structure with MIL-53 Topology Ahnfeldt, Tim; Gunzelmann, Daniel; Loiseau, Thierry Inorganic Chemistry, Vol. 48, Issue 7 https://doi.org/10.1021/ic8023265	journal	April 2009
A porous stainless steel supported silica membrane for WGS reaction in a catalytic membrane reactor Brunetti, A.; Barbieri, G.; Drioli, E. Chemical Engineering Science, Vol. 62, Issue 18-20 https://doi.org/10.1016/j.ces.2007.01.054	journal	September 2007
Affinity between Metal–Organic Frameworks and Polyimides in Asymmetric Mixed Matrix Membranes for Gas Separations Ren, Huiqing; Jin, Jiaying; Hu, Jun Industrial & Engineering Chemistry Research, Vol. 51, Issue 30 https://doi.org/10.1021/ie300553k	journal	July 2012
MIL-53 frameworks in mixed-matrix membranes Hsieh, Josephine O.; Balkus, Kenneth J.; Ferraris, John P. Microporous and Mesoporous Materials, Vol. 196 https://doi.org/10.1016/j.micromeso.2014.05.006	journal	September 2014
Metal–organic framework based mixed matrix membranes: a solution for highly efficient CO ₂ capture? Seoane, Beatriz; Coronas, Joaquin; Gascon, Ignacio Chemical Society Reviews, Vol. 44, Issue 8 https://doi.org/10.1039/C4CS00437J	journal	January 2015
Techno-economic analysis of gasification routes for ammonia production from Victorian brown coal Habgood, David C. C.; Hoadley, Andrew F. A.; Zhang, Lian Chemical Engineering Research and Design, Vol. 102 https://doi.org/10.1016/j.cherd.2015.06.008	journal	October 2015
Metal organic framework based mixed matrix membranes: An increasingly important field of research with a large application potential Zornoza, Beatriz; Tellez, Carlos; Coronas, Joaquin Microporous and Mesoporous Materials, Vol. 166 https://doi.org/10.1016/j.micromeso.2012.03.012	journal	January 2013
Membrane separation processes for the benefit of the sulfur–iodine and hybrid sulfur thermochemical cycles Orme, Christopher J.; Klaehn, John R.; Stewart, Frederick F. International Journal of Hydrogen Energy, Vol. 34, Issue 9 https://doi.org/10.1016/j.ijhydene.2008.06.046	journal	May 2009
Field evaluation of carbon molecular sieve membranes for the separation and purification of hydrogen from coal- and biomass-derived syngas Parsley, Doug; Ciora, Richard J.; Flowers, Diane L. Journal of Membrane Science, Vol. 450 https://doi.org/10.1016/j.memsci.2013.08.008	journal	January 2014
Metal–organic frameworks in mixed-matrix membranes for gas separation Tanh Jeazet, Harold B.; Staudt, Claudia; Janiak, Christoph Dalton Transactions, Vol. 41, Issue 46 https://doi.org/10.1039/c2dt31550e	journal	January 2012
Sonication-induced Ostwald ripening of ZIF-8 nanoparticles and formation of ZIF-8/polymer composite membranes Thompson, Joshua A.; Chapman, Karena W.; Koros, William J. Microporous and Mesoporous Materials, Vol. 158 https://doi.org/10.1016/j.micromeso.2012.03.052	journal	August 2012
High-temperature membrane reactors: potential and problems Saracco, G.; Neomagus, H. W. J. P.; Versteeg, G. F. Chemical Engineering Science, Vol. 54, Issue 13-14, p. 1997-2017 https://doi.org/10.1016/S0009-2509(99)00009-3	journal	July 1999
Dual-layer hollow carbon fiber membranes for gas separation consisting of carbon and mixed matrix layers Jiang, Lan Ying; Chung, Tai-Shung; Rajagopalan, Raj Carbon, Vol. 45, Issue 1 https://doi.org/10.1016/j.carbon.2006.07.008	journal	January 2007
Wall-catalyzed water-gas shift reaction in multi-tubular Pd and 80wt%Pd–20wt%Cu membrane reactors at 1173K Iyoha, Osemwengie; Enick, Robert; Killmeyer, Richard Journal of Membrane Science, Vol. 298, Issue 1-2 https://doi.org/10.1016/j.memsci.2007.03.053	journal	July 2007
Enhancement of molecular-sieving properties by constructing surface nano-metric layer via vapor cross-linking Japip, Susilo; Liao, Kuo-Sung; Xiao, Youchang Journal of Membrane Science, Vol. 497 https://doi.org/10.1016/j.memsci.2015.09.045	journal	January 2016
Membrane reactors for fuel cell quality hydrogen through WGSR – Review of their status, challenges and opportunities Babita, K.; Sridhar, S.; Raghavan, K. V. International Journal of Hydrogen Energy, Vol. 36, Issue 11 https://doi.org/10.1016/j.ijhydene.2011.02.107	journal	June 2011
An alternative pathway for the synthesis of isocyanato- and urea-functionalised metal–organic frameworks Lescouet, Tristan; Vitillo, Jenny G.; Bordiga, Silvia Dalton Transactions, Vol. 42, Issue 23 https://doi.org/10.1039/c3dt32714k	journal	January 2013
Zeolitic imidazolate framework composite membranes and thin films: synthesis and applications Yao, Jianfeng; Wang, Huanting Chem. Soc. Rev., Vol. 43, Issue 13 https://doi.org/10.1039/C3CS60480B	journal	January 2014
The upper bound revisited Robeson, Lloyd M. Journal of Membrane Science, Vol. 320, Issue 1-2, p. 390-400 https://doi.org/10.1016/j.memsci.2008.04.030	journal	July 2008
Mixed matrix membranes based on NH2-functionalized MIL-type MOFs: Influence of structural and operational parameters on the CO2/CH4 separation performance Rodenas, Tania; van Dalen, Marion; Serra-Crespo, Pablo Microporous and Mesoporous Materials, Vol. 192 https://doi.org/10.1016/j.micromeso.2013.08.049	journal	July 2014

Similar Records

Water-Gas-Shift Membrane Reactor for High-Pressure Hydrogen Production. A comprehensive project report (FY2010 - FY2012)

Technical Report · Tue Jan 01 00:00:00 EST 2013 · OSTI ID:1534104

Klaehn, John; Peterson, Eric; Orme, Christopher; +14 more

Integrated Water Gas Shift Membrane Reactors Utilizing Novel, Non Precious Metal Mixed Matrix Membrane

Technical Report · Mon Sep 30 00:00:00 EDT 2013 · OSTI ID:1534104

Ferraris, John P.

Novel Zeolitic Imidazolate Framework/Polymer Membranes for Hydrogen Separations in Coal Processing

Technical Report · Thu Jan 31 00:00:00 EST 2013 · OSTI ID:1534104

Musselman, Inga H.

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: Amine-functionalized (Al) MIL-53/VTEC™ mixed-matrix membranes for H2/CO2 mixture separations at high pressure and high temperature

Citation Formats

References (69)

Similar Records

Related Subjects

Title: Amine-functionalized (Al) MIL-53/VTEC™ mixed-matrix membranes for H₂/CO₂ mixture separations at high pressure and high temperature