Quasi-Steady-State Polarization Reveals the Interplay of Capacitive and Faradaic Processes in Capacitive Deionization

doi:10.1002/celc.201700082

Title: Quasi-Steady-State Polarization Reveals the Interplay of Capacitive and Faradaic Processes in Capacitive Deionization

Abstract

Not provided.

Authors:

Holubowitch, Nicolas ^[1]; Omosebi, Ayokunle ^[1]; Gao, Xin ^[1]; Landon, James ^[1]; Liu, Kunlei ^[2]

Center for Applied Energy Research, University of Kentucky, Lexington KY 40511 USA
Center for Applied Energy Research, University of Kentucky, Lexington KY 40511 USA; Department of Mechanical Engineering, University of Kentucky, Lexington KY 40506 USA

Publication Date:: 2017-06-08

Research Org.:: West Virginia Univ., Morgantown, WV (United States)

Sponsoring Org.:: USDOE Office of Policy and International Affairs (PO)

OSTI Identifier:: 1533132

DOE Contract Number:: PI0000017

Resource Type:: Journal Article

Journal Name:: ChemElectroChem

Additional Journal Information:: Journal Volume: 4; Journal Issue: 9; Journal ID: ISSN 2196-0216

Publisher:: ChemPubSoc Europe

Country of Publication:: United States

Language:: English

Subject:: Electrochemistry

Citation Formats


                    Holubowitch, Nicolas, Omosebi, Ayokunle, Gao, Xin, Landon, James, and Liu, Kunlei. Quasi-Steady-State Polarization Reveals the Interplay of Capacitive and Faradaic Processes in Capacitive Deionization.  United States: N. p., 2017. 
        Web.  doi:10.1002/celc.201700082.

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                    Holubowitch, Nicolas, Omosebi, Ayokunle, Gao, Xin, Landon, James, & Liu, Kunlei. Quasi-Steady-State Polarization Reveals the Interplay of Capacitive and Faradaic Processes in Capacitive Deionization.  United States.  doi:10.1002/celc.201700082.

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                    Holubowitch, Nicolas, Omosebi, Ayokunle, Gao, Xin, Landon, James, and Liu, Kunlei. Thu .  
        "Quasi-Steady-State Polarization Reveals the Interplay of Capacitive and Faradaic Processes in Capacitive Deionization".  United States.  doi:10.1002/celc.201700082.

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@article{osti_1533132,

  title        = {Quasi-Steady-State Polarization Reveals the Interplay of Capacitive and Faradaic Processes in Capacitive Deionization},

  author       = {Holubowitch, Nicolas and Omosebi, Ayokunle and Gao, Xin and Landon, James and Liu, Kunlei},

  abstractNote = {Not provided.},

  doi          = {10.1002/celc.201700082},

  journal      = {ChemElectroChem},

  issn         = {2196-0216},

  number       = 9,

  volume       = 4,

  place        = {United States},

  year         = {2017},

  month        = {6}

}

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DOI: 10.1002/celc.201700082

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Works referenced in this record:

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Similar Records

Title: Quasi-Steady-State Polarization Reveals the Interplay of Capacitive and Faradaic Processes in Capacitive Deionization

Abstract

Citation Formats

Capacitive deionization as an electrochemical means of saving energy and delivering clean water. Comparison to present desalination practices: Will it compete? journal, April 2010

Direct prediction of the desalination performance of porous carbon electrodes for capacitive deionization journal, January 2013

Capacitive deionization with Ca-alginate coated-carbon electrode for hardness control journal, August 2016

Using capacitive deionisation for inland brackish groundwater desalination in a remote location journal, January 2013

Water desalination via capacitive deionization: what is it and what can we expect from it? journal, January 2015

Graphene-containing flowable electrodes for capacitive energy storage journal, October 2015

Tracking the structural arrangement of ions in carbon supercapacitor nanopores using in situ small-angle X-ray scattering journal, January 2015

Two-Dimensional Porous Electrode Model for Capacitive Deionization journal, October 2015

Three-Dimensional Graphene/Metal Oxide Nanoparticle Hybrids for High-Performance Capacitive Deionization of Saline Water journal, August 2013

Capacitive deionization (CDI) for desalination and water treatment — past, present and future (a review) journal, August 2008

Cell voltage versus electrode potential range in aqueous supercapacitors journal, April 2015

Desalting by Means of Porous Carbon Electrodes journal, January 1971

A control system for operating and investigating reactors: The demonstration of parasitic reactions in the water desalination by capacitive de-ionization journal, March 2011

Capacitive Deionization of NaCl Solutions at Non-Steady-State Conditions: Inversion Functionality of the Carbon Electrodes journal, August 2011

Electrode reactions and adsorption/desorption performance related to the applied potential in a capacitive deionization process journal, August 2010

Desalination stability of capacitive deionization using ordered mesoporous carbon: Effect of oxygen-containing surface groups and pore properties journal, November 2015

Surface charge enhanced carbon electrodes for stable and efficient capacitive deionization using inverted adsorption–desorption behavior journal, January 2015

Around the thermodynamic limitations of supercapacitors operating in aqueous electrolytes journal, July 2016

Design of graphene-coated hollow mesoporous carbon spheres as high performance electrodes for capacitive deionization journal, January 2014

Side Reactions in Capacitive Deionization (CDI) Processes: The Role of Oxygen Reduction journal, December 2016

The effect of the flow-regime, reversal of polarization, and oxygen on the long term stability in capacitive de-ionization processes journal, January 2015

Investigation of oxygen reduction on activated carbon electrodes in alkaline solution journal, May 2007

The Origins of Low Efficiency in Electrochemical De-Ionization Systems journal, January 2016

Thermodynamic cycle analysis for capacitive deionization journal, April 2009

Novel Graphene-Like Electrodes for Capacitive Deionization journal, November 2010

Review on the science and technology of water desalination by capacitive deionization journal, October 2013

Electrochemistry and capacitive charging of porous electrodes in asymmetric multicomponent electrolytes journal, June 2012

Proton-selective electrode for pH sensing journal, December 2016

Determination of the electrode potential causing Faradaic reactions in membrane capacitive deionization journal, August 2014

A systematic study on the changes in properties of an activated carbon cloth upon polarization journal, February 2011

Electrochemical Characterization of Activated Carbon-Fiber Cloth Polarizable Electrodes for Electric Double-Layer Capacitors journal, January 1990

Limitation of Charge Efficiency in Capacitive Deionization journal, January 2009

Examination of Water Electrolysis and Oxygen Reduction As Self-Discharge Mechanisms for Carbon-Based, Aqueous Electrolyte Electrochemical Capacitors journal, February 2011

Capacitive Deionization using Biomass-based Microporous Salt-Templated Heteroatom-Doped Carbons journal, May 2015

Asymmetric capacitive deionization utilizing nitric acid treated activated carbon fiber as the cathode journal, September 2015

Surface-treated carbon electrodes with modified potential of zero charge for capacitive deionization journal, April 2016

Electro-removal of arsenic(III) and arsenic(V) from aqueous solutions by capacitive deionization journal, July 2016

The feasibility of boron removal from water by capacitive deionization journal, July 2011

Pathways to low-cost electrochemical energy storage: a comparison of aqueous and nonaqueous flow batteries journal, January 2014

On porous electrodes in electrolyte solutions journal, October 1963

Complementary surface charge for enhanced capacitive deionization journal, April 2016

Continuous operation of membrane capacitive deionization cells assembled with dissimilar potential of zero charge electrode pairs journal, May 2015

Dependence of the Capacitive Deionization Performance on Potential of Zero Charge Shifting of Carbon Xerogel Electrodes during Long-Term Operation journal, January 2014

Requirements for performance characterization of C double-layer supercapacitors: Applications to a high specific-area C-cloth material journal, June 2006

Mechanistic insights into the use of oxide nanoparticles coated asymmetric electrodes for capacitive deionization journal, February 2013

Comparison of salt adsorption capacity and energy consumption between constant current and constant voltage operation in capacitive deionization journal, November 2014

Capacitive deionization as an electrochemical means of saving energy and delivering clean water. Comparison to present desalination practices: Will it compete?
journal, April 2010

Direct prediction of the desalination performance of porous carbon electrodes for capacitive deionization
journal, January 2013

Capacitive deionization with Ca-alginate coated-carbon electrode for hardness control
journal, August 2016

Using capacitive deionisation for inland brackish groundwater desalination in a remote location
journal, January 2013

Water desalination via capacitive deionization: what is it and what can we expect from it?
journal, January 2015

Graphene-containing flowable electrodes for capacitive energy storage
journal, October 2015

Tracking the structural arrangement of ions in carbon supercapacitor nanopores using in situ small-angle X-ray scattering
journal, January 2015

Two-Dimensional Porous Electrode Model for Capacitive Deionization
journal, October 2015

Three-Dimensional Graphene/Metal Oxide Nanoparticle Hybrids for High-Performance Capacitive Deionization of Saline Water
journal, August 2013

Capacitive deionization (CDI) for desalination and water treatment — past, present and future (a review)
journal, August 2008

Cell voltage versus electrode potential range in aqueous supercapacitors
journal, April 2015

Desalting by Means of Porous Carbon Electrodes
journal, January 1971

A control system for operating and investigating reactors: The demonstration of parasitic reactions in the water desalination by capacitive de-ionization
journal, March 2011

Capacitive Deionization of NaCl Solutions at Non-Steady-State Conditions: Inversion Functionality of the Carbon Electrodes
journal, August 2011

Electrode reactions and adsorption/desorption performance related to the applied potential in a capacitive deionization process
journal, August 2010

Desalination stability of capacitive deionization using ordered mesoporous carbon: Effect of oxygen-containing surface groups and pore properties
journal, November 2015

Surface charge enhanced carbon electrodes for stable and efficient capacitive deionization using inverted adsorption–desorption behavior
journal, January 2015

Around the thermodynamic limitations of supercapacitors operating in aqueous electrolytes
journal, July 2016

Design of graphene-coated hollow mesoporous carbon spheres as high performance electrodes for capacitive deionization
journal, January 2014

Side Reactions in Capacitive Deionization (CDI) Processes: The Role of Oxygen Reduction
journal, December 2016

The effect of the flow-regime, reversal of polarization, and oxygen on the long term stability in capacitive de-ionization processes
journal, January 2015

Investigation of oxygen reduction on activated carbon electrodes in alkaline solution
journal, May 2007

The Origins of Low Efficiency in Electrochemical De-Ionization Systems
journal, January 2016

Thermodynamic cycle analysis for capacitive deionization
journal, April 2009

Novel Graphene-Like Electrodes for Capacitive Deionization
journal, November 2010

Review on the science and technology of water desalination by capacitive deionization
journal, October 2013

Electrochemistry and capacitive charging of porous electrodes in asymmetric multicomponent electrolytes
journal, June 2012

Proton-selective electrode for pH sensing
journal, December 2016

Determination of the electrode potential causing Faradaic reactions in membrane capacitive deionization
journal, August 2014

A systematic study on the changes in properties of an activated carbon cloth upon polarization
journal, February 2011

Electrochemical Characterization of Activated Carbon-Fiber Cloth Polarizable Electrodes for Electric Double-Layer Capacitors
journal, January 1990

Limitation of Charge Efficiency in Capacitive Deionization
journal, January 2009

Examination of Water Electrolysis and Oxygen Reduction As Self-Discharge Mechanisms for Carbon-Based, Aqueous Electrolyte Electrochemical Capacitors
journal, February 2011

Capacitive Deionization using Biomass-based Microporous Salt-Templated Heteroatom-Doped Carbons
journal, May 2015

Asymmetric capacitive deionization utilizing nitric acid treated activated carbon fiber as the cathode
journal, September 2015

Surface-treated carbon electrodes with modified potential of zero charge for capacitive deionization
journal, April 2016

Electro-removal of arsenic(III) and arsenic(V) from aqueous solutions by capacitive deionization
journal, July 2016

The feasibility of boron removal from water by capacitive deionization
journal, July 2011

Pathways to low-cost electrochemical energy storage: a comparison of aqueous and nonaqueous flow batteries
journal, January 2014

On porous electrodes in electrolyte solutions
journal, October 1963

Complementary surface charge for enhanced capacitive deionization
journal, April 2016

Continuous operation of membrane capacitive deionization cells assembled with dissimilar potential of zero charge electrode pairs
journal, May 2015

Dependence of the Capacitive Deionization Performance on Potential of Zero Charge Shifting of Carbon Xerogel Electrodes during Long-Term Operation
journal, January 2014

Requirements for performance characterization of C double-layer supercapacitors: Applications to a high specific-area C-cloth material
journal, June 2006

Mechanistic insights into the use of oxide nanoparticles coated asymmetric electrodes for capacitive deionization
journal, February 2013

Comparison of salt adsorption capacity and energy consumption between constant current and constant voltage operation in capacitive deionization
journal, November 2014