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Fuel cell cathode catalyst

Patent ·
OSTI ID:1531563

A fuel cell cathode catalyst is provided which comprises nanostructured elements comprising microstructured support whiskers bearing nanoscopic catalyst particles. The nanoscopic catalyst particles are made by the alternating application of first and second layers, the first layer comprising platinum and the second layer being an alloy or intimate mixture of iron and a second metal selected from the group consisting of Group VIb metals, Group VIIb metals and Group VIIIb metals other than platinum and iron, where the atomic ratio of iron to the second metal in the second layer is between 0 and 10, where the planar equivalent thickness ratio of the first layer to the second layer is between 0.3 and 5, and wherein the average bilayer planar equivalent thickness of the first and second layers is less than 100 Å.

Research Organization:
3M Innovative Properties Company, Saint Paul, MN (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FC02-99EE50582
Assignee:
3M Innovative Properties Company (Saint Paul, MN)
Patent Number(s):
7,419,741
Application Number:
10/674,594
OSTI ID:
1531563
Country of Publication:
United States
Language:
English

References (16)

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Fabrication of thin films with highly porous microstructures
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journal May 1995
High Throughput Experimental and Theoretical Predictive Screening of Materials − A Comparative Study of Search Strategies for New Fuel Cell Anode Catalysts journal October 2003
Vacuum vapor deposited thin films of a perylene dicarboximide derivative: Microstructure versus deposition parameters journal May 1988
Oxygen reduction on high surface area Pt-based alloy catalysts in comparison to well defined smooth bulk alloy electrodes journal August 2002
Fabrication of biologically based microstructure composites for vacuum field emission journal October 1992
Investigation of Ternary Catalysts for Methanol Electrooxidation journal January 2001
Effects of morphology on NO2 detection in air at room temperature with phthalocyanine thin films journal December 1990
Oxygen Reduction Reaction on Pt and Pt Bimetallic Surfaces: A Selective Review journal July 2001
Oxygen Reduction on Carbon-Supported Pt−Ni and Pt−Co Alloy Catalysts journal April 2002
An XPS study on binary and ternary alloys of transition metals with platinized carbon and its bearing upon oxygen electroreduction in direct methanol fuel cells journal May 2001
Summary Abstract: Dramatic variation of the physical microstructure of a vapor deposited organic thin film
  • Kam, K. K.; Debe, M. K.; Poirier, R. J.
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 5, Issue 4 https://doi.org/10.1116/1.574490
journal July 1987
Effect of gravity on copper phthalocyanine thin films III: Microstructure comparisons of copper phthalocyanine thin films grown in microgravity and unit gravity journal May 1990
First thin film realization of a helicoidal bianisotropic medium
  • Robbie, Kevin; Brett, Michael J.; Lakhtakia, Akhlesh
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 13, Issue 6 https://doi.org/10.1116/1.579626
journal November 1995
Ion‐bombardment‐induced whisker formation on graphite
  • Floro, J. A.; Rossnagel, S. M.; Robinson, R. S.
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 1, Issue 3 https://doi.org/10.1116/1.572029
journal July 1983
Enhanced electrocatalysis of oxygen reduction on platinum alloys in proton exchange membrane fuel cells journal October 1993

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