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Title: Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments

Abstract

Not provided.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]
  1. UCSD-CNRS Joint Research Chemistry Laboratory, UMI 3555, Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla CA 92093-0358 USA
Publication Date:
Research Org.:
Univ. of California, San Diego, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1533103
DOE Contract Number:  
SC0009376
Resource Type:
Journal Article
Journal Name:
Angewandte Chemie (International Edition)
Additional Journal Information:
Journal Volume: 56; Journal Issue: 34; Journal ID: ISSN 1433-7851
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
Chemistry

Citation Formats

Melaimi, Mohand, Jazzar, Rodolphe, Soleilhavoup, Michèle, and Bertrand, Guy. Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments. United States: N. p., 2017. Web. doi:10.1002/anie.201702148.
Melaimi, Mohand, Jazzar, Rodolphe, Soleilhavoup, Michèle, & Bertrand, Guy. Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments. United States. doi:10.1002/anie.201702148.
Melaimi, Mohand, Jazzar, Rodolphe, Soleilhavoup, Michèle, and Bertrand, Guy. Mon . "Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments". United States. doi:10.1002/anie.201702148.
@article{osti_1533103,
title = {Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments},
author = {Melaimi, Mohand and Jazzar, Rodolphe and Soleilhavoup, Michèle and Bertrand, Guy},
abstractNote = {Not provided.},
doi = {10.1002/anie.201702148},
journal = {Angewandte Chemie (International Edition)},
issn = {1433-7851},
number = 34,
volume = 56,
place = {United States},
year = {2017},
month = {6}
}

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31 P NMR Chemical Shifts of Carbene-Phosphinidene Adducts as an Indicator of the π-Accepting Properties of Carbenes
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Determining the π-Acceptor Properties of N-Heterocyclic Carbenes by Measuring the 77 Se NMR Chemical Shifts of Their Selenium Adducts
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Organic Mixed-Valence Compounds: A Playground for Electrons and Holes
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Organische gemischtvalente Verbindungen: ein Spielplatz für Elektronen und Löcher
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Diradicals
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Tuning Ground States of Bis(triarylamine) Dications: From a Closed-Shell Singlet to a Diradicaloid with an Excited Triplet State
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Tuning Ground States of Bis(triarylamine) Dications: From a Closed-Shell Singlet to a Diradicaloid with an Excited Triplet State
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C 4 Cumulene and the Corresponding Air-Stable Radical Cation and Dication
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C 4 Cumulene and the Corresponding Air-Stable Radical Cation and Dication
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The Fate of NHC-Stabilized Dicarbon
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A Stable Silicon(0) Compound with a Si=Si Double Bond
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Formation of Trichlorosilyl-Substituted Carbon-Centered Stable Radicals through the Use of π-Accepting Carbenes
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Formation of Trichlorosilyl-Substituted Carbon-Centered Stable Radicals through the Use of π-Accepting Carbenes
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Synthesis and Characterization of a Triphenyl-Substituted Radical and an Unprecedented Formation of a Carbene-Functionalized Quinodimethane
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Carbene Supported Dimer of Heavier Ketenimine Analogue with P and Si Atoms
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Stable Radicals from Commonly Used Precursors Trichlorosilane and Diphenylchlorophosphine
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Carbene-Dichlorosilylene Stabilized Phosphinidenes Exhibiting Strong Intramolecular Charge Transfer Transition
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Experimental Charge Density Study of a Silylone
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Experimentelle Elektronendichteuntersuchung eines Silylons
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Electron-Induced Conversion of Silylones to Six-Membered Cyclic Silylenes
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Cyclic Alkyl(amino) Carbene Stabilized Biradical of Disilicontetrachloride
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Formation of a 1,4-Diamino-2,3-disila-1,3-butadiene Derivative
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One-Electron-Mediated Rearrangements of 2,3-Disiladicarbene
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A Triatomic Silicon(0) Cluster Stabilized by a Cyclic Alkyl(amino) Carbene
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A Triatomic Silicon(0) Cluster Stabilized by a Cyclic Alkyl(amino) Carbene
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Bonding situation in silicon complexes [(L) 2 (Si 2 )] and [(L) 2 (Si)] with NHC and cAAC ligands
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Lewis Base Stabilized Dicarbon: Predictions from Theory
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Lewis Base Stabilized Dicarbon: Predictions from Theory
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Stabilization of Heterodiatomic SiC Through Ligand Donation: Theoretical Investigation of SiC(L) 2 (L=NHC Me , CAAC Me , PMe 3 )
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Stabilisierung von heterodiatomarem SiC durch Donorliganden - theoretische Untersuchung von SiC(L) 2 (L=NHC Me , CAAC Me , PMe 3 )
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π-Bonding and the Lone Pair Effect in Multiple Bonds between Heavier Main Group Elements
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Synthesis of a Bent 2-Silaallene with a Perturbed Electronic Structure from a Cyclic Alkyl(amino) Carbene-Diiodosilylene
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A Stable Dimer of SiS 2 Arranged between Two Carbene Molecules
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A soluble molecular variant of the semiconducting silicondiselenide
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Carbene Activation of P4 and Subsequent Derivatization
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Carbene Activation of P4 and Subsequent Derivatization
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Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P4 cage and P8 clusters
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Nonmetal-Mediated Fragmentation of P 4 : Isolation of P 1 and P 2 Bis(carbene) Adducts
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Nonmetal-Mediated Fragmentation of P 4 : Isolation of P 1 and P 2 Bis(carbene) Adducts
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NHC-Mediated Aggregation of P 4 :  Isolation of a P 12 Cluster
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Isolation of a Neutral P 8 Cluster by [2+2] Cycloaddition of a Diphosphene Facilitated by Carbene Activation of White Phosphorus
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Isolation of a Neutral P 8 Cluster by [2+2] Cycloaddition of a Diphosphene Facilitated by Carbene Activation of White Phosphorus
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Interaction of PN with metal atoms in a krypton matrix
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Isolation of a Carbene-Stabilized Phosphorus Mononitride and Its Radical Cation (PN +. )
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Isolation of a Carbene-Stabilized Phosphorus Mononitride and Its Radical Cation (PN+.)
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Persistent and Stable Radicals of the Heavier Main Group Elements and Related Species
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The Complexed Triphosphaallyl Radical, Cation, and Anion Family
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Eine Familie mit komplexiertem Triphosphaallyl-Radikal, -Kation und -Anion
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Preparation and Characterization of an Air-Tolerant 1,3-Diphosphacyclobuten-4-yl Radical
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Preparation and Characterization of an Air-Tolerant 1,3-Diphosphacyclobuten-4-yl Radical
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An Isolable and Monomeric Phosphorus Radical That Is Resonance-Stabilized by the Vanadium(IV/V) Redox Couple
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An Isolable and Monomeric Phosphorus Radical That Is Resonance-Stabilized by the Vanadium(IV/V) Redox Couple
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N-Heterocyclic carbenes versus transition metals for stabilizing phosphinyl radicals
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Stable Cubic Phosphorus-Containing Radicals
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Stable Cubic Phosphorus-Containing Radicals
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A Crystalline Phosphinyl Radical Cation
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A Singlet Phosphinidene Stable at Room Temperature
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Singlet (Phosphino)phosphinidenes are Electrophilic
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Transition-Metal-like Behavior of Main Group Elements: Ligand Exchange at a Phosphinidene
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Carbene Stabilization of Diarsenic: From Hypervalency to Allotropy
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One-, Two-, and Three-Electron Reduction of a Cyclic Alkyl(amino)carbene-SbCl 3 Adduct
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Ein-, Zwei- und Drei-Elektronen-Reduktion eines CAAC-SbCl 3 - Addukts
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Persistent Antimony- and Bismuth-Centered Radicals in Solution
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Persistent Antimony- and Bismuth-Centered Radicals in Solution
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Elusive Antimony-Centered Radical Cations: Isolation, Characterization, Crystal Structures, and Reactivity Studies
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Elusive Antimony-Centered Radical Cations: Isolation, Characterization, Crystal Structures, and Reactivity Studies
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Facile Synthesis of Silver(I)−Carbene Complexes. Useful Carbene Transfer Agents
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A Cyclization-Rearrangement Cascade for the Synthesis of Structurally Complex Chiral Gold(I)-Aminocarbene Complexes
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Spectroscopic Evidence for a Monomeric Copper(I) Hydride and Crystallographic Characterization of a Monomeric Silver(I) Hydride
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Air-Stable (CAAC)CuCl and (CAAC)CuBH 4 Complexes as Catalysts for the Hydrolytic Dehydrogenation of BH 3 NH 3
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Trinuclear Gold Clusters Supported by Cyclic (alkyl)(amino)carbene Ligands: Mimics for Gold Heterogeneous Catalysts
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Trinuclear Gold Clusters Supported by Cyclic (alkyl)(amino)carbene Ligands: Mimics for Gold Heterogeneous Catalysts
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(Aminocarbene)(Divinyltetramethyldisiloxane)Iron(0) Compounds: A Class of Low-Coordinate Iron(0) Reagents
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