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Platinum nickel catalyst alloy

Patent ·
OSTI ID:1531878

A Pt--Ni catalyst is provided which demonstrates an unusually high oxygen reduction mass activity. In some embodiments, the Pt--Ni catalyst is a Pt--Ni binary alloy. In some embodiments, the catalyst may be characterized as having a Pt fcc lattice parameter of less than 3.71 Angstroms or 0.371 nm. In some embodiments the catalyst has a Pt fcc lattice parameter of between 3.69 Angstroms (or 0.369 nm) and 3.73 Angstroms (or 0.373 nm). In some embodiments, the catalyst may be characterized as having a composition of close to Pt.sub.xNi.sub.(1-x), where x is between 0.2 and 0.4. In some embodiments the catalyst comprises nanostructured elements comprising microstructured support whiskers bearing a thin film of nanoscopic catalyst particles comprising a catalyst material described above. The catalyst may be particularly useful as a fuel cell catalyst and more specifically as a fuel cell cathode catalyst.

Research Organization:
3M Innovative Properties Company, St. Paul, MN (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG36-07GO17007
Assignee:
3M Innovative Properties Company (St. Paul, MN)
Patent Number(s):
8,557,484
Application Number:
13/643,353
OSTI ID:
1531878
Country of Publication:
United States
Language:
English

References (30)

Studies of Transition Metal Dissolution from Combinatorially Sputtered, Nanostructured Pt[sub 1−x]M[sub x] (M = Fe, Ni; 0 journal January 2005
Water flow in the gas diffusion layer of PEM fuel cells journal September 2005
Influence of Bi Modification of Pt Anode Catalyst in Direct Formic Acid Fuel Cells journal April 2006
Improved Preparation Process of Very-Low-Platinum-Loading Electrodes for Polymer Electrolyte Fuel Cells journal January 1998
Preparation and electrocatalytic properties of Pt–SiO2 nanocatalysts for ethanol electrooxidation journal March 2007
Compositional Control in Electrodeposited Ni[sub x]Pt[sub 1−x] Films journal January 2008
An investigation of high temperature thermodynamic properties in the Pt-Zr and Pt-Hf systems journal March 1977
Nanostructured Pt-alloy electrocatalysts for PEM fuel cell oxygen reduction reaction journal January 2010
Carbon-Supported Pt−Co Catalysts Prepared by a Modified Polyol Process as Cathodes for PEM Fuel Cells journal February 2007
The inclusion of Mo, Nb and Ta in Pt and PtRu carbon supported electrocatalysts in the quest for improved CO tolerant PEMFC anodes journal November 2002
Thin film Pt/TiO2 catalysts for the polymer electrolyte fuel cell journal January 2007
Electrochemical characteristics of Pt–WO3/C and Pt–TiO2/C electrocatalysts in a polymer electrolyte fuel cell journal December 2001
CO Tolerance of Pt alloy electrocatalysts for polymer electrolyte fuel cells and the detoxification mechanism journal January 2001
Binary systems of platinum and a second metal as oxidation catalysts for methanol fuel cells journal November 1976
Pt-, PtNi- and PtCo-supported catalysts for oxygen reduction in PEM fuel cells journal October 2006
Development of anode catalysts for a direct ethanol fuel cell journal April 2004
Extraordinary Oxygen Reduction Activity of Pt3Ni7 journal January 2011
Study of silica supported PtxNi1-x catalysts by ion scattering spectroscopy journal March 1997
Economical Sputtering System To Produce Large-Size Composition-Spread Libraries Having Linear and Orthogonal Stoichiometry Variations journal August 2002
Dissolution of Transition Metals in Combinatorially Sputtered Pt[sub 1−x−y]M[sub x]M[sub y][sup ʹ] (M, M[sup ʹ]=Co, Ni, Mn, Fe) PEMFC Electrocatalysts journal January 2006
Methanol tolerant oxygen-reduction activity of carbon supported platinum–bismuth bimetallic nanoparticles journal July 2008
Thermal morphological evolution of platinum nano-particles in Pt–Al2O3 nano-composites journal August 2005
Electrochemical oxidation of ethanol on Pt–ZrO2/C catalyst journal November 2005
Designer platinum nanoparticles: Control of shape, composition in alloy, nanostructure and electrocatalytic property journal April 2009
PtxNi1−x nanoparticles as catalysts for hydrogen generation from hydrolysis of ammonia borane journal November 2009
Characterization of Pt-Cu binary catalysts for oxygen reduction for fuel cell applications journal December 2006
Characterization of PEMFCs gas diffusion layers properties journal May 2006
Oxygen Reduction Kinetics on Electrodeposited Pt, Pt100 − xNix, and Pt100 − xCox journal January 2009
Study of the oxygen electroreduction at nanostructured PtBi catalysts in alkaline medium journal March 2008
PtxNi alloy nanoparticles as cathode catalyst for PEM fuel cells with enhanced catalytic activity journal November 2009

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