skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: A Plastic-Crystal Electrolyte Interphase for All-Solid-State Sodium Batteries


Not provided.

 [1];  [1];  [1];  [1]; ORCiD logo [1]
  1. Texas Materials Institute, The University of Texas at Austin, Austin TX 78712 USA
Publication Date:
Research Org.:
Univ. of Texas, Austin, TX (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
DOE Contract Number:  
Resource Type:
Journal Article
Journal Name:
Angewandte Chemie (International Edition)
Additional Journal Information:
Journal Volume: 56; Journal Issue: 20; Journal ID: ISSN 1433-7851
Country of Publication:
United States

Citation Formats

Gao, Hongcai, Xue, Leigang, Xin, Sen, Park, Kyusung, and Goodenough, John B. A Plastic-Crystal Electrolyte Interphase for All-Solid-State Sodium Batteries. United States: N. p., 2017. Web. doi:10.1002/anie.201702003.
Gao, Hongcai, Xue, Leigang, Xin, Sen, Park, Kyusung, & Goodenough, John B. A Plastic-Crystal Electrolyte Interphase for All-Solid-State Sodium Batteries. United States. doi:10.1002/anie.201702003.
Gao, Hongcai, Xue, Leigang, Xin, Sen, Park, Kyusung, and Goodenough, John B. Wed . "A Plastic-Crystal Electrolyte Interphase for All-Solid-State Sodium Batteries". United States. doi:10.1002/anie.201702003.
title = {A Plastic-Crystal Electrolyte Interphase for All-Solid-State Sodium Batteries},
author = {Gao, Hongcai and Xue, Leigang and Xin, Sen and Park, Kyusung and Goodenough, John B.},
abstractNote = {Not provided.},
doi = {10.1002/anie.201702003},
journal = {Angewandte Chemie (International Edition)},
issn = {1433-7851},
number = 20,
volume = 56,
place = {United States},
year = {2017},
month = {4}

Works referenced in this record:

Sodium and sodium-ion energy storage batteries
journal, August 2012

  • Ellis, Brian L.; Nazar, Linda F.
  • Current Opinion in Solid State and Materials Science, Vol. 16, Issue 4, p. 168-177
  • DOI: 10.1016/j.cossms.2012.04.002

Electrochemical energy storage in a sustainable modern society
journal, January 2014

Towards greener and more sustainable batteries for electrical energy storage
journal, November 2014

Electrochemical Nature of the Cathode Interface for a Solid-State Lithium-Ion Battery: Interface between LiCoO 2 and Garnet-Li 7 La 3 Zr 2 O 12
journal, October 2016

Impedance Characterization of Li Ion Transport at the Interface between Laminated Ceramic and Polymeric Electrolytes
journal, January 2012

  • Tenhaeff, W. E.; Perry, K. A.; Dudney, N. J.
  • Journal of The Electrochemical Society, Vol. 159, Issue 12
  • DOI: 10.1149/2.063212jes

Design principles for electrolytes and interfaces for stable lithium-metal batteries
journal, September 2016

Interface-Engineered All-Solid-State Li-Ion Batteries Based on Garnet-Type Fast Li + Conductors
journal, July 2016

  • van den Broek, Jan; Afyon, Semih; Rupp, Jennifer L. M.
  • Advanced Energy Materials, Vol. 6, Issue 19
  • DOI: 10.1002/aenm.201600736

Review—Solid Electrolytes in Rechargeable Electrochemical Cells
journal, January 2015

  • Goodenough, John B.; Singh, Preetam
  • Journal of The Electrochemical Society, Vol. 162, Issue 14
  • DOI: 10.1149/2.0021514jes

Development of Sulfide Solid Electrolytes and Interface Formation Processes for Bulk-Type All-Solid-State Li and Na Batteries
journal, July 2016

  • Hayashi, Akitoshi; Sakuda, Atsushi; Tatsumisago, Masahiro
  • Frontiers in Energy Research, Vol. 4
  • DOI: 10.3389/fenrg.2016.00025

Interfacial behaviours between lithium ion conductors and electrode materials in various battery systems
journal, January 2016

  • Wu, Bingbin; Wang, Shanyu; Evans IV, Willie J.
  • Journal of Materials Chemistry A, Vol. 4, Issue 40
  • DOI: 10.1039/C6TA05439K

Novel technique to form electrode–electrolyte nanointerface in all-solid-state rechargeable lithium batteries
journal, December 2008

Dielectric Modification of 5V-Class Cathodes for High-Voltage All-Solid-State Lithium Batteries
journal, March 2014

  • Yada, Chihiro; Ohmori, Akihiro; Ide, Kazuto
  • Advanced Energy Materials, Vol. 4, Issue 9
  • DOI: 10.1002/aenm.201301416

Solid state thin-film lithium battery systems
journal, October 1999

A hybrid solid electrolyte for flexible solid-state sodium batteries
journal, January 2015

  • Kim, Jae-Kwang; Lim, Young Jun; Kim, Hyojin
  • Energy & Environmental Science, Vol. 8, Issue 12
  • DOI: 10.1039/C5EE01941A

A ceramic/polymer composite solid electrolyte for sodium batteries
journal, January 2016

  • Zhang, Zhizhen; Zhang, Qiangqiang; Ren, Cheng
  • Journal of Materials Chemistry A, Vol. 4, Issue 41
  • DOI: 10.1039/C6TA07590H

A Battery Made from a Single Material
journal, April 2015

Application of quasi-solid-state silica nanoparticles–ionic liquid composite electrolytes to all-solid-state lithium secondary battery
journal, June 2012

Evaluation of the wetting time of porous electrodes in electrolytic solutions containing ionic liquid
journal, May 2013

  • Kühnel, Ruben-Simon; Obeidi, Shahmahmood; Lübke, Mechthild
  • Journal of Applied Electrochemistry, Vol. 43, Issue 7
  • DOI: 10.1007/s10800-013-0558-x

Static and dynamic wetting behaviour of ionic liquids
journal, August 2015

  • Delcheva, Iliana; Ralston, John; Beattie, David A.
  • Advances in Colloid and Interface Science, Vol. 222
  • DOI: 10.1016/j.cis.2014.07.003

The use of protic ionic liquids with cathodes for sodium-ion batteries
journal, January 2016

  • Vogl, T.; Vaalma, C.; Buchholz, D.
  • Journal of Materials Chemistry A, Vol. 4, Issue 27
  • DOI: 10.1039/C6TA02277D

Characterization of NaX (X: TFSI, FSI) – PEO based solid polymer electrolytes for sodium batteries
journal, September 2015

Enhanced electrochemical properties of PEO-based composite polymer electrolyte with shape-selective molecular sieves
journal, June 2006

Ionic conductivity in crystalline polymer electrolytes
journal, August 2001

  • Gadjourova, Zlatka; Andreev, Yuri G.; Tunstall, David P.
  • Nature, Vol. 412, Issue 6846
  • DOI: 10.1038/35087538

Relaxation dynamics and ionic conductivity in a fragile plastic crystal
journal, October 2010

  • Bauer, Th.; Köhler, M.; Lunkenheimer, P.
  • The Journal of Chemical Physics, Vol. 133, Issue 14
  • DOI: 10.1063/1.3487521

Phase Transitions in Plastic Crystals
journal, October 1962

Lithium-doped plastic crystal electrolytes exhibiting fast ion conduction for secondary batteries
journal, December 1999

  • MacFarlane, Douglas R.; Huang, Junhua; Forsyth, Maria
  • Nature, Vol. 402, Issue 6763
  • DOI: 10.1038/45514

The plastic-crystalline phase of succinonitrile as a universal matrix for solid-state ionic conductors
journal, June 2004

  • Alarco, Pierre-Jean; Abu-Lebdeh, Yaser; Abouimrane, Ali
  • Nature Materials, Vol. 3, Issue 7
  • DOI: 10.1038/nmat1158

An All-solid-state and All-organic Sodium-ion Battery based on Redox-active Polymers and Plastic Crystal Electrolyte
journal, October 2015

Interfacial Observation between LiCoO 2 Electrode and Li 2 S−P 2 S 5 Solid Electrolytes of All-Solid-State Lithium Secondary Batteries Using Transmission Electron Microscopy
journal, February 2010

  • Sakuda, Atsushi; Hayashi, Akitoshi; Tatsumisago, Masahiro
  • Chemistry of Materials, Vol. 22, Issue 3
  • DOI: 10.1021/cm901819c

Characterization of the interface between LiCoO2 and Li7La3Zr2O12 in an all-solid-state rechargeable lithium battery
journal, January 2011

In Situ STEM-EELS Observation of Nanoscale Interfacial Phenomena in All-Solid-State Batteries
journal, May 2016

Preparation and Electrical Properties of Dense Ceramics with NASICON Composition Sintered at Reduced Temperatures
journal, July 2004

Spark Plasma Sintering (SPS) of NASICON Ceramics
journal, February 2004

Fast Na+-ion transport in skeleton structures
journal, February 1976

In Situ Synthesis of a Hierarchical All-Solid-State Electrolyte Based on Nitrile Materials for High-Performance Lithium-Ion Batteries
journal, May 2015

  • Zhou, Dong; He, Yan-Bing; Liu, Ruliang
  • Advanced Energy Materials, Vol. 5, Issue 15
  • DOI: 10.1002/aenm.201500353

Preparation and performance of a non-ionic plastic crystal electrolyte with the addition of polymer for lithium ion batteries
journal, December 2013

Routes to High Energy Cathodes of Sodium-Ion Batteries
journal, December 2015

  • Fang, Chun; Huang, Yunhui; Zhang, Wuxing
  • Advanced Energy Materials, Vol. 6, Issue 5
  • DOI: 10.1002/aenm.201501727

Conductive Organic Plastic Crystals Based on Pyrazolium Imides
journal, September 2003

  • Abu-Lebdeh, Yaser; Alarco, Pierre-Jean; Armand, Michel
  • Angewandte Chemie International Edition, Vol. 42, Issue 37
  • DOI: 10.1002/anie.200250706

Conductive Organic Plastic Crystals Based on Pyrazolium Imides
journal, September 2003

  • Abu-Lebdeh, Yaser; Alarco, Pierre-Jean; Armand, Michel
  • Angewandte Chemie, Vol. 115, Issue 37
  • DOI: 10.1002/ange.200250706

A Sodium-Ion Battery with a Low-Cost Cross-Linked Gel-Polymer Electrolyte
journal, June 2016

  • Gao, Hongcai; Zhou, Weidong; Park, Kyusung
  • Advanced Energy Materials, Vol. 6, Issue 18
  • DOI: 10.1002/aenm.201600467

Superionic glass-ceramic electrolytes for room-temperature rechargeable sodium batteries
journal, January 2012

  • Hayashi, Akitoshi; Noi, Kousuke; Sakuda, Atsushi
  • Nature Communications, Vol. 3, Issue 1
  • DOI: 10.1038/ncomms1843

Hierarchical Carbon Framework Wrapped Na 3 V 2 (PO 4 ) 3 as a Superior High-Rate and Extended Lifespan Cathode for Sodium-Ion Batteries
journal, August 2015

Importance of Coulombic Efficiency Measurements in R&D Efforts to Obtain Long-Lived Li-Ion Batteries
journal, January 2016

  • Dahn, J. R.; Burns, J. C.; Stevens, D. A.
  • Interface magazine, Vol. 25, Issue 3
  • DOI: 10.1149/2.F07163if

Electrochemical performance of an all-solid-state lithium ion battery with garnet-type oxide electrolyte
journal, March 2012

Modification of Interface Between LiCoO[sub 2] Electrode and Li[sub 2]S–P[sub 2]S[sub 5] Solid Electrolyte Using Li[sub 2]O–SiO[sub 2] Glassy Layers
journal, January 2009

  • Sakuda, Atsushi; Kitaura, Hirokazu; Hayashi, Akitoshi
  • Journal of The Electrochemical Society, Vol. 156, Issue 1
  • DOI: 10.1149/1.3005972

Inorganic solid/organic liquid hybrid electrolyte for use in Li-ion battery
journal, September 2012

Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction
journal, December 2015

Investigation on diffusion behavior of Li+ in LiFePO4 by capacity intermittent titration technique (CITT)
journal, March 2009

Lithium-Ion Electrolytes Containing Ester Cosolvents for Improved Low Temperature Performance
journal, January 2010

  • Smart, M. C.; Ratnakumar, B. V.; Chin, K. B.
  • Journal of The Electrochemical Society, Vol. 157, Issue 12
  • DOI: 10.1149/1.3501236

Charge transfer kinetics at the solid–solid interface in porous electrodes
journal, April 2014

  • Bai, Peng; Bazant, Martin Z.
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4585

Electrochemical Polarization
journal, January 1957

  • Stern, M.; Geaby, A. L.
  • Journal of The Electrochemical Society, Vol. 104, Issue 1
  • DOI: 10.1149/1.2428496