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Title: Systematic Study of Open-Shell Trigonal Pyramidal Transition-Metal Complexes with a Rigid-Ligand Scaffold

Abstract

Not provided.

Authors:
ORCiD logo [1]; ORCiD logo [2];  [3];  [2]; ORCiD logo [2]
  1. Faculty of Chemistry, Jagiellonian University, Ingardena 3 30-060 Kraków Poland; Department of Chemistry, Texas A&M University, College Station Texas 77842-3012 USA
  2. Department of Chemistry, Texas A&M University, College Station Texas 77842-3012 USA
  3. Faculty of Chemistry, Jagiellonian University, Ingardena 3 30-060 Kraków Poland
Publication Date:
Research Org.:
Texas A & M Univ., College Station, TX (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1533135
DOE Contract Number:  
FG02-02ER45999; SC0012582
Resource Type:
Journal Article
Journal Name:
Chemistry - A European Journal
Additional Journal Information:
Journal Volume: 23; Journal Issue: 15; Journal ID: ISSN 0947-6539
Publisher:
ChemPubSoc Europe
Country of Publication:
United States
Language:
English
Subject:
Chemistry

Citation Formats

Pinkowicz, Dawid, Birk, Francisco J., Magott, Michał, Schulte, Kelsey, and Dunbar, Kim R. Systematic Study of Open-Shell Trigonal Pyramidal Transition-Metal Complexes with a Rigid-Ligand Scaffold. United States: N. p., 2017. Web. doi:10.1002/chem.201605528.
Pinkowicz, Dawid, Birk, Francisco J., Magott, Michał, Schulte, Kelsey, & Dunbar, Kim R. Systematic Study of Open-Shell Trigonal Pyramidal Transition-Metal Complexes with a Rigid-Ligand Scaffold. United States. doi:10.1002/chem.201605528.
Pinkowicz, Dawid, Birk, Francisco J., Magott, Michał, Schulte, Kelsey, and Dunbar, Kim R. Tue . "Systematic Study of Open-Shell Trigonal Pyramidal Transition-Metal Complexes with a Rigid-Ligand Scaffold". United States. doi:10.1002/chem.201605528.
@article{osti_1533135,
title = {Systematic Study of Open-Shell Trigonal Pyramidal Transition-Metal Complexes with a Rigid-Ligand Scaffold},
author = {Pinkowicz, Dawid and Birk, Francisco J. and Magott, Michał and Schulte, Kelsey and Dunbar, Kim R.},
abstractNote = {Not provided.},
doi = {10.1002/chem.201605528},
journal = {Chemistry - A European Journal},
issn = {0947-6539},
number = 15,
volume = 23,
place = {United States},
year = {2017},
month = {2}
}

Works referenced in this record:

Will Spin-Relaxation Times in Molecular Magnets Permit Quantum Information Processing?
journal, January 2007


Quantum Oscillations of the Total Spin in a Heterometallic Antiferromagnetic Ring: Evidence from Neutron Spectroscopy
journal, April 2007


Molecular spins for quantum information technologies
journal, January 2011

  • Troiani, Filippo; Affronte, Marco
  • Chemical Society Reviews, Vol. 40, Issue 6
  • DOI: 10.1039/c0cs00158a

Quantum computing in molecular magnets
journal, April 2001

  • Leuenberger, Michael N.; Loss, Daniel
  • Nature, Vol. 410, Issue 6830
  • DOI: 10.1038/35071024

Design of magnetic coordination complexes for quantum computing
journal, January 2012

  • Aromí, Guillem; Aguilà, David; Gamez, Patrick
  • Chem. Soc. Rev., Vol. 41, Issue 2
  • DOI: 10.1039/C1CS15115K

Molecular spintronics
journal, January 2011


A Mononuclear Transition Metal Single-Molecule Magnet in a Nuclear Spin-Free Ligand Environment
journal, September 2014

  • Fataftah, Majed S.; Zadrozny, Joseph M.; Rogers, Dylan M.
  • Inorganic Chemistry, Vol. 53, Issue 19
  • DOI: 10.1021/ic501906z

Transformation of the coordination complex [Co(C 3 S 5 ) 2 ] 2− from a molecular magnet to a potential qubit
journal, January 2016

  • Fataftah, Majed S.; Coste, Scott C.; Vlaisavljevich, Bess
  • Chemical Science, Vol. 7, Issue 9
  • DOI: 10.1039/C6SC02170K

High-spin molecules: [Mn12O12(O2CR)16(H2O)4]
journal, March 1993

  • Sessoli, Roberta; Tsai, Hui Lien; Schake, Ann R.
  • Journal of the American Chemical Society, Vol. 115, Issue 5
  • DOI: 10.1021/ja00058a027

Magnetic bistability in a metal-ion cluster
journal, September 1993

  • Sessoli, R.; Gatteschi, D.; Caneschi, A.
  • Nature, Vol. 365, Issue 6442
  • DOI: 10.1038/365141a0

Symmetry-Supported Magnetic Blocking at 20 K in Pentagonal Bipyramidal Dy(III) Single-Ion Magnets
journal, February 2016

  • Chen, Yan-Cong; Liu, Jun-Liang; Ungur, Liviu
  • Journal of the American Chemical Society, Vol. 138, Issue 8
  • DOI: 10.1021/jacs.5b13584

A Ferromagnetically Coupled Mn19 Aggregate with a RecordS=83/2 Ground Spin State
journal, July 2006

  • Ako, Ayuk M.; Hewitt, Ian J.; Mereacre, Valeriu
  • Angewandte Chemie International Edition, Vol. 45, Issue 30
  • DOI: 10.1002/anie.200601467

A Ferromagnetically Coupled Mn19 Aggregate with a RecordS=83/2 Ground Spin State
journal, July 2006

  • Ako, Ayuk M.; Hewitt, Ian J.; Mereacre, Valeriu
  • Angewandte Chemie, Vol. 118, Issue 30
  • DOI: 10.1002/ange.200601467

Pressure-induced Jahn–Teller switching in a Mn12 nanomagnet
journal, January 2010

  • Parois, Pascal; Moggach, Stephen A.; Sanchez-Benitez, Javier
  • Chemical Communications, Vol. 46, Issue 11
  • DOI: 10.1039/b923962f

A Criterion for the Anisotropy Barrier in Single-Molecule Magnets
journal, November 2007


Lanthanide Single-Molecule Magnets
journal, March 2013

  • Woodruff, Daniel N.; Winpenny, Richard E. P.; Layfield, Richard A.
  • Chemical Reviews, Vol. 113, Issue 7
  • DOI: 10.1021/cr400018q

Understanding the Magnetic Anisotropy toward Single-Ion Magnets
journal, October 2016


Rational Design of Single-Ion Magnets and Spin Qubits Based on Mononuclear Lanthanoid Complexes
journal, October 2012

  • Baldoví, José J.; Cardona-Serra, Salvador; Clemente-Juan, Juan M.
  • Inorganic Chemistry, Vol. 51, Issue 22
  • DOI: 10.1021/ic302068c

Shedding Light on the Single-Molecule Magnet Behavior of Mononuclear Dy III Complexes
journal, November 2013

  • Aravena, Daniel; Ruiz, Eliseo
  • Inorganic Chemistry, Vol. 52, Issue 23
  • DOI: 10.1021/ic402367c

An electrostatic model for the determination of magnetic anisotropy in dysprosium complexes
journal, October 2013

  • Chilton, Nicholas F.; Collison, David; McInnes, Eric J. L.
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms3551

Exploiting single-ion anisotropy in the design of f-element single-molecule magnets
journal, January 2011

  • Rinehart, Jeffrey D.; Long, Jeffrey R.
  • Chemical Science, Vol. 2, Issue 11
  • DOI: 10.1039/c1sc00513h

Review of purely 4f and mixed-metal nd-4f single-molecule magnets containing only one lanthanide ion
journal, September 2014


An Organolanthanide Building Block Approach to Single-Molecule Magnets
journal, May 2016


A N 2 3– Radical-Bridged Terbium Complex Exhibiting Magnetic Hysteresis at 14 K
journal, September 2011

  • Rinehart, Jeffrey D.; Fang, Ming; Evans, William J.
  • Journal of the American Chemical Society, Vol. 133, Issue 36
  • DOI: 10.1021/ja206286h

A Stable Pentagonal Bipyramidal Dy(III) Single-Ion Magnet with a Record Magnetization Reversal Barrier over 1000 K
journal, January 2016

  • Liu, Jiang; Chen, Yan-Cong; Liu, Jun-Liang
  • Journal of the American Chemical Society, Vol. 138, Issue 16
  • DOI: 10.1021/jacs.6b02638

Slow Magnetic Relaxation in a High-Spin Iron(II) Complex
journal, February 2010

  • Freedman, Danna E.; Harman, W. Hill; Harris, T. David
  • Journal of the American Chemical Society, Vol. 132, Issue 4
  • DOI: 10.1021/ja909560d

Slow Magnetic Relaxation in a Family of Trigonal Pyramidal Iron(II) Pyrrolide Complexes
journal, December 2010

  • Harman, W. Hill; Harris, T. David; Freedman, Danna E.
  • Journal of the American Chemical Society, Vol. 132, Issue 51
  • DOI: 10.1021/ja105291x

Magnetic anisotropy in two- to eight-coordinated transition–metal complexes: Recent developments in molecular magnetism
journal, February 2016

  • Bar, Arun Kumar; Pichon, Céline; Sutter, Jean-Pascal
  • Coordination Chemistry Reviews, Vol. 308
  • DOI: 10.1016/j.ccr.2015.06.013

3d single-ion magnets
journal, January 2015

  • Craig, Gavin A.; Murrie, Mark
  • Chemical Society Reviews, Vol. 44, Issue 8
  • DOI: 10.1039/C4CS00439F

The rise of 3-d single-ion magnets in molecular magnetism: towards materials from molecules?
journal, January 2016

  • Frost, Jamie M.; Harriman, Katie L. M.; Murugesu, Muralee
  • Chemical Science, Vol. 7, Issue 4
  • DOI: 10.1039/C5SC03224E

Zero-field slow magnetic relaxation from single Co(ii) ion: a transition metal single-molecule magnet with high anisotropy barrier
journal, January 2013

  • Zhu, Yuan-Yuan; Cui, Chang; Zhang, Yi-Quan
  • Chemical Science, Vol. 4, Issue 4
  • DOI: 10.1039/c3sc21893g

Ligands effects on the magnetic anisotropy of tetrahedral cobalt complexes
journal, January 2014

  • Saber, Mohamed R.; Dunbar, Kim R.
  • Chem. Commun., Vol. 50, Issue 82
  • DOI: 10.1039/C4CC05724D

Mononuclear Single-Molecule Magnets: Tailoring the Magnetic Anisotropy of First-Row Transition-Metal Complexes
journal, April 2013

  • Gomez-Coca, Silvia; Cremades, Eduard; Aliaga-Alcalde, Núria
  • Journal of the American Chemical Society, Vol. 135, Issue 18
  • DOI: 10.1021/ja4015138

Universal Theoretical Approach to Extract Anisotropic Spin Hamiltonians
journal, October 2009

  • Maurice, Rémi; Bastardis, Roland; Graaf, Coen de
  • Journal of Chemical Theory and Computation, Vol. 5, Issue 11
  • DOI: 10.1021/ct900326e

Rigorous Extraction of the Anisotropic Multispin Hamiltonian in Bimetallic Complexes from the Exact Electronic Hamiltonian
journal, December 2009

  • Maurice, Rémi; Guihéry, Nathalie; Bastardis, Roland
  • Journal of Chemical Theory and Computation, Vol. 6, Issue 1
  • DOI: 10.1021/ct900473u

Ising-type magnetic anisotropy and single molecule magnet behaviour in mononuclear trigonal bipyramidal Co( ii ) complexes
journal, January 2014

  • Ruamps, Renaud; Batchelor, Luke J.; Guillot, Régis
  • Chemical Science, Vol. 5, Issue 9
  • DOI: 10.1039/C4SC00984C

The Ligand Field of the Azido Ligand: Insights into Bonding Parameters and Magnetic Anisotropy in a Co(II)–Azido Complex
journal, January 2015

  • Schweinfurth, David; Sommer, Michael G.; Atanasov, Mihail
  • Journal of the American Chemical Society, Vol. 137, Issue 5
  • DOI: 10.1021/ja512232f

Synthesis of vanadium and titanium complexes of the type RM[(Me3SiNCH2CH2)3N] (R = Cl, alkyl) and the structure of ClV[(Me3SiNCH2CH2)3N]
journal, April 1992

  • Cummins, Christopher C.; Schrock, Richard R.; Davis, William M.
  • Organometallics, Vol. 11, Issue 4
  • DOI: 10.1021/om00040a011

Transition Metal Complexes That Contain a Triamidoamine Ligand
journal, January 1997

  • Schrock, Richard R.
  • Accounts of Chemical Research, Vol. 30, Issue 1
  • DOI: 10.1021/ar950195t

Trigonal-Monopyramidal MIII Complexes of the Type[M(N3N)](M= Ti, V, Cr, Mn, Fe; N3N=[(tBuMe2Si)CH2CH2]3N)
journal, November 1992

  • Cummins, Christopher C.; Lee, Jenny; Schrock, Richard R.
  • Angewandte Chemie International Edition in English, Vol. 31, Issue 11
  • DOI: 10.1002/anie.199215011

Trigonal-monopyramidale MIII-Komplexe des Typs [M(N3N)] (M = Ti, V, Cr, Mn, Fe; N3N = [(tBuMe2Si)CH2CH2]3N)
journal, November 1992

  • Cummins, Christopher C.; Lee, Jenny; Schrock, Richard R.
  • Angewandte Chemie, Vol. 104, Issue 11
  • DOI: 10.1002/ange.19921041119

A Pair of Remarkably Stable Mononuclear Chromium(III) and Chromium(IV) Hydrides
journal, September 2003

  • Filippou, Alexander C.; Schneider, Sven; Schnakenburg, Gregor
  • Angewandte Chemie International Edition, Vol. 42, Issue 37
  • DOI: 10.1002/anie.200352177

A Pair of Remarkably Stable Mononuclear Chromium(III) and Chromium(IV) Hydrides
journal, September 2003

  • Filippou, Alexander C.; Schneider, Sven; Schnakenburg, Gregor
  • Angewandte Chemie, Vol. 115, Issue 37
  • DOI: 10.1002/ange.200352177

Huge Magnetic Anisotropy in a Trigonal-Pyramidal Nickel(II) Complex
journal, December 2013

  • Gómez-Coca, Silvia; Cremades, Eduard; Aliaga-Alcalde, Núria
  • Inorganic Chemistry, Vol. 53, Issue 2
  • DOI: 10.1021/ic402256v

Structure and Physical Properties of Trigonal Monopyramidal Iron(II), Cobalt(II), Nickel(II), and Zinc(II) Complexes
journal, April 1998

  • Ray, Manabendra; Hammes, Brian S.; Yap, Glenn P. A.
  • Inorganic Chemistry, Vol. 37, Issue 7
  • DOI: 10.1021/ic970831e

[Na(THF) 2 Cr(N 3 N)]:  The First Trigonal Monopyramidal Chromium(II) Complex
journal, November 2003

  • Filippou, Alexander C.; Schneider, Sven; Schnakenburg, Gregor
  • Inorganic Chemistry, Vol. 42, Issue 22
  • DOI: 10.1021/ic0349961

Origin of slow magnetic relaxation in Kramers ions with non-uniaxial anisotropy
journal, July 2014

  • Gómez-Coca, Silvia; Urtizberea, Ainhoa; Cremades, Eduard
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5300