Recent advances in chemical dearomatization of nonactivated arenes
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January 2018 |
Catalytic Asymmetric Dearomatization Reactions
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December 2012 |
Transition-Metal-Mediated Dearomatization Reactions
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July 2000 |
Group 6 Dihapto-Coordinate Dearomatization Agents for Organic Synthesis
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October 2017 |
Selective Arene Hydrogenation for Direct Access to Saturated Carbo- and Heterocycles
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April 2019 |
Privileged chiral N-heterocyclic carbene ligands for asymmetric transition-metal catalysis
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January 2017 |
N-Heterocyclic Carbenes in Asymmetric Hydrogenation
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August 2016 |
Highly Selective Hydrogenation of Aromatic Ketones and Phenols Enabled by Cyclic (Amino)(alkyl)carbene Rhodium Complexes
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July 2015 |
Hydrogenation of fluoroarenes: Direct access to all- cis -(multi)fluorinated cycloalkanes
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August 2017 |
Complete Hydrodehalogenation of Polyfluorinated and Other Polyhalogenated Benzenes under Mild Catalytic Conditions
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May 2013 |
Hydrodefluorination and Hydrogenation of Fluorobenzene under Mild Aqueous Conditions
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August 2012 |
Hydrodefluorination of fluorobenzene catalyzed by rhodium metal prepared from [Rh(COD)2]+BF4− and supported on SiO2 and Pd-SiO2
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January 2004 |
Hydrodefluorination of Fluorobenzene and 1,2-Difluorobenzene under Mild Conditions over Rhodium Pyridylphosphine and Bipyridyl Complexes Tethered on a Silica-Supported Palladium Catalyst
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May 1999 |
The formation of all-cis-(multi)fluorinated piperidines by a dearomatization–hydrogenation process
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January 2019 |
Silylarene Hydrogenation: A Strategic Approach that Enables Direct Access to Versatile Silylated Saturated Carbo‐ and Heterocycles
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July 2018 |
Hydrogenation of Borylated Arenes
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May 2019 |
Rh(CAAC)-Catalyzed Arene Hydrogenation: Evidence for Nanocatalysis and Sterically Controlled Site-Selective Hydrogenation
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July 2018 |
Carbene Ligands in Surface Chemistry: From Stabilization of Discrete Elemental Allotropes to Modification of Nanoscale and Bulk Substrates
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September 2015 |
Nanoclusters in Ionic Liquids: Evidence for N -Heterocyclic Carbene Formation from Imidazolium-Based Ionic Liquids Detected by 2 H NMR
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April 2005 |
N-Heterocyclic carbene coated metal nanoparticles
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January 2009 |
Ballbot-type motion of N-heterocyclic carbenes on gold surfaces
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October 2016 |
Elucidating the Binding Modes of N-Heterocyclic Carbenes on a Gold Surface
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September 2018 |
Ruthenium Nanoparticles Stabilized by N-Heterocyclic Carbenes: Ligand Location and Influence on Reactivity
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October 2011 |
Organometallic Ruthenium Nanoparticles: Synthesis, Surface Chemistry, and Insights into Ligand Coordination
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January 2018 |
N-Heterocyclic-Carbene-Treated Gold Surfaces in Pentacene Organic Field-Effect Transistors: Improved Stability and Contact at the Interface
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March 2018 |
Versatile Micropatterns of N-Heterocyclic Carbenes on Gold Surfaces: Increased Thermal and Pattern Stability with Enhanced Conductivity
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July 2018 |
Stabilization of High Oxidation State Upconversion Nanoparticles by N-Heterocyclic Carbenes
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March 2017 |
N-Heterocyclic carbene-stabilized gold nanoparticles and their assembly into 3D superlattices
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January 2009 |
Ultra stable self-assembled monolayers of N-heterocyclic carbenes on gold
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March 2014 |
Ultrastable Gold Nanoparticles Modified by Bidentate N -Heterocyclic Carbene Ligands
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January 2018 |
Modular Bidentate Hybrid NHC-Thioether Ligands for the Stabilization of Palladium Nanoparticles in Various Solvents
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April 2016 |
Negatively Charged N-Heterocyclic Carbene-Stabilized Pd and Au Nanoparticles and Efficient Catalysis in Water
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August 2015 |
Long-chain NHC-stabilized RuNPs as versatile catalysts for one-pot oxidation/hydrogenation reactions
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January 2016 |
Molecular Adsorbates Switch on Heterogeneous Catalysis: Induction of Reactivity by N-Heterocyclic Carbenes
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June 2017 |
Asymmetric Nanocatalysis: N-Heterocyclic Carbenes as Chiral Modifiers of Fe3O4/Pd nanoparticles
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September 2010 |
A Molecular Surface Functionalization Approach to Tuning Nanoparticle Electrocatalysts for Carbon Dioxide Reduction
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June 2016 |
Chelating N-Heterocyclic Carbene Ligands Enable Tuning of Electrocatalytic CO 2 Reduction to Formate and Carbon Monoxide: Surface Organometallic Chemistry
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March 2018 |
A New Mode of Operation of Pd-NHC Systems Studied in a Catalytic Mizoroki–Heck Reaction
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April 2017 |
Fast and Slow Release of Catalytically Active Species in Metal/NHC Systems Induced by Aliphatic Amines
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April 2018 |
Stable crystalline annulated diaminocarbenes: coordination with rhodium(i), iridium(i) and catalytic hydroformylation studies
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January 2009 |
Anionic N-Heterocyclic Carbenes with N,N′-Bis(fluoroaryl) and N,N′-Bis(perfluoroaryl) Substituents
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October 2010 |
A cationic rhodium(I) N-heterocyclic carbene complex isolated as an aqua adduct
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August 2011 |
Synthesis and Structure of Silver and Rhodium 1,2,3-Triazol-5-ylidene Mesoionic Carbene Complexes
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December 2011 |
N-Heterocyclic Carbene Complexes of Rhodium and Iridium: Steric Effects on Molecular Conformation
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October 2009 |
Transfer Hydrogenation of Imines and Alkenes and Direct Reductive Amination of Aldehydes Catalyzed by Triazole-Derived Iridium(I) Carbene Complexes
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February 2007 |
Cationic Iridium Complexes Bearing Imidazol-2-ylidene Ligands as Transfer Hydrogenation Catalysts
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August 2001 |
A Cationic Iridium Complex Bearing an Imidazol-2-ylidene Ligand as Alkene Hydrogenation Catalyst
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February 2001 |
In-Depth Study on Chloride Abstractions from (NHC)Ir(COD)Cl Complexes
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February 2017 |
Iridium(I) Hydroxides: Powerful Synthons for Bond Activation
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April 2013 |
Asymmetric Hydrogenation of Enamides with Rh-BisP* and Rh-MiniPHOS Catalysts. Scope, Limitations, and Mechanism
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June 2001 |
Challenging the Major/Minor Concept in Rh-Catalyzed Asymmetric Hydrogenation
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March 2015 |
Investigating the Kinetics of Homogeneous Hydrogenation Reactions Using PHIP NMR Spectroscopy
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June 1999 |
In situ Transfer of Parahydrogen-Induced Nuclear Spin Polarization—Structural Characterization of Hydrogenation Intermediates
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October 2000 |
Rhodium catalyzed hydrogenation reactions in aqueous micellar systems as green solvents
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January 2011 |
Solvent effects in catalysis: rational improvements of catalysts via manipulation of solvent interactions
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January 2016 |
Investigations into the Formation and Stability of Cationic Rhodium Diphosphane η 6 -Arene Complexes
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August 2012 |
The Inhibiting Influence of Aromatic Solvents on the Activity of Asymmetric Hydrogenations We would like to thank the Deutsche Forschungsgemeinschaft as well as the Fonds der Chemischen Industrie for their generous support of this work. We are also indebted to Prof. Dr. U. Rosenthal and Dr. D. Selent for helpful discussions. Franz Hein prepared bis(η6-arene)-chromium(I)-complex cations already in 1919; their true structure as hexahapto complexes was only realized more than 35 years later.
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March 2002 |
Highly Efficient Asymmetric Synthesis of β-Amino Acid Derivatives via Rhodium-Catalyzed Hydrogenation of β-(Acylamino)acrylates
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September 1999 |
Pressure Dependent Highly Enantioselective Hydrogenation of Unsaturated β-Amino Acid Precursors
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September 2001 |
Rh−DuPHOS-Catalyzed Enantioselective Hydrogenation of Enol Esters. Application to the Synthesis of Highly Enantioenriched α-Hydroxy Esters and 1,2-Diols
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May 1998 |
Homogeneous catalysis of arene hydrogenation by cationic rhodium arene complexes
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July 1983 |
Novel coordination chemistry and catalytic properties of cationic 1,2-bis(diphenylphosphino)ethanerhodium(I) complexes
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November 1977 |
Cationic Rhodium-BINAP Complexes: Full Characterization of Solvate- and Arene-Bridged Dimeric Species
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October 2011 |
A Two-Coordinate Nickel Imido Complex That Effects C−H Amination
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February 2011 |
Mechanistic Investigations of the Hydrogenolysis of Diaryl Ethers Catalyzed by Nickel Complexes of N -Heterocyclic Carbene Ligands
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November 2017 |
One-Pot, Single-Step, and Gram-Scale Synthesis of Mononuclear [(η 6 -arene)Ni(N-heterocyclic carbene)] Complexes: Useful Precursors of the Ni 0 –NHC Unit
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February 2014 |
Taming a monomeric [Cu(η 6 -C 6 H 6 )] + complex with silylene
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January 2018 |
Labile Rhodium(I)–N-Heterocyclic Carbene Complexes
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April 2013 |
Hydride-Rhodium(III)-N-Heterocyclic Carbene Catalysts for Vinyl-Selective H/D Exchange: A Structure-Activity Study
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June 2014 |
Hydrogenation and hydrogenolysis of thiophenic molecules catalysed by soluble metal complexes
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January 1996 |
Ruthenium, rhodium, and iridium complexes of .pi.-bound thiophene and benzo[b]thiophenes: models for thiophene binding to HDS catalysts
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March 1988 |
Sulfur versus 2,3-.eta.2 coordination of benzo[b]thiophene (BT) in Cp'(CO)2Re(BT)
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May 1991 |
The benzo[b]thiophene (BT) rhenium complexes Cp'(CO)2Re(BT): models for BT adsorption on hydrodesulfurization catalysts
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October 1992 |
Equilibrium studies of the displacement of .eta.1-(S)-thiophenes (Th) from Cp(CO)(PPh3)Ru(.eta.1-(S)-Th)+
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February 1992 |
Synthesis and protonation of the bridging benzo[b]thiophene (BT) complexes [Cp'(CO)2Re](.eta.2:.eta.1(S)-.mu.2-BT)[Re(CO)2Cp'']
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January 1994 |
Coordination and Oxidative Addition at a Low-Coordinate Rhodium(I)β-Diiminate Centre
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March 2002 |
Understanding active species in catalytic transformations: From molecular catalysis to nanoparticles, leaching, “Cocktails” of catalysts and dynamic systems
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September 2017 |
Full-Range Interconversion of Nanocrystals and Bulk Metal with a Highly Selective Molecular Catalyst
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May 2018 |
On the Nature of the Active Species in Palladium Catalyzed Mizoroki–Heck and Suzuki–Miyaura Couplings – Homogeneous or Heterogeneous Catalysis, A Critical Review
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April 2006 |
Monomolecular, nanosized and heterogenized palladium catalysts for the Heck reaction
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May 2007 |
Visual Observation of Redistribution and Dissolution of Palladium during the Suzuki–Miyaura Reaction
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April 2008 |
Studies on the catalytic ability of palladium wire, foil and sponge in the Suzuki–Miyaura cross-coupling
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September 2011 |