skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: 1D Co- and N-Doped Hierarchically Porous Carbon Nanotubes Derived from Bimetallic Metal Organic Framework for Efficient Oxygen and Tri-iodide Reduction Reactions

Journal Article · · Advanced Energy Materials
 [1];  [1];  [1]
  1. Univ. of Texas, Austin, TX (United States). Materials Science and Engineering Program. Texas Materials Inst.

Hierarchically porous Co- and N-doped carbon nanotubes are designed as highly efficient electrocatalysts for both oxygen and tri-iodide reduction reactions via a dual-template synthesis approach. Bimetallic Zn/Co-based-zeolitic imidazolate frameworks coated on tellurium nanotubes are pyrolyzed, generating a structure with high surface area, hierarchical pore structure, abundant Co–Nx active sites, and a 1D tubular graphitic carbon framework.

Research Organization:
Univ. of Texas, Austin, TX (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0005397
OSTI ID:
1533072
Journal Information:
Advanced Energy Materials, Vol. 7, Issue 7; ISSN 1614-6832
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 177 works
Citation information provided by
Web of Science

References (44)

3D Nitrogen-Doped Graphene Aerogel-Supported Fe 3 O 4 Nanoparticles as Efficient Electrocatalysts for the Oxygen Reduction Reaction journal May 2012
Catalysis Research of Relevance to Carbon Management:  Progress, Challenges, and Opportunities journal April 2001
Low-cost dye-sensitized solar cell based on nine kinds of carbon counter electrodes journal January 2011
Atomic cobalt on nitrogen-doped graphene for hydrogen generation journal October 2015
Functionalized Graphene as a Catalytic Counter Electrode in Dye-Sensitized Solar Cells journal October 2010
Nitrogen-Doped Carbon Nanotube Arrays with High Electrocatalytic Activity for Oxygen Reduction journal February 2009
A metal–organic framework route to in situ encapsulation of Co@Co 3 O 4 @C core@bishell nanoparticles into a highly ordered porous carbon matrix for oxygen reduction journal January 2015
(Fe,Co)@nitrogen-doped graphitic carbon nanocubes derived from polydopamine-encapsulated metal–organic frameworks as a highly stable and selective non-precious oxygen reduction electrocatalyst journal January 2015
A metal–organic framework-derived bifunctional oxygen electrocatalyst journal January 2016
Boron-Doped Carbon Nanotubes as Metal-Free Electrocatalysts for the Oxygen Reduction Reaction journal June 2011
Heterometal-Embedded Organic Conjugate Frameworks from Alternating Monomeric Iron and Cobalt Metalloporphyrins and Their Application in Design of Porous Carbon Catalysts journal April 2015
Bimetallic Metal-Organic Frameworks for Controlled Catalytic Graphitization of Nanoporous Carbons journal July 2016
Nitrogen-Doped Graphene as Efficient Metal-Free Electrocatalyst for Oxygen Reduction in Fuel Cells journal February 2010
High-Loading Cobalt Oxide Coupled with Nitrogen-Doped Graphene for Oxygen Reduction in Anion-Exchange-Membrane Alkaline Fuel Cells journal April 2013
Highly Efficient Dye-Sensitized Solar Cells Based on Carbon Black Counter Electrodes journal January 2006
Sulfur and Nitrogen Dual-Doped Mesoporous Graphene Electrocatalyst for Oxygen Reduction with Synergistically Enhanced Performance journal October 2012
Nitrogen-Doped Graphene Foams as Metal-Free Counter Electrodes in High-Performance Dye-Sensitized Solar Cells journal November 2012
Synthesis of Uniform Te@Carbon-Rich Composite Nanocables with Photoluminescence Properties and Carbonaceous Nanofibers by the Hydrothermal Carbonization of Glucose journal April 2006
A class of non-precious metal composite catalysts for fuel cells journal September 2006
Nitrogen-Enriched Core-Shell Structured Fe/Fe3C-C Nanorods as Advanced Electrocatalysts for Oxygen Reduction Reaction journal February 2012
An Advanced Nitrogen-Doped Graphene/Cobalt-Embedded Porous Carbon Polyhedron Hybrid for Efficient Catalysis of Oxygen Reduction and Water Splitting journal December 2014
All-carbon-nanofiber electrodes for high-energy rechargeable Li–O2 batteries journal January 2011
High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt journal April 2011
A quasi core–shell nitrogen-doped graphene/cobalt sulfide conductive catalyst for highly efficient dye-sensitized solar cells journal January 2014
Nitrogen-Doped Nanoporous Carbon/Graphene Nano-Sandwiches: Synthesis and Application for Efficient Oxygen Reduction journal August 2015
Li−Air Rechargeable Battery Based on Metal-free Graphene Nanosheet Catalysts journal April 2011
High-Yield Synthesis, Controllable Evolution, and Thermoelectric Properties of Te/Bi2Te3 Heterostructure Nanostrings journal February 2015
A Graphene Composite Material with Single Cobalt Active Sites: A Highly Efficient Counter Electrode for Dye-Sensitized Solar Cells journal April 2016
Can Boron and Nitrogen Co-doping Improve Oxygen Reduction Reaction Activity of Carbon Nanotubes? journal January 2013
Graphene Oxide Gel-Derived, Free-Standing, Hierarchically Porous Carbon for High-Capacity and High-Rate Rechargeable Li-O2 Batteries journal May 2012
Switching effective oxygen reduction and evolution performance by controlled graphitization of a cobalt–nitrogen–carbon framework system journal January 2016
Opening of Bottleneck Pores for the Improvement of Nitrogen Doped Carbon Electrocatalysts journal January 2016
Podlike N-Doped Carbon Nanotubes Encapsulating FeNi Alloy Nanoparticles: High-Performance Counter Electrode Materials for Dye-Sensitized Solar Cells journal May 2014
Nanowire-Directed Templating Synthesis of Metal–Organic Framework Nanofibers and Their Derived Porous Doped Carbon Nanofibers for Enhanced Electrocatalysis journal October 2014
Iron-Based Catalysts with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel Cells journal April 2009
Nitrogen-doped porous carbon derived from a bimetallic metal–organic framework as highly efficient electrodes for flow-through deionization capacitors journal January 2016
Metal Nanoparticles and Related Materials Supported on Carbon Nanotubes: Methods and Applications journal February 2006
From Bimetallic Metal-Organic Framework to Porous Carbon: High Surface Area and Multicomponent Active Dopants for Excellent Electrocatalysis journal July 2015
Directed Growth of Metal-Organic Frameworks and Their Derived Carbon-Based Network for Efficient Electrocatalytic Oxygen Reduction journal January 2016
Metal–organic-framework-engaged formation of Co nanoparticle-embedded carbon@Co 9 S 8 double-shelled nanocages for efficient oxygen reduction journal January 2016
Well-Dispersed ZIF-Derived Co,N-Co-doped Carbon Nanoframes through Mesoporous-Silica-Protected Calcination as Efficient Oxygen Reduction Electrocatalysts journal December 2015
A Graphene Composite Material with Single Cobalt Active Sites: A Highly Efficient Counter Electrode for Dye-Sensitized Solar Cells journal April 2016
Nitrogen-Doped Graphene Foams as Metal-Free Counter Electrodes in High-Performance Dye-Sensitized Solar Cells journal November 2012
Sulfur and Nitrogen Dual-Doped Mesoporous Graphene Electrocatalyst for Oxygen Reduction with Synergistically Enhanced Performance journal October 2012

Cited By (46)

2D Nitrogen‐Doped Carbon Nanotubes/Graphene Hybrid as Bifunctional Oxygen Electrocatalyst for Long‐Life Rechargeable Zn–Air Batteries journal November 2019
Applications of Metal–Organic‐Framework‐Derived Carbon Materials journal December 2018
Atomic‐ and Molecular‐Level Design of Functional Metal–Organic Frameworks (MOFs) and Derivatives for Energy and Environmental Applications journal August 2019
General Dimension-Controlled Synthesis of Hollow Carbon Embedded with Metal Singe Atoms or Core-Shell Nanoparticles for Energy Storage Applications journal August 2018
Recent Development of Zeolitic Imidazolate Frameworks (ZIFs) Derived Porous Carbon Based Materials as Electrocatalysts journal July 2018
Rational Design of Dodecahedral MnCo 2 O 4.5 Hollowed-Out Nanocages as Efficient Bifunctional Electrocatalysts for Oxygen Reduction and Evolution journal October 2018
Multidimensional Ordered Bifunctional Air Electrode Enables Flash Reactants Shuttling for High‐Energy Flexible Zn‐Air Batteries journal May 2019
Atomar dispergierte Metallzentren in Metall-organischen Gerüststrukturen für die elektrokatalytische und photokatalytische Energieumwandlung journal June 2018
Atomically Dispersed Metal Sites in MOF-Based Materials for Electrocatalytic and Photocatalytic Energy Conversion journal June 2018
Recent Progress of Carbon-Based Materials in Oxygen Reduction Reaction Catalysis journal January 2018
Impact of Textural Properties of Mesoporous Porphyrinic Carbon Electrocatalysts on Oxygen Reduction Reaction Activity journal April 2018
Bimetal/Metal Oxide Encapsulated in Graphitic Nitrogen Doped Mesoporous Carbon Networks for Enhanced Oxygen Electrocatalysis journal January 2019
Metal–Organic Frameworks‐Derived Mesoporous Si/SiO x @NC Nanospheres as a Long‐Lifespan Anode Material for Lithium‐Ion Batteries journal August 2019
Cobalt Oxide Nanoparticles Embedded in N‐Doped Porous Carbon as an Efficient Electrode for Supercapacitor journal March 2019
Hierarchically Porous Co and N-Codoped Carbon Hollow Structure Derived from PS@ZIF-67 as an Electrocatalyst for Oxygen Reduction journal May 2018
Well‐Defined Cobalt Catalyst with N‐Doped Carbon Layers Enwrapping: The Correlation between Surface Atomic Structure and Electrocatalytic Property journal December 2017
Active Sites Engineering toward Superior Carbon-Based Oxygen Reduction Catalysts via Confinement Pyrolysis journal April 2018
ZIF-8/ZIF-67-Derived Co-N x -Embedded 1D Porous Carbon Nanofibers with Graphitic Carbon-Encased Co Nanoparticles as an Efficient Bifunctional Electrocatalyst journal May 2018
Recent Advances for MOF‐Derived Carbon‐Supported Single‐Atom Catalysts journal February 2019
Rational Microstructure Design on Metal–Organic Framework Composites for Better Electrochemical Performances: Design Principle, Synthetic Strategy, and Promotion Mechanism journal January 2020
Rational Design of LaNiO 3 /Carbon Composites as Outstanding Platinum-Free Photocathodes in Dye-Sensitized Solar Cells With Enhanced Catalysis for the Triiodide Reduction Reaction journal June 2017
An Intrinsically Conductive Phosphorus‐Doped Perovskite Oxide as a New Cathode for High‐Performance Dye‐Sensitized Solar Cells by Providing Internal Conducting Pathways journal May 2019
Electronic Structures and Catalytic Activities of Niobium Oxides as Electrocatalysts in Liquid‐Junction Photovoltaic Devices journal November 2019
Strategies for Enhancing the Electrocatalytic Activity of M–N/C Catalysts for the Oxygen Reduction Reaction journal May 2018
Metal-organic framework based nanomaterials for electrocatalytic oxygen redox reaction journal March 2019
Metal organic frameworks derived single atom catalysts for electrocatalytic energy conversion journal March 2019
An easy synthesis of Ni-Co doped hollow C-N tubular nanocomposites as excellent cathodic catalysts of alkaline and neutral zinc-air batteries journal May 2019
Rationally designed bimetallic Au@Pt nanoparticles for glucose oxidation journal January 2019
Design and synthesis of Co–N–C porous catalyst derived from metal organic complexes for highly effective ORR journal January 2017
Co–VN encapsulated in bamboo-like N-doped carbon nanotubes for ultrahigh-stability of oxygen reduction reaction journal January 2018
In situ directional formation of Co@CoO x -embedded 1D carbon nanotubes as an efficient oxygen electrocatalyst for ultra-high rate Zn–air batteries journal January 2017
MOF-derived nanohybrids for electrocatalysis and energy storage: current status and perspectives journal January 2018
Electronic structure engineering to boost oxygen reduction activity by controlling the coordination of the central metal journal January 2018
Unveiling dual-linkage 3D hexaiminobenzene metal–organic frameworks towards long-lasting advanced reversible Zn–air batteries journal January 2019
Metal–organic framework-derived one-dimensional porous or hollow carbon-based nanofibers for energy storage and conversion journal January 2018
1D N-doped hierarchically porous hollow carbon tubes derived from a supramolecular template as metal-free electrocatalysts for a highly efficient oxygen reduction reaction journal January 2018
Bifunctional electrocatalysts of MOF-derived Co–N/C on bamboo-like MnO nanowires for high-performance liquid- and solid-state Zn–air batteries journal January 2018
From a ZIF-8 polyhedron to three-dimensional nitrogen doped hierarchical porous carbon: an efficient electrocatalyst for the oxygen reduction reaction journal January 2018
Cu x S nanoparticle@carbon nanorod composites prepared from metal–organic frameworks as efficient electrode catalysts for quantum dot sensitized solar cells journal January 2019
Metal–organic frameworks: a promising platform for constructing non-noble electrocatalysts for the oxygen-reduction reaction journal January 2019
The integration of Mo 2 C-embedded nitrogen-doped carbon with Co encapsulated in nitrogen-doped graphene layers derived from metal–organic-frameworks as a multi-functional electrocatalyst journal January 2019
Cu and Co nanoparticle-Co-decorated N-doped graphene nanosheets: a high efficiency bifunctional electrocatalyst for rechargeable Zn–air batteries journal January 2019
Enhancing the triiodide reduction activity of a perovskite-based electrocatalyst for dye-sensitized solar cells through exsolved silver nanoparticles journal January 2019
Novel folic acid complex derived nitrogen and nickel co-doped carbon nanotubes with embedded Ni nanoparticles as efficient electrocatalysts for CO 2 reduction journal January 2020
Cuprum Metal-Organic-Framework and Polyacrylonitrile-Derived Cu-N-C Electrocatalyst for Application in Zinc-Air Batteries journal January 2020
An Intrinsically Conductive Phosphorus‐Doped Perovskite Oxide as a New Cathode for High‐Performance Dye‐Sensitized Solar Cells by Providing Internal Conducting Pathways journal May 2019