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Title: Equatorial Ligand Perturbations Influence the Reactivity of Manganese(IV)-Oxo Complexes

Abstract

Not provided.

Authors:
 [1];  [1];  [1];  [1];  [2];  [1];  [2];  [1]
  1. Department of Chemistry, University of Kansas, Lawrence KS USA
  2. Chemical Physics, Department of Chemistry, Lund University, Box 124 22100 Lund Sweden
Publication Date:
Research Org.:
Univ. of Kansas, Lawrence, KS (United States); Stanford Univ., CA (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1533097
DOE Contract Number:  
SC0016359; AC02-76SF00515; SC0012704
Resource Type:
Journal Article
Journal Name:
Angewandte Chemie (International Edition)
Additional Journal Information:
Journal Volume: 56; Journal Issue: 15; Journal ID: ISSN 1433-7851
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
Chemistry

Citation Formats

Massie, Allyssa A., Denler, Melissa C., Cardoso, Luísa Thiara, Walker, Ashlie N., Hossain, M. Kamal, Day, Victor W., Nordlander, Ebbe, and Jackson, Timothy A. Equatorial Ligand Perturbations Influence the Reactivity of Manganese(IV)-Oxo Complexes. United States: N. p., 2017. Web. doi:10.1002/anie.201612309.
Massie, Allyssa A., Denler, Melissa C., Cardoso, Luísa Thiara, Walker, Ashlie N., Hossain, M. Kamal, Day, Victor W., Nordlander, Ebbe, & Jackson, Timothy A. Equatorial Ligand Perturbations Influence the Reactivity of Manganese(IV)-Oxo Complexes. United States. doi:10.1002/anie.201612309.
Massie, Allyssa A., Denler, Melissa C., Cardoso, Luísa Thiara, Walker, Ashlie N., Hossain, M. Kamal, Day, Victor W., Nordlander, Ebbe, and Jackson, Timothy A. Thu . "Equatorial Ligand Perturbations Influence the Reactivity of Manganese(IV)-Oxo Complexes". United States. doi:10.1002/anie.201612309.
@article{osti_1533097,
title = {Equatorial Ligand Perturbations Influence the Reactivity of Manganese(IV)-Oxo Complexes},
author = {Massie, Allyssa A. and Denler, Melissa C. and Cardoso, Luísa Thiara and Walker, Ashlie N. and Hossain, M. Kamal and Day, Victor W. and Nordlander, Ebbe and Jackson, Timothy A.},
abstractNote = {Not provided.},
doi = {10.1002/anie.201612309},
journal = {Angewandte Chemie (International Edition)},
issn = {1433-7851},
number = 15,
volume = 56,
place = {United States},
year = {2017},
month = {3}
}

Works referenced in this record:

Status of Reactive Non-Heme Metal–Oxygen Intermediates in Chemical and Enzymatic Reactions
journal, August 2014

  • Ray, Kallol; Pfaff, Florian Felix; Wang, Bin
  • Journal of the American Chemical Society, Vol. 136, Issue 40
  • DOI: 10.1021/ja507807v

A Balancing Act: Stability versus Reactivity of Mn(O) Complexes
journal, September 2015


Peroxo and oxo intermediates in mononuclear nonheme iron enzymes and related active sites
journal, February 2009

  • Solomon, Edward I.; Wong, Shaun D.; Liu, Lei V.
  • Current Opinion in Chemical Biology, Vol. 13, Issue 1
  • DOI: 10.1016/j.cbpa.2009.02.011

Lessons from nature: unraveling biological CH bond activation
journal, February 2009


Toward the Synthesis of More Reactive S = 2 Non-Heme Oxoiron(IV) Complexes
journal, July 2015


Reactive Intermediates in Cytochrome P450 Catalysis
journal, April 2013

  • Krest, Courtney M.; Onderko, Elizabeth L.; Yosca, Timothy H.
  • Journal of Biological Chemistry, Vol. 288, Issue 24
  • DOI: 10.1074/jbc.R113.473108

Manganese Catalyzed C–H Halogenation
journal, May 2015


Iron and Manganese Catalysts for the Selective Functionalization of Arene C(sp 2 )−H Bonds by Carbene Insertion
journal, April 2016

  • Conde, Ana; Sabenya, Gerard; Rodríguez, Mònica
  • Angewandte Chemie International Edition, Vol. 55, Issue 22
  • DOI: 10.1002/anie.201601750

Iron and Manganese Catalysts for the Selective Functionalization of Arene C(sp 2 )−H Bonds by Carbene Insertion
journal, April 2016

  • Conde, Ana; Sabenya, Gerard; Rodríguez, Mònica
  • Angewandte Chemie, Vol. 128, Issue 22
  • DOI: 10.1002/ange.201601750

Enantioselective Epoxidations of Olefins with Various Oxidants on Bioinspired Mn Complexes: Evidence for Different Mechanisms and Chiral Additive Amplification
journal, January 2016

  • Ottenbacher, Roman V.; Samsonenko, Denis G.; Talsi, Evgenii P.
  • ACS Catalysis, Vol. 6, Issue 2
  • DOI: 10.1021/acscatal.5b02299

Bioinspired oxidations of aliphatic C–H groups with H2O2 in the presence of manganese complexes
journal, September 2015


Metal complex assembly controlled by surface ligand distribution on mesoporous silica: Quantification using refractive index matching and impact on catalysis
journal, March 2016

  • Smith, Brian J.; Hernández Gallegos, Pedro A.; Butsch, Katharina
  • Journal of Catalysis, Vol. 335
  • DOI: 10.1016/j.jcat.2015.11.008

Oxidative Reactivity Difference among the Metal Oxo and Metal Hydroxo Moieties: pH Dependent Hydrogen Abstraction by a Manganese(IV) Complex Having Two Hydroxide Ligands
journal, December 2008

  • Yin, Guochuan; Danby, Andrew M.; Kitko, David
  • Journal of the American Chemical Society, Vol. 130, Issue 48
  • DOI: 10.1021/ja804305x

Evidence for a Precursor Complex in CH Hydrogen Atom Transfer Reactions Mediated by a Manganese(IV) Oxo Complex
journal, April 2011

  • Garcia-Bosch, Isaac; Company, Anna; Cady, Clyde W.
  • Angewandte Chemie International Edition, Vol. 50, Issue 25
  • DOI: 10.1002/anie.201100907

Evidence for a Precursor Complex in CH Hydrogen Atom Transfer Reactions Mediated by a Manganese(IV) Oxo Complex
journal, April 2011

  • Garcia-Bosch, Isaac; Company, Anna; Cady, Clyde W.
  • Angewandte Chemie, Vol. 123, Issue 25
  • DOI: 10.1002/ange.201100907

A Highly Reactive Mononuclear Non-Heme Manganese(IV)–Oxo Complex That Can Activate the Strong C–H Bonds of Alkanes
journal, December 2011

  • Wu, Xiujuan; Seo, Mi Sook; Davis, Katherine M.
  • Journal of the American Chemical Society, Vol. 133, Issue 50
  • DOI: 10.1021/ja208523u

A Mononuclear Non-Heme Manganese(IV)–Oxo Complex Binding Redox-Inactive Metal Ions
journal, January 2013

  • Chen, Junying; Lee, Yong-Min; Davis, Katherine M.
  • Journal of the American Chemical Society, Vol. 135, Issue 17
  • DOI: 10.1021/ja312113p

Spectroscopic properties and reactivity of a mononuclear oxomanganese(iv) complex
journal, January 2013

  • Leto, Domenick F.; Ingram, Rena; Day, Victor W.
  • Chemical Communications, Vol. 49, Issue 47
  • DOI: 10.1039/c3cc00244f

Mononuclear nonheme iron( iv )–oxo and manganese( iv )–oxo complexes in oxidation reactions: experimental results prove theoretical prediction
journal, January 2015

  • Chen, Junying; Cho, Kyung-Bin; Lee, Yong-Min
  • Chemical Communications, Vol. 51, Issue 66
  • DOI: 10.1039/C5CC04217H

Theoretical Investigations into C–H Bond Activation Reaction by Nonheme Mn IV O Complexes: Multistate Reactivity with No Oxygen Rebound
journal, September 2012

  • Cho, Kyung-Bin; Shaik, Sason; Nam, Wonwoo
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 19
  • DOI: 10.1021/jz301241z

Factors Controlling the Chemoselectivity in the Oxidation of Olefins by Nonheme Manganese(IV)-Oxo Complexes
journal, August 2016

  • Kim, Surin; Cho, Kyung-Bin; Lee, Yong-Min
  • Journal of the American Chemical Society, Vol. 138, Issue 33
  • DOI: 10.1021/jacs.6b06252

Spectroscopic and Computational Investigations of a Mononuclear Manganese(IV)-Oxo Complex Reveal Electronic Structure Contributions to Reactivity
journal, November 2016

  • Leto, Domenick F.; Massie, Allyssa A.; Rice, Derek B.
  • Journal of the American Chemical Society, Vol. 138, Issue 47
  • DOI: 10.1021/jacs.6b08661

Mechanistic elucidation of C–H oxidation by electron rich non-heme iron( iv )–oxo at room temperature
journal, January 2015

  • Rana, Sujoy; Dey, Aniruddha; Maiti, Debabrata
  • Chemical Communications, Vol. 51, Issue 77
  • DOI: 10.1039/C5CC04803F

The pentadentate ligands 2PyN2Q and N4Py, and their Cu(II) and Zn(II) complexes: A synthetic, spectroscopic and crystallographic structural study
journal, February 2015


Origin of the Zero-Field Splitting in Mononuclear Octahedral Mn IV Complexes: A Combined Experimental and Theoretical Investigation
journal, January 2016


C−H Bond Cleavage with Reductants: Re-Investigating the Reactivity of Monomeric Mn III/IV −Oxo Complexes and the Role of Oxo Ligand Basicity
journal, March 2009

  • Parsell, Trenton H.; Yang, Meng-Yin; Borovik, A. S.
  • Journal of the American Chemical Society, Vol. 131, Issue 8
  • DOI: 10.1021/ja8100825

Evidence for an Alternative to the Oxygen Rebound Mechanism in C–H Bond Activation by Non-Heme Fe IV O Complexes
journal, December 2012

  • Cho, Kyung-Bin; Wu, Xiujuan; Lee, Yong-Min
  • Journal of the American Chemical Society, Vol. 134, Issue 50
  • DOI: 10.1021/ja308290r

To rebound or dissociate? This is the mechanistic question in C–H hydroxylation by heme and nonheme metal–oxo complexes
journal, January 2016

  • Cho, Kyung-Bin; Hirao, Hajime; Shaik, Sason
  • Chemical Society Reviews, Vol. 45, Issue 5
  • DOI: 10.1039/C5CS00566C

Preparation and Properties of a Monomeric Mn IV −Oxo Complex
journal, July 2006

  • Parsell, Trenton H.; Behan, Rachel K.; Green, Michael T.
  • Journal of the American Chemical Society, Vol. 128, Issue 27
  • DOI: 10.1021/ja062332v

A nonheme manganese( iv )–oxo species generated in photocatalytic reaction using water as an oxygen source
journal, January 2015

  • Wu, Xiujuan; Yang, Xiaonan; Lee, Yong-Min
  • Chemical Communications, Vol. 51, Issue 19
  • DOI: 10.1039/C4CC10411K

Hydrogen-Atom Abstraction Reactions by Manganese(V)- and Manganese(IV)-Oxo Porphyrin Complexes in Aqueous Solution
journal, October 2009

  • Arunkumar, Chellaiah; Lee, Yong-Min; Lee, Jung Yoon
  • Chemistry - A European Journal, Vol. 15, Issue 43
  • DOI: 10.1002/chem.200901362

Modeling TauD- J : A High-Spin Nonheme Oxoiron(IV) Complex with High Reactivity toward C–H Bonds
journal, February 2015

  • Biswas, Achintesh N.; Puri, Mayank; Meier, Katlyn K.
  • Journal of the American Chemical Society, Vol. 137, Issue 7
  • DOI: 10.1021/ja511757j