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Nanosegregated surfaces as catalysts for fuel cells

Patent ·
OSTI ID:1531669
A method of preparing a nanosegregated Pt alloy having enhanced catalytic properties. The method includes providing a sample of Pt and one or more of a transition metal in a substantially inert environment, and annealing the sample in such an environment for a period of time and at a temperature profile to form a nanosegregated Pt alloy having a Pt-skin on a surface. The resulting alloy is characterized by a plurality of compositionally oscillatory atomic layers resulting in an advantageous electronic structure with enhanced catalytic properties.
Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-06CH11357; W-31109-ENG-38
Assignee:
UChicago Argonne, LLC (Chicago, IL)
Patent Number(s):
7,871,738
Application Number:
12/338,736
OSTI ID:
1531669
Country of Publication:
United States
Language:
English

References (17)

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E LECTRONIC S TRUCTURE AND C ATALYSIS ON M ETAL S URFACES journal October 2002
Oxygen reduction on high surface area Pt-based alloy catalysts in comparison to well defined smooth bulk alloy electrodes journal August 2002
Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces journal February 2007
Bimetallic Surface Chemistry journal October 1990
Effect of Surface Composition on Electronic Structure, Stability, and Electrocatalytic Properties of Pt-Transition Metal Alloys:  Pt-Skin versus Pt-Skeleton Surfaces journal July 2006
Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs journal March 2005
Changing the Activity of Electrocatalysts for Oxygen Reduction by Tuning the Surface Electronic Structure journal April 2006
Improved Oxygen Reduction Activity on Pt3Ni(111) via Increased Surface Site Availability journal January 2007
Monodisperse FePt Nanoparticles and Ferromagnetic FePt Nanocrystal Superlattices journal March 2000
Near-surface alloys for hydrogen fuel cell applications journal January 2006
Electrochemical dissolution of surface alloys in acids: Thermodynamic trends from first-principles calculations journal May 2007
Oxygen Reduction on Carbon-Supported Pt−Ni and Pt−Co Alloy Catalysts journal April 2002
Theoretical surface science and catalysis—calculations and concepts book January 2000
A General Approach to the Size- and Shape-Controlled Synthesis of Platinum Nanoparticles and Their Catalytic Reduction of Oxygen journal April 2008
Mechanisms for the Shape-Control and Shape-Evolution of Colloidal Semiconductor Nanocrystals journal March 2003
Structural characteristics of a uniquely nanostructured organic thin film
  • Debe, M. K.; Drube, A. R.
  • Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 13, Issue 3, Article No. 1236 https://doi.org/10.1116/1.588243
journal May 1995

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